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WO1999056922A1 - Procede de moulage par injection de liquide pour la production d'articles en caoutchouc de silicone renforce - Google Patents

Procede de moulage par injection de liquide pour la production d'articles en caoutchouc de silicone renforce Download PDF

Info

Publication number
WO1999056922A1
WO1999056922A1 PCT/US1999/010078 US9910078W WO9956922A1 WO 1999056922 A1 WO1999056922 A1 WO 1999056922A1 US 9910078 W US9910078 W US 9910078W WO 9956922 A1 WO9956922 A1 WO 9956922A1
Authority
WO
WIPO (PCT)
Prior art keywords
mold
mixture
mold cavity
fabric
silicone rubber
Prior art date
Application number
PCT/US1999/010078
Other languages
English (en)
Inventor
Timothy D. Pryce
Sean M. Walton
Donald G. Morgan
A. Rooney Simkus
Original Assignee
Chase-Walton Elastomers, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chase-Walton Elastomers, Inc. filed Critical Chase-Walton Elastomers, Inc.
Publication of WO1999056922A1 publication Critical patent/WO1999056922A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2083/00—Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2083/00—Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material
    • B29K2083/005—LSR, i.e. liquid silicone rubbers, or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00—Tubular articles
    • B29L2023/005—Hoses, i.e. flexible

