WO1997025369B1 - MEMBRANES COMPOSITES A BASE DE α,β,β-TRIFLUOROSTYRENE ET DE α,β,β-TRIFLUOROSTYRENE SUBSTITUE - Google Patents
MEMBRANES COMPOSITES A BASE DE α,β,β-TRIFLUOROSTYRENE ET DE α,β,β-TRIFLUOROSTYRENE SUBSTITUEInfo
- Publication number
- WO1997025369B1 WO1997025369B1 PCT/CA1997/000003 CA9700003W WO9725369B1 WO 1997025369 B1 WO1997025369 B1 WO 1997025369B1 CA 9700003 W CA9700003 W CA 9700003W WO 9725369 B1 WO9725369 B1 WO 9725369B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- zero
- integer greater
- composite membrane
- perfluoroalkyls
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title claims abstract 25
- 239000002131 composite material Substances 0.000 title claims abstract 24
- SUTQSIHGGHVXFK-UHFFFAOYSA-N 1,2,2-trifluoroethenylbenzene Chemical compound FC(F)=C(F)C1=CC=CC=C1 SUTQSIHGGHVXFK-UHFFFAOYSA-N 0.000 claims abstract 6
- 125000003118 aryl group Chemical group 0.000 claims 23
- 125000000217 alkyl group Chemical group 0.000 claims 16
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 16
- 229910018828 PO3H2 Inorganic materials 0.000 claims 14
- 239000000463 material Substances 0.000 claims 9
- 229910006095 SO2F Inorganic materials 0.000 claims 8
- 229910006069 SO3H Inorganic materials 0.000 claims 8
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims 8
- 229910004727 OSO3H Inorganic materials 0.000 claims 7
- 229910018814 PO2 Inorganic materials 0.000 claims 7
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 7
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 4
- 229910052731 fluorine Inorganic materials 0.000 claims 4
- 239000011737 fluorine Substances 0.000 claims 4
- 239000012634 fragment Substances 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 3
- -1 polytetrafluorethylene Polymers 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229920000098 polyolefin Polymers 0.000 claims 2
- 239000002033 PVDF binder Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 229920000295 expanded polytetrafluoroethylene Polymers 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Chemical class 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Abstract
L'invention concerne une membrane composite dans laquelle un substrat poreux est imprégné d'une composition polymère contenant diverses combinaisons de α,β,β-trifluorostyrène, de α,β,β-trifluorostyrène substitué et d'unités monomères à base d'éthylène. Quand la composition polymère comporte des groupes échangeurs d'ions, les membranes composites obtenues sont utiles dans des applications électrochimiques, notamment comme électrolytes à membrane dans les cellules électrochimiques.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002240495A CA2240495C (fr) | 1996-01-05 | 1997-01-03 | Membranes composites a base de .alpha.,.beta.,.beta.-trifluorostyrene et de .alpha.,.beta.,.beta.-trifluorostyrene substitue |
AT97900054T ATE194366T1 (de) | 1996-01-05 | 1997-01-03 | Verbundmembran aus alpha,beta,beta-trifluorstyrol und substituiertem alpha,beta,beta-trifluorstyrol |
JP9524691A JP2000502625A (ja) | 1996-01-05 | 1997-01-03 | α,β,β―トリフルオロスチレンをベースとする複合膜および置換α,β,β―トリフルオロスチレンをベースとする複合膜 |
AU11872/97A AU704923B2 (en) | 1996-01-05 | 1997-01-03 | Alpha,beta,beta-trifluorostyrene-based and substituted alpha,beta,beta-trifluorostyrene-based composite membranes |
EP97900054A EP0882088B1 (fr) | 1996-01-05 | 1997-01-03 | Membranes composites a base de alpha,beta,beta-trifluorostyrene et de alpha,beta,beta-trifluorostyrene substitue |
