WO1998011868A1 - Pressurised device with foaming composition containing non-ionic and anionic surfactants - Google Patents
Pressurised device with foaming composition containing non-ionic and anionic surfactants Download PDFInfo
- Publication number
- WO1998011868A1 WO1998011868A1 PCT/FR1997/001607 FR9701607W WO9811868A1 WO 1998011868 A1 WO1998011868 A1 WO 1998011868A1 FR 9701607 W FR9701607 W FR 9701607W WO 9811868 A1 WO9811868 A1 WO 9811868A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxyethylenated
- polyethylene glycol
- mono
- stearate
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 239000003945 anionic surfactant Substances 0.000 title claims abstract description 13
- 238000005187 foaming Methods 0.000 title claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 title claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002202 Polyethylene glycol Substances 0.000 claims description 39
- 229920001223 polyethylene glycol Polymers 0.000 claims description 39
- 239000004094 surface-active agent Substances 0.000 claims description 38
- -1 alkyl ether carboxylic acids Chemical class 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 15
- 239000003380 propellant Substances 0.000 claims description 15
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 14
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 12
- 229940049964 oleate Drugs 0.000 claims description 12
- 230000008719 thickening Effects 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 11
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 11
- 230000001804 emulsifying effect Effects 0.000 claims description 10
- 239000011707 mineral Substances 0.000 claims description 10
- 239000013543 active substance Substances 0.000 claims description 9
- 229920001451 polypropylene glycol Polymers 0.000 claims description 9
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 claims description 8
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 229920005862 polyol Polymers 0.000 claims description 8
- 229940035044 sorbitan monolaurate Drugs 0.000 claims description 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 7
- 229940070765 laurate Drugs 0.000 claims description 7
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- 229940075466 undecylenate Drugs 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 5
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 5
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 claims description 4
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 claims description 4
- 244000060011 Cocos nucifera Species 0.000 claims description 4
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 4
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims description 4
- 235000004443 Ricinus communis Nutrition 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- 229940061720 alpha hydroxy acid Drugs 0.000 claims description 4
- 150000001280 alpha hydroxy acids Chemical class 0.000 claims description 4
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims description 4
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 229940071160 cocoate Drugs 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 150000002194 fatty esters Chemical class 0.000 claims description 4
- 229940100242 glycol stearate Drugs 0.000 claims description 4
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000223 polyglycerol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 239000003760 tallow Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- FWRBVROZVUCLNY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O FWRBVROZVUCLNY-UHFFFAOYSA-N 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- OQQOAWVKVDAJOI-UHFFFAOYSA-N (2-dodecanoyloxy-3-hydroxypropyl) dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCC OQQOAWVKVDAJOI-UHFFFAOYSA-N 0.000 claims description 2
- BZANQLIRVMZFOS-ZKZCYXTQSA-N (3r,4s,5s,6r)-2-butoxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound CCCCOC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O BZANQLIRVMZFOS-ZKZCYXTQSA-N 0.000 claims description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 claims description 2
- QHZLMUACJMDIAE-SFHVURJKSA-N 1-hexadecanoyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)CO QHZLMUACJMDIAE-SFHVURJKSA-N 0.000 claims description 2
- IVZJIRUIKQHFCM-UHFFFAOYSA-N 1-hydroxybutyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(O)CCC IVZJIRUIKQHFCM-UHFFFAOYSA-N 0.000 claims description 2
- ARIWANIATODDMH-AWEZNQCLSA-N 1-lauroyl-sn-glycerol Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)CO ARIWANIATODDMH-AWEZNQCLSA-N 0.000 claims description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 2
- GJVUMEONPPTZEY-UHFFFAOYSA-N 2,3-dihydroxypropyl undec-10-enoate Chemical compound OCC(O)COC(=O)CCCCCCCCC=C GJVUMEONPPTZEY-UHFFFAOYSA-N 0.000 claims description 2
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-CBPJZXOFSA-N D-Gulose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O WQZGKKKJIJFFOK-CBPJZXOFSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-IVMDWMLBSA-N D-allopyranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@@H]1O WQZGKKKJIJFFOK-IVMDWMLBSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims description 2
- ZAQJHHRNXZUBTE-WUJLRWPWSA-N D-xylulose Chemical compound OC[C@@H](O)[C@H](O)C(=O)CO ZAQJHHRNXZUBTE-WUJLRWPWSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 229930091371 Fructose Natural products 0.000 claims description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 2
- 239000005715 Fructose Substances 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 claims description 2
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 2
- QHZLMUACJMDIAE-UHFFFAOYSA-N Palmitic acid monoglyceride Natural products CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 claims description 2
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 2
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 2
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 2
- AQKOHYMKBUOXEB-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-(16-methylheptadecanoyloxy)oxolan-2-yl]-2-(16-methylheptadecanoyloxy)ethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCC(C)C)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCC(C)C AQKOHYMKBUOXEB-RYNSOKOISA-N 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 claims description 2
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 claims description 2
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 claims description 2
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- ALSTYHKOOCGGFT-UHFFFAOYSA-N cis-oleyl alcohol Natural products CCCCCCCCC=CCCCCCCCCO ALSTYHKOOCGGFT-UHFFFAOYSA-N 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims description 2
- GTZOYNFRVVHLDZ-UHFFFAOYSA-N dodecane-1,1-diol Chemical compound CCCCCCCCCCCC(O)O GTZOYNFRVVHLDZ-UHFFFAOYSA-N 0.000 claims description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 2
- 229930182830 galactose Natural products 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 229940095098 glycol oleate Drugs 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000001587 sorbitan monostearate Substances 0.000 claims description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 claims description 2
- 229940035048 sorbitan monostearate Drugs 0.000 claims description 2
- 229950004959 sorbitan oleate Drugs 0.000 claims description 2
- 235000019337 sorbitan trioleate Nutrition 0.000 claims description 2
- 229960000391 sorbitan trioleate Drugs 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 claims description 2
- 150000003626 triacylglycerols Chemical class 0.000 claims 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims 2
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims 1
- ABFWOTZXBYVPIF-UHFFFAOYSA-N 2-hydroxyethyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCO ABFWOTZXBYVPIF-UHFFFAOYSA-N 0.000 claims 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims 1
- FTFKTIQTEUKUDM-UHFFFAOYSA-N [1-hydroxy-3-(16-methylheptadecanoyloxy)propan-2-yl] 2-oxopyrrolidine-1-carboxylate Chemical compound N1(C(CCC1)=O)C(=O)OC(COC(CCCCCCCCCCCCCCC(C)C)=O)CO FTFKTIQTEUKUDM-UHFFFAOYSA-N 0.000 claims 1
- 150000008131 glucosides Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- YWXYYJSYQOXTPL-SLPGGIOYSA-N isosorbide mononitrate Chemical compound [O-][N+](=O)O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 YWXYYJSYQOXTPL-SLPGGIOYSA-N 0.000 claims 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 239000001593 sorbitan monooleate Substances 0.000 claims 1
- 235000011069 sorbitan monooleate Nutrition 0.000 claims 1
- 229940035049 sorbitan monooleate Drugs 0.000 claims 1
- 239000001570 sorbitan monopalmitate Substances 0.000 claims 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 claims 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 claims 1
- 150000003445 sucroses Chemical class 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 abstract description 5
- 239000000443 aerosol Substances 0.000 description 11
- 235000010755 mineral Nutrition 0.000 description 9
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 8
- 239000003643 water by type Substances 0.000 description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- 210000003128 head Anatomy 0.000 description 5
- 239000001282 iso-butane Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 3
- 229920001213 Polysorbate 20 Polymers 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 229940079868 disodium laureth sulfosuccinate Drugs 0.000 description 3
- YGAXLGGEEQLLKV-UHFFFAOYSA-L disodium;4-dodecoxy-4-oxo-2-sulfonatobutanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOC(=O)CC(C([O-])=O)S([O-])(=O)=O YGAXLGGEEQLLKV-UHFFFAOYSA-L 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229960005323 phenoxyethanol Drugs 0.000 description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 3
- 229940068977 polysorbate 20 Drugs 0.000 description 3
- 229940057950 sodium laureth sulfate Drugs 0.000 description 3
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000003255 anti-acne Effects 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 230000001153 anti-wrinkle effect Effects 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 229940073499 decyl glucoside Drugs 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000001475 halogen functional group Chemical group 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 208000017520 skin disease Diseases 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-NQXXGFSBSA-N D-ribulose Chemical compound OC[C@@H](O)[C@@H](O)C(=O)CO ZAQJHHRNXZUBTE-NQXXGFSBSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-UHFFFAOYSA-N D-threo-2-Pentulose Natural products OCC(O)C(O)C(=O)CO ZAQJHHRNXZUBTE-UHFFFAOYSA-N 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920002884 Laureth 4 Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 201000004681 Psoriasis Diseases 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 210000000744 eyelid Anatomy 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 125000005456 glyceride group Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940061515 laureth-4 Drugs 0.000 description 1
- 125000005645 linoleyl group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000002366 mineral element Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 239000008389 polyethoxylated castor oil Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000008054 sulfonate salts Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
- B65D83/141—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant specially adapted for specific contents or propellants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
Definitions
- Pressurized foaming device comprising nonionic and anionic surfactants
- the subject of the invention is new aerosol devices comprising a cosmetic or dermatological cleaning and make-up removing composition.
- the user expects a composition for cleaning and removing make-up from the skin that it makes it possible to remove all kinds of lipstick makeup products, powder, eye shadow, foundation, etc., without damaging the skin and leaving it clean and soft.