Definitions

  • Silicone rubber articles such as hoses, sheets, and seals, are often reinforced with a fabric mesh in a multi- step process requiring manual steps and experienced personnel.
  • a fabric mesh is wrapped around a cylindrical mandrel and uncured silicone rubber is wrapped around the mesh. The rubber is then cured by heating, and during the curing process the mesh becomes embedded within the cured rubber wall.
  • Such a manual process is time consuming, requires experienced personnel for effective fabrication, and is expensive because of the human labor required.
  • Liquid injection molding (LIM) is a known process for fabricating articles from silicone and other rubber materials. With this process, two liquid components of a silicone rubber are mixed and injected into a heated mold. The mixture cures in the mold to produce a finished article.
  • the present invention relates to a process for producing an article of reinforced silicone rubber and an article produced by the process of the invention.
  • a mold having a mold cavity therein of the appropriate configuration to form the desired finished article, such as a hose or a sheet.
  • a reinforcing fabric is placed within the mold cavity. At least a portion of the edge of the fabric is fastened to the perimeter of the mold cavity adjacent the entry point for the liquid silicone rubber mixture .
  • First and second components of a silicone rubber are provided in first and second reservoirs respectively. Each component is liquid at room temperature.
  • the first component includes a catalyst therein to cause the components to cure upon mixing.
  • the second component includes a cure inhibiting agent therein selected to slow the cure rate of the silicone rubber until a mixture of the first and second components have filled the mold cavity.
  • the first and second components are then mixed.
  • a preselected amount of the mixture is fed into the mold cavity to fill the mold cavity and surround and penetrate the reinforcing fabric.
  • the silicone rubber is allowed to cure, and the article is removed from the mold.
  • the reinforcing fabric is an open weave fabric having a sufficient stiffness to retain its shape within the mold cavity.
  • the silicone rubber mixture flows along both sides of the fabric and through the spaces between the warp and weft fibers of the fabric, thereby embedding the fabric in the silicone rubber upon curing.
  • Fig. 2 is a side view of a mold for producing a reinforced silicone rubber hose according to the present invention
  • Fig. 3 is an end view of the mold of Fig. 2 ;
  • Fig. 4 is a cross-sectional view along line A-A of Fig. 3;
  • Fig. 5 is a side view of a mold for producing a reinforced silicone rubber sheet according to the present invention.
  • Fig. 6 is a cross-sectional view along line B-B of Fig. 5;
  • Fig. 7 is a cross-sectional view along line C-C of Fig . 6 ; and Fig. 8 is an enlarged view of area D indicated in dotted lines in Fig. 7.
  • the silicone rubber for producing a reinforced article according to the present invention is supplied in two parts 10, 12, components A and B.
  • Each component is a liquid at room temperature.
  • One component contains a catalyst and the other component contains an inhibiting agent.
  • the catalyst causes the components to react and cure to form a solid silicone rubber.
  • the inhibiting agent acts to slow the reaction sufficiently to allow the mixture to reach and fill the mold before curing to a solid.
  • Liquid silicone rubber components are commercially available from a number of silicone suppliers, such as General Electric, Dow Corning, or Wacker.
  • the particular silicone is selected based on the desired hardness of the article upon curing, the desired cure rate, and the viscosity of the mixture of the components prior to curing.
  • the viscosity should be chosen to provide good flow through the mold runner system and mold cavity to ensure that the mold cavity is properly filled. A viscosity of 375,000 centipoise has been found to be satisfactory.
  • Additives 16 such as a coloring agent may be mixed in if desired as well, as is known in the art.
  • a static mixer is suitable, although other mixers may be used if desired.
  • the mixture is then fed under pressure to an injection barrel or reservoir 18. From the barrel, the mixture is injected into the runner system of a mold 20 and into the mold cavity 22.
  • the mold cavity has a configuration of the article to be manufactured.
  • Figs. 2 through 4 illustrate a mold 30 for producing a reinforced hose.
  • the mold illustrated forms a hose with three ribs, although no or any other number of ribs may be provided if desired.
  • the mold is formed in two halves 32, 34 separated by a parting line 36 and has a cylindrical cavity 38 formed therein.
  • the cylindrical cavity has two end sections 40, 42 with slightly narrowed diameters.
  • a cylindrical mandrel 44 is also provided in the cavity. The mandrel extends into the narrowed end sections of the cavity and is clamped therein by closure of the mold to retain the mandrel centered in the cylindrical cavity.
  • a guide pin (not shown) may also be provided to center and fix the mandrel in the mold cavity.
  • the reinforcing fabric 46 Prior to feeding the mixture into the mold, multiple plies of reinforcing fabric 46 are cut, on a bias, to the appropriate size and formed around the mandrel. At least one edge 48 of the fabric is clamped between the cavity wall and the mandrel 44. The other edge 50 of the fabric may remain free from clamping. The fabric is cut on the bias to achieve the desired pressure rating of the finished hose and to ease removal of the finished hose from the mandrel .
  • the reinforcing fabric 46 may be any desired material, such as cotton, fiberglass, polyester, or nylon, such as NOMEX or KEVLAR, as is known in the art.
  • the fabric may be woven, knit, or braided with open spaces between the fibers to allow the liquid silicone rubber mixture to flow through the spaces.
  • the mixture also flows along both sides of the length of the fabric.
  • the fabric also has a sufficient stiffness to provide a degree of rigidity so that it retains its shape and does not collapse against the mandrel .
  • a suitable stiffness can be achieved by a sufficient amount of sizing on the fabric.
  • the mixture is injected into the mold through an entry or injection point 52. Air in the mold is vented out through suitable vent ports.
  • the mold parting line 36 may serve as a vent port.
  • the injection point is located near the edge 48 of the fabric 46 that is clamped to the mold. In this way, the mixture flows along the length of the cavity 38 from the clamped edge 48 toward the free edge 50 of the fabric.
  • the flow of the silicone mixture aids in holding the fabric in place spaced from the cavity walls, so that the fabric is embedded generally in the middle of the finished article.
  • the fabric is chosen to match the viscosity of the mixture. The more viscous the mixture is, the more open the weave or the spaces between the fibers should be.
  • each injection point should be located at an edge of the fabric that is clamped to the mold.
  • the mold is opened and the cured article removed from the mold cavity.
  • the article is taken off the mandrel .
  • Suitable mechanical strippers or air hoses may be used if necessary, as known in the art.
  • the mold adjacent to the cavity is maintained at a temperature of at least approximately 300°F in any manner known in the art .
  • the mandrel and runner system of the mold are not purposely heated, although the mandrel in particular heats up during the molding process.
  • the mandrel is preferably cooled after each cycle by, for example, immersion in a cool fluid such as water after removing the mandrel from the cured hose .
  • the mandrel can be cooled in any other manner known in the art, such as by flow of a cooling fluid through channels therein, if desired.
  • Figs. 5 through 8 illustrate a mold 60 for fabricating a reinforced silicone rubber sheet.
  • the mold is formed from two halves 62, 64 separated by a parting line 66 and has a square or rectangular cavity 68 of small thickness formed therein. (See Figs. 6 and 8) In the particular mold illustrated, two square mold cavities are illustrated, each for fabricating a 6-inch by 6-inch sheet having a thickness of 0.060 inch. It will be appreciated, however, that any desired number of cavities may be provided.
  • each cavity 68 includes a lip 70 of reduced thickness surrounding the perimeter 72 of the cavity.
  • Pins 74 extend upwardly from one half 62 of the mold along the lip 70 and fit into corresponding apertures in the other half of the mold.
  • the fabric is placed in the mold with one, several, or all edges of the fabric overlapping the lip and the pins protruding through the fabric. When the mold is closed, the pins fit into the corresponding apertures, thereby fastening the fabric to the mold. At least the edge of the fabric adjacent the injection point 76 is fastened to the mold.
  • a runner 78 brings the liquid silicone rubber mixture to a sprue 80 and chamber 82 located between the two cavities.
  • a well 84 may also be provided below the sprue and chamber for receiving the mixture.
  • Narrow ducts 86 lead from the chamber 82 into the two mold cavities. Air is vented through the parting line 66 or other vent ports.
  • the mold may include heating rods or channels 88 for a heated fluid to heat the mold to a suitable temperature, such as at least approximately 300°F.
  • One or more thermocouples may also be placed in openings 90 in the mold to monitor the temperature, as is known in the art.
  • Guide pins 92 may be provided to align the two mold halves 62, 64.
  • the mold halves may also include opposed lips 94 for receiving a clamping device (not shown) to retain the molds tightly closed during the injection and curing steps .
  • the article can be made with little or no flashing by controlling the amount of the liquid silicone rubber mixture that is injected into the mold cavity.
  • the injection barrel 18 includes a volume sensor 96 such that the amount of the mixture in the barrel can be determined and controlled. For example, when the desired volume of mixture has entered the injection barrel, a valve 98 may be closed to prevent any further mixture from flowing in. The valve can be operated automatically or manually, as desired. Other ways of measuring the amount of mixture, such as a flow meter in the line to the barrel, may be used, as will be appreciated by those in the art. In this manner, the amount of mixture allowed into the mold is precisely the amount needed to fill the mold cavity to form the article with substantially no flash to be removed from the article after removal from the mold.
  • the present process has been used satisfactorily to fabricate reinforced silicone rubber hoses having a diameter of from 2.5 inches to 4 inches and a length of 9 inches. Such articles have a cycle time of less than 15 minutes and typically of 5 to 10 minutes. Reinforced silicone sheets having a width of 6 inches, a length of 6 inches, and a thickness of 0.060 inch have also been satisfactorily made. It will be appreciated that articles having different dimensions and configurations from those specifically illustrated and described herein may be fabricated by the presently claimed process.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