DE69702442T DE69702442T2 (de) | 1996-01-05 | 1997-01-03 | Verbundmembran aus alpha,beta,beta-trifluorstyrol und substituiertem alpha,beta,beta-trifluorstyrol |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/583,638 US5834523A (en) | 1993-09-21 | 1996-01-05 | Substituted α,β,β-trifluorostyrene-based composite membranes |
US08/583,638 | 1996-01-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1997025369A1 WO1997025369A1 (fr) | 1997-07-17 |
WO1997025369B1 true WO1997025369B1 (fr) | 1997-09-12 |
Family
ID=24333969
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA1997/000003 WO1997025369A1 (fr) | 1996-01-05 | 1997-01-03 | MEMBRANES COMPOSITES A BASE DE α,β,β-TRIFLUOROSTYRENE ET DE α,β,β-TRIFLUOROSTYRENE SUBSTITUE |
Country Status (8)
Country | Link |
---|---|
US (5) | US5834523A (fr) |
EP (1) | EP0882088B1 (fr) |
JP (1) | JP2000502625A (fr) |
AT (1) | ATE194366T1 (fr) |
AU (1) | AU704923B2 (fr) |
CA (1) | CA2240495C (fr) |
DE (1) | DE69702442T2 (fr) |
WO (1) | WO1997025369A1 (fr) |
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JPH0327053A (ja) | 1989-06-23 | 1991-02-05 | Daikin Ind Ltd | 静電荷現像用キャリアー |
JPH03232529A (ja) * | 1990-02-09 | 1991-10-16 | Yuasa Kasei Kk | 分離膜 |
CA2085549A1 (fr) * | 1991-12-25 | 1993-06-26 | Noboru Nakano | Pile a combustile et membrane electrolytique pour une telle pile |
JPH0629032A (ja) * | 1992-07-08 | 1994-02-04 | Sumitomo Electric Ind Ltd | 高分子電解質膜及びその製造法 |
JP3232529B2 (ja) | 1992-09-25 | 2001-11-26 | 日新製鋼株式会社 | リードフレーム用Fe−Ni系合金及びその製造方法 |
US5834523A (en) * | 1993-09-21 | 1998-11-10 | Ballard Power Systems, Inc. | Substituted α,β,β-trifluorostyrene-based composite membranes |
US5602185A (en) | 1993-09-21 | 1997-02-11 | Ballard Power Systems Inc. | Substituted trifluorostyrene compositions |
US5422411A (en) * | 1993-09-21 | 1995-06-06 | Ballard Power Systems Inc. | Trifluorostyrene and substituted trifluorostyrene copolymeric compositions and ion-exchange membranes formed therefrom |
US5599614A (en) * | 1995-03-15 | 1997-02-04 | W. L. Gore & Associates, Inc. | Integral composite membrane |
US5547551A (en) * | 1995-03-15 | 1996-08-20 | W. L. Gore & Associates, Inc. | Ultra-thin integral composite membrane |
WO1996040798A1 (fr) * | 1995-06-07 | 1996-12-19 | Ballard Power Systems Inc. | Compositions copolymere de trifluorostyrene, de trifluorostyrene substitue et d'ethylene substitue, et membranes echangeuses d'ions constituees de ces compositions |
-
1996
- 1996-01-05 US US08/583,638 patent/US5834523A/en not_active Expired - Fee Related
-
1997
- 1997-01-03 AU AU11872/97A patent/AU704923B2/en not_active Ceased
- 1997-01-03 JP JP9524691A patent/JP2000502625A/ja active Pending
- 1997-01-03 WO PCT/CA1997/000003 patent/WO1997025369A1/fr active IP Right Grant
- 1997-01-03 DE DE69702442T patent/DE69702442T2/de not_active Expired - Lifetime
- 1997-01-03 EP EP97900054A patent/EP0882088B1/fr not_active Expired - Lifetime
- 1997-01-03 AT AT97900054T patent/ATE194366T1/de not_active IP Right Cessation
- 1997-01-03 CA CA002240495A patent/CA2240495C/fr not_active Expired - Fee Related
-
1998
- 1998-11-05 US US09/186,449 patent/US5985942A/en not_active Expired - Fee Related
-
1999
- 1999-11-15 US US09/441,181 patent/US6258861B1/en not_active Expired - Fee Related
-
2001
- 2001-07-09 US US09/901,269 patent/US6437011B2/en not_active Expired - Fee Related
-
2002
- 2002-06-25 US US10/179,073 patent/US20020161061A1/en not_active Abandoned
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