- the usual makeup removers are generally in the form of a gel, lotion or cream
- new makeup removers appeared, in the form of transparent aerosol devices, containing a transparent, single-phase and foaming makeup-removing composition
- compositions for topical application conditioned in aerosols, foaming, transparent, monophasic and stable
- These compositions comprise a surfactant and a propellant in a hydroalcoholic medium
- the alcohol is preferably a monohydric alcohol in C r C 3
- the use of alcohol, and in particular of ethanol, in such compositions involves a risk linked to inflammability. Consequently, attempts have been made to avoid the use of monohydric alcohol in C, -C, in facial cleansing compositions
- Such devices free of C r C 3 monohydric alcohol are described in particular in document WO95 / 05796
- the device described in this document comprises a single-phase, fluid composition, free of monohydric alcohol, consisting of a hydrocarbon-based propellant and of an aqueous concentrate comprising ⁇ -olefin sulfonate salts, betai ⁇ es and alkylpolyglucosides
- this device is not without drawbacks • the composition it contains is not stable over time, in particular it sees a halo of aggregates suspended in the composition appear during storage.
- the aerosol bottle being transparent, such instability is not acceptable to the consumer.
- Document EP-676188 discloses a similar device, comprising a monophasic, fluid composition, free of monohydric alcohols, consisting of a propellant gas and an aqueous concentrate
- the propellant gas comprises a mixture of dimethyl ether and a hydrocarbon gas
- the concentrate aqueous comprises surfactants and preferably a coupling agent
- dimethyl ether is a flammable solvent, with a very low flash point use is therefore not free from risks, both for the production site and for the user of the aerosol device
- dimethyl ether has an unpleasant odor, capable of denaturing the fragrance of the composition
- Canadian patent CA1002256 discloses a transparent, uniform aerosol system usable for the distribution of transparent aqueous cosmetic products, including make-up removers.
- the use as a surfactant of a tethanolum salt of an acyllactylic acid makes it possible to obtain a system in which the propellant is completely dissolved in the aqueous phase
- a transparent aerosol system comprising a transparent foaming composition, free from alcohol, conditioned in aerosol
- This composition comprises an aqueous solution of a foaming surfactant, which is generally an anionic, in which a liquid propellant is dispersed thanks to a second surfactant, soluble in the propellant and insoluble in water
- transparent aerosol devices comprising a transparent, stable, foaming cosmetic composition, pressurized by a gas in particular hydrocarbon, free of monohydric alcohol in C r C 3 and comprising surfactants
- the subject of the invention is therefore a pressurized device comprising (i) a pressurized bottle provided with a dispensing head, (n) a single-phase transparent composition comprising A- 0.5 to 10% by weight of a propellant,
- composition B 90 to 99.5% by weight of an aqueous composition comprising nonionic surfactants and anionic surfactants, this device being capable of dispensing a foam when the dispensing head is actuated, characterized in that composition B comprises *
- the transparent monophasic composition is free of dialkyl ether and of monohydric alcohol in C r C 3
- compositions of the invention are dispensed in the form of a creamy foam which cleanses the skin without attacking it.
- the compositions distributed by this device make it possible to obtain a foam which is soft for the skin and for the mucous membranes (lips, inside of the eyelids), having remarkable cleansing properties, which allows its use for cleansing and removing make-up from the face, including for removing make-up from products known to be difficult to remove, such as "waterproof" make-up
- the pressurized bottles used in the invention are transparent.
- Such bottles are well known to those skilled in the art and in common use, one can for example refer to the patent application.
- WO95 / 05796 on the subject of these bottles They highlight in particular the surprising character of the invention through the bottle, a transparent emulsion is observed, having a fluidity comparable to that of water, said emulsion being restored in the form of '' a creamy foam through the dispensing means, and not in the form of a spray as expected a priori
- a bottle and a distribution means which can be used in the present invention are for example shown in patent application FR-95-12788
- propellant gases known for such applications can be used. Mention may in particular be made of hydrocarbon gases, such as, for example, propane, n-butane, isobutane and their mixtures, gases fluorinated, such as, for example, chlorodifluoromethane, dichlorodifluoromethane, difluoroethane, chlorodifuoroethane, dichlorotetrafluoroethane, etc. and their mixtures, nitrogen, air and carbon dioxide and their mixtures can also be used as propellants in the present invention.
- hydrocarbon gases having from 2 to 6 carbon atoms are used.
- compositions of the invention those having 1.5 to 6% by weight relative to the total weight of the composition of propellant are preferred.
- transparent means that through the bottle containing the composition one can distinguish the characters printed on a j ournal page placed behind this bottle This term also means that a sample of 10 cm thickness of composition a maximum light transmission of at least 4% in any wavelength between 200 nm and 800 nm
- the device according to the invention therefore comprises an aqueous composition B which comprises nonionic surfactants and anionic surfactants, in particular at least one nonionic emulsifying surfactant, at least one nonionic thickening surfactant, and at least one surfactant anionic Composition B therefore does not contain a cationic or amphoteric surfactant
- composition B is adjusted, and in particular the choice and the percentage of the thickener (s), so that this composition B has a Brookfield viscosity at 25 ° C of between 5 and 200 mPa s, and preferably between 10 and 150m Pa s
- the aqueous composition B comprises 1 to 25%, and even more preferably 3 to 12% by weight, of at least one non-lonic emulsifying surfactant
- the aqueous composition B comprises 0.5 to 30%, and even more preferably 1 to 6% by weight, of at least one nonionic thickening surfactant
- the nonionic emulsifying surfactants which can be used in the present invention are preferably chosen from those having an HLB balance of between 12 and 18.
- the HLB balance (hydrophilic-lipophilic balance) of an emulsifier is calculated according to the following formula
- these surfactants are chosen from the adducts of 1 to 200 moles of ethylene oxide or of propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 ato- carbon.
- products such as those described above are chosen having an esterification rate less than or equal to 2
- nonionic thickening surfactants which can be used in the present invention are preferably chosen from, alone or as a mixture, a- the C r C 6 alkanolamides of C8-C22 alkyl ether carboxylic acids, b- the adducts from 10 to 300 moles of ethylene oxide or propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 carbon atoms.
- esters are preferably having an esterification rate greater than or equal to 2, g- polyoxyethylenated and / or polyoxypropylenated and / or polyglycerolated C 12 -C 22 fatty alcohols, comprising from 20 to 500 ethylene oxide and / or propylene oxide residues and / or glycerol, d- C 12 -C 22 fatty esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerol, e- block polymers of polyethylene glycol and / or polypropylene glycol
- compositions according to the invention comprise at least two thickening surfactants each belonging to two different families, among the families of thickeners a a e described above.
- C r C 6 alkanolamide of C 8 -C 22 alkyl ether carboxylic acid denotes products corresponding to the formula
- R represents an alkyl chain having 8 to 30 carbon atoms
- R ' represents an alkyl chain having 1 to 6 carbon atoms
- Y represents an ethylene di-yl or propylene 1, 3-d ⁇ -yl radical and n represents a whole number from 0 to 100
- R can be chosen from stearyl, oleyl, ⁇ cinoleyl, linoleyl, lauryl, my ⁇ style, capryle, palmityl radicals or from mixtures of C 8 -C 22 alkyl radicals
- R can for example be chosen from methyl and ethyl radicals , n- propyl, isopropyl, terbutyl, n-hexyl
- partial polyol esters which can be used in the present invention, mention may be made in particular of those which are derived from glycol, glycerol and sugars, such as, for example, glucose, fructose, maltose, ⁇ bose, arabinose, xylose, lyxose, ribulose, xylulose, allose, altrose, mannose, gulose, galactose, sucrose, sorbitol
- sugars such as, for example, glucose, fructose, maltose, ⁇ bose, arabinose, xylose, lyxose, ribulose, xylulose, allose, altrose, mannose, gulose, galactose, sucrose, sorbitol
- thickening surfactants which can be used in the present invention, the following products may be mentioned, for example.
- castor oil monoethanolamides of alkyl acid (C 13 , C 15 ) carboxylic ether (2 EO), mo ⁇ oethanoiamide of ether carboxylic acid (50 EO), oxyethylenated tallow mono- and di-glycenes (200 EO), oxyethylenated tallow mono- and di-glycerides (82 EO), oxyethylenated coconut mono- and di-glycerides (78 EO), stearic and hydroxystearic acid triglycerides (40 EO), mono-stearate of polyethylene glycol (100 EO), the polyglycerolated dodecanediol alcohol (3, 5 mo.es) and more generally the products described in patent FR-2091516, oxyethylenated 2-octyl dodecanol (250 EO), alcohol oxye
- the following products may be mentioned, for example, the oxyethylenated glycerol mono- undecylenate (7 EO), the oxyethylene glycerol monostearate (15 EO), the glycerol mono-laurate oxyethylenated (20 EO), oxyethylenated glycerol di-laurate (20 EO), oxyethylenated di-glycerol stearate (4 EO), oxyethylenated giycerol cocoate (7 EO), monoisos pyrrolidone carboxylate- oxyethylenated glycerol tearate (250E), oxyethylenated glycerol mono stearate (20 EO), oxyethylenated glycerol monostearate (30 EO), oxyethylenated glycerol
- compositions of the present invention preferably comprise at least one thickening surfactant as defined above.
- the amount of thickener used is adapted to satisfy the viscosity criterion given above. An excessive amount of this type of compound can cause a significant thickening of the composition of the invention, which then becomes difficult to dispense in an aerosol. A quantity which is too small has the disadvantage of jeopardizing the stability of the composition.
