WO1998034965B1 - Preparation of vinyl-containing macromers - Google Patents
Preparation of vinyl-containing macromersInfo
- Publication number
- WO1998034965B1 WO1998034965B1 PCT/US1998/002656 US9802656W WO9834965B1 WO 1998034965 B1 WO1998034965 B1 WO 1998034965B1 US 9802656 W US9802656 W US 9802656W WO 9834965 B1 WO9834965 B1 WO 9834965B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- vinyl
- transition metal
- olefin
- ratio
- Prior art date
Links
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract 8
- 229920002554 vinyl polymer Polymers 0.000 title claims abstract 3
- 239000000203 mixture Substances 0.000 claims abstract 7
- 229910052723 transition metal Inorganic materials 0.000 claims abstract 5
- 150000003624 transition metals Chemical class 0.000 claims abstract 5
- 150000001336 alkenes Chemical group 0.000 claims abstract 4
- 239000003054 catalyst Substances 0.000 claims abstract 4
- 238000000034 method Methods 0.000 claims abstract 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 3
- 229920000098 polyolefin Polymers 0.000 claims abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
Abstract
Polymeric compositions of matter are described comprising olefin polymer chains having Mn of about 400 to 75,000, a ratio of vinyl groups to total olefin groups according to formula (1), where a = -0.24 and b = 0.8, and where the total number of vinyl groups per 1000 carbon atoms is greater than or equal to 8000 Mn. The invention includes a method for preparing these polymeric products comprising contacting one or more olefin comonomers with a catalyst system containing a transition metal catalyst compound and an alumoxane wherein the aluminum to transition metal ratio is from 10:1 to less than or equal to 220:1 (Al:Me). The process conditions of the invention permit predictable macromer characteristics of both molecular weight and vinyl unsaturation.
Claims
1. A composition of matter comprising olefin polymer chains having Mn of about 1500 to 75,000, a ratio of vinyl groups to total olefin groups according to the formula
(1) vinyl groups/ olefm groups > [comonomer mole percent + 0.1]" x 10Λχb
where, a = -0.24 and b = 0.8, and where the total number of vinyl groups per 1000 carbon atoms is greater than or equal to 8000-*-Mn.
2. The composition of claim 1 wherein a =* -0.20.
3. The composition of claim 1 wherein a = -0.18 and b = 0.83.
4. The composition of claim 1 wherein a = -0.15 andb = 0.83.
5. The composition of claim 1 wherein said olefin polymer comprises one or more of the group consisting of ethylene, C3-C]2 α-olefins, isobutylene and norbomene.
6. A method for preparing polymers having high levels of vinyl unsaturation comprising contacting, under batchwise, solution polymerization conditions, one or more olefin monomers with a catalyst solution composition containing a transition metal catalyst compound and an alumoxane wherein the aluminum to transition metal ratio is from 10:1 to 220.1.
