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WO1997003000A1 - Valve for a pressurised container and container provided therewith - Google Patents

Valve for a pressurised container and container provided therewith Download PDF

Info

Publication number
WO1997003000A1
WO1997003000A1 PCT/FR1996/001082 FR9601082W WO9703000A1 WO 1997003000 A1 WO1997003000 A1 WO 1997003000A1 FR 9601082 W FR9601082 W FR 9601082W WO 9703000 A1 WO9703000 A1 WO 9703000A1
Authority
WO
WIPO (PCT)
Prior art keywords
valve
control rod
container
orifice
movable member
Prior art date
Application number
PCT/FR1996/001082
Other languages
French (fr)
Inventor
Jean-Marc Aumegeas
Pierre-André Lasserre
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Publication of WO1997003000A1 publication Critical patent/WO1997003000A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K17/00Safety valves; Equalising valves, e.g. pressure relief valves
    • F16K17/36Safety valves; Equalising valves, e.g. pressure relief valves actuated in consequence of extraneous circumstances, e.g. shock, change of position
    • F16K17/366Safety valves; Equalising valves, e.g. pressure relief valves actuated in consequence of extraneous circumstances, e.g. shock, change of position the closure member being a movable ball
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/14Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
    • B65D83/56Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant with arrangements for interruption of dispensing when the container is inverted