- the aqueous composition B comprises from 2 to 12%, and even more preferably from 4 to 10% by weight of anionic surfactant.
- anionic can be chosen from those described in the document "Encyclopedia of Chemical Technology, KIRK-OTHMER", p.347-460, 3rd edition, WILEY
- the aqueous composition B comprises at least two anionic surfactants
- it comprises at least one foaming surfactant and at least one mild surfactant.
- foaming surfactant is preferably meant a surfactant chosen from sulfates, the sulphate ethers and their salts Among the sulphate and ether sulphate salts, the sodium and triethanolamine salts are preferably chosen.
- mild surfactant is preferably meant a surfactant chosen from sulphosuccinates, isethionates, carboxylates and sarcosinates
- compositions B also comprise at least one alkyl polyglucoside.
- this alkyl polyglucoside represents from 0.01 to 10%, and even more preferably from 1 to 6% by weight of B
- compositions B can comprise up to approximately 98% of water.
- water means pure demineralized water.
- all or part of the water used in compositions B can optionally be chosen from mineral and thermal waters. .
- mineral water is suitable for consumption, which is not always the case with thermal water
- Each of these waters contains, among other things, solubilized minerals and / or trace elements These waters are known for be used for specific treatment purposes according to the specific trace elements and minerals they contain, such as hydration and desensitization of the skin or the treatment of certain dermatoses
- mineral or thermal waters we will not only designate the natural mineral or thermal waters, but also natural mineral or thermal waters enriched with mineral constituents and / or additional elements, as well as aqueous mineral and / or mineral-element solutions prepared from purified water (demineralized or distilled)
- a natural thermal or mineral water used according to the invention can, for example, be chosen from Vittel water, the waters of the Vichy basin, U ⁇ age water, Roche Posay water, Bourboule, water from Engh ⁇ en-les-Ba ⁇ ns, water from Saint Gervais-les-Bains, water from Néns-les-Batns, water from Allevar-les-Bains, water from Digne, water from aizi Guatemala, water from Neyrac-les-Bains, water from Lons-le- Saunier, Eaux Bonnes, water from Rochefort, water from Saint Christau, water from Fumades and the water of Tercis-les-Bains, the water of Avene
- the cosmetic or dermatological compositions of the invention can, in addition, contain adjuvants customary in the fields concerned such as preservatives, antioxidants, perfumes, filters, coloring matters, hydrophilic or lipophilic active agents
- the active ingredients for the skin can be anti-aging active agents, anti-wrinkle active agents, moisturizers or humectants, depigmenting active agents, anti-free radical active agents (radical oxygen species), nutritive active agents, active protective, restructuring active, firming active, anti-acne active, exfoliating active, emollient active or active treating skin diseases such as yeast, dermatitis, psoriasis, etc.
- active agents are used, depending on their nature, in the usual proportions and for example from 0.01% to 10% by weight relative to the total weight of the composition.
- anti-acne, anti-aging, anti-wrinkle, hydrating, exfoliating active agents there may be mentioned more particularly ⁇ -hydroxy acids (glycolic, lactic, malic, citric, etc.).
- antioxidants there may be mentioned for example sulfites.
- Citric acid 1 9% Lactic acid 1, 7%
- the aqueous composition B is prepared by mixing, with stirring, all the ingredients mentioned.
- the viscosity of the aqueous composition B is measured: it is equal to 26 mPa.s.
- These compositions are then introduced into a pressurized bottle provided with a dispensing head into which the pressurized gas G is introduced. The whole is stirred so as to obtain a homogeneous mixture of the two initial phases.
- the devices and compositions according to Examples 1 and 2 are perfectly transparent and halo-free, both at the time of their preparation and after several months of storage at room temperature in a room benefiting from natural lighting By actuation of the head distribution, a creamy foam is obtained which is not very irritating and has good cleaning properties for human skin.
- a device comprising a halo is obtained as soon as it is prepared.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Materials Engineering (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Mechanical Engineering (AREA)
- Cosmetics (AREA)
Abstract
Description
Dispositif pressurisé à composition moussante comprenant des tensioac- tifs non-ioniques et anioniques Pressurized foaming device comprising nonionic and anionic surfactants
L'invention a pour objet de nouveaux dispositifs aérosols comprenant une composition cosmétique ou dermatologique nettoyante et démaquillante.The subject of the invention is new aerosol devices comprising a cosmetic or dermatological cleaning and make-up removing composition.
L'utilisateur attend d'une composition pour le nettoyage et le démaquillage de la peau qu'elle permette d'ôter toutes sortes de produits de maquillage rouge à lè- vres, poudre, ombre à paupières, fond de teint, etc., sans abîmer la peau et en la laissant propre et douce. Les démaquillants habituels sont généralement sous la forme d'un gel, d'une lotion ou d'une crème Toutefois, le marché attend de nouvelles formes de produits, à la fois plus esthétiques et éventuellement ludiques Pour repondre à cette attente, de nouveaux démaquillants sont apparus, sous la forme de dispositifs aérosols transparents, contenant une composition démaquillante transparente, monophasique et moussanteThe user expects a composition for cleaning and removing make-up from the skin that it makes it possible to remove all kinds of lipstick makeup products, powder, eye shadow, foundation, etc., without damaging the skin and leaving it clean and soft. The usual makeup removers are generally in the form of a gel, lotion or cream However, the market is waiting for new forms of products, both more aesthetic and possibly fun To meet this expectation, new makeup removers appeared, in the form of transparent aerosol devices, containing a transparent, single-phase and foaming makeup-removing composition
On connaît, en particulier par le brevet américain US 3,719,752, des compositions pour application topique, conditionnées en aérosols, moussantes, transpa- rentes, monophasiques et stables Ces compositions comprennent un tensioactif et un gaz propulseur dans un milieu hydroalcoolique L'alcool est de préférence un alcool monohydrique en CrC3 Toutefois l'emploi d'alcool, et en particulier d'éthanol, dans de telles compositions implique un risque lié à l'inflammabiiité On a par conséquent cherché à éviter l'emploi d'alcool monohydrique en C,-C, dans les compositions nettoyantes pour le visageKnown, in particular from US Pat. No. 3,719,752, compositions for topical application, conditioned in aerosols, foaming, transparent, monophasic and stable These compositions comprise a surfactant and a propellant in a hydroalcoholic medium The alcohol is preferably a monohydric alcohol in C r C 3 However, the use of alcohol, and in particular of ethanol, in such compositions involves a risk linked to inflammability. Consequently, attempts have been made to avoid the use of monohydric alcohol in C, -C, in facial cleansing compositions
De tels dispositifs exempts d'alcool monohydrique en CrC3 sont décrits en particulier par le document WO95/05796 Le dispositif décrit dans ce document comprend une composition monophasique, fluide, exempte d'alcool monohydrique, constituée d'un gaz propulseur hydrocarboné et d'un concentré aqueux comprenant des sels d'α-oléfine sulfonate, des bétaiπes et des alkylpolyglucosides Toutefois ce dispositif n'est pas dépourvu d'inconvénients • la composition qu'il renferme n'est pas stable dans le temps, en particulier on voit apparaître au stockage un halo d'agrégats en suspension dans la composition. La bouteille ae- rosol étant transparente, une telle instabilité n'est pas acceptable pour le consommateurSuch devices free of C r C 3 monohydric alcohol are described in particular in document WO95 / 05796 The device described in this document comprises a single-phase, fluid composition, free of monohydric alcohol, consisting of a hydrocarbon-based propellant and of an aqueous concentrate comprising α-olefin sulfonate salts, betaiπes and alkylpolyglucosides However this device is not without drawbacks • the composition it contains is not stable over time, in particular it sees a halo of aggregates suspended in the composition appear during storage. The aerosol bottle being transparent, such instability is not acceptable to the consumer.
