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WO1999041349A1 - Composition de lavage et de revetement pour les surfaces en verre, ceramique et metal. - Google Patents

Composition de lavage et de revetement pour les surfaces en verre, ceramique et metal. Download PDF

Info

Publication number
WO1999041349A1
WO1999041349A1 PCT/GB1999/000305 GB9900305W WO9941349A1 WO 1999041349 A1 WO1999041349 A1 WO 1999041349A1 GB 9900305 W GB9900305 W GB 9900305W WO 9941349 A1 WO9941349 A1 WO 9941349A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition according
silicone
polymers
emulsion
emulsifying agent
Prior art date
Application number
PCT/GB1999/000305
Other languages
English (en)
Inventor
John Somerville Armstrong
Original Assignee
Agency Design Services Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9803244.4A external-priority patent/GB9803244D0/en
Priority claimed from GBGB9824101.1A external-priority patent/GB9824101D0/en
Application filed by Agency Design Services Limited filed Critical Agency Design Services Limited
Priority to AU25272/99A priority Critical patent/AU2527299A/en
Priority to GB9923817A priority patent/GB2339205A/en
Publication of WO1999041349A1 publication Critical patent/WO1999041349A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3738—Alkoxylated silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/82—Compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/16—Metals

Definitions

  • This invention concerns a composition specifically designed for cleaning glass, ceramics and metal, e.g. stainless steel, surfaces in general, and for the removal of lipstick soiling in particular.
  • a glass washing composition which is effective in removing lipstick residues and comprises a non-ionic surfactant or mixture thereof in the range 2.5-50% (w/w) and selected from the group comprising alkoxylates, ethylene oxide/propylene oxide block co-polymers, and short-chain alkyl esters of mono- or di- carboxylic acids.
  • Synperonic LF/RA series of non-ionic surfactants comprising alkoxylated alcohols and supplied by ICI Surfactants of Cleveland were disclosed as being effective in aqueous solution, with a preferred isopropyl alcohol co-solvent and citric acid as water softening agent.
  • One object of the present invention is to provide an improved composition which will, more effectively and reliably than hitherto clean all the stains associated with food and drink, as well as lipstick residue, not only from glassware but from ceramics and stainless steel surfaces too.
  • Another object of the invention is to provide a composition which when used for cleaning beer glasses will enhance the subsequent beer head retention - in contrast to conventional detergent mixtures which generally result in poorer beer head retention after the cleaning process.
  • the present invention provides a cleaning and coating composition for glassware, ceramics and metal comprising an emulsifying agent or a mixture thereof selected from the group comprising poly glycol ethers, and a silicone surfactant and/or emulsion.
  • the emulsifying agent and the silicone surfactant and/or emulsion are dissolved in water in amounts sufficient to achieve complete removal of any lipstick residue from glassware, ceramics or metal.
  • dishwashing/rinsing formulations in accordance with the invention additionally include a non-ionic surfactant, preferably selected from the group comprising alkoxylates, ethylene oxide/propylene oxide block co-polymers, and short-chain alkyl esters of mono- or di- carboxylic acids.
  • a non-ionic surfactant preferably selected from the group comprising alkoxylates, ethylene oxide/propylene oxide block co-polymers, and short-chain alkyl esters of mono- or di- carboxylic acids.
  • the poly glycol ether emulsifying agent which is used in the composition of the invention is capable of producing an emulsion with the hydrophobic waxes in the lipstick stains thus rendering them amenable to the solvent action of the non-ionic surfactants in these formulations. With these constituents at the optimum concentration and ratio, the cleaning composition of the invention reliably removes lipstick stains no matter how persistent.
  • Typical examples of this group of emulsifying agents are the alkylarylpolyglycol ether Emulsogen ELN and the fatty alcohol polyglycol ether EPN.207 both from CLARIANT Specialities Limited (formerly Hoechst) of Hoechst House, 50 Salisbury Road, Hounslow, Middlesex, TW46JH.
  • CLARIANT Specialities Limited formerly Hoechst
  • Other examples are the EMULSOGEN range 1557, L, LP, M, MEB, MHK, MS, NO60, N090, OG, P, also all from Clariant Specialities Limited.
