WO1997039152A1 - Procede pour la fabrication d'une bande laminee a chaud en acier a haute resistance - Google Patents
Procede pour la fabrication d'une bande laminee a chaud en acier a haute resistance Download PDFInfo
- Publication number
- WO1997039152A1 WO1997039152A1 PCT/BE1997/000020 BE9700020W WO9739152A1 WO 1997039152 A1 WO1997039152 A1 WO 1997039152A1 BE 9700020 W BE9700020 W BE 9700020W WO 9739152 A1 WO9739152 A1 WO 9739152A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hot
- steel
- temperature
- cooling
- strip
- Prior art date
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 41
- 239000010959 steel Substances 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 20
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011572 manganese Substances 0.000 claims abstract description 5
- 230000009467 reduction Effects 0.000 claims abstract description 5
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 4
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012535 impurity Substances 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 3
- 239000010955 niobium Substances 0.000 claims abstract description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000010703 silicon Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 7
- 238000004804 winding Methods 0.000 claims description 7
- 238000005096 rolling process Methods 0.000 claims description 5
- 230000009466 transformation Effects 0.000 claims description 2
- 238000005098 hot rolling Methods 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910000922 High-strength low-alloy steel Inorganic materials 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 2
- 230000003679 aging effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910001563 bainite Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
Definitions
- the present invention relates to a process for the manufacture of a hot-rolled strip of high-strength steel, intended for direct use, that is to say without hot rolling being followed by cold rolling.
- these steels are now required to have a breaking load (Rm) greater than 550 MPa, a ratio of the elastic limit (Re) to the breaking load (Rm), ie Re / Rm , less than 0.7 and a high ductility, expressed by an elongation (A) greater than 20%.
- the resilience must also be high, for example at least 150 J / cm 2 at -50 ° C, in order to give the steel a high impact resistance. Good oligocyclic fatigue strength and high weldability are also considered essential characteristics.
- the current practice for the manufacture of a hot-rolled strip intended for direct use consists in continuously casting a steel slab whose thickness is generally greater than 150 mm, for example between 150 mm and 300 mm.
- This slab is rolled at high temperature in a roughing rolling mill in order to produce a blank whose thickness is generally between 20 mm and 40 mm.
- This blank is then rolled in a hot finishing train to the desired thickness, most often between 1.5 mm and 5 mm.
- the rolling of the blanks to the final thickness is carried out in full in the austenitic domain, with inlet temperatures to the hot finishing train above 950 ° C.
- the hot strip thus laminated is transferred to a water cooling table and is then wound in the ferritic region with a winding temperature above 500 ° C.
- the high levels of resistance desired for these steels can be obtained by the addition of alloying elements (Mn, Si, Cr, ...), which generate the formation of multi-phase microstructures out of balance under certain cooling and cooling conditions. winding.
- alloying elements Mn, Si, Cr, ...), which generate the formation of multi-phase microstructures out of balance under certain cooling and cooling conditions. winding.
- Obtaining these multiphase steels (ferrite, bainite, martensite, residual austenite, etc.) requires the use of complex cooling cycles comprising accelerated cooling and staged quenching phases. However, these practices may not be compatible with certain applications such as, for example, welding.
- the object of the present invention is to propose a method for manufacturing a hot-rolled strip intended for direct use, which makes it possible to greatly improve the mechanical properties mentioned above while ensuring consistency of these properties along the strip as well. produced.
- a method for manufacturing a hot rolled strip from. high strength steel in which a hot rolled steel is rolled, the carbon, manganese and silicon contents of which are between 0.04% by weight and 0.2%, between 0.5% and 2% and between 0.010% and 0.5% respectively, is characterized in that said steel additionally contains niobium in a content of between 0.01% and 0.1 % by weight, the remainder being iron and usual impurities, in that the hot rolling is carried out to finish said steel between an initial temperature below 950 ° C and a final temperature above the transformation temperature of the austenite made of ferrite (Ar3), with a thickness reduction rate of at least 85%, in that said hot-rolled steel is cooled in a period of less than 5 s with a cooling rate greater than 20 ° C / s from said final temperature to a temperature below 200 ° C and in that said hot rolled steel is coiled at said temperature below 200 ° C.