Le document EP-676188 révèle un dispositif analogue, comprenant une composition monophasique, fluide, exempte d'alcools monohydrique, constituée d'un gaz propulseur et d'un concentré aqueux Le gaz propulseur comprend un mélange de diméthyléther et un gaz hydrocarboné, le concentré aqueux comprend des tensioactifs et préférentiellement un agent de couplage On sait par ailleurs que le dimethyléther est un solvant inflammable, de très bas point d'éclair Son utilisation n'est donc pas exempte de risques, aussi bien pour le site de production que pour l'utilisateur du dispositif aérosol En outre, le diméthyléther a une odeur désagréable, susceptible de dénaturer le parfum de la compositionDocument EP-676188 discloses a similar device, comprising a monophasic, fluid composition, free of monohydric alcohols, consisting of a propellant gas and an aqueous concentrate The propellant gas comprises a mixture of dimethyl ether and a hydrocarbon gas, the concentrate aqueous comprises surfactants and preferably a coupling agent We also know that dimethyl ether is a flammable solvent, with a very low flash point use is therefore not free from risks, both for the production site and for the user of the aerosol device In addition, dimethyl ether has an unpleasant odor, capable of denaturing the fragrance of the composition
Le brevet canadien CA1002256 révèle un système aérosol transparent, uniforme utilisable pour la distribution de produits cosmétiques aqueux transparents, dont des produits démaquillants L'utilisation comme tensioactif d'un sel de tπéthano- lamme d'un acide acyllactylique permet d'obtenir un système dans lequel le gaz propulseur est complètement dissous dans la phase aqueuseCanadian patent CA1002256 discloses a transparent, uniform aerosol system usable for the distribution of transparent aqueous cosmetic products, including make-up removers. The use as a surfactant of a tethanolum salt of an acyllactylic acid makes it possible to obtain a system in which the propellant is completely dissolved in the aqueous phase
On connaît par le brevet américain US 4,772,427 des gels douches pressurisés, à post-moussage, comprenant de l'eau, un alkyléther sulfate de métal alcalin, un alcool gras éthoxylé ou un ester gras éthoxyle, du myπstate d'isopropyle et un gaz propulseur incorporé à la structure de gel De tels produits peuvent être transparents ou opaques Le document ne divulgue ni ne suggère le moyen d'obtenir des dispositifs pressurises comprenant une composition moussante, transparente, stableUS patent 4,772,427 discloses pressurized, post-foaming shower gels comprising water, an alkali metal alkyl ether sulfate, an ethoxylated fatty alcohol or an ethoxylated fatty ester, isopropyl myπstate and a propellant incorporated into the gel structure Such products may be transparent or opaque The document does not disclose or suggest the means of obtaining pressurized devices comprising a foaming composition, transparent, stable
Le brevet américain US 3,840,465 révèle un système aérosol transparent com- prenant une composition transparente moussante, exempte d'alcool conditionnée en aérosol Cette composition comprend une solution aqueuse d'un tensioactif moussant, qui est généralement un anionique, dans laquelle est dispersé un propulseur liquide grâce a un second tensioactif, soluble dans le propulseur et insoluble dans l'eauAmerican patent US 3,840,465 discloses a transparent aerosol system comprising a transparent foaming composition, free from alcohol, conditioned in aerosol This composition comprises an aqueous solution of a foaming surfactant, which is generally an anionic, in which a liquid propellant is dispersed thanks to a second surfactant, soluble in the propellant and insoluble in water
On sait, en particulier par le document US 3,719,752 et par l'instabilité de certaines compositions, que de telles compositions sont extrêmement sensibles a de petites variations dans les composants dont elles sont constituées et dans les proportions de ces composantsIt is known, in particular from document US Pat.
Aussi c'est avec étonnement que la demanderesse a découvert qu'il était possible de disposer de dispositifs aérosols transparents, comprenant une composition cosmétique transparente, stable, moussante, pressurisée par un gaz notamment hydrocarboné, exempte d'alcool monohydrique en CrC3 et comprenant des ten- sioactifsAlso it is with astonishment that the Applicant has discovered that it was possible to have transparent aerosol devices, comprising a transparent, stable, foaming cosmetic composition, pressurized by a gas in particular hydrocarbon, free of monohydric alcohol in C r C 3 and comprising surfactants
L invention a donc pour objet un dispositif pressurisé comprenant (i) une bouteille pressurisée munie d'une tête de distribution, (n) une composition transparente monophasique comprenant A- 0,5 à 10% en poids d'un gaz propulseur,The subject of the invention is therefore a pressurized device comprising (i) a pressurized bottle provided with a dispensing head, (n) a single-phase transparent composition comprising A- 0.5 to 10% by weight of a propellant,
B- 90 à 99,5% en poids d'une composition aqueuse comprenant des tensioactifs non-ioniques et des tensioactifs anioniques, ce dispositif étant apte a distribuer une mousse lorsque l'on actionne la tête de distribution, caractérisé en ce que la composition B comprend * B- 90 to 99.5% by weight of an aqueous composition comprising nonionic surfactants and anionic surfactants, this device being capable of dispensing a foam when the dispensing head is actuated, characterized in that composition B comprises *
(a) au moins un tensioactif émulsionnant non-ionique,(a) at least one nonionic emulsifying surfactant,
(b) au moins un tensioactif épaississant non-ionique, et (c) au moins un tensioactif anionique(b) at least one nonionic thickening surfactant, and (c) at least one anionic surfactant
De préférence, la composition transparente monophasique est exempte de dial- kyléther et d'alcool monohydrique en CrC3 Preferably, the transparent monophasic composition is free of dialkyl ether and of monohydric alcohol in C r C 3
Lorsque l'on actionne le bouton-poussoir faisant partie de la tête de distribution, les compositions de l'invention sont distribuées sous la forme d'une mousse crémeuse qui nettoie la peau sans l'agresser. Les compositions distribuées par ce dispositif permettent l'obtention d'une mousse douce pour la peau et pour les muqueuses (lèvres, intérieur des paupières), ayant des propriétés nettoyantes remarquables, ce qui permet son utilisation pour le nettoyage et le démaquillage du visage, y compris pour le démaquillage de produits réputés difficiles a démaquiller, comme les maquillages « waterproof »When the push button forming part of the dispensing head is actuated, the compositions of the invention are dispensed in the form of a creamy foam which cleanses the skin without attacking it. The compositions distributed by this device make it possible to obtain a foam which is soft for the skin and for the mucous membranes (lips, inside of the eyelids), having remarkable cleansing properties, which allows its use for cleansing and removing make-up from the face, including for removing make-up from products known to be difficult to remove, such as "waterproof" make-up
De façon préférentielle, les bouteilles pressurisées utilisées dans l'invention sont transparentes. De telles bouteilles sont bien connues de l'homme du métier et d'utilisation courante, on pourra par exemple se référer à la demande de brevetPreferably, the pressurized bottles used in the invention are transparent. Such bottles are well known to those skilled in the art and in common use, one can for example refer to the patent application.
WO95/05796 au sujet de ces bouteilles Elles mettent particulièrement en valeur le caractère surprenant de l'invention au travers de la bouteille on observe une emulsion transparente, ayant une fluidité comparable à celle de l'eau, ladite emulsion étant restituée sous la forme d'une mousse onctueuse au travers du moyen de distribution, et non sous la forme d'un spray comme on s'y attend a priori On peut utiliser n'importe quel moyen de distribution de bouteille aérosol connu de l'homme du métier Une bouteille et un moyen de distribution pouvant être utilises dans la présente invention sont par exemple représentés dans la demande de brevet FR-95-12788WO95 / 05796 on the subject of these bottles They highlight in particular the surprising character of the invention through the bottle, a transparent emulsion is observed, having a fluidity comparable to that of water, said emulsion being restored in the form of '' a creamy foam through the dispensing means, and not in the form of a spray as expected a priori We can use any means of dispensing aerosol bottle known to those skilled in the art A bottle and a distribution means which can be used in the present invention are for example shown in patent application FR-95-12788
On peut utiliser dans les dispositifs selon l'invention tous les gaz propulseurs connus pour de telles applications On peut citer en particulier les gaz hydrocarbones, comme par exemple le propane, le n-butane, l'isobutane et leurs mélan- ges , les gaz fluorés comme par exemple ie chlorodifluorométhane, le dichlorodi- fluoromethane, le difluoroéthane, le chlorodifiuoroéthane, le dichlorotetrafluo- roéthane, etc. et leurs mélanges , l'azote, l'air et le dioxyde de carbone et leurs mélanges peuvent également être utilisés comme gaz propulseurs dans la présente invention De façon préférentielle, on utilise dans la présente invention des gaz hydrocarbonés ayant de 2 à 6 atomes de carbone Parmi les compositions de l'invention, on préfère celles ayant de 1 ,5 à 6% en poids par rapport au poids total de la composition, de gaz propulseur Le mot « transparent » signifie qu'au travers de la bouteille contenant la composition on peut distinguer les caractères imprimés sur une page de journal placée derrière cette bouteille Ce terme signifie également qu'un échantillon de 10 cm d'épaisseur de la composition a une transmission maximum de la lumière d'au moins 4% dans n'importe quelle longueur d'onde comprise entre 200 nm et 800 nmIn the devices according to the invention, all the propellant gases known for such applications can be used. Mention may in particular be made of hydrocarbon gases, such as, for example, propane, n-butane, isobutane and their mixtures, gases fluorinated, such as, for example, chlorodifluoromethane, dichlorodifluoromethane, difluoroethane, chlorodifuoroethane, dichlorotetrafluoroethane, etc. and their mixtures, nitrogen, air and carbon dioxide and their mixtures can also be used as propellants in the present invention. Preferably, in the present invention, hydrocarbon gases having from 2 to 6 carbon atoms are used. carbon Among the compositions of the invention, those having 1.5 to 6% by weight relative to the total weight of the composition of propellant are preferred The word "transparent" means that through the bottle containing the composition one can distinguish the characters printed on a j ournal page placed behind this bottle This term also means that a sample of 10 cm thickness of composition a maximum light transmission of at least 4% in any wavelength between 200 nm and 800 nm