Definitions

  • the present invention relates to a valve for a pressurized container, and more specifically relates to a valve of the type comprising a valve body and a control rod movable in the valve body between an open position of the valve and a closed position. thereof, and a movable member sensitive to the action of gravity, intended to prevent the distribution of the product contained in the container when the latter is moved, beyond a predetermined limit, from a normal position d 'use.
  • the latter generally corresponds to an arrangement of the container either upside down or upside down, with its substantially vertical axis.
  • the aforementioned movable member intervenes to oppose the opening of the valve if the head of the container does not occupy a normal position of use.
  • FR-A-2,375,111 discloses a valve equipped with a valve sensitive to the action of gravity, placed in a pipe for supplying the valve with product.
  • This valve comprises a ball capable of being applied against a product passage orifice serving as a seat for the ball when the container is upside down, for closing said supply conduit.
  • the valve has the drawback, given the small cross section of said orifice, of subjecting the flow of the product to a significant pressure drop.
  • the object of the present invention is to provide a valve which is simple in construction, does not cause excessive pressure drop and whose operation is particularly reliable.
  • said movable member is able to cooperate with the control rod to be interposed between the latter and the valve body when the container is moved away from a normal position of use and that the control rod is urged to move towards said open position.
  • the interior of the valve body communicates by a product supply orifice with the interior of the container and the control rod is able to maintain said movable member in a position for closing said orifice when it is urged to move in the direction of said valve opening position.
  • the invention also relates to a container equipped with a valve as mentioned above.
  • FIG. 1 is a schematic axial section of a valve according to a first embodiment of the invention
  • FIG. 2 represents the valve of FIG. 1 in its normal position of use
  • FIG. 3 shows the valve of FIG. 1 in an inverted position relative to the normal position of use, the control rod being at rest,
  • FIG. 4 is a view similar to FIG. 3, the control rod being pushed in
  • FIG. 5 is a schematic axial section of a valve according to a second embodiment of the invention.
  • FIG. 6 represents the valve of FIG. 5, in the normal position of use
  • FIG. 7 represents the valve of FIG. 5 in an inverted position relative to the normal position of use, the control rod being at rest, and
  • Figure 8 is a view similar to Figure 7, the control rod being pressed.
  • valve 1 according to a first embodiment of the invention.
  • This valve 1 comprises a valve body 2 and a control rod 3 elongated along a longitudinal axis X and able to move axially in the valve body 2 between a closed position of the valve (shown in FIG. 1) and a valve open position (shown in Figure 2).
  • the valve body comprises, in the embodiment described, an upper part 2a. housing a return spring 4 for the control rod 3 in said closed position and a lower part 2b housing a movable member sensitive to the action of gravity, constituted in the example described by a ball 5 whose role will be specified in the following.
  • Part 2a is closed at its upper end by a sealing washer 6 through the center 7 by the control rod 3.
  • the washer 6 rests on the upper end face 8 of the portion 2a, bordered by a boss ring 9 intended for fixing the valve body 2 by crimping in a housing 10a_ a cup 10 to crimp itself at its periphery on a container known in itself and not shown.
  • the control rod 3 passes through the bottom of the housing 10a ⁇ by means of a bore 11.
  • the cup 10 maintains the part 2a. tight against the sealing washer 6 and ensures a tight fixing of the valve body 2 in the housing 10a ⁇
  • the control rod 3 is traversed by an inner conduit 12 opening at one end on its upper end edge 13 and at the other end on a lateral orifice 14 located at about mid-length thereof.
  • the spring 4 is wound on a cylindrical surface 15 of the control rod 3 serving as a guide, bears axially at its upper end on the base of a crown 16 projecting from the rod 3 and at its lower end on a transverse wall lower part 17 of part 2a , generally extending perpendicular to the axis X.
  • the control rod 3 is biased by the spring 4 upwards until a lip stops device 16a ⁇ of the crown 16 against the sealing washer 6.
  • the orifice 14 then opens onto the thickness of the sealing washer 6 and is closed by the latter.
  • the tightness of the closure is improved by the fact that the lip 16 ⁇ , by applying to the lower front face of the sealing washer 6, isolates the center 7 of the latter from the interior of the container.
  • the aforementioned wall 17 is traversed in its center by a bore 18 for the passage of the lower end 19 of the control rod 3.
  • the diameter of this bore 18 is chosen so as to provide space with the portion of the control rod 3 which is engaged inside of it an annular clearance 20 allowing the product contained in the container to flow from the inside of the lower part 2b of the valve body 2 towards the inside of the upper part 2a.
  • Part 2b is closed at its lower end by an insert 21 comprising a tube 22, provided with an anchoring cone 23 to be inserted into a tube immersed in the product to be dispensed, inside the container. This product is surmounted, in the normal position of use of the container, by a propellant gas under pressure.
  • the part 21 comprises an upper tube 24 extending inside the part 2b of the valve body 2.
  • the tubes 22 and 24, of axis X are connected to a support wall 25 which is flat and perpendicular to the X axis, fixed at its periphery to the lower end of part 2b.
  • the part 21 forms with the part 2b of the valve body a cavity 26 in which the ball 5 can move.
  • This cavity 26 is delimited radially on the outside by an internal conical surface 27 of the part 2b, forming an angle of a few degrees with the longitudinal axis X, and superiorly by a surface 28 of the part 2b, symmetrical of revolution around the axis X, having the shape of a spherical cap concave downwards and crossed at its top by the hole 18
  • the cavity 26 is delimited radially on the inside by the external surface 29 of the upper conical tube 24, parallel to the surface 27, and forming with the latter an annular groove of width adapted to receive the ball 5.
  • the distance separating the surfaces 27 and 29 is slightly greater than the diameter of the ball 5.
  • the internal section of the tubing 22 is constant, cylindrical of revolution around the axis X.
  • the internal section of the upper tubing 24 narrows in the direction of the control rod 3. More specifically, this internal section converges to form a cone of generator inclined relative to the axis X by an angle greater than the angle between the generator of the surface 27 and the axis X.
  • the wall of the upper tube 24 thickens as one approaches from its upper end where it defines a product supply orifice 31 whose diameter is less than the diameter of the ball 5, and which corresponds in the example described to approximately one third of it.
  • the end surface 32 of the upper tube 24 bordering the orifice 31 is convex towards the control rod 3.
  • the lower end surface 19 of the control rod 3 is concave, shaped to match the curvature of the ball 5 and cause it to move when the container is used upside down, as will be explained below.
  • the valve 1 is intended to operate normally when the container is used upside down, as shown in FIGS. 1 and 2, and to be inoperative when the container is used upside down, as shown in FIGS. 3 and 4.
  • the ball 5 is housed in the concavity of the end 19. If the user pushes the control rod 3 into the body 2, the ball 5 moves with the control rod 3 and it is applied by the latter against the edges of the orifice 31 which it comes to close, as shown in FIG. 4. The ball 5 thus opposes the passage of product and the valve is inoperative.
  • the stroke of the control rod which is necessary to apply the ball 5 against the orifice 31 and to close the latter, is greater than the stroke necessary to clear the orifice 14.
  • the orifice 31 and the end 19 of the control rod 3 could be brought closer so that, when the control rod 3 applies the ball 5 against the orifice 31 , the orifice 14 is always closed by the sealing washer 6.
  • the ball 5 would then act simply to limit the displacement travel of the control rod 3 in order to prevent it from reaching the depression necessary to release the orifice 14 and open the valve.
  • valve according to a second embodiment of the invention, the valve operating normally when the container is upside down, and being rendered inoperative when the container is inverted.
  • the valve 1a has a part 2a , identical to that of the previous embodiment, and similarly fixed to the cup 10 of the container.
  • the valve 1 ' comprises a control rod 3' which differs from the control rod 3 previously described in that it extends beyond the bore 18 to protrude inside a second part 2b 'of the valve body 2 '.
  • Part 2b ' is identical externally to part 2b previously described, but defines a cavity 26', in which the ball 5 moves, of different shape.
  • the cavity 26 ' is delimited laterally by a surface conical 27 ′ converging away from the control rod 3 ′, of generatrix making an angle of a few degrees with the axis X.
  • This conical surface 27 ′ is connected above a surface 28 ′ concave towards the control rod 3 ′, constituted in the example described by a spherical cap.
  • the cavity 26 ' is delimited opposite the surface 28' by the transverse wall 17 of the part 2a. valve body 2 '.
  • the surface 28 ' is crossed at its top by a bore 31' opening into the interior of the tube 22, which is devoid of dip tube in this embodiment and which could be omitted.
  • the part 2b ' internally comprises a web of material 24' of frustoconical shape, defining with the surface 27 'an annular groove whose opening width is slightly greater than the diameter of the ball 5.
  • the control rod 3' When the control rod 3' is at rest, its end 19 'is located at the upper end of the web 24'.
  • the diameter of the bore 31 ' is less than the diameter of the ball 5.
  • the end 19' has a convex spherical shape in the direction of the bore 31 '.
  • the ball 5 rests in the bottom of the annular groove delimited by the web of material 24 'and the surface 27'.
  • the orifice 14 is released, and the product can flow along the arrowed path P in FIG. 6, through the bore 31 ′, the annular clearance formed between the bore 18 and the control rod 3 ', the annular gap between the lip 16a and the sealing washer 6, to leave the control rod 3' through the conduit 12.
  • the invention makes it possible to make a valve of a pressurized container inoperative or not depending on the head-up or head-down position of the latter, without however causing a pressure drop excessive flow of product leaving the container.
  • the structure of a valve according to the invention is simple, and it is inexpensive to produce. Holding the ball control rod in the closed position allows the use of a ball of small dimensions and low weight, and to obtain rapid movements of the ball towards the positions rendering the valve inoperative or on the contrary allowing its normal operation.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)

