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WO1997011143A2 - Compositions detergentes tres puissantes comprenant des sels d'esters methyliques alpha sulfones d'acide gras et utilisation des sels d'acides gras alpha sulfones pour inhiber la redeposition des salissures sur le tissu - Google Patents

Compositions detergentes tres puissantes comprenant des sels d'esters methyliques alpha sulfones d'acide gras et utilisation des sels d'acides gras alpha sulfones pour inhiber la redeposition des salissures sur le tissu Download PDF

Info

Publication number
WO1997011143A2
WO1997011143A2 PCT/US1996/014889 US9614889W WO9711143A2 WO 1997011143 A2 WO1997011143 A2 WO 1997011143A2 US 9614889 W US9614889 W US 9614889W WO 9711143 A2 WO9711143 A2 WO 9711143A2
Authority
WO
WIPO (PCT)
Prior art keywords
detergent
alkyl
weight
fatty acid
sulfonated
Prior art date
Application number
PCT/US1996/014889
Other languages
English (en)
Other versions
WO1997011143A3 (fr
Inventor
Branko Sajic
Irma Ryklin
Arshad Malik
Y. Kameshwer Rao
Original Assignee
Stepan Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stepan Company filed Critical Stepan Company
Priority to EP96932244A priority Critical patent/EP0792336A2/fr
Priority to JP9512836A priority patent/JPH10502969A/ja
Priority to MX9703647A priority patent/MX9703647A/es
Priority to CA002205592A priority patent/CA2205592C/fr
Priority to US08/836,821 priority patent/US5945394A/en
Priority to NZ318989A priority patent/NZ318989A/en
Priority to AU71112/96A priority patent/AU699950B2/en
Priority to BR9606651A priority patent/BR9606651A/pt
Publication of WO1997011143A2 publication Critical patent/WO1997011143A2/fr
Publication of WO1997011143A3 publication Critical patent/WO1997011143A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • R 3 (0R 4 ) X —N—(R5) 2
  • R 3 is selected from an alkyl, hydroxyalkyl, acylamidopropyl and alkyl phenyl group, or mixtures thereof, containing from 8 to 26 carbon atoms, preferably 8 to 16 carbon atoms
  • R 4 is an alkylene or hydroxyalkylene group containing from 2 to 3 carbon atoms, preferably 2 carbon atoms, or mixtures thereof
  • x is from 0 to 3, preferably 0
  • each R 5 is an alkyl or hydroxyalkyl group containing from 1 to 3, preferably from 1 to 2 carbon atoms, or a polyethylene oxide group containing from 1 to 3, preferably 1, ethylene oxide groups.
  • the R 5 groups can be attached to each other, e.g., through an oxygen or nitrogen atom, to form a ring structure.
  • the polymeric soil release agents for which performance is enhanced by polyhydroxy fatty acid amide in the presence of anionic surfactant include those soil release agents having: (a) one or more nonionic hydrophile components consisting essentially of (1) polyoxyethylene segments with a degree of polymerization of at least 2, or (ii) oxypropylene or polyoxypropylene segments with a degree of polymerization of from 2 to 10, wherein said hydrophile segment does not encompass any oxypropylene unit unless it is bonded to adjacent moieties at each end by ether linkages, or (iii) a mixture of oxyalkylene units comprising oxyethylene and from 1 to about 30 oxypropylene units wherein said mixture contains a sufficient amount of oxyethylene units such that the hydrophile component has hydrophilicity great enough to increase the hydrophilicity of conventional polyester synthetic fiber surfaces upon deposit of the soil release agent on such surface, said hydrophile segments preferably comprising at least about 25% oxyethylene units and more preferably, especially for such components having about 20 to 30
  • the choice of brightener for use in detergent compositions will depend upon a number of factors, such as the type of detergent, the nature of other components present in the detergent composition, the temperatures of wash water, the degree of agitation, and the ratio of the material washed to tub size.
  • these brighteners include 4-methyl-7-diethylamino coumarin; 1, 2-bis (-benzimidazol-2-yl) ethylene; 1,3- diphenylphrazolines; 2,5-bis(benzoxazol-2-yl)thiophene; 2-styryl- naphth-[l,2-d]oxazole; and 2-(stilbene-4-yl)2-H-naphtho-[l,2- d]triazole.
  • a Laundry detergent formulations may be prepared by adding water to a suitable vessel equipped with mixing means. The remaining ingredients are added in the order in which they are listed in the formulations set forth in the following examples. The resulting mixtures are continuously mixed until a liquid of uniform consistency is obtained. The pH may be adjusted as needed to about 8.5-8.8 using suitable alkaline or acidic reagents.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Compositions détergentes constituées: (a) d'un ester d'alkyle α-sulfoné d'un acide gras comprenant un nombre moyen d'atomes de carbone compris entre environ 12 et 14; (b) d'un tensio-actif anionique; et (c) d'un tensio-actif non ionique. Des procédés de préparation de ces compositions sont également décrits ainsi que des procédés pour inhiber la redéposition des salissures sur le tissu, dans lesquels le tissu est traité avec un détergent comprenant un sel d'un acide gras α-sulfoné à 8 à 22 atomes de carbone.
PCT/US1996/014889 1995-09-18 1996-09-17 Compositions detergentes tres puissantes comprenant des sels d'esters methyliques alpha sulfones d'acide gras et utilisation des sels d'acides gras alpha sulfones pour inhiber la redeposition des salissures sur le tissu WO1997011143A2 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP96932244A EP0792336A2 (fr) 1995-09-18 1996-09-17 Compositions detergentes tres puissantes comprenant des sels d'esters methyliques alpha sulfones d'acide gras et utilisation des sels d'acides gras alpha sulfones pour inhiber la redeposition des salissures sur le tissu
JP9512836A JPH10502969A (ja) 1995-09-18 1996-09-17 αスルホン化脂肪酸メチルエステルの塩を含んでなる重質液体洗剤組成物および織物への汚れの再付着を抑制するαスルホン化脂肪酸塩の使用
MX9703647A MX9703647A (es) 1995-09-18 1996-09-17 Composiciones detergentes liquidas que comprenden sales de esteres metilicos de acidos grasos alfa-sulfonados y uso de las sales de acidos grasos alfa-sufonados para inhibir la redeposicion de suciedad o manchas en los tejidos.
CA002205592A CA2205592C (fr) 1995-09-18 1996-09-17 Compositions detergentes tres puissantes comprenant des sels d'esters methyliques alpha sulfones d'acide gras et utilisation des sels d'acides gras alpha sulfones pour inhiber la redeposition des salissures sur le tissu
US08/836,821 US5945394A (en) 1995-09-18 1996-09-17 Heavy duty liquid detergent compositions comprising salts of α-sulfonated fatty acid methyl esters and use of α-sulphonated fatty acid salts to inhibit redeposition of soil on fabric
NZ318989A NZ318989A (en) 1995-09-18 1996-09-17 Heavy duty detergent containing an alpha-sulphonated alkyl ester of a fatty acid; inhibition of soil redeposition
AU71112/96A AU699950B2 (en) 1995-09-18 1996-09-17 Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulphonated fatty acid salts to in hibit redeposition of soil on fabric
BR9606651A BR9606651A (pt) 1995-09-18 1996-09-17 Composição detergente e processo para inibir a redeposição de sujeira em tecido