Le dispositif selon l'invention comprend donc une composition aqueuse B qui comprend des tensioactifs non-ioniques et des tensioactifs anioniques, notam- ment au moins un tensioactif émulsionnant non-ionique, au moins un tensioactif épaississant non-ionique, et au moins un tensioactif anionique La composition B ne comprend donc pas de tensioactif cationique ou amphotereThe device according to the invention therefore comprises an aqueous composition B which comprises nonionic surfactants and anionic surfactants, in particular at least one nonionic emulsifying surfactant, at least one nonionic thickening surfactant, and at least one surfactant anionic Composition B therefore does not contain a cationic or amphoteric surfactant
De préférence, la composition B est ajustée, et en particulier le choix et le pour- centage du ou des épaississants, de telle sorte que cette composition B ait une viscosité Brookfield à 25°C comprise entre 5 et 200 mPa s, et de préférence entre 10 et 150m Pa sPreferably, composition B is adjusted, and in particular the choice and the percentage of the thickener (s), so that this composition B has a Brookfield viscosity at 25 ° C of between 5 and 200 mPa s, and preferably between 10 and 150m Pa s
De préférence, la composition aqueuse B comprend 1 à 25%, et encore plus préferentiellement 3 à 12% en poids, d'au moins un tensioactif émulsionnant non- loniquePreferably, the aqueous composition B comprises 1 to 25%, and even more preferably 3 to 12% by weight, of at least one non-lonic emulsifying surfactant
De façon avantageuse, la composition aqueuse B comprend 0,5 à 30%, et encore plus préferentiellement 1 à 6% en poids, d'au moins un tensioactif épaississant non-ioniqueAdvantageously, the aqueous composition B comprises 0.5 to 30%, and even more preferably 1 to 6% by weight, of at least one nonionic thickening surfactant
On peut se reporter au document « Encyclopedia of Chemical Technology, KIRK- OTHMER », volume 22, p 333-432, 3eme édition, 1979, WILEY, pour la définition des propriétés et des fonctions (émulsionnant, épaississant) des tensioactifs, en particulier p 360-377 de cette référence, pour les tensioactifs non-ioniquesReference may be made to the document “Encyclopedia of Chemical Technology, KIRK-OTHMER”, volume 22, p 333-432, 3rd edition, 1979, WILEY, for the definition of the properties and functions (emulsifier, thickener) of the surfactants, in particular p 360-377 of this reference, for nonionic surfactants
Les tensioactifs emulsionnants non-ioniques utilisables dans la présente invention sont préferentiellement choisis parmi ceux ayant une balance HLB comprise entre 12 et 18 On calcule la balance HLB (balance hydrophile-lipophile) d'un émulsionnant suivant la formule suivanteThe nonionic emulsifying surfactants which can be used in the present invention are preferably chosen from those having an HLB balance of between 12 and 18. The HLB balance (hydrophilic-lipophilic balance) of an emulsifier is calculated according to the following formula
100-L HLB=100-L HLB =
5 dans laquelle L représente le pourcentage en poids du groupement pophile par rapport au poids de la molécule entière5 in which L represents the percentage by weight of the population group relative to the weight of the whole molecule
Préferentiellement, ces tensioactifs sont choisis parmi les produits d'addition de 1 à 200 moles d'oxyde d'éthylene ou d'oxyde de propylene sur des esters partiels de polyols ayant 2 à 16 atomes de carbone et d'acides gras ayant 12 à 22 ato- mes de carbone. Avantageusement, on choisit des produits tels que ceux décrits ci-dessus ayant un taux d'estérification inférieur ou égal à 2Preferably, these surfactants are chosen from the adducts of 1 to 200 moles of ethylene oxide or of propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 ato- carbon. Advantageously, products such as those described above are chosen having an esterification rate less than or equal to 2
Les tensioactifs épaississants non-ioniques utilisables dans la présente invention sont préferentiellement choisis parmi, seuls ou en mélange, a- les CrC6 alcanolamides d'acides C8-C22 alkyl éther carboxyliques , b- les produits d'addition de 10 à 300 moles d'oxyde d'éthylene ou d'oxyde de propylene sur des esters partiels de polyols ayant 2 à 16 atomes de carbone et d'acides gras ayant 12 à 22 atomes de carbone Parmi cette famille de pro- duits, on choisit préferentiellement ceux ayant un taux d'estérification supérieur ou égal à 2 , g- les alcools gras en C12-C22 polyoxyéthylénés et/ou polyoxypropylénés et/ou polyglycérolés, comportant de 20 à 500 résidus oxyde d'éthylene et/ou oxyde de propylene et/ou glycérol, d- les esters gras en C12-C22 de polyoxyéthylene et/ou de polyoxypropylène et/ou de polyglycérol, e- les polymères blocs de poiyéthyiène glycol et/ou de polypropylène glycolThe nonionic thickening surfactants which can be used in the present invention are preferably chosen from, alone or as a mixture, a- the C r C 6 alkanolamides of C8-C22 alkyl ether carboxylic acids, b- the adducts from 10 to 300 moles of ethylene oxide or propylene oxide on partial esters of polyols having 2 to 16 carbon atoms and of fatty acids having 12 to 22 carbon atoms. Among this family of products, those chosen are preferably having an esterification rate greater than or equal to 2, g- polyoxyethylenated and / or polyoxypropylenated and / or polyglycerolated C 12 -C 22 fatty alcohols, comprising from 20 to 500 ethylene oxide and / or propylene oxide residues and / or glycerol, d- C 12 -C 22 fatty esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerol, e- block polymers of polyethylene glycol and / or polypropylene glycol
Avantageusement, les compositions selon l'invention comprennent au moins deux tensioactifs épaississants appartenant chacun à deux familles différentes, parmi les familles d'épaississants a a e décrites ci-dessusAdvantageously, the compositions according to the invention comprise at least two thickening surfactants each belonging to two different families, among the families of thickeners a a e described above.
Par CrC6 alcanolamide d'acide C8-C22 alkyl éther carboxylique, on désigne des produits repondant à la formuleThe term C r C 6 alkanolamide of C 8 -C 22 alkyl ether carboxylic acid denotes products corresponding to the formula
OO
R-(OY)n-OCH2C NH ROHR- (OY) n -OCH 2 C NH ROH
(D(D
dans laquelle R représente une chaîne alkyle ayant 8 à 30 atomes de carbone, R' représente une chaîne alkyle ayant 1 à 6 atomes de carbone, Y représente un radical éthylène di-yle ou propylene 1 ,3-dι-yle et n représente un nombre entier allant de 0 à 100in which R represents an alkyl chain having 8 to 30 carbon atoms, R 'represents an alkyl chain having 1 to 6 carbon atoms, Y represents an ethylene di-yl or propylene 1, 3-dι-yl radical and n represents a whole number from 0 to 100
Par exemple, R peut être choisi parmi les radicaux stéaryle, oléyle, πcinoléyle, linoleyle, lauryle, myπstyle, capryle, palmityle ou parmi des mélanges de radicaux alkyles en C8-C22 R peut par exemple être choisi parmi les radicaux méthyle, éthyle, n- propyle, isopropyle, terbutyle, n-hexyleFor example, R can be chosen from stearyl, oleyl, πcinoleyl, linoleyl, lauryl, myπstyle, capryle, palmityl radicals or from mixtures of C 8 -C 22 alkyl radicals R can for example be chosen from methyl and ethyl radicals , n- propyl, isopropyl, terbutyl, n-hexyl
Parmi les esters partiels de polyols utilisables dans la présente invention, on peut citer particulièrement ceux qui dérivent du glycol, du glycérol et des sucres, comme par exemple du glucose, du fructose, du maltose, du πbose, de l'arabinose, du xylose, du lyxose, du ribulose, du xylulose, de l'allose, de l'altrose, du mannose, du gulose, du galactose, du saccharose, du sorbitolAmong the partial polyol esters which can be used in the present invention, mention may be made in particular of those which are derived from glycol, glycerol and sugars, such as, for example, glucose, fructose, maltose, πbose, arabinose, xylose, lyxose, ribulose, xylulose, allose, altrose, mannose, gulose, galactose, sucrose, sorbitol
Parmi les tensioactifs épaississants utilisables dans la présente invention on peut citer par exemple les produits suivants . l'huile de ricin, les monoéthanolamides d'acide alkyl (C13, C15) éther carboxylique (2 OE), la moπoéthanoiamide d'acide éther carboxylique (50 OE), les mono- et di-glycéndes de suif oxyéthylénés (200 OE), les mono- et di-glycérides de suif oxyéthylénés (82 OE), les mono- et di- glycéπdes de coprah oxyéthylénés (78 OE), les triglycérides d'acide stéaπque et hydroxystéarique (40 OE), le mono-stéarate de polyéthylène glycol (100 OE), l'alcool dodécanediol polyglycérolé (3, 5mo.es) et de façon plus générale les produits décrits dans le brevet FR-2091516, l'octyl-2 dodécanol oxyéthyléné (250 OE), l'alcool stearylique oxyéthyléné (100 OE), l'alcool oléique oxyéthyléné (50 OE), le di-oléate de polyéthylène glycol (50 OE), ie palmitate de glycérol oxy- éthyléné (200 OE), le tn-isostéarate de sorbitane oxyéthyléné (160 OE), le tri- isostéarate de sorbitane oxyéthyléné (200 OE), le stéarate de polyéthylèneglycol (150 OE), ), le di-oléate de méthyl glucose oxyéthyléné (120 OE), le tétra-stearate de penta-érythπtyle oxyéthyléné (150 OE), le di-oléate de polyéthylène glycol (55 OE), l'undécylénate de polyéthylène glycol (300 OE), le di-stéarate de polyéthy- lène glycol (150 OE).Among the thickening surfactants which can be used in the present invention, the following products may be mentioned, for example. castor oil, monoethanolamides of alkyl acid (C 13 , C 15 ) carboxylic ether (2 EO), moπoethanoiamide of ether carboxylic acid (50 EO), oxyethylenated tallow mono- and di-glycenes (200 EO), oxyethylenated tallow mono- and di-glycerides (82 EO), oxyethylenated coconut mono- and di-glycerides (78 EO), stearic and hydroxystearic acid triglycerides (40 EO), mono-stearate of polyethylene glycol (100 EO), the polyglycerolated dodecanediol alcohol (3, 5 mo.es) and more generally the products described in patent FR-2091516, oxyethylenated 2-octyl dodecanol (250 EO), alcohol oxyethylenated stearyl (100 EO), oxyethylenated oleic alcohol (50 EO), polyethylene glycol di-oleate (50 EO), ie oxyethylenated glycerol palmitate (200 EO), sorbitan tn-isostearate oxyethylenated (160 EO), oxyethylenated sorbitan triisostearate (200 EO), polyethylene glycol stearate (150 EO),), di- oxyethylenated methyl glucose oleate (120 EO), oxyethylenated penta-erythrytyl tetra-stearate (150 EO), polyethylene glycol di-oleate (55 EO), polyethylene glycol undecylenate (300 EO), di- polyethylene glycol stearate (150 EO).