Abstract

A valve for a container suitable for containing a pressurised substance is disclosed. The valve comprises a valve body and a control rod that is movable within the valve body between a valve opening position and a valve closing position when the container is in a normal use position. The valve further comprises a gravity-responsive movable member for disabling the valve when the container is moved out of the normal use position beyond a predetermined point. Said movable member (5) engages the control rod (3') when said container is moved out of the normal use position beyond said predetermined point, and positions itself between the valve body and the control rod when said rod is urged into said valve opening position.

Description

Valve pour récipient pressurisé et récipient ainsi équipé. Valve for pressurized container and container so equipped.

La présente invention se rapporte à une valve pour récipient pressurisé, et concerne plus précisément une valve du type comportant un corps de valve et une tige de commande mobile dans le corps de valve entre une position d'ouverture de la valve et une position de fermeture de celle-ci, et un organe mobile sensible à l'action de la pesanteur, destiné à empêcher la distribution du produit contenu dans le récipient lorsque ce dernier est écarté, au-delà d'une limite prédéterminée, d'une position normale d'utilisation.The present invention relates to a valve for a pressurized container, and more specifically relates to a valve of the type comprising a valve body and a control rod movable in the valve body between an open position of the valve and a closed position. thereof, and a movable member sensitive to the action of gravity, intended to prevent the distribution of the product contained in the container when the latter is moved, beyond a predetermined limit, from a normal position d 'use.

