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WO1998033962A1 - Spandex a faible pouvoir adhesif et procede de production - Google Patents

Spandex a faible pouvoir adhesif et procede de production Download PDF

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Publication number
WO1998033962A1
WO1998033962A1 PCT/US1998/001673 US9801673W WO9833962A1 WO 1998033962 A1 WO1998033962 A1 WO 1998033962A1 US 9801673 W US9801673 W US 9801673W WO 9833962 A1 WO9833962 A1 WO 9833962A1
Authority
WO
WIPO (PCT)
Prior art keywords
spandex
tack
additive
carbon atoms
dry
Prior art date
Application number
PCT/US1998/001673
Other languages
English (en)
Inventor
Iftekhar A. Karimi
Hong Liu
Robert Lee Lock
Bryan Benedict Sauer
Original Assignee
E.I. Du Pont De Nemours And Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E.I. Du Pont De Nemours And Company filed Critical E.I. Du Pont De Nemours And Company
Priority to JP53304498A priority Critical patent/JP4014228B2/ja
Priority to US09/355,233 priority patent/US6232374B1/en
Priority to BR9807050-9A priority patent/BR9807050A/pt
Priority to DE69802905T priority patent/DE69802905T2/de
Priority to EP98903807A priority patent/EP0960224B1/fr
Publication of WO1998033962A1 publication Critical patent/WO1998033962A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes

Definitions

  • This invention relates to spandex having low tackiness and, more particularly, to spandex having dispersed therein effective amounts of an anti-tack additive.
  • Spandex is known to be tacky. This is especially important in wound packages of dry-spun spandex, where the pressure can be very high due to "package relaxation", which is the recovery of the filament from the stretch it experiences during spinning. The high pressure can make it especially difficult to remove and use filament near the core of the package, where conditions are most extreme. Time and temperature contribute to tackiness, so that wound packages of spandex that have been stored, for example for months, experience significantly more core waste than freshly spun and wound packages . Reducing the tackiness and the resulting waste would improve the economics of spandex filament production. Steps taken to reduce tack, however, should not interfere with the continuity of the dry-spinning process by which spandex is made.
  • United States Patent Number 4,296,174 discloses the incorporation of metal salts of fatty acids such as calcium stearate into dry-spun spandex to reduce the tackiness of the spandex.
  • metal salts of fatty acids such as calcium stearate
  • Such additives are problematic in the dry-spinning process, creating deposits within the spinneret capillaries and plugging filters in the polymer solution lines. These effects are detrimental to spinning continuity, i.e. when the capillaries or filters become plugged, the continuous filament production is interrupted and the process must be stopped to clean out the plugging deposits or replace the plugged parts with clean ones.
  • An anti-tack additive with a combination of good dry- spinning processibility and anti-tack characteristics is still desired.
  • JP '259 discloses a method for producing thermoplastic polyurethane elastic nonwoven fabric by melt-extruding and melt-blowing thermoplastic polyurethane which has been blended with 0.1-2.0 wt % of a compound represented by the formula:
  • thermoplastic resin is melt-spun and simultaneously powerfully impacted by a high- temperature, high-speed gas discharged from adjoining gas jets which blasts apart the melt-spun fibers into ultrafine fibers which are then collected on a moving plate thereby giving a nonwoven sheet .
  • the sheet can be unrolled after having been rolled up.
  • JP '259 teaches the undesirability of polyurethane elastic fiber production by dry spinning, as disclosed in Japanese Patent Application Publication No. 52-81,177. An anti-tack additive for dry-spun polyurethane fiber is still desired.
  • United States Patent Number 3,382,202 discloses an additive system to impart substantially non-blocking and non-tacky characteristics to formed polyurethane structures.
  • the additive system consists essentially of (1) about 0.5 to 4.0 parts of certain amides and bis-amides derived from fatty acids, including ethylene bis-stearamide and stearamide, and (2) about 1 to 15 parts of a finely divided inert particulate solid such as diatomaceous earth, silica, talc, feldspar, mica, carbon black, calcium bicarbonate, or sodium bicarbonate.
  • An anti-tack additive that does not require a second inert component is still desired.
  • the spandex of the present invention contains 0.1-5.0% by weight of the spandex of an anti-tack additive dispersed in the spandex wherein the additive is a compound of formula (I) or mixtures thereof:
  • each of R 1 and R 2 is independently selected from the group consisting of alkyl having 14 to 22 carbon atoms and alkenyl having 14 to 22 carbon atoms, and Z is selected from the group consisting of
  • R3 is alkylene having 2 to 6 carbon atoms
  • R contains an aromatic or a cycloaliphatic group and has 6 to 18 carbon atoms, each of the nitrogen atoms being bonded to a ring carbon in the R 4 moiety.
  • the process of the present invention for making spandex comprises the steps of : preparing a polyurethane solution; mixing into the solution 0.1-5.0% by weight of the spandex of an anti-tack additive of formula (I) or mixtures thereof; and dry-spinning the solution to form spandex.
  • the spandex supply package of the present invention comprises a cylindrical core and spandex wound up on said core, wherein the spandex contains 0.1-5.0% by weight of the spandex of an anti-tack additive of formula (I) or mixtures thereof.
  • EBS Ethylene bis-stearamide (N,N'-1,2- ethanediylbis-octadecanamide) MDI 1, 1 ' -Methylenebis (4-isocyanatobenzene)
  • spandex means a dry-spun, manufactured fiber in which the fiber-forming substance is a long chain synthetic elastomer comprised of at least 85% by weight of a segmented polyurethane. Polyurethaneureas are a sub-class of such polyurethanes . Such spandex can be typically wound up on a cylindrical core, or tube, to form a supply package .
  • the polymers used to make the spandex of this invention can be generally prepared by capping a macromolecular glycol with a diisocyanate, dissolving the resulting capped glycol in a suitable solvent, and chain extending the capped glycol with a diamine, a diol or an aminoalcohol .
  • Small amounts of monofunctional chain terminators such as dialkylamines can be added to control the molecular weight of the polymer.
  • Any organic diisocyanate can be used for the purposes of this invention, such as MDI, 2,4-tolylene diisocyanate, PICM, hexamethylene diisocyanate, 3,3,5- trimethyl-5-methylenecyclohexyl diisocyanate (isophorone diisocyanate), and the like. MDI is preferred.
  • the macromolecular glycol can be selected from one or more of several types of such glycols .
  • Polyether glycols suitable for use in the present invention include those derived from tetramethylene glycol, 3-methyl-l, 5-pentane diol, tetrahydrofuran, 3 -methyltetrahydrofuran, and the like, and copolymers thereof.
  • Glycol-terminated polyesters which can be used in the conjunction with the present invention include the reaction products of ethylene glycol, tetramethylene glycol (butanediol) , and/or 2,2- dimethyl-1, 3 -propane diol and the like with diacids such as adipic acid, succinic acid, dodecanedioic acid, and the like. Copolymers are also contemplated.