7. The method of claim 6 wherein the aluminum to transition metal ratio is from 20: 1 to 140:1.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP53504998A JP2001511214A (en) | 1997-02-07 | 1998-02-06 | Preparation of vinyl-containing macromers |
| CA002276214A CA2276214A1 (en) | 1997-02-07 | 1998-02-06 | Preparation of vinyl-containing macromers |
| KR10-1999-7007118A KR100503523B1 (en) | 1997-02-07 | 1998-02-06 | Preparation of vinyl-containing macromers |
| EP98906330.0A EP0958309B2 (en) | 1997-02-07 | 1998-02-06 | Preparation of vinyl-containing macromers |
| DE69836415.5T DE69836415T3 (en) | 1997-02-07 | 1998-02-06 | PREPARATION OF VINYL-CONTAINING POLYMERS |
| ES98906330.0T ES2277381T5 (en) | 1997-02-07 | 1998-02-06 | Preparation of vinyl containing macromers |
| BR9806952A BR9806952A (en) | 1997-02-07 | 1998-02-06 | Preparation of macromers containing vinyl. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3732397P | 1997-02-07 | 1997-02-07 | |
| US60/037,323 | 1997-11-17 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO1998034965A1 WO1998034965A1 (en) | 1998-08-13 |
| WO1998034965B1 true WO1998034965B1 (en) | 1998-11-12 |
| WO1998034965A9 WO1998034965A9 (en) | 1999-01-14 |
Family
ID=21893724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1998/002656 WO1998034965A1 (en) | 1997-02-07 | 1998-02-06 | Preparation of vinyl-containing macromers |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6444773B1 (en) |
| EP (1) | EP0958309B2 (en) |
| JP (1) | JP2001511214A (en) |
| KR (1) | KR100503523B1 (en) |
| CN (1) | CN1246127A (en) |
| BR (1) | BR9806952A (en) |
| CA (1) | CA2276214A1 (en) |
| DE (1) | DE69836415T3 (en) |
| ES (1) | ES2277381T5 (en) |
| WO (1) | WO1998034965A1 (en) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2356612T3 (en) | 1998-11-02 | 2011-04-11 | Dow Global Technologies Inc. | ETHYLENE / ALFA-OLEFINE / DIENO INTERPOLYMERS REO-FLUIDIFICANTS AND THEIR PREPARATION. |
| US6372847B1 (en) | 2000-05-10 | 2002-04-16 | Exxon Mobil Chemical Patents, Inc. | Polyolefin compositions having improved low temperature toughness |
| US6891018B2 (en) * | 2000-07-26 | 2005-05-10 | Mitsui Chemicals, Inc. | Ethylene copolymer and uses thereof |
| EP1241194B1 (en) * | 2000-07-26 | 2013-09-04 | Mitsui Chemicals, Inc. | Polymer and process for producing the same |
| EP1270603B1 (en) * | 2001-06-20 | 2014-04-09 | Mitsui Chemicals, Inc. | Olefin polymerization catalyst, process for polymerizing olefins |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| ES2394304T3 (en) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Multiple catalyst system for the polymerization of olefins and polymers produced from them |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| CA2465479A1 (en) * | 2003-04-28 | 2004-10-28 | Tosoh Corporation | Polyethylene composition and process for producing same |
| US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
| US7928164B2 (en) * | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
| US7951872B2 (en) * | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
| US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
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| US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
| JP5714913B2 (en) * | 2008-03-13 | 2015-05-07 | ダウ グローバル テクノロジーズ エルエルシー | Long chain branching (LCB), block, or interconnected ethylene copolymers in combination with one other polymer |
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| US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
| US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
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| US8283428B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
| US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
| US8093335B2 (en) * | 2008-12-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin in-reactor blends and molded articles therefrom |
| US8318648B2 (en) * | 2009-12-15 | 2012-11-27 | Exxonmobil Research And Engineering Company | Polyether-containing lubricant base stocks and process for making |
| US8907034B2 (en) | 2010-09-30 | 2014-12-09 | Dow Global Technologies Llc | Comb architecture olefin block copolymers |