Dans la pratique, cette dernière correspond généralement à une disposition du récipient soit tête en haut, soit tête en bas, avec son axe sensiblement vertical. L'organe mobile précité intervient pour s'opposer à l'ouverture de la valve si la tête du récipient n'occupe pas une position normale d'utilisation.In practice, the latter generally corresponds to an arrangement of the container either upside down or upside down, with its substantially vertical axis. The aforementioned movable member intervenes to oppose the opening of the valve if the head of the container does not occupy a normal position of use.

On connaît par FR-A-2.375.111 une valve équipée d'un clapet sensible à l'action de la pesanteur, placé dans un conduit d'alimentation de la valve en produit. Ce clapet comporte une bille apte à s'appliquer contre un orifice de passage de produit servant de siège à la bille lorsque le récipient est à l'envers, pour obturer ledit conduit d'alimentation. Le clapet présente l'inconvénient, compte tenu de la faible section dudit orifice, de faire subir à l'écoulement du produit une perte de charge non négligeable.FR-A-2,375,111 discloses a valve equipped with a valve sensitive to the action of gravity, placed in a pipe for supplying the valve with product. This valve comprises a ball capable of being applied against a product passage orifice serving as a seat for the ball when the container is upside down, for closing said supply conduit. The valve has the drawback, given the small cross section of said orifice, of subjecting the flow of the product to a significant pressure drop.

On a proposé, dans FR-A-2.680.161, de remédier à cet inconvénient en augmentant la section dudit orifice et en établissant, lorsque la valve est fermée, une communication entre le volume intérieur sous pression du récipient et la région de la valve située en aval de la bille afin d'équilibrer les pressions de part et d'autre de cette dernière et d'éviter qu'elle ne reste plaquée par la pression contre ledit orifice lorsque le récipient retrouve une position normale d'utilisation.It has been proposed, in FR-A-2,680,161, to remedy this drawback by increasing the section of said orifice and by establishing, when the valve is closed, a communication between the interior volume under pressure of the container and the region of the valve located downstream of the ball in order to balance the pressures on either side of the latter and to prevent it from remaining pressed against the said orifice when the container returns to a normal position of use.

La présente invention a pour objet de proposer une valve qui soit de construction simple, n'entraîne pas de perte de charge excessive et dont le fonctionnement est particulièrement fiable.The object of the present invention is to provide a valve which is simple in construction, does not cause excessive pressure drop and whose operation is particularly reliable.

Elle y parvient par le fait que ledit organe mobile est apte à coopérer avec la tige de commande pour s' interposer entre cette dernière et le corps de valve lorsque le récipient est écarté d'une position normale d'utilisation et que la tige de commande est sollicitée en déplacement vers ladite position d'ouverture.It achieves this by the fact that said movable member is able to cooperate with the control rod to be interposed between the latter and the valve body when the container is moved away from a normal position of use and that the control rod is urged to move towards said open position.

Ainsi, il est possible dans une réalisation particulière de l'invention, de faire en sorte que ledit organe mobile empêche la tige de commande d'atteindre ladite position d'ouverture.Thus, it is possible in a particular embodiment of the invention, to ensure that said movable member prevents the control rod from reaching said open position.

Dans une autre réalisation de l'invention, l'intérieur du corps de valve communique par un orifice d'alimentation en produit avec 1'intérieur du récipient et la tige de commande est apte à maintenir ledit organe mobile dans une position d'obturation dudit orifice lorsqu'elle est sollicitée en déplacement en direction de ladite position d'ouverture de la valve.In another embodiment of the invention, the interior of the valve body communicates by a product supply orifice with the interior of the container and the control rod is able to maintain said movable member in a position for closing said orifice when it is urged to move in the direction of said valve opening position.

Grâce à l'invention, il n'est pas nécessaire de prévoir une communication entre le volume intérieur sous pression du récipient et la région de la valve située en aval de l'organe mobile lorsque ce dernier occupe une position rendant la valve inopérante.Thanks to the invention, it is not necessary to provide a communication between the interior volume under pressure of the container and the region of the valve located downstream of the movable member when the latter occupies a position rendering the valve inoperative.

En outre, il est possible d'acheminer le produit vers l'orifice de décharge de la valve sans perte de charge excessive.In addition, it is possible to convey the product to the discharge port of the valve without excessive pressure drop.