  • glycols for use in the present invention are polyetheresters comprised of elements of the above polyethers and polyesters, and diol- terminated polycarbonates such as poly (pentane-1, 5- carbonate) diol, poly (hexane-l, 6-carbonate) diol, and the like.
  • Completion of the formation of the polymer can be accomplished by dissolving the capped glycol in a suitable solvent and chain extending with diols or diamines to form polyurethanes or the sub-class known as polyurethaneureas , respectively.
  • Solvents suitable include dimethylacetamide (DMAc) , N-methylpyrrolidone, and dimethylformamide. DMAc is preferred.
  • Suitable diol chain extenders include ethylene glycol, tetramethylene glycol, and the like.
  • Diamines that can be used with the present invention include EDA, 1,3- cyclohexane diamine, 1, 4-cyclohexane diamine, 1,3- propylene diamine, 2-methylpentamethylene diamine (MPMD) , 1,2-propylene diamine, and the like, and mixtures thereof .
  • Diamine chain extenders and the resulting polyurethaneureas are preferred.
  • a small amount of a monoamine such as DEA can be mixed into the chain extender and reacted with the capped glycol in order to control the molecular weight of the final polyurethaneurea or polyurethane.
  • the anti-tack additive can be mixed into the solution.
  • the anti-tack additive is a compound of formula (I) or mixtures thereof:
  • each of R 1 R 2 is independently selected from the group consisting of alkyl having 14 to 22 carbon atoms and alkenyl having 14 to 22 carbon atoms, and Z is selected from the group consisting of
  • R 3 is alkylene having 2 to 6 carbon atoms, and R 4 contains an aromatic or a cycloaliphatic group and has 6 to 18 carbon atoms, each of the nitrogen atoms being bonded to a ring carbon in the R 4 moiety.
  • R 1 R 2 and is substantially a linear, unsaturated C13H35 moiety and Z is -C(0) -NH-CH 2 CH 2 -NH-C(0) -
  • the additive is ethylene bis- oleylamide, which is preferred;
  • the solution having the anti-tack additive dispersed therein is dry-spun to form the spandex of the invention.
  • Dry-spinning is the process of forcing a polymer solution through spinneret orifices into a shaft to form a filament. Heated inert gas is passed through the chamber, evaporating the solvent from the filament as the filament passes through the shaft. The resulting spandex can then be wound on a cylindrical core to form a spandex supply package .
  • the anti-tack additive of this invention is present in the spandex in an amount of 0.1-5.0% by weight of the spandex to reduce tack in dry-spun spandex while surprisingly also providing improved dry- spinning continuity compared to other anti-tack additives .
  • spandex of the present invention can contain conventional additives that are added for specific purposes, such as antioxidants, thermal stabilizers, UV stabilizers, pigments and delustrants (for example titanium dioxide) , dyes and dye enhancers, lubricating agents (for example silicone oil) , additives to enhance resistance to chlorine degradation (for example zinc oxide, magnesium oxide and mixtures of huntite and hydromagnesite) , and the like, so long as such additives do not produce antagonistic effects with the spandex elastomer or anti-tack additive of this invention.
  • additives that are added for specific purposes, such as antioxidants, thermal stabilizers, UV stabilizers, pigments and delustrants (for example titanium dioxide) , dyes and dye enhancers, lubricating agents (for example silicone oil) , additives to enhance resistance to chlorine degradation (for example zinc oxide, magnesium oxide and mixtures of huntite and hydromagnesite) , and the like, so long as such additives do not produce antagonistic effects with the spandex elast
  • the spandex can be of any decitex. Fine decitex filaments (below about 132 decitex and especially below about 44 decitex) are particularly susceptible to process disruptions due to their low diameter and the tenuous, low viscosity nature of the hot spinning solution as it exits from the spinneret orifice. Under such circumstances, the dry-spinning continuity is readily affected by filter blinding and spinneret deposits in the small-diameter spinneret holes that are used. Therefore, the present invention is particularly advantageous in the manufacture of fine decitex spandex.
  • the spandex of the present invention can be made with excellent dry-spinning continuity, relatively high levels of the anti-tack additive can be used.
  • the useful amount of the anti-tack additive in the present spandex is in the range of 0.1% to 5.0%, preferably 0.4% to 2.0%, expressed as a weight percent based on the weight of the fiber. Below 0.1 wt%, there is little effect on the tackiness of the spandex, and above 5.0 wt%, the mechanical properties of the spandex are adversely affected.
  • a metal ion is not necessary to give the observed advantages, and in fact it is preferred that metal ions not be included as part of the additive.
  • the amounts of the additives are given as weight percents based on total fiber weight.
  • Polymer for the dry-spun spandex in Examples 1, 2 and 3 was made by capping a 3550 molecular weight 87.5/12.5 (mole ratio) copolyether of tetrahydrofuran and 3-methyltetrahydrofuran with MDI at a capping ratio (the mole ratio of diisocyanate to polymeric glycol) of about 1.85.
  • the resulting capped glycol was chain extended in DMAc with EDA and terminated with DEA.
  • the polymer solution was then mixed with a slurry of additives in DMAc to form a "base solution" .
  • the dry-spun fiber contained 1.5 wt% CYANOX® 1790 antioxidant [2,4,6-tris (2, 6-dimethyl-4-t-butyl-3- hydroxybenzyl) isocyanurate Cytec Industries], West Patterson, NJ] , 0.4 wt% CYASORB® UV stabilizer [2,4- di (2 ' ,4 ' -dimethylphenyl) -6- (2" -hydroxy-4" -n- octyloxyophenyl) -1,3, 5-triazine, Cytec Industries], 0.5 wt% METHACROL® 2462B UV stabilizer (a polymer of PICM and N-t-butyldiethanolamine, a registered trademark of E.
  • Polymer for the dry-spun spandex in Examples 4 and 5 was made by capping an 1800 molecular weight polytetramethyleneether glycol with MDI at a capping ratio of about 1.7.
  • the resulting capped glycol was chain extended in DMAc solvent with a mixture of EDA and MPMD (90/10 mole ratio) and terminated with DEA.
  • the polymer solution was mixed with a slurry to form a base solution.