  • Preferred dishwashing/rinsing formulations in accordance with the invention include a blend of non-ionic surfactants carefully chosen to provide optimum conditions in foam control and hard surface wetting properties. These surface active ingredients, when combined with the emulsifying agent impart good emulsification and grease removal to the product.
  • non-ionic surfactants used in preferred formulations are speciality alkoxylates whose structure has been carefully designed to give a balance in foam control, cloud point, wetting and low foam detergency in a high temperature environment. - 5 - Surfactants meeting these specifications can be found in the ICI Synperonic LF/RA series and equivalent products by other manufacturers. Details of the ICI Synperonic LF/RA series and various comparable non-ionic surfactant products of other manufacturers are provided in the applicant's earlier application WO98/04660.
  • fatty alcohol alkoxylates sold under the names Genapol 2822 and Genapol 2908 by Clariant Specialities Limited (see above for their address)
  • Clariant Specialities Limited see above for their address
  • mixtures of various members of the Plurafac LF range sold by BASF such as binary mixtures of 401 and 403.
  • An innovative aspect of this invention is that by careful adjustment of the emulsifying agent: surfactant ratio the formulation can find application both as a wash and rinse composition.
  • a further constituent which aids the wetting of the surface by the emulsifying agent, allows for effective cleaning at a lower temperature, e.g. 55°C, and additionally provides a surface coating which enhances beer head retention in the case of beer glasses, is a silicone glycol co-polymer.
  • a silicone glycol co-polymer Commercially available - 6 - examples of such silicone glycol co-polymers, which have been found to be highly effective are Dow Corning DC 193 and Basildon Chemical's BC 403.
  • the Dow Corning 193 can be obtained from Dow Corning Limited, Avco House, Castle Street, Reading, Berkshire, RG1 7DZ.
  • Basildon 403 can be obtained from Basildon Chemical Company Limited, Kimber Road, Abingdon, Oxon, 0X14 1RZ.
  • An alternative silicone emulsion constituent which has a similar effect is a water soluble organosilicone co-polymer hitherto sold under the name SILWET (Registered Trade Mark) Co-polymer 2020 by OSi Specialities, a Witco Company, but now also sold under the name SILSOFT (Registered Trade Mark) by the same Company.
  • SILWET Registered Trade Mark
  • SILSOFT Registered Trade Mark
  • the preferred formulations also contains a builder component which may be any complexing agent capable of bonding to the minerals present in wash water. Typically this can be provided by the presence of citric acid, EDTA (ethylenediaminetetraacetate) or NTA (nitrilotriacetate) separately or in combination in the formulation.
  • a builder component which may be any complexing agent capable of bonding to the minerals present in wash water. Typically this can be provided by the presence of citric acid, EDTA (ethylenediaminetetraacetate) or NTA (nitrilotriacetate) separately or in combination in the formulation.
  • a viscosity regulator in these formulations can be any aliphatic alcohol of which iso-propyl alcohol (IPA) is a good example.
  • IPA iso-propyl alcohol
  • an anti-foam to inhibit foam formation.
  • This may be a silicone oil type product - 7 - and effective examples are the products FD supplied by Basildon Chemical Co. Limited or Dow Corning Anti-foam compound or equivalents by other manufacturers.
  • a silicone oil may adversely affect beer head retention
  • a preferable alternative anti-foam product may include a mineral oil instead.
  • An example of such a product is that sold under the name BEVALOID 691 by Rhodia of Woodley, Stockport, Cheshire.
  • Formulations in accordance with the invention may also include other conventional detergent components such as perfumes, dyes, germicides, preservatives, etc.
  • the silicone surfactant and/or emulsion is preferably selected from the group comprising silicone glycol co-polymers, organosilicone co- polymers more generally, silicone-silicone co-polymers, polyorganosiloxanes and polyorganosilanols, or any mixture thereof .
  • silicone surfactant and emulsions are: - 8 - Dow Corning DC 193 and Basildon Chemicals BC 403, both of which are silicone glycol co-polymers and have been referred to previously for use in preferred dishwashing/rinsing formulations.
  • Dow Corning 3225C which is a volatile silicone-silicone co- polymer, more specifically a dispersion of a high molecular weight silicone surfactant in a volatile silicone fluid.