L'invention a encore pour objet un récipient équipé d'une valve telle que précitée.The invention also relates to a container equipped with a valve as mentioned above.

D'autres caractéristiques et avantages de la présente invention apparaîtront à la lecture de la description détaillée qui va suivre, de deux exemples de réalisation non limitatifs de l'invention, et à l'examen du dessin annexé sur lequel :Other characteristics and advantages of the present invention will appear on reading the detailed description which follows, of two non-limiting exemplary embodiments of the invention, and on examining the appended drawing in which:

- la figure 1 est une coupe axiale, schématique, d'une valve conforme à un premier exemple de réalisation de l'invention,FIG. 1 is a schematic axial section of a valve according to a first embodiment of the invention,

- la figure 2 représente la valve de la figure 1 dans sa position normale d'utilisation,FIG. 2 represents the valve of FIG. 1 in its normal position of use,

- la figure 3 montre la valve de la figure 1 dans une position inversée par rapport à la position normale d'utilisation, la tige de commande étant au repos,FIG. 3 shows the valve of FIG. 1 in an inverted position relative to the normal position of use, the control rod being at rest,

- la figure 4 est une vue analogue à la figure 3, la tige de commande étant enfoncée,FIG. 4 is a view similar to FIG. 3, the control rod being pushed in,

- la figure 5 est une coupe axiale, schématique, d'une valve conforme à un deuxième exemple de réalisation de l'invention,FIG. 5 is a schematic axial section of a valve according to a second embodiment of the invention,

- la figure 6 représente la valve de la figure 5, en position normale d'utilisation, - la figure 7 représente la valve de la figure 5 dans une position inversée par rapport à la position normale d'utilisation, la tige de commande étant au repos, etFIG. 6 represents the valve of FIG. 5, in the normal position of use, FIG. 7 represents the valve of FIG. 5 in an inverted position relative to the normal position of use, the control rod being at rest, and

- la figure 8 est une vue analogue à la figure 7, la tige de commande étant enfoncée.- Figure 8 is a view similar to Figure 7, the control rod being pressed.

On a représenté sur la figure 1 une valve 1 conforme à un premier exemple de réalisation de l'invention. Cette valve 1 comporte un corps de valve 2 et une tige de commande 3 allongée selon un axe longitudinal X et apte à se déplacer axialement dans le corps de valve 2 entre une position de fermeture de la valve (représentée sur la figure 1) et une position d'ouverture de la valve (représentée sur la figure 2). Le corps de valve comporte, dans l'exemple de réalisation décrit, une partie supérieure 2a. logeant un ressort 4 de rappel de la tige de commande 3 dans ladite position de fermeture et une partie inférieure 2b logeant un organe mobile sensible à l'action de la pesanteur, constitué dans l'exemple décrit par une bille 5 dont le rôle sera précisé dans la suite.There is shown in Figure 1 a valve 1 according to a first embodiment of the invention. This valve 1 comprises a valve body 2 and a control rod 3 elongated along a longitudinal axis X and able to move axially in the valve body 2 between a closed position of the valve (shown in FIG. 1) and a valve open position (shown in Figure 2). The valve body comprises, in the embodiment described, an upper part 2a. housing a return spring 4 for the control rod 3 in said closed position and a lower part 2b housing a movable member sensitive to the action of gravity, constituted in the example described by a ball 5 whose role will be specified in the following.

La partie 2a est fermée à son extrémité supérieure par une rondelle d'étanchéité 6 traversée en son centre 7 par la tige de commande 3. La rondelle 6 repose sur la tranche d'extrémité supérieure 8 de la partie 2a,, bordée par un bossage annulaire 9 destiné à la fixation du corps de valve 2 par sertissage dans un logement 10a_ d'une coupelle 10 à sertir elle-même à sa périphérie sur un récipient connu en lui-même et non représenté. La tige de commande 3 traverse le fond du logement 10a^ à la faveur d'un perçage 11. La coupelle 10 maintient la partie 2a. serrée contre la rondelle d'étanchéité 6 et assure une fixation étanche du corps de valve 2 dans le logement 10a^Part 2a is closed at its upper end by a sealing washer 6 through the center 7 by the control rod 3. The washer 6 rests on the upper end face 8 of the portion 2a, bordered by a boss ring 9 intended for fixing the valve body 2 by crimping in a housing 10a_ a cup 10 to crimp itself at its periphery on a container known in itself and not shown. The control rod 3 passes through the bottom of the housing 10a ^ by means of a bore 11. The cup 10 maintains the part 2a. tight against the sealing washer 6 and ensures a tight fixing of the valve body 2 in the housing 10a ^