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US52950195A 1995-09-18 1995-09-18
US59174896A 1996-01-25 1996-01-25
US08/529,501 1996-01-25
US08/591,748 1996-01-25

Publications (2)

Publication Number Publication Date
WO1997011143A2 true WO1997011143A2 (fr) 1997-03-27
WO1997011143A3 WO1997011143A3 (fr) 1997-04-24

Family

ID=27063032

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/014889 WO1997011143A2 (fr) 1995-09-18 1996-09-17 Compositions detergentes tres puissantes comprenant des sels d'esters methyliques alpha sulfones d'acide gras et utilisation des sels d'acides gras alpha sulfones pour inhiber la redeposition des salissures sur le tissu

Country Status (10)

Country Link
EP (1) EP0792336A2 (fr)
JP (1) JPH10502969A (fr)
AR (1) AR003618A1 (fr)
AU (1) AU699950B2 (fr)
BR (1) BR9606651A (fr)
CA (1) CA2205592C (fr)
CO (1) CO5040238A1 (fr)
MX (1) MX9703647A (fr)
NZ (1) NZ318989A (fr)
WO (1) WO1997011143A2 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006089013A1 (fr) * 2005-02-14 2006-08-24 The Dial Corporation Composition de detergent amelioree presentant un plus grand pouvoir blanchissant
WO2015091110A3 (fr) * 2013-12-17 2015-08-13 Henkel Ag & Co. Kgaa Détergent contenant du méthylestersulfonate (mes) et du méthylesteréthoxylate (mee)
EP2489722A4 (fr) * 2009-10-15 2016-06-01 Lion Corp Composition détergente liquide
WO2016160407A1 (fr) * 2015-03-31 2016-10-06 Stepan Company Détergents à base de tensioactifs ester gras alpha-sulfonés
EP3441447A1 (fr) * 2017-08-09 2019-02-13 Henkel AG & Co. KGaA Éther de cellulose non ionique en tant que renforçateur d'élimination de salissures lors du nettoyage de surfaces dures
EP3990603B1 (fr) 2019-06-28 2022-12-07 Unilever Global Ip Limited Composition de détergent