Parmi les esters de polyols polyoxyalkylénes utilisables comme tensio-actifs emulsionnants on peut citer par exemple les produits suivants le mono- undécylenate de glycérol oxyéthyléné (7 OE), le monostéarate de glycérol oxy- éthylène (15 OE), le mono-laurate de glycérol oxyéthyléné (20 OE), le di-laurate de glycérol oxyéthyléné (20 OE), le stéarate de di-glycérol oxyéthyléné (4 OE), le cocoate de giycerol oxyéthyléné (7 OE), le pyrrolidone carboxylate de monoisos- tearate de glycérol oxyéthyléné (250E), le mono stéarate de glycérol oxyéthyléné (20 OE), le monostéarate de glycérol oxyéthyléné (30 OE), le stéarate de di- glycérol oxyéthyléné (4 OE), les mono- et di-glycéπdes de coprah oxyéthyléné (30 OE), le lanolate de sorbitane oxyéthyléné (40 OE), le mono-oléate de sorbi- tane oxyéthyléné (20 OE), le tri-oléate de sorbitane oxyéthyléné (20 OE), le mo- no-palmitate de sorbitane oxyéthyléné (20 OE), ie mono-stéarate de sorbitane oxyéthyléné (20 OE), le mono-laurate de sorbitane oxyéthyléné (20 OE), l'undécylénate de sorbitane oxyéthyléné (20 OE), I undécylénate de sorbitane oxyéthyléné (18 OE), l'hexa-stéarate de sorbitane oxyéthyléné (6 OE), le mono- laurate de sorbitane oxyéthyléné (44 OE), le tétra-oléate de sorbitane oxyéthyléné (30 OE), le mono-stéarate de sorbitane oxyéthyléné (4 OE), l'oléate de sorbitane oxyéthyléné (40 OE), le mono-laurate de sorbitane oxyéthyléné (4 OE), le mono-laurate de sorbitane oxyéthyléné (10 OE), le tétra-oléate de sorbitane oxyéthyléné (40 OE), le cocoate de butyl glucoside oxyéthyléné (3 OE), le di-stearate de méthyl glucoside oxypropyléné (20 OP), le mono-laurate de méthyl glucoside oxyéthyléné (20 OE), le benzoate de méthyl glucose oxyéthyiéné (20 OE), les esters de tπ-glycérides de ricin et de saccharose oxyéthylénés (1 ,4 OE), les esters de tπ-glycéπdes de ricin et de saccharose oxyéthylénés (2 OE), le sesquis- téarate de méthyl glucose oxyéthyléné (20 OE), le di-stéarate de méthyl glucose oxyéthyléné (20 OE), le mono-stéarate de butanediol oxyéthyléné (4 OE), le mo- no-stéarate de polyéthylène glycol oxyéthyléné (50 OE), le di-stéarate de polyéthylène glycol, le myπstate de polyéthylène glycol (8 OE), le mono-stéarate de polyéthylène glycol (8 OE), le mono-stéarate de polyéthylène glycol (20 OE), le laurate de polyéthylène glycol (6 OE), le di-stéarate de polyéthylène glycol (8 OE), le di-laurate de polyéthylène glycol (8 OE), le mono-oiéate de polyéthylène glycol (8 OE), le di-heptanoate de tétra-éthylene glycol, le di-oléate de polyéthylène glycol (8 OE), l'oléate de polypropylène glycol (26 OE), le di- polyhydroxystearate (6 hydroxy) de polyéthylène glycol (30 OE), le stéarate de polyéthylène glycol (40 OE), le di-laurate de polyéthylène glycol (8 OE)Among the polyoxyalkylene polyol esters which can be used as emulsifying surfactants, the following products may be mentioned, for example, the oxyethylenated glycerol mono- undecylenate (7 EO), the oxyethylene glycerol monostearate (15 EO), the glycerol mono-laurate oxyethylenated (20 EO), oxyethylenated glycerol di-laurate (20 EO), oxyethylenated di-glycerol stearate (4 EO), oxyethylenated giycerol cocoate (7 EO), monoisos pyrrolidone carboxylate- oxyethylenated glycerol tearate (250E), oxyethylenated glycerol mono stearate (20 EO), oxyethylenated glycerol monostearate (30 EO), oxyethylenated glycerol stearate (4 EO), oxyethylenated coconut mono- and di-glycerides (30 EO) ), oxyethylenated sorbitan lanolate (40 EO), oxyethylenated sorbitane mono-oleate (20 EO), oxyethylenated sorbitan trioleate (20 EO), oxyethylenated sorbitan mo-palmitate (20 EO) ), ie mono-stearate of so oxyethylenated rbitane (20 EO), oxyethylenated sorbitan mono-laurate (20 EO), oxyethylenated sorbitan undecylenate (20 EO), Oxyethylenated sorbitan undecylenate (18 EO), oxyethylenated sorbitan hexa-stearate (6 EO), oxyethylenated sorbitan mono-laurate (44 EO), oxyethylenated sorbitan tetra-oleate (30 EO), oxyethylenated sorbitan mono-stearate (4 EO), oxyethylenated sorbitan oleate (40 EO), oxyethylenated sorbitan mono-laurate (4 EO), oxyethylenated sorbitan mono-laurate (10 EO), oxyethylenated sorbitan tetra-oleate (40 EO), butyl glucoside oxyethylenated (3 EO) cocoate, di- oxypropylenated methyl glucoside stearate (20 OP), oxyethylenated methyl glucoside mono-laurate (20 EO), oxyethylenated methyl glucose benzoate (20 EO), esters of oxyethylenated castor and sucrose tπ-glycerides (1, 4 EO), oxyethylenated tic glyceride and castor esters (2 EO), oxyethylenated methyl glucose sesear tearate (20 EO), di - oxyethylenated methyl glucose stearate (20 EO), oxyethylenated butanediol mono-stearate (4 EO), oxyethylenated polyethylene glycol monostearate (50 EO), polyethylene glycol di-stearate, polyethylene myπstate glycol (8 EO), polyethylene glycol mono-stearate (8 EO), polyethylene glycol mono-stearate (20 EO), polyethylene glycol laurate (6 EO), polyethylene glycol di-stearate (8 EO) ), polyethylene glycol di-laurate (8 EO), polyethylene glycol mono-oleate (8 EO), tetra-ethylene glycol di-heptanoate, polyethylene glycol di-oleate (8 EO), polypropylene glycol oleate (26 EO), polyethylene glycol di-polyhydroxystearate (6 hydroxy) (30 EO), st polyethylene glycol arate (40 EO), polyethylene glycol di-laurate (8 EO)
Parmi les produits utilisables dans la présente invention, disponibles commercialement, on peut citerAmong the products which can be used in the present invention, which are commercially available, mention may be made of
- les CrC6 alcanoiamides d'acides C8-C22 alkyl éther carboxylique qui sont par exemple commercialisés par la société HENKEL sous la marque COMPERLAN, ou par la société CHEM Y sous le nom de marque AMINOL , - les produits d'addition d'oxyde d'éthylene ou d'oxyde de propylene sur des esters partiels de polyols et d'acides gras, qui sont par exemple commercialisés par la société BASF sous la marque CREMOPHOR, ou par la société AMERCHOL sous la marque GLUCAMATE ,- C r C 6 alkanoiamides of C 8 -C 22 alkyl ether carboxylic acids which are for example marketed by the company HENKEL under the brand COMPERLAN, or by the company CHEM Y under the brand name AMINOL, - the products of addition of ethylene oxide or propylene oxide on partial esters of polyols and fatty acids, which are for example marketed by the company BASF under the brand CREMOPHOR, or by the company AMERCHOL under the brand GLUCAMATE,
- les alcools gras en C,2-C22 polyoxyéthylenes et/ou polyoxypropylénes et/ou polyglyceroles, qui sont par exemple commercialisés par la société ICI sous la marque BRU ,polyoxyethylenes and / or polyoxypropylenes and / or polyglyceroles, C, 2 -C 22 fatty alcohols, which are for example marketed by the company ICI under the brand BRU,
- les esters gras en C12-C22 de polyoxyethylene et/ou de polyoxypropylene et/ou de polyglycérol, qui sont par exemple commercialises par la société ICI sous la marque MYRJ , - les polymères blocs de polyéthylène glycol et/ou de polypropylène glycol, qui sont par exemple commercialisés par la société ICI sous la marque SYNPERONIC- C 12 -C 22 fatty esters of polyoxyethylene and / or polyoxypropylene and / or polyglycerol, which are for example marketed by the company ICI under the brand MYRJ, - block polymers of polyethylene glycol and / or polypropylene glycol , which are for example marketed by ICI under the brand SYNPERONIC
Les compositions de la présente invention comprennent de préférence au moins un tensioactif épaississant tel que défini ci-dessus En pratique, la quantité d'épaississant utilisée est adaptée pour satisfaire ie critère de viscosité donné ci- dessus Une quantité excessive de ce type de composé peut entraîner un epais- sissement important de la composition de l'invention, qui devient alors difficile a distribuer en aérosol Une quantité trop faible présente l'inconvénient de mettre en péril la stabilité de la composition.The compositions of the present invention preferably comprise at least one thickening surfactant as defined above. In practice, the amount of thickener used is adapted to satisfy the viscosity criterion given above. An excessive amount of this type of compound can cause a significant thickening of the composition of the invention, which then becomes difficult to dispense in an aerosol. A quantity which is too small has the disadvantage of jeopardizing the stability of the composition.