La tige de commande 3 est parcourue par un conduit intérieur 12 débouchant à une extrémité sur sa tranche d'extrémité supérieure 13 et à l'autre extrémité sur un orifice latéral 14 situé à mi-longueur environ de celle-ci. Le ressort 4 est enroulé sur une surface cylindrique 15 de la tige de commande 3 servant de guide, prend appui axialement à son extrémité supérieure sur la base d'une couronne 16 formant saillie sur la tige 3 et à son extrémité inférieure sur une paroi transversale inférieure 17 de la partie 2a, s'étendant généralement perpendiculairement à l'axe X. La tige de commande 3 est rappelée par le ressort 4 vers le haut jusqu'à butée d'une lèvre périphérique 16a^ de la couronne 16 contre la rondelle d'étanchéité 6. L'orifice 14 débouche alors sur l'épaisseur de la rondelle d'étanchéité 6 et se trouve obturé par cette dernière. L'étanchéité de la fermeture est améliorée par le fait que la lèvre 16^, en s'appliquant sur la face frontale inférieure de la rondelle d'étanchéité 6, isole le centre 7 de cette dernière de l' intérieur du récipient.The control rod 3 is traversed by an inner conduit 12 opening at one end on its upper end edge 13 and at the other end on a lateral orifice 14 located at about mid-length thereof. The spring 4 is wound on a cylindrical surface 15 of the control rod 3 serving as a guide, bears axially at its upper end on the base of a crown 16 projecting from the rod 3 and at its lower end on a transverse wall lower part 17 of part 2a , generally extending perpendicular to the axis X. The control rod 3 is biased by the spring 4 upwards until a lip stops device 16a ^ of the crown 16 against the sealing washer 6. The orifice 14 then opens onto the thickness of the sealing washer 6 and is closed by the latter. The tightness of the closure is improved by the fact that the lip 16 ^, by applying to the lower front face of the sealing washer 6, isolates the center 7 of the latter from the interior of the container.