- the cooling is carried out in as short a time as possible, preferably less than 1 s.
- the cooling speed of the hot rolled steel is between 30 ° C / s and 1000 ° C / s, this value representing an average cooling speed between the temperature finishing and winding temperature.
- this cooling is carried out continuously and monotonously up to said temperature below 200 ° C., called the winding temperature, the highest values of the cooling speed making it possible to increase the elastic limit and the breaking load. without altering the strength-ductility compromise.
- said winding temperature is between 20 ° C and 150 ° C.
- the various aforementioned operations may correspond to successive stages related to the installation itself.
- the initial temperature of the finish rolling normally designates the temperature of entry into the finishing train
- the final temperature designates the temperature of exit from this finishing train
- the cooling of the strip comprises the transfer of the strip between the exit of the train finisher and entry of the cooling section, transfer which must be carried out in as short a time as possible, and the cooling carried out on an appropriate cooling table.
- Table I indicates the chemical composition of the steels used for the manufacture of these strips.
- This table shows the improvements in different mechanical properties observed on the hot strips treated by the two processes.
- These two properties are particularly important for the use of resistance steels.
- the tensile curve of the steel of the invention is continuous and without stepping of the elastic limit, which gives the hot strip of the invention non-aging properties appreciated by users. .
- the improvement in the properties of the hot strips is also visible in the plot of the oligocyclic fatigue resistance curve, shown in the diagram in FIG. 1.
- a strong improvement in the resistance to oligocyclic fatigue is indeed observed in favor of hot rolled steel according to the invention.
- This improvement is expressed by a relative decrease in resistance to 0.25% (R0.25) much less for the steel of the invention (14%) than for the reference steel HSLA (35%), corresponding also at a higher number of cycles (N) for the steel of the invention (45,000) than for the HSLA steel (15,000).
- Fig. 2 shows the evolution of the Charpy resilience (5 mm test pieces) as a function of the test temperature.
- the examination of Table III and of FIG. 2 shows the marked improvement observed in the case of rolled steel according to the method of the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97903163A EP0894149B1 (fr) | 1996-04-16 | 1997-02-24 | Procede pour la fabrication d'une bande laminee a chaud en acier a haute resistance |
DE69707660T DE69707660T2 (de) | 1996-04-16 | 1997-02-24 | Verfahren zum herstellen eines stahlbandes hoher festigkeit durch walmwalzen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9600324 | 1996-04-16 | ||
BE9600324A BE1010142A6 (fr) | 1996-04-16 | 1996-04-16 | Procede pour la fabrication d'une bande laminee a chaud en acier a haute resistance. |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997039152A1 true WO1997039152A1 (fr) | 1997-10-23 |
Family
ID=3889675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/BE1997/000020 WO1997039152A1 (fr) | 1996-04-16 | 1997-02-24 | Procede pour la fabrication d'une bande laminee a chaud en acier a haute resistance |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0894149B1 (fr) |
BE (1) | BE1010142A6 (fr) |
DE (1) | DE69707660T2 (fr) |
WO (1) | WO1997039152A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000055381A1 (fr) * | 1999-03-13 | 2000-09-21 | Thyssen Krupp Stahl Ag | Procede de production de feuillard a chaud |
WO2003031669A1 (fr) * | 2001-10-04 | 2003-04-17 | Nippon Steel Corporation | Tole d'acier mince hautement resistante pouvant etre emboutie et presentant d'excellentes proprietes de memoire de forme et procede de production associe |