  • Dow Corning 2-8707 which is an emulsion of polydimethylsilanol fluid.
  • Dow Corning 8075 which is a polydiorganosiloxane.
  • Dow Corning 7224 which is an emulsion of amino functional polydimethylsiloxane .
  • SILWET Registered Trade Mark 2020 or SILSOFT (Registered Trade Mark) 2020 which is a water soluble organosilicone co-polymer and is available from OSi Specialities (a Witco Company) .
  • Dow Corning preparations - 3225C, 2-8707, 8075 and 7224 are noted as useful for inclusion in car polishes and shampoos and plastics and vinyl surface treatments compositions.
  • Dow Corning 3225C is known to have been used in cosmetic preparations such as sun tan lotions and SILWET/SILSOFT are promoted for use in cosmetics, hair shampoos, sunscreens, body lotions and anti-perspirants. None of them are known to have been used previously in glass (windscreen) cleaning - 9 - compositions .
  • Dow Corning 3225C has the property of depression of the freezing point of water and therefore usefully serves an additional antifreeze function in windscreen washing preparations which incorporate same.
  • windscreen washing compositions in accordance with the invention can be dispersed in an excess of water.
  • windscreen washing compositions in accordance with the invention should be dispersed in an excess of an alcohol, such as industrial methylated spirits, methanol, ethanol, iso-propyl alcohol or n-propanol .
  • the detergent was modified by the addition of citric acid and EDTA to give improved results in hard water areas. Additional anti-foam agent was also added. - 11 - Lipstick was thickly applied to test glasses before washing. The removal of lipstick and the overall appearance of the glasses assessed.
  • the basic detergent was used with further quantities of citric acid being added but without the use of EDTA.
  • the rinse aid volume was increased to approximately 5 ml per cycle and the temperature of the rinse cycle reduced to 68 °C to prevent surfactant breakdown.
  • the wash water temperature was increased to 75°C.
  • the quantity of rinse aid was reduced to 2.5 ml per wash cycle.
  • the wash temperature was set at 65 °C and the rinse temperature at 60°C.
  • the solvent level of the rinse aid supplied was increased by the addition of 10% isopropyl alcohol. Twenty further washes were run with the wash water at 65 °C and the rinse water at 60 °C. - 12 - Results
  • the rinse aid formulations tested gave a clear finish to glasses with few water marks being visible.
  • formulation 2A produced complete lipstick removal from glasses even at low dosage levels. However, it was also found that complete lipstick removal was obtained in a control wash where no detergent was used, rinse aid only being dosed through the automatic feed lines during the rinse cycle.
  • the - 17 - levels of the various constituents could be reduced substantially without significantly changing the excellent results obtained.
  • the amount of Emulsogen EPN 207 in particular, could be reduced to 10% or less.
  • the amounts of Dow Corning 193 and of citric acid could be reduced to 2.5% or less and 5% or less respectively.
  • Rinse Aid formulation (specifically for dishwashers)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention porte sur un détergent pour le lavage de la vaisselle et un auxiliaire de rinçage qui comprennent chacun un agent émulsifiant de polyglycol éther et un tensioactif ou émulsion de silicone dispersés dans un excédent d'eau. Le silicone peut comprendre un ou plusieurs des copolymères organosiliciés inclus dans le groupe précité tels que les copolymères glycol siliciés, les copolymères silicone-silicone, les polyorganosiloxanes et les polyorganosilanols. L'agent émulsifiant est de préférence présent dans une quantité comprise entre 0,5 et 25 % en poids. Le composé de silicone est de préférence présent dans une quantité comprise entre 0,5 et 10 % en poids. Une composition de lavage pour pare-brise, qui forme également un revêtement facilitant le ruissellement en surface de l'eau de pluie, a la même composition basique que celle de l'agent émulsifiant, mais est présente dans une quantité relativement plus faible.
PCT/GB1999/000305 1998-02-17 1999-02-16 Composition de lavage et de revetement pour les surfaces en verre, ceramique et metal. WO1999041349A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU25272/99A AU2527299A (en) 1998-02-17 1999-02-16 A cleaning and coating composition for glass, ceramic and metal surfaces
GB9923817A GB2339205A (en) 1998-02-17 1999-02-16 A cleaning and coating composition for glass, ceramic and metal surfaces