De préférence, la composition aqueuse B comprend de 2 à 12%, et encore plus préferentiellement de 4 a 10% en poids de tensioactif anionique Ce tensioactif anionique peut être choisi parmi ceux décrits dans le document « Encyclopedia of Chemical Technology, KIRK-OTHMER », p.347-460, 3eme édition, WILEYPreferably, the aqueous composition B comprises from 2 to 12%, and even more preferably from 4 to 10% by weight of anionic surfactant. This surfactant anionic can be chosen from those described in the document "Encyclopedia of Chemical Technology, KIRK-OTHMER", p.347-460, 3rd edition, WILEY
Selon un mode préféré de réalisation de l'invention, la composition aqueuse B comprend au moins deux tensioactifs anioniques Avantageusement, elle comprend au moins un tensioactif moussant et au moins un tensioactif doux Par tensioactif moussant on entend de préférence un tensioactif choisi parmi les sulfates, les éthers sulfates et leurs sels Parmi les sels de sulfate et d'éther sulfates, on choisit préferentiellement les sels de sodium et de triéthanolamme Par tensioactif doux on entend de préférence un tensioactif choisi parmi les sulfo- succinates, les iséthionates, les carboxylates et les sarcosinatesAccording to a preferred embodiment of the invention, the aqueous composition B comprises at least two anionic surfactants Advantageously, it comprises at least one foaming surfactant and at least one mild surfactant. By foaming surfactant is preferably meant a surfactant chosen from sulfates, the sulphate ethers and their salts Among the sulphate and ether sulphate salts, the sodium and triethanolamine salts are preferably chosen. By mild surfactant is preferably meant a surfactant chosen from sulphosuccinates, isethionates, carboxylates and sarcosinates
Avantageusement les compositions B comprennent en outre au moins un alkyl- polyglucoside De façon préférentielle, cet alkylpolyglucoside représente de 0,01 a 10%, et encore plus préferentiellement de 1 à 6% en poids de BAdvantageously, the compositions B also comprise at least one alkyl polyglucoside. Preferably, this alkyl polyglucoside represents from 0.01 to 10%, and even more preferably from 1 to 6% by weight of B
Les compositions B peuvent comprendre jusqu'à environ 98% d'eau Habituellement, on entend par eau, de l'eau pure déminéralisée Toutefois tout ou partie de l'eau utilisée dans les compositions B peut éventuellement être choisie parmi les eaux minérales etyou thermales. En général, une eau minérale est propre à la consommation, ce qui n'est pas toujours le cas d'une eau thermale Chacune de ces eaux contient, entre autre, des minéraux solubilises et/ou des oligo-élements Ces eaux sont connues pour être employées à des fins de traitement spécifique selon les oligo-éléments et les minéraux particuliers qu'elles contiennent, tels que l'hydratation et la desensibilisation de la peau ou le traitement de certaines dermatoses Par eaux minérales ou thermales, on désignera non seulement les eaux minérales ou thermales naturelles, mais également des eaux minérales ou thermales naturelles enrichies en constituants minéraux et/ou en o go-élements supplémentaires, ainsi que des solutions aqueuses minérales et/ou oiigo- élémentaires préparées à partir d'eau purifiée (déminéralisée ou distillée)The compositions B can comprise up to approximately 98% of water. Usually, the term “water” means pure demineralized water. However, all or part of the water used in compositions B can optionally be chosen from mineral and thermal waters. . In general, mineral water is suitable for consumption, which is not always the case with thermal water Each of these waters contains, among other things, solubilized minerals and / or trace elements These waters are known for be used for specific treatment purposes according to the specific trace elements and minerals they contain, such as hydration and desensitization of the skin or the treatment of certain dermatoses By mineral or thermal waters, we will not only designate the natural mineral or thermal waters, but also natural mineral or thermal waters enriched with mineral constituents and / or additional elements, as well as aqueous mineral and / or mineral-element solutions prepared from purified water (demineralized or distilled)
Une eau thermale ou minérale naturelle utilisée selon l'invention peut, par exemple être choisie parmi l'eau de Vittel, les eaux du bassin de Vichy, l'eau d'Uπage, l'eau de la Roche Posay, l'eau de la Bourboule, l'eau d'Enghιen-les-Baιns, l'eau de Saint Gervais-les-Bains, l'eau de Néns-les-Batns, l'eau d'Allevar-les-Bains, l'eau de Digne, l'eau de aizières, l'eau de Neyrac-les-Bains, l'eau de Lons-le- Saunier, les Eaux Bonnes, l'eau de Rochefort, l'eau de Saint Christau, l'eau des Fumades et l'eau de Tercis-les-bains, l'eau d'AveneA natural thermal or mineral water used according to the invention can, for example, be chosen from Vittel water, the waters of the Vichy basin, Uπage water, Roche Posay water, Bourboule, water from Enghιen-les-Baιns, water from Saint Gervais-les-Bains, water from Néns-les-Batns, water from Allevar-les-Bains, water from Digne, water from aizières, water from Neyrac-les-Bains, water from Lons-le- Saunier, Eaux Bonnes, water from Rochefort, water from Saint Christau, water from Fumades and the water of Tercis-les-Bains, the water of Avene
Les compositions cosmétiques ou dermatologiques de l'invention peuvent, en outre, contenir des adjuvants habituels dans les domaines concernes tels que les conservateurs, les antioxydants, les parfums, les filtres, les matières colorantes, les actifs hydrophiles ou lipophiles Les actifs pour la peau peuvent être des actifs anti-âge, des actifs anti-rides, des hydratants ou des humectants, des actifs dépigmentants, des actifs anti-radicaux libres (espèces radicalaires de l'oxygène), des actifs nutritifs, des actifs protecteurs, des actifs restructurants, des actifs raffermissants, des actifs antiacnéiques, des actifs exfoliants, des actifs émollients ou encore des actifs traitants des maladies de peau comme les mycoses, les dermites, le psoriasis, etc. Ces actifs sont utilisés, selon leur nature, dans les proportions habituelles et par exemple de 0,01 % à 10 % en poids par rapport au poids total de la composition. Comme actifs anti-acnéiques, anti-âge, anti-ride, hydratants, exfoliants, on peut citer plus particulièrement les α-hydroxy-acides (acides glycolique, lactique, mali- que, citrique, etc.). Comme anti-oxydants, on peut citer par exemple les sulfites.The cosmetic or dermatological compositions of the invention can, in addition, contain adjuvants customary in the fields concerned such as preservatives, antioxidants, perfumes, filters, coloring matters, hydrophilic or lipophilic active agents The active ingredients for the skin can be anti-aging active agents, anti-wrinkle active agents, moisturizers or humectants, depigmenting active agents, anti-free radical active agents (radical oxygen species), nutritive active agents, active protective, restructuring active, firming active, anti-acne active, exfoliating active, emollient active or active treating skin diseases such as yeast, dermatitis, psoriasis, etc. These active agents are used, depending on their nature, in the usual proportions and for example from 0.01% to 10% by weight relative to the total weight of the composition. As anti-acne, anti-aging, anti-wrinkle, hydrating, exfoliating active agents, there may be mentioned more particularly α-hydroxy acids (glycolic, lactic, malic, citric, etc.). As antioxidants, there may be mentioned for example sulfites.
Les exemples suivants sont donnés à titre d'illustration de l'invention et n'ont pas de caractère limitatif.The following examples are given by way of illustration of the invention and are not intended to be limiting.
Toutes les quantités sont données en pourcentage en poids de matière active par rapport au poids total de la composition. Les matières premières sont données en nom CTFA. La viscosité est mesurée à 25°C à l'aide d'un viscosimètre Brookfield dont la vitesse du module tournant (module I) est fixée à 5 tours/min.All the amounts are given as a percentage by weight of active material relative to the total weight of the composition. The raw materials are given in CTFA name. The viscosity is measured at 25 ° C. using a Brookfield viscometer, the speed of the rotating module (module I) is fixed at 5 revolutions / min.
Exemple 1 : G :Example 1: G:
Isobutane 4 % B : Sodium laureth sulfate 8 %Isobutane 4% B: Sodium laureth sulfate 8%
Laureth-66 PPG-14 dicarbamate 3 %Laureth-66 PPG-14 dicarbamate 3%
Decyl glucoside 2,4 %Decyl glucoside 2.4%
Disodium laureth sulfosuccinate 1 ,9 %Disodium laureth sulfosuccinate 1, 9%
Citric acid 1 ,9 % Lactic acid 1 ,7 %Citric acid 1, 9% Lactic acid 1, 7%
Polysorbate 20 1 %Polysorbate 20 1%
Phenoxyethanol 0,5 %Phenoxyethanol 0.5%
Conservateur qsConservative qs
Eau déminéralisée qspDemineralized water qs
Mode opératoire : La composition aqueuse B est préparée par mélange sous agitation de tous les ingrédients cités. On mesure la viscosité de la composition aqueuse B : elle est égale à 26 mPa.s. Ces compositions sont ensuite introduites dans une bouteille pressurisée munie d'une tête de distribution dans laquelle on introduit le gaz pressurisé G. L'ensemble est agité de façon à obtenir un mélange homogène des deux phases initiales.Procedure: The aqueous composition B is prepared by mixing, with stirring, all the ingredients mentioned. The viscosity of the aqueous composition B is measured: it is equal to 26 mPa.s. These compositions are then introduced into a pressurized bottle provided with a dispensing head into which the pressurized gas G is introduced. The whole is stirred so as to obtain a homogeneous mixture of the two initial phases.