  • the additive slurry was such that in addition to any of the anti-tack additives contemplated by the present invention, the dry-spun fiber contained 1.5 wt% CYANOX® 1790 antioxidant, 2.0 wt% METHACROL® 2138F UV stabilizer (a copolymer of diisopropylaminoethyl methacrylate and n-decyl methacrylate in a 75/25 ratio by weight, E. I. du Pont de Nemours and Company, Wilmington, DE) , and 0.6 wt% silicone oil lubricant substantially as disclosed in United States Patent Number 3,296,063.
  • An anti-tack slurry was prepared and mixed into the base solution to form a spinning solution which was dry-spun to produce the spandex.
  • a 4.5% by weight of a finish comprising 94 wt% of the same silicone oil and 4 wt% magnesium stearate (average particle size 5 microns) was applied by a conventional finish roll to the 44 decitex spandex before it was wound onto 83 mm (outer diameter) tubes to form 410 g (fiber weight) packages having a final outer diameter of 150 mm.
  • the stretch applied to the spandex during winding was in the range of about 25% to 29%.
  • the additive slurries were milled in a 1.5-liter capacity Premier Mill (Premier Mill Corp., Reading, PA) model HM1.5VSD, operated at 75% loading of 0.8 mm zirconia beads.
  • the shaft spacer tip velocity was about 60 meters per minute and the slurry flow rate was 40 g/min.
  • the slurries were generally milled in one pass.
  • the slurry fluid in each case was DMAc.
  • the same polyurethaneurea was added as that into which the additive was to be mixed.
  • the slurry can be added into the polymer stream by itself or in combination with other, standard, additives or it can be added just prior to the spinning operation provided that there is sufficient mixing.
  • controls are the samples with no further additive beyond those mixed into the base solution.
  • a control was prepared and dry-spun with each set of test samples.
  • Over-end take-off tension was determined in accordance with the procedures disclosed in Hanzel et al, United States Patent 4,296,174, column 4, lines 20-45, with reference to Figure 6 of the patent. In this technique, measurement is made of the average tension (i.e., average tensile load) required to remove a 183 m length of sample of spandex yarn from a tubular supply package of the yarn at a delivery rate of 45.7 meters per minute.
  • average tension i.e., average tensile load
  • the anti-tack additive was prepared by reacting MDI or PICM with an unsaturated or saturated 18-carbon monoamine .
  • the unsaturated amine was ADOGEN® 172-D (a mixture of C-14 to C 18 amines comprising 75% C- ⁇ _8 amine and being 80% unsaturated,
  • the saturated amine was a technical grade 18-carbon monoamine (87% saturated amine, Aldrich Chemical Co. Milwaukee, WI) .
  • the reaction product of unsaturated C ⁇ _ Q amine with MDI is designated “I”
  • the product of saturated C-ig amine with MDI is designated “II”
  • the product of saturated C-ig amine with PICM is designated “III”.
  • the OETOT is reported in grams after oven-aging, and the core OETOT of the spandex of this invention is reported as a percent of the core OETOT of the control, which had no anti-tack additive.
  • Low OETOT compared to the control is desirable because it indicates that less tension (i.e. a smaller tensile load) is needed to unwind the spandex indicating that the spandex is less tacky.
  • the residual DMAc in the dry-spun spandex was in the range of 0.14 to 0.20 weight percent.
  • the anti-tack additive in this Example was EBS (Witco Chemical, EBS-Powdered Metal Ultra Fine) .
  • EBS Wood Chemical, EBS-Powdered Metal Ultra Fine
  • the EBS slurry 80 parts by weight DMAc, 7 parts of the same polyurethaneurea that was to be spun, and 13 parts EBS was milled in one pass through the mill.
  • EBS showed excellent tack reduction, even in the absence of finely divided inert particles.
  • Dioctadecyl urea was effective for reducing tack in dry-spun spandex.
  • This example compares EBS with metal stearates with regard to their effect on spandex tackiness .
  • the EBS slurry was prepared as described in Example 2.
  • a calcium stearate slurry comprising 19% calcium stearate ("CaSt", obtained from Witco Chemical as "FP" grade) and 71% silicone oil (based on total weight of the slurry, the silicone oil being substantially as disclosed in United States Patent Number 3,296,063) was prepared in a vertical 600-liter in-line homogenizer (Model 6002, Silverson Machines, East Longmeadow, MA) .
  • Magnesium stearate (median particle size 4.3 microns, Mallinckrodt Chemical Co.) was micronized to a particle size in the range of 0.2 to 9 microns. Micronizing breaks up the larger aggregates of magnesium stearate, thus shifting the distribution toward smaller particles.
  • the slurry was passed twice through the Premier Mill at a rate of 50 g/min, using an 85% loading of 0.8 mm-1.0 mm zirconium silicate beads and a shaft spacer tip velocity of 60 meters per minute. The temperature was kept below 50°C to prevent the magnesium stearate from softening. After milling, the slurry was passed through a 40 micron absolute wire mesh filter. The median particle size of the resulting magnesium stearate was about 2 microns.
  • the residual DMAc in the spandex was in the range of 0.4 to 0.6 percent , based on weight of fiber.
  • the residual DMAc was in the range of 0.4 to 0.6 weight percent, based on fiber.
  • EXAMPLE 6 This Example illustrates the spinning continuity when dry-spinning polymer solutions containing an anti-tack additive of the present invention compared to the spinning continuity when dry- spinning polymer solutions containing an anti-tack additive not of this invention.
  • a test system was used which comprised (a) a solution pump, (b) a candle filter with a 30-micron Dynalloy sintered metal filter element (Memtec America, Deland, FL) , (c) a metering pump, and (d) a spinneret plate having 0.03 cm (12 mil) diameter spinneret orifices.
  • the polymer solution tested was the base solution as prepared for Examples 1, 2, and 3 with either 0.5 wt% EBS of this invention or 0.2 wt% micronized magnesium stearate.
  • the polymer solution flux through the candle filter was 9.1 grams per square centimeter per hour.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Wrappers (AREA)