EP1362930A4 (fr) * | 2001-02-23 | 2004-11-24 | Nippon Steel Corp | Feuille mince d'acier a resistance de fatigue d'entaille excellente, destinee a une automobile, et procede de production |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008010062A1 (de) * | 2007-06-22 | 2008-12-24 | Sms Demag Ag | Verfahren zum Warmwalzen und zur Wärmebehandlung eines Bandes aus Stahl |
CN116875786A (zh) * | 2023-04-27 | 2023-10-13 | 唐山不锈钢有限责任公司 | Bj770钢带的生产方法及其制备直缝臂架钢管的方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3102831A (en) * | 1960-08-10 | 1963-09-03 | Molybdenum Corp | Production of columbium containing steels |
US3849209A (en) * | 1972-02-01 | 1974-11-19 | Nippon Steel Corp | Manufacturing method of high tension, high toughness steel |
US4184898A (en) * | 1977-07-20 | 1980-01-22 | Nippon Kokan Kabushiki Kaisha | Method of manufacturing high strength low alloys steel plates with superior low temperature toughness |
US4188241A (en) * | 1977-12-06 | 1980-02-12 | Nippon Steel Corporation | Method for producing high tensile strength, high ductility, low yield ratio hot rolled steel sheet |
FR2446323A1 (fr) * | 1979-01-12 | 1980-08-08 | Nippon Steel Corp | Procede de fabrication de toles d'acier a deux phases ayant une resistance a la traction elevee et un rapport limite elastique/resistance a la traction de faible valeur ainsi que d'excellentes proprietes de vieillissement apres travail, et produit ainsi obtenu |
-
1996
- 1996-04-16 BE BE9600324A patent/BE1010142A6/fr not_active IP Right Cessation
-
1997
- 1997-02-24 DE DE69707660T patent/DE69707660T2/de not_active Revoked
- 1997-02-24 EP EP97903163A patent/EP0894149B1/fr not_active Revoked
- 1997-02-24 WO PCT/BE1997/000020 patent/WO1997039152A1/fr not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3102831A (en) * | 1960-08-10 | 1963-09-03 | Molybdenum Corp | Production of columbium containing steels |
US3849209A (en) * | 1972-02-01 | 1974-11-19 | Nippon Steel Corp | Manufacturing method of high tension, high toughness steel |
US4184898A (en) * | 1977-07-20 | 1980-01-22 | Nippon Kokan Kabushiki Kaisha | Method of manufacturing high strength low alloys steel plates with superior low temperature toughness |
US4188241A (en) * | 1977-12-06 | 1980-02-12 | Nippon Steel Corporation | Method for producing high tensile strength, high ductility, low yield ratio hot rolled steel sheet |
FR2446323A1 (fr) * | 1979-01-12 | 1980-08-08 | Nippon Steel Corp | Procede de fabrication de toles d'acier a deux phases ayant une resistance a la traction elevee et un rapport limite elastique/resistance a la traction de faible valeur ainsi que d'excellentes proprietes de vieillissement apres travail, et produit ainsi obtenu |
Non-Patent Citations (1)
Title |
---|
YOKOI T ET AL: "DEVELOPMENT OF HOT-ROLLED GALVANNEALED HIGH-STRENGTH STEEL SHEETS WITH GOOD STRETCH FLANGEABILITY", CAHIERS D'INFORMATIONS TECHNIQUES DE LA REVUE DE METALLURGIE, PARIS, FR, vol. 89, no. 2, 1 February 1992 (1992-02-01), pages 163 - 170, XP000267962 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000055381A1 (fr) * | 1999-03-13 | 2000-09-21 | Thyssen Krupp Stahl Ag | Procede de production de feuillard a chaud |
US6855218B1 (en) | 1999-03-13 | 2005-02-15 | Thyssen Krupp Stahl Ag | Method for producing a hot-rolled strip |
EP1362930A4 (fr) * | 2001-02-23 | 2004-11-24 | Nippon Steel Corp | Feuille mince d'acier a resistance de fatigue d'entaille excellente, destinee a une automobile, et procede de production |
WO2003031669A1 (fr) * | 2001-10-04 | 2003-04-17 | Nippon Steel Corporation | Tole d'acier mince hautement resistante pouvant etre emboutie et presentant d'excellentes proprietes de memoire de forme et procede de production associe |
US7503984B2 (en) | 2001-10-04 | 2009-03-17 | Nippon Steel Corporation | High-strength thin steel sheet drawable and excellent in shape fixation property and method of producing the same |
Also Published As
Publication number | Publication date |
---|---|
EP0894149A1 (fr) | 1999-02-03 |
BE1010142A6 (fr) | 1998-01-06 |
EP0894149B1 (fr) | 2001-10-24 |
DE69707660D1 (de) | 2001-11-29 |
DE69707660T2 (de) | 2002-06-20 |
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