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB9803244.4 1998-02-17
GBGB9803244.4A GB9803244D0 (en) 1998-02-17 1998-02-17 A detergent mixture for the effective removal of lipstick soiling from and ceramic surfaces
GB9812187.4 1998-06-08
GBGB9812187.4A GB9812187D0 (en) 1998-02-17 1998-06-08 A detergent mixture for the effective removal of lipstick soiling from glass orceramic surfaces
GB9824101.1 1998-11-04
GBGB9824101.1A GB9824101D0 (en) 1998-02-17 1998-11-04 A cleaning and coating composition for glass,ceramic and metal surfaces

Publications (1)

Publication Number Publication Date
WO1999041349A1 true WO1999041349A1 (fr) 1999-08-19

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PCT/GB1999/000305 WO1999041349A1 (fr) 1998-02-17 1999-02-16 Composition de lavage et de revetement pour les surfaces en verre, ceramique et metal.

Country Status (3)

Country Link
AU (1) AU2527299A (fr)
GB (1) GB2339205A (fr)
WO (1) WO1999041349A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1127939A1 (fr) * 2000-02-22 2001-08-29 Unilever N.V. Composition de nettoyage de la vaisselle
WO2002034869A1 (fr) * 2000-10-25 2002-05-02 Unilever Plc Compositions pour lave-vaisselle
EP1245666A1 (fr) * 2001-03-26 2002-10-02 The Procter & Gamble Company Composition pour nettoyer les surfaces dures
WO2005100523A1 (fr) * 2004-04-16 2005-10-27 Henkel Kommanditgesellschaft Auf Aktien Nettoyant hydrophylisant pour surfaces dures
WO2006083813A2 (fr) * 2005-01-31 2006-08-10 The Procter & Gamble Company Composition d'agent de rinçage
DE102005058328A1 (de) * 2005-12-07 2007-06-21 Fritz Heuer Oberflächenveredelungsverfahren, insbesondere für Edelstahloberflächen
US12157868B2 (en) 2019-06-21 2024-12-03 Ecolab Usa Inc. Solidified nonionic surfactant composition comprising a solid urea binder

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2003173A (en) * 1977-08-29 1979-03-07 Sandoz Ltd Detergent composition
GB2068405A (en) * 1980-01-24 1981-08-12 Sandoz Ltd Biodegradable detergent composition
DE3327926A1 (de) * 1983-08-03 1985-02-21 Collo Gmbh, 5303 Bornheim Schutzmittel fuer haushaltszwecke
CS164886A1 (en) * 1986-03-11 1987-02-12 Jindrich Dipl Tech Matejka Pripravek na lesteni dokonale hladkych ploch
CS531289A2 (en) * 1989-09-15 1991-04-11 Ludek Ing Holub Preparation for motor-cars washing
JPH0649498A (ja) * 1992-08-04 1994-02-22 Toho Chem Ind Co Ltd 洗浄剤用組成物
EP0592906A1 (fr) * 1992-10-10 1994-04-20 Caramba Chemie GmbH Agent de nettoyage pour jantes
WO1994024256A1 (fr) * 1993-04-20 1994-10-27 Ecolab Inc. Agents de rinçage peu ecumants comprenant un copolymere sequences a l'oxyde d'ethylene/oxyde de propylene
WO1996012005A1 (fr) * 1994-10-14 1996-04-25 Colgate-Palmolive Company Composition de nettoyage du verre
WO1998017765A1 (fr) * 1996-10-23 1998-04-30 Agency Design Services Limited Composition, procede de traitement d'une surface non poreuse et surface non poreuse ainsi traitee
WO1998030662A1 (fr) * 1997-01-13 1998-07-16 Ecolab Inc. Combinaison d'un tensio-actif silicone non ionique et d'un tensio-actif non ionique dans un detergent en bloc solide