Exemple 2 : G :Example 2: G:
Isobutane 5 * 0 B :Isobutane 5 * 0 B:
Sodium laureth sulfate 5,3 %Sodium laureth sulfate 5.3%
Laureth-66 PPG-14 dicarbamate 0,3 %Laureth-66 PPG-14 dicarbamate 0.3%
Decyl glucoside 5 %Decyl glucoside 5%
Disodium laureth sulfosuccinate 1 ,9 % Cocamide MEA 1 ,5 %Disodium laureth sulfosuccinate 1, 9% Cocamide MEA 1, 5%
Polysorbate 20 3,4 %Polysorbate 20 3.4%
Phenoxyethanol 0,5 %Phenoxyethanol 0.5%
Alpha hydroxy acides qs %Alpha hydroxy acids qs%
Conservateur qs Eau déminéralisée qspPreservative qs Demineralized water qs
Mode opératoire : voir exemple 1.Procedure: see example 1.
Viscosité de la composition aqueuse B ' 50 mPa.sViscosity of the aqueous composition B '50 mPa.s
Les dispositifs et les compositions selon les exemples 1 et 2 sont parfaitement transparents et exempts de halo, aussi bien au moment de leur préparation qu'après plusieurs mois de stockage à température ambiante dans un local bénéficiant d'un éclairage naturel Par actionnement de la tête de distribution on obtient une mousse onctueuse, peu irritante et présentant de bonnes propriétés de nettoyage de la peau humaine.The devices and compositions according to Examples 1 and 2 are perfectly transparent and halo-free, both at the time of their preparation and after several months of storage at room temperature in a room benefiting from natural lighting By actuation of the head distribution, a creamy foam is obtained which is not very irritating and has good cleaning properties for human skin.
Exemple 3 (comparatif) . G : Isobutane 5 %Example 3 (comparative). G: Isobutane 5%
B :B:
Sodium laureth sulfate 8,4 %Sodium laureth sulfate 8.4%
Laureth-66 PPG-14 dicarbamate 0,3 %Laureth-66 PPG-14 dicarbamate 0.3%
Polysorbate 20 3,4 % Polysorbate 21 1 %Polysorbate 20 3.4% Polysorbate 21 1%
PEG-150 dιstéarate 0,5 %PEG-150 0.5% stearate
Laureth-4 0,5 %Laureth-4 0.5%
Disodium laureth sulfosuccinate 1 ,5 % Cocamido propyl bétaïne 1.5 % Phenoxyethanol 0,5 % Alpha hydroxy acides qs % Conservateur qs Eau déminéralisée qspDisodium laureth sulfosuccinate 1.5% Cocamido propyl betaine 1.5% Phenoxyethanol 0.5% Alpha hydroxy acids qs% Preservative qs Demineralized water qs
Mode opératoire : voir exemple 1.Procedure: see example 1.
On obtient un dispositif comportant un halo dès sa préparation. A device comprising a halo is obtained as soon as it is prepared.
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR96/11317 | 1996-09-17 | ||
| FR9611317A FR2753373B1 (en) | 1996-09-17 | 1996-09-17 | PRESSURIZED DEVICE WITH FOAMING COMPOSITION COMPRISING NON-IONIC AND ANIONIC SURFACTANTS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1998011868A1 true WO1998011868A1 (en) | 1998-03-26 |
Family
ID=9495806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FR1997/001607 WO1998011868A1 (en) | 1996-09-17 | 1997-09-11 | Pressurised device with foaming composition containing non-ionic and anionic surfactants |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR2753373B1 (en) |
| WO (1) | WO1998011868A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10033414B4 (en) * | 2000-07-08 | 2004-02-19 | Wella Aktiengesellschaft | Clear, two-phase, foam-forming aerosol hair care product |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2804020B1 (en) * | 2000-01-21 | 2002-08-09 | Oreal | LOW-ETOXYL SORBITAN ESTER-BASED KERATIN MATERIAL WASHING COMPOSITION |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2080289A5 (en) * | 1970-02-09 | 1971-11-12 | Alberto Culver Co | |
| EP0247766A2 (en) * | 1986-05-28 | 1987-12-02 | Lloyd I. Osipow | Instant lathering shampoo |
| US4772427A (en) * | 1987-12-01 | 1988-09-20 | Colgate-Palmolive Co. | Post-foaming gel shower product |
| WO1993009761A1 (en) * | 1991-11-22 | 1993-05-27 | Richardson-Vicks Inc. | Combined personal cleansing and moisturizing compositions |
-
1996
- 1996-09-17 FR FR9611317A patent/FR2753373B1/en not_active Expired - Fee Related
-
1997
- 1997-09-11 WO PCT/FR1997/001607 patent/WO1998011868A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2080289A5 (en) * | 1970-02-09 | 1971-11-12 | Alberto Culver Co | |
| EP0247766A2 (en) * | 1986-05-28 | 1987-12-02 | Lloyd I. Osipow | Instant lathering shampoo |
| US4772427A (en) * | 1987-12-01 | 1988-09-20 | Colgate-Palmolive Co. | Post-foaming gel shower product |
| WO1993009761A1 (en) * | 1991-11-22 | 1993-05-27 | Richardson-Vicks Inc. | Combined personal cleansing and moisturizing compositions |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10033414B4 (en) * | 2000-07-08 | 2004-02-19 | Wella Aktiengesellschaft | Clear, two-phase, foam-forming aerosol hair care product |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2753373A1 (en) | 1998-03-20 |
| FR2753373B1 (en) | 1998-10-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0792632B1 (en) | Pressurized transparent apparatus with a foaming composition containing non ionic and amphoteric surfactants | |
| CA1138739A (en) | Make up remover for the face and eyes | |
| CA1289888C (en) | Therapeutic or cosmetic composition in the form of a liquid solution from essentially anhydroux oxygen peroxide | |
| EP1084702B2 (en) | Cosmetic composition particularly for skin cleansing | |
| CA2054955C (en) | Cosmetic, pharmaceutic or food composition comprising a lipid vesicles dispersion | |
| EP0077742B1 (en) | Copper lanolate and topic compositions containing it | |
| CA2288250C (en) | Powdered cosmetic and/or dermatological lotion and its use | |
| BE898268A (en) | New anti-acne composition based on benzoyl peroxide and at least one other active ingredient. | |
| FR2564318A1 (en) | ANHYDROUS COMPOSITION FOR CLEANING THE SKIN | |
| EP0739619A1 (en) | Foaming o/w emulsion based on non-ionic surfactants, a fatty phase and a cross-linked cationic or anionic polymer for topical use | |
| FR2755852A1 (en) | USE OF GLYCEROL ALKYLETHER IN A COSMETIC AND / OR DERMATOLOGICAL COMPOSITION AS ACTIVE FOR THE TREATMENT OF SEBORRHEA AND ACNE | |
| WO1994024097A1 (en) | Amino deoxyalditol lipophilic derivatives for use in cosmetics, cosmetic compositions containing same and novel alkyl carbamates | |
| CA1179270A (en) | Shampoo composition containing anthraline or a derivative thereof, and its use for the treatment of skin deseases | |
| EP2205203B1 (en) | Novel compounds prepared by adding an oxetane derivative to an alcohol | |
| WO2007113440A1 (en) | Novel surfactant concentrate derived from alkyl polyglycosides and use thereof for preparing, without heating, cosmetic and/or pharmaceutical formulations | |
| FR2604355A1 (en) | COMPOSITION FOR CLEANING THE SKIN IN THE FORM OF A STICK OR STICK | |
| EP0577506A1 (en) | Use of aminopolyol carbamates as thickeners in solutions of surface active agents | |
| WO1998011868A1 (en) | Pressurised device with foaming composition containing non-ionic and anionic surfactants | |
| EP0819427B1 (en) | Use of 2(3-iodo-2-propynyl)-butylcarbamate in a cosmetic and/or dermatological composition as active ingredient for the treatment of seborrhea | |
| EP0974342A1 (en) | Single phase transparent aqueous composition | |
| FR2543828A1 (en) | NOVEL ANTI-ACNEIC COMPOSITION BASED ON TIOXOLONE AND AT LEAST ONE OTHER ACTIVE INGREDIENT | |
| JP2003034670A (en) | Vegetable acylamino acid or salt thereof | |
| FR2843540A1 (en) | Transparent composition for external application comprising a volatile hydrocarbon, non-ionic surfactant and hexylene glycol, useful for skin cleansing or make-up removal | |
| KR100241586B1 (en) | Pressurized transparent apparatus with a foaming composition containing nonionic and amphoteric surfactants | |
| FR3127401A1 (en) | Composition comprising low molecular weight hyaluronic acid, polyglycerol ester and sclerotium gum |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Kind code of ref document: A1 Designated state(s): CA JP KR PL RU US |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
| DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| NENP | Non-entry into the national phase |
Ref country code: JP Ref document number: 1998514337 Format of ref document f/p: F |
|
| 122 | Ep: pct application non-entry in european phase | ||
| NENP | Non-entry into the national phase |
Ref country code: CA |