| US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
| US8785562B2 (en) | 2011-03-25 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Amphiphilic block polymers prepared by alkene metathesis |
| WO2012134721A2 (en) * | 2011-03-25 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
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| US8318998B2 (en) | 2011-03-25 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers |
| US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
| US8455597B2 (en) | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
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| US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
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| US8501894B2 (en) | 2011-03-25 | 2013-08-06 | Exxonmobil Chemical Patents Inc. | Hydrosilyation of vinyl macromers with metallocenes |
| US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
| US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
| US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
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| CN104411778B (en) | 2012-08-03 | 2017-07-28 | 埃克森美孚化学专利公司 | The polyalphaolefin prepared using modified Salan catalyst compounds |
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| WO2014022012A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
| CN104661751B (en) * | 2012-09-24 | 2017-02-22 | 埃克森美孚化学专利公司 | Production of vinyl terminated polyethylene |
| WO2014052200A1 (en) * | 2012-09-27 | 2014-04-03 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polymers and methods to produce thereof |
| WO2014070502A1 (en) * | 2012-11-02 | 2014-05-08 | Exxonmobil Chemical Patents Inc. | Supported salan catalysts |
| US9422385B2 (en) | 2013-01-30 | 2016-08-23 | Exxonmobil Chemical Patents Inc. | Polyethylene copolymers with vinyl terminated macromonomers as comonomers |
| US9540465B2 (en) | 2013-11-19 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Boron-bridged metallocene catalyst systems and polymers produced therefrom |
| US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
| US9321856B2 (en) | 2013-12-19 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Process to produce functionalized polymer |
| KR101792171B1 (en) | 2014-12-08 | 2017-10-31 | 주식회사 엘지화학 | Olefin based polymer with excellent melt strength and film comprising the same |
| ES2784518T3 (en) | 2014-12-09 | 2020-09-28 | Mitsui Chemicals Inc | Propylene-based resin composition |
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| US10995166B2 (en) * | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
| US20190135960A1 (en) * | 2017-11-07 | 2019-05-09 | Nova Chemicals (International) S.A. | Process to manufacture ethylene interpolymer products |
| WO2020131311A1 (en) | 2018-12-18 | 2020-06-25 | Exxonmobil Research And Engineering Company | Modified asphalts and methods for producing the same |
| WO2020140064A1 (en) | 2018-12-28 | 2020-07-02 | Dow Global Technologies Llc | Organometallic chain transfer agents |
| CN113454130B (en) | 2018-12-28 | 2024-12-13 | 陶氏环球技术有限责任公司 | Telechelic polyolefins and methods for preparing telechelic polyolefins |
| US20220073716A1 (en) | 2018-12-28 | 2022-03-10 | Dow Global Technologies Llc | Curable compositions comprising unsaturated polyolefins |
| US12180314B2 (en) | 2018-12-28 | 2024-12-31 | Dow Global Technologies Llc | Curable compositions comprising unsaturated polyolefins |
Family Cites Families (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3350723A (en) | 1965-04-27 | 1967-11-07 | Arthur M Dyer | Water volume control for water closet |
| US3989768A (en) | 1971-02-22 | 1976-11-02 | Cpc International Inc. | Chemically joined phase separated thermoplastic graft copolymers |
| BE793639A (en) | 1972-01-03 | 1973-07-03 | Xerox Corp | ELECTROSTATOGRAPHIC DEVELOPER |
| JPS52141888A (en) | 1976-05-21 | 1977-11-26 | Nippon I P Rubber Kk | Ethyleneepropylene copolymers rubber |
| US4335225A (en) | 1978-06-20 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Elastomeric polypropylene |