L'invention se rapporte à un procédé de production d'un article en caoutchouc de silicone renforcé à l'aide d'un mélange de caoutchouc de silicone liquide à deux composants (A, B). Selon ledit procédé, on place un tissu ajouré de renforcement (46) dans une cavité de moulage (22) présentant la forme de l'article à fabriquer. On mélange les deux composants (A, B) du mélange de caoutchouc de silicone liquide. On introduit dans la cavité de moulage (22) une quantité préétablie dudit mélange de façon à remplir ladite cavité (22), à entourer le tissu de renforcement (46) et à pénétrer dans les espaces existant entre les fibres du tissu. Puis on laisse durcir le caoutchouc de silicone avant de retirer l'article du moule (30).
PCT/US1999/010078 1998-05-07 1999-05-07 Procede de moulage par injection de liquide pour la production d'articles en caoutchouc de silicone renforce WO1999056922A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US8460898P 1998-05-07 1998-05-07
US60/084,608 1998-05-07

Publications (1)

Publication Number Publication Date
WO1999056922A1 true WO1999056922A1 (fr) 1999-11-11

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/010078 WO1999056922A1 (fr) 1998-05-07 1999-05-07 Procede de moulage par injection de liquide pour la production d'articles en caoutchouc de silicone renforce

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EP1658957A1 (fr) * 2004-11-23 2006-05-24 Carl Freudenberg KG Procédé de moulage et mélange in situ de caoutchouc liquide
FR2900593A1 (fr) * 2006-05-04 2007-11-09 Hutchinson Sa Procede de fabrication d'un composite polymere(s)/renfort textile ou metallique, composite obtenu par ce procede et soufflet de decouplage qui en est constitue
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US9427189B2 (en) 2013-03-04 2016-08-30 Hello Inc. Monitoring system and device with sensors that are responsive to skin pigmentation
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US9445651B2 (en) 2013-03-04 2016-09-20 Hello Inc. Wearable device with overlapping ends coupled by magnets
US9530089B2 (en) 2013-03-04 2016-12-27 Hello Inc. Wearable device with overlapping ends coupled by magnets of a selected width, length and depth
US9526422B2 (en) 2013-03-04 2016-12-27 Hello Inc. System for monitoring individuals with a monitoring device, telemetry system, activity manager and a feedback system
US9532716B2 (en) 2013-03-04 2017-01-03 Hello Inc. Systems using lifestyle database analysis to provide feedback
US9553486B2 (en) 2013-03-04 2017-01-24 Hello Inc. Monitoring system and device with sensors that is remotely powered
US9582748B2 (en) 2013-03-04 2017-02-28 Hello Inc. Base charging station for monitoring device
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US9848776B2 (en) 2013-03-04 2017-12-26 Hello Inc. Methods using activity manager for monitoring user activity
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Cited By (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1658957A1 (fr) * 2004-11-23 2006-05-24 Carl Freudenberg KG Procédé de moulage et mélange in situ de caoutchouc liquide
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EP1852245A3 (fr) * 2006-05-04 2010-02-17 Hutchinson Procédé de fabrication d'un composite polymère(s)/renfort textile ou métallique, composite obtenu par ce procédé et soufflet de découplage qui en est constitué
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