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5481719B2 (ja) * 2007-12-28 2014-04-23 ライオン株式会社 粒状洗剤組成物
JP5481720B2 (ja) * 2007-12-28 2014-04-23 ライオン株式会社 粒状洗剤組成物
ATE534721T1 (de) * 2009-09-14 2011-12-15 Procter & Gamble Reinigungsmittelzusammensetzung
WO2012144438A1 (fr) * 2011-04-18 2012-10-26 ライオン株式会社 Détergent liquide
CN106047529A (zh) * 2016-06-30 2016-10-26 安徽泰隆成亚集团股份有限公司 环保浓缩型衣料用液体洗涤剂

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA795748A (en) * 1968-10-01 Stepan Chemical Company Heavy-duty synthetic detergent compositions
BE631335A (fr) * 1962-04-24
GB1368736A (en) * 1970-09-09 1974-10-02 Unilever Ltd Detergent compositions
DE2333356C3 (de) * 1973-06-30 1982-03-11 Henkel KGaA, 4000 Düsseldorf Waschmittel
JPS6059960B2 (ja) * 1980-11-28 1985-12-27 ライオン株式会社 粉セツケン組成物
DE3726326A1 (de) * 1987-08-07 1989-02-16 Henkel Kgaa Verbesserte wasch- und reinigungsmittel fuer textilien (ii)
GB8808041D0 (en) * 1988-04-06 1988-05-05 Unilever Plc Detergent composition
JPH0637639B2 (ja) * 1988-10-12 1994-05-18 ライオン株式会社 高嵩密度粒状洗剤組成物
US5118440A (en) * 1990-03-05 1992-06-02 The Procter & Gamble Company Light-duty liquid dishwashing detergent composition containing alkyl polysaccharide and alpha-sulfonated fatty acid alkyl ester surfactants
JPH06330084A (ja) * 1993-05-21 1994-11-29 Lion Corp 洗浄剤組成物
EP0723576B1 (fr) * 1993-10-12 2000-03-01 Stepan Company Compositions detergentes liquides comprenant des sels d'esters methyliques ou ethyliques alpha sulfones d'acide gras et des agents tensio-actifs anioniques

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006089013A1 (fr) * 2005-02-14 2006-08-24 The Dial Corporation Composition de detergent amelioree presentant un plus grand pouvoir blanchissant
WO2006088928A1 (fr) * 2005-02-14 2006-08-24 The Dial Corporation Composition surfactante contenant un sulfate d'alcool-ethoxy destinee a s'utiliser dans des detergents a lessive et processus de fabrication correspondant
US7754669B2 (en) 2005-02-14 2010-07-13 The Dial Corporation Detergent composition with enhanced whitening power
EP2489722A4 (fr) * 2009-10-15 2016-06-01 Lion Corp Composition détergente liquide
KR101791707B1 (ko) 2009-10-15 2017-10-30 라이온 가부시키가이샤 액체 세정제 조성물
WO2015091110A3 (fr) * 2013-12-17 2015-08-13 Henkel Ag & Co. Kgaa Détergent contenant du méthylestersulfonate (mes) et du méthylesteréthoxylate (mee)
WO2016160407A1 (fr) * 2015-03-31 2016-10-06 Stepan Company Détergents à base de tensioactifs ester gras alpha-sulfonés
EP3441447A1 (fr) * 2017-08-09 2019-02-13 Henkel AG & Co. KGaA Éther de cellulose non ionique en tant que renforçateur d'élimination de salissures lors du nettoyage de surfaces dures
EP3990603B1 (fr) 2019-06-28 2022-12-07 Unilever Global Ip Limited Composition de détergent

Also Published As

Publication number Publication date
AR003618A1 (es) 1998-08-05
MX9703647A (es) 1997-08-30
CO5040238A1 (es) 2001-05-29
CA2205592A1 (fr) 1997-03-27
AU7111296A (en) 1997-04-09
WO1997011143A3 (fr) 1997-04-24
AU699950B2 (en) 1998-12-17
CA2205592C (fr) 2001-12-11
JPH10502969A (ja) 1998-03-17
NZ318989A (en) 1999-10-28
BR9606651A (pt) 1997-09-30
EP0792336A2 (fr) 1997-09-03

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