Abstract

L'invention concerne des Spandex contenant certains additifs anti-adhésifs et présentant une bonne continuité en filage à sec, ainsi qu'un procédé pour produire ce type de spandex.
PCT/US1998/001673 1997-01-31 1998-01-27 Spandex a faible pouvoir adhesif et procede de production WO1998033962A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP53304498A JP4014228B2 (ja) 1997-01-31 1998-01-27 低粘性を有するスパンデックス及びその製法
US09/355,233 US6232374B1 (en) 1997-01-31 1998-01-27 Spandex with low tackiness and process for making same
BR9807050-9A BR9807050A (pt) 1997-01-31 1998-01-27 Spandex, embalagem para suprimento de spandex e processo de fabricação de spandex.
DE69802905T DE69802905T2 (de) 1997-01-31 1998-01-27 Spandex mit niedriger klebrigkeit und herstellungsverfahren
EP98903807A EP0960224B1 (fr) 1997-01-31 1998-01-27 Spandex a faible pouvoir adhesif et procede de production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3677497P 1997-01-31 1997-01-31
US60/036,774 1997-01-31

Publications (1)

Publication Number Publication Date
WO1998033962A1 true WO1998033962A1 (fr) 1998-08-06

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PCT/US1998/001673 WO1998033962A1 (fr) 1997-01-31 1998-01-27 Spandex a faible pouvoir adhesif et procede de production

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US (1) US6232374B1 (fr)
EP (1) EP0960224B1 (fr)
JP (1) JP4014228B2 (fr)
KR (1) KR100459051B1 (fr)
BR (1) BR9807050A (fr)
DE (1) DE69802905T2 (fr)
WO (1) WO1998033962A1 (fr)