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2003173A (en) * 1977-08-29 1979-03-07 Sandoz Ltd Detergent composition
GB2068405A (en) * 1980-01-24 1981-08-12 Sandoz Ltd Biodegradable detergent composition
DE3327926A1 (de) * 1983-08-03 1985-02-21 Collo Gmbh, 5303 Bornheim Schutzmittel fuer haushaltszwecke
CS164886A1 (en) * 1986-03-11 1987-02-12 Jindrich Dipl Tech Matejka Pripravek na lesteni dokonale hladkych ploch
CS531289A2 (en) * 1989-09-15 1991-04-11 Ludek Ing Holub Preparation for motor-cars washing
JPH0649498A (ja) * 1992-08-04 1994-02-22 Toho Chem Ind Co Ltd 洗浄剤用組成物
EP0592906A1 (fr) * 1992-10-10 1994-04-20 Caramba Chemie GmbH Agent de nettoyage pour jantes
WO1994024256A1 (fr) * 1993-04-20 1994-10-27 Ecolab Inc. Agents de rinçage peu ecumants comprenant un copolymere sequences a l'oxyde d'ethylene/oxyde de propylene
WO1996012005A1 (fr) * 1994-10-14 1996-04-25 Colgate-Palmolive Company Composition de nettoyage du verre
WO1998017765A1 (fr) * 1996-10-23 1998-04-30 Agency Design Services Limited Composition, procede de traitement d'une surface non poreuse et surface non poreuse ainsi traitee
WO1998030662A1 (fr) * 1997-01-13 1998-07-16 Ecolab Inc. Combinaison d'un tensio-actif silicone non ionique et d'un tensio-actif non ionique dans un detergent en bloc solide

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8713, Derwent World Patents Index; Class A26, AN 87-086892, XP002101457 *
DATABASE WPI Section Ch Week 9131, Derwent World Patents Index; Class A97, AN 91-223470, XP002101456 *
DATABASE WPI Section Ch Week 9412, Derwent World Patents Index; Class A97, AN 94-098091, XP002101455 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1127939A1 (fr) * 2000-02-22 2001-08-29 Unilever N.V. Composition de nettoyage de la vaisselle
WO2002034869A1 (fr) * 2000-10-25 2002-05-02 Unilever Plc Compositions pour lave-vaisselle
EP1245666A1 (fr) * 2001-03-26 2002-10-02 The Procter & Gamble Company Composition pour nettoyer les surfaces dures
WO2002077142A1 (fr) * 2001-03-26 2002-10-03 The Procter & Gamble Company Composition pour nettoyer une surface dure
WO2005100523A1 (fr) * 2004-04-16 2005-10-27 Henkel Kommanditgesellschaft Auf Aktien Nettoyant hydrophylisant pour surfaces dures
WO2006083813A2 (fr) * 2005-01-31 2006-08-10 The Procter & Gamble Company Composition d'agent de rinçage
WO2006083813A3 (fr) * 2005-01-31 2006-09-08 Procter & Gamble Composition d'agent de rinçage
US7320957B2 (en) 2005-01-31 2008-01-22 The Procter & Gamble Company Rinse-aid composition comprising a magnesium salt and zinc salt mixture
DE102005058328A1 (de) * 2005-12-07 2007-06-21 Fritz Heuer Oberflächenveredelungsverfahren, insbesondere für Edelstahloberflächen
US12157868B2 (en) 2019-06-21 2024-12-03 Ecolab Usa Inc. Solidified nonionic surfactant composition comprising a solid urea binder

Also Published As

Publication number Publication date
GB9923817D0 (en) 1999-12-08
GB2339205A (en) 2000-01-19
AU2527299A (en) 1999-08-30

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