| DE3127133A1 (en) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | METHOD FOR PRODUCING POLYOLEFINS AND THEIR COPOLYMERISATS |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| CA1280543C (en) | 1985-01-31 | 1991-02-19 | B. Joseph Scheve | Polypropylene with free-end long chain branching, process for making it, and use thereof |
| DE3508887A1 (en) | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | METHOD FOR PRODUCING OPTICALLY ACTIVE POLYOLEFINES |
| US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| IL80888A (en) * | 1985-12-12 | 1991-12-12 | Exxon Chemical Patents Inc | Olefin polymerization catalysts,their preparation and use thereof |
| WO1988002378A1 (en) | 1986-09-24 | 1988-04-07 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefin |
| JPH0780933B2 (en) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | Olefin Polymerization Method |
| KR910008277B1 (en) | 1986-12-03 | 1991-10-12 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | Solid catalyst olefin polymerization and process its preparation |
| JP2618384B2 (en) * | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | Solid catalyst for olefin polymerization and its preparation |
| US5391629A (en) | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| JPH0742301B2 (en) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | Particulate aluminoxane, its manufacturing method and its use |
| DE8703096U1 (en) | 1987-02-27 | 1987-08-20 | Söffner, Georg, 8000 München | Container for holding at least one condom |
| US4769910A (en) | 1987-03-30 | 1988-09-13 | Northern Telecom Limited | Cutting tool for cylindrical articles |
| JP2538588B2 (en) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | Method for producing solid catalyst for olefin polymerization |
| US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| DE3742934A1 (en) | 1987-12-18 | 1989-06-29 | Hoechst Ag | METHOD FOR PRODUCING A CHIRAL, STEREORIGIDAL METALLOCEN COMPOUND |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| EP0354893B2 (en) | 1988-08-05 | 2002-03-13 | Fina Technology, Inc. | Process for producing large symmetrical polymer particles |
| US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| EP0366411A3 (en) | 1988-10-28 | 1991-04-24 | Exxon Chemical Patents Inc. | Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions |
| US4999403A (en) | 1988-10-28 | 1991-03-12 | Exxon Chemical Patents Inc. | Graft polymers of functionalized ethylene-alpha-olefin copolymer with polypropylene, methods of preparation, and use in polypropylene compositions |
| US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
| US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| DE3907964A1 (en) | 1989-03-11 | 1990-09-13 | Hoechst Ag | METHOD FOR PRODUCING A SYNDIOTACTIC POLYOLEFIN |
| US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5763549A (en) | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
| DK0426637T4 (en) | 1989-10-30 | 2002-01-14 | Fina Technology | Process for the preparation of metallocene catalysts for polymerization of olefins |
| JP3131218B2 (en) | 1989-12-06 | 2001-01-31 | トランスウィッチ・コーポレーション | Waveform shaping transversal filter |
| DE69019535T2 (en) | 1990-01-02 | 1995-10-19 | Exxon Chemical Patents Inc., Linden, N.J. | IONIC METALLOCENE CATALYSTS ON SUPPORT FOR OLEFIN POLYMERIZATION. |
| GB2241244B (en) | 1990-02-22 | 1994-07-06 | James C W Chien | Thermoplastic elastomers |
| CA2057892C (en) | 1990-04-09 | 1995-08-08 | Tetsunosuke Shiomura | Propylene copolymer |
| WO1991017194A1 (en) | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF |
| RU2118203C1 (en) | 1990-06-22 | 1998-08-27 | Экксон Кэмикал Пейтентс Инк. | Catalytic system for polyolefin production and composition used for olefin polymerization |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| DE69130320T2 (en) | 1990-07-24 | 1999-04-08 | Mitsui Chemicals Inc | CATALYST FOR ALPHA-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY (ALPHA) OLEFINES THEREOF |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| JP3076619B2 (en) | 1991-05-14 | 2000-08-14 | 三井化学株式会社 | Method for producing block copolymer |