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WO2010111088A3 (fr) * 2009-03-23 2011-01-13 Invista Technologies S.A.R.L. Fibre élastique contenant un additif anti-adhésion
WO2012040076A3 (fr) * 2010-09-21 2012-06-14 Invista Technologies S.A.R.L Procédés de fabrication et d'utilisation d'une fibre élastique contenant un additif anti-collant

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US6372834B1 (en) * 1999-12-15 2002-04-16 Dupont Toray-Co. Ltd. Stabilized spandex
US6664299B2 (en) 2002-02-14 2003-12-16 Dow Corning Corporation Masterbatch method for economically and efficiently producing soap dispersions in textile fluids for synthetic fiber treatment
EP1742847B1 (fr) * 2004-03-19 2011-11-30 Pvaxx Research and Development Limited Appareil porteur de charge et procedes de fabrication
KR100659798B1 (ko) * 2005-12-02 2006-12-19 주식회사 효성 탄성사용 ｏｅｔｏ 해사장치 및 이에 의한 해사방법
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US8506627B2 (en) 2008-08-13 2013-08-13 Allergan, Inc. Soft filled prosthesis shell with discrete fixation surfaces
KR20120114314A (ko) * 2009-12-23 2012-10-16 인비스타 테크놀러지스 에스.에이.알.엘. 점착 방지 첨가제를 함유하는 탄성 섬유
CA2895083A1 (fr) 2012-12-13 2014-06-19 Allergan, Inc. Dispositif et procede de fabrication d'un implant mammaire a surface variable
CA2949231A1 (fr) 2014-05-16 2015-11-19 Allergan, Inc. Coque souple de prothese remplie a texture variable
KR102160834B1 (ko) * 2014-12-26 2020-09-29 효성티앤씨 주식회사 해사성이 개선된 스판덱스의 제조방법
WO2017086658A1 (fr) * 2015-11-16 2017-05-26 주식회사 효성 Élasthanne à propriété de déroulage améliorée et sans apparition de mousse et son procédé de fabrication
JP7412175B2 (ja) * 2017-04-12 2024-01-12 ザ ライクラ カンパニー ユーケー リミテッド 表面摩擦と粘着性が低減された弾性繊維

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WO2010111088A3 (fr) * 2009-03-23 2011-01-13 Invista Technologies S.A.R.L. Fibre élastique contenant un additif anti-adhésion
CN102362020A (zh) * 2009-03-23 2012-02-22 英威达技术有限公司 含有防粘添加剂的弹性纤维
US8377554B2 (en) 2009-03-23 2013-02-19 Invista North America S.ár.l. Elastic fiber containing an anti-tack additive
CN102362020B (zh) * 2009-03-23 2015-11-25 英威达技术有限公司 含有防粘添加剂的弹性纤维
KR101752923B1 (ko) 2009-03-23 2017-07-03 인비스타 테크놀러지스 에스.에이 알.엘. 점착 방지 첨가제를 함유하는 탄성 섬유
WO2012040076A3 (fr) * 2010-09-21 2012-06-14 Invista Technologies S.A.R.L Procédés de fabrication et d'utilisation d'une fibre élastique contenant un additif anti-collant
CN103109005A (zh) * 2010-09-21 2013-05-15 英威达技术有限公司 制备和使用包含抗粘添加剂的弹性纤维的方法
JP2013537265A (ja) * 2010-09-21 2013-09-30 インヴィスタ テクノロジーズ エスアエルエル 粘着防止添加剤含有弾性繊維の製造および使用方法
US9315924B2 (en) 2010-09-21 2016-04-19 Invista North America S.A.R.L. Methods of making and using elastic fiber containing an anti-tack additive
KR101874136B1 (ko) 2010-09-21 2018-07-03 인비스타 테크놀러지스 에스.에이 알.엘. 점착 방지 첨가제를 함유하는 탄성 섬유의 제조 및 사용 방법

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EP0960224A1 (fr) 1999-12-01
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KR100459051B1 (ko) 2004-12-03
JP4014228B2 (ja) 2007-11-28
JP2001509847A (ja) 2001-07-24
US6232374B1 (en) 2001-05-15
EP0960224B1 (fr) 2001-12-12
BR9807050A (pt) 2000-03-14
DE69802905D1 (de) 2002-01-24

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