| DE4120009A1 (en) | 1991-06-18 | 1992-12-24 | Basf Ag | SOLUBLE CATALYST SYSTEMS FOR THE PRODUCTION OF POLYALK-1-ENEN WITH HIGH MOLES |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
| TW300901B (en) | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| DE4130299A1 (en) | 1991-09-12 | 1993-03-18 | Basf Ag | METHOD FOR PRODUCING HIGH PRESSURE POLYPROPYLENE |
| EP0537686B1 (en) | 1991-10-15 | 2005-01-12 | Basell Polyolefine GmbH | Process for preparing an olefinpolymer by using metallocenes having specially substituted indenylligands |
| JPH07501845A (en) | 1991-12-13 | 1995-02-23 | エクソン・ケミカル・パテンツ・インク | Copolymers of ethylene and longer alpha olefins |
| AU3809893A (en) | 1992-03-16 | 1993-10-21 | Exxon Chemical Patents Inc. | Ionic catalyst for the production of poly-alpha-olefins of controlled tacticity |
| US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
| US5310794A (en) | 1992-03-31 | 1994-05-10 | Himont Incorporated | Theromoplastic blends containing graft copolymers of polyacrylates as impact modifiers |
| EP0641362B1 (en) | 1992-04-20 | 1998-11-11 | Exxon Chemical Patents Inc. | Ethylene/branched olefin copolymers |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
| EP0572034A2 (en) | 1992-05-29 | 1993-12-01 | Idemitsu Kosan Company Limited | Ethylenic copolymer and ethylenic copolymer composition |
| DK0574597T3 (en) | 1992-06-13 | 1998-09-14 | Targor Gmbh | Process for the preparation of bridged closed chiral metallocene catalysts of the bisindenyl type |
| US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
| DE69334188T2 (en) | 1992-08-05 | 2008-10-23 | Exxonmobil Chemical Patents Inc., Baytown | Process for the preparation of a supported activator component |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| KR950703595A (en) | 1992-09-29 | 1995-09-20 | 벤셔 카펜헤르 | LONG CHAIN BRANCHED POLYMERS AND A PROCESS TO MAKE LONG CHAIN BRANCHED POLYMERS |
| DE69312306T2 (en) | 1992-10-02 | 1997-11-13 | Dow Chemical Co | APPLICATION OF HOMOGENIC COMPLEX CATALYST FOR OLEFIN POLYMERIZATION |
| DE69333470T2 (en) | 1992-10-28 | 2004-08-19 | Idemitsu Kosan Co. Ltd. | OLEFIN COPOLYMERS AND METHOD FOR THE PRODUCTION THEREOF |
| US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| US5747620A (en) * | 1993-02-22 | 1998-05-05 | Idemitsu Kosan Co., Ltd. | Ethylene copolymer, thermoplastic resin composition containing same, and process for preparing ethylene copolymer |
| US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
| EP0727446B1 (en) | 1993-10-26 | 2000-09-13 | Idemitsu Kosan Company Limited | Branched ethylene macromonomer and polymer produced therefrom |
| US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
| US5539056A (en) | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
| CA2223258A1 (en) | 1995-07-06 | 1997-01-23 | Exxon Chemical Patents, Inc. | Method for producing prepolymerized, supported metallocene catalyst systems |
| US6084030A (en) | 1995-08-04 | 2000-07-04 | Dsm Copolymer, Inc. | Branched polymers with polyolefin arms |
| US20010014718A1 (en) | 1995-09-11 | 2001-08-16 | Mamoru Kagami | Resin compositions and use of the same |
| US5914372A (en) | 1997-01-23 | 1999-06-22 | Jsr Corporation | Ethylene copolymer rubber composition |
| US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
-
1998
- 1998-02-06 EP EP98906330.0A patent/EP0958309B2/en not_active Expired - Lifetime
- 1998-02-06 KR KR10-1999-7007118A patent/KR100503523B1/en not_active Expired - Fee Related
- 1998-02-06 CA CA002276214A patent/CA2276214A1/en not_active Abandoned
- 1998-02-06 BR BR9806952A patent/BR9806952A/en not_active IP Right Cessation
- 1998-02-06 WO PCT/US1998/002656 patent/WO1998034965A1/en active IP Right Grant
- 1998-02-06 DE DE69836415.5T patent/DE69836415T3/en not_active Expired - Lifetime
- 1998-02-06 JP JP53504998A patent/JP2001511214A/en not_active Ceased
- 1998-02-06 ES ES98906330.0T patent/ES2277381T5/en not_active Expired - Lifetime
- 1998-02-06 CN CN98802127A patent/CN1246127A/en active Pending
-
2000
- 2000-03-08 US US09/521,043 patent/US6444773B1/en not_active Expired - Lifetime
-
2001
- 2001-11-06 US US09/992,768 patent/US6555635B2/en not_active Expired - Lifetime
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