La paroi 17 précitée est traversée en son centre par un perçage 18 pour le passage de l'extrémité inférieure 19 de la tige de commande 3. Le diamètre de ce perçage 18 est choisi de manière à ménager avec la portion de la tige de commande 3 qui est engagée à l'intérieur de celui-ci un jeu annulaire 20 permettant au produit contenu dans le récipient de s'écouler depuis l'intérieur de la partie inférieure 2b du corps de valve 2 vers l'intérieur de la partie supérieure 2a.. La partie 2b est fermée à son extrémité inférieure par une pièce rapportée 21 comportant une tubulure 22, munie d'un cône d'ancrage 23 à insérer dans un tube plongeant au sein du produit à distribuer, à l'intérieur du récipient. Ce produit est surmonté, en position normale d'utilisation du récipient, par un gaz propulseur sous pression. La pièce 21 comporte une tubulure supérieure 24 s'étendant à l'intérieur de la partie 2b du corps de valve 2. Les tubulures 22 et 24, d'axe X, se raccordent sur une paroi de support 25 plane et perpendiculaire à l'axe X, fixée à sa périphérie à l'extrémité inférieure de la partie 2b. La pièce 21 forme avec la partie 2b du corps de valve une cavité 26 dans laquelle peut se mouvoir la bille 5. Cette cavité 26 est délimitée radialement à l'extérieur par une surface conique interne 27 de la partie 2b, formant un angle de quelques degrés avec l'axe longitudinal X, et supérieurement par une surface 28 de la partie 2b, symétrique de révolution autour de l'axe X, ayant la forme d'une calotte sphérique concave vers le bas et traversée à son sommet par le perçage 18. La cavité 26 est délimitée radialement à l'intérieur par la surface externe 29 de la tubulure supérieure 24, conique, parallèle à la surface 27, et formant avec cette dernière une gorge annulaire de largeur adaptée à recevoir la bille 5. Dans l'exemple décrit, la distance séparant les surfaces 27 et 29 est légèrement supérieure au diamètre de la bille 5. La section interne de la tubulure 22 est constante, cylindrique de révolution autour de l'axe X. La section interne de la tubulure supérieure 24 se rétrécit en direction de la tige de commande 3. Plus précisément, cette section interne converge en formant un cône de génératrice inclinée par rapport à l'axe X d'un angle supérieur à l'angle entre la génératrice de la surface 27 et l'axe X. La paroi de la tubulure supérieure 24 s'épaissit à mesure que l'on se rapproche de son extrémité supérieure où elle définit un orifice d'alimentation en produit 31 dont le diamètre est inférieur au diamètre de la bille 5, et qui correspond dans l'exemple décrit à environ un tiers de celui-ci. La surface d'extrémité 32 de la tubulure supérieure 24 bordant l'orifice 31 est convexe vers la tige de commande 3.The aforementioned wall 17 is traversed in its center by a bore 18 for the passage of the lower end 19 of the control rod 3. The diameter of this bore 18 is chosen so as to provide space with the portion of the control rod 3 which is engaged inside of it an annular clearance 20 allowing the product contained in the container to flow from the inside of the lower part 2b of the valve body 2 towards the inside of the upper part 2a. Part 2b is closed at its lower end by an insert 21 comprising a tube 22, provided with an anchoring cone 23 to be inserted into a tube immersed in the product to be dispensed, inside the container. This product is surmounted, in the normal position of use of the container, by a propellant gas under pressure. The part 21 comprises an upper tube 24 extending inside the part 2b of the valve body 2. The tubes 22 and 24, of axis X, are connected to a support wall 25 which is flat and perpendicular to the X axis, fixed at its periphery to the lower end of part 2b. The part 21 forms with the part 2b of the valve body a cavity 26 in which the ball 5 can move. This cavity 26 is delimited radially on the outside by an internal conical surface 27 of the part 2b, forming an angle of a few degrees with the longitudinal axis X, and superiorly by a surface 28 of the part 2b, symmetrical of revolution around the axis X, having the shape of a spherical cap concave downwards and crossed at its top by the hole 18 The cavity 26 is delimited radially on the inside by the external surface 29 of the upper conical tube 24, parallel to the surface 27, and forming with the latter an annular groove of width adapted to receive the ball 5. In the example described, the distance separating the surfaces 27 and 29 is slightly greater than the diameter of the ball 5. The internal section of the tubing 22 is constant, cylindrical of revolution around the axis X. The internal section of the upper tubing 24 narrows in the direction of the control rod 3. More specifically, this internal section converges to form a cone of generator inclined relative to the axis X by an angle greater than the angle between the generator of the surface 27 and the axis X. The wall of the upper tube 24 thickens as one approaches from its upper end where it defines a product supply orifice 31 whose diameter is less than the diameter of the ball 5, and which corresponds in the example described to approximately one third of it. The end surface 32 of the upper tube 24 bordering the orifice 31 is convex towards the control rod 3.

La surface d'extrémité inférieure 19 de la tige de commande 3 est concave, conformée pour épouser la courbure de la bille 5 et l'entraîner en déplacement lorsque le récipient est utilisé tête en bas, comme cela sera précisé dans la suite.The lower end surface 19 of the control rod 3 is concave, shaped to match the curvature of the ball 5 and cause it to move when the container is used upside down, as will be explained below.

La valve 1 est destinée à fonctionner normalement lorsque le récipient est utilisé tête en haut, comme représenté sur les figures 1 et 2, et à être inopérante lorsque le récipient est utilisé tête en bas, comme représenté sur les figures 3 et 4.The valve 1 is intended to operate normally when the container is used upside down, as shown in FIGS. 1 and 2, and to be inoperative when the container is used upside down, as shown in FIGS. 3 and 4.

En position normale d'utilisation du récipient, lorsque la tige de commande 3 est enfoncée dans le corps de valve 2, l'orifice 14 débouche sous la rondelle d'étanchéité 6 et autorise un départ de produit selon le trajet fléché P de la figure 2. Le produit provenant du tube plongeur fixé à l'embout 22 traverse l'orifice d'alimentation 31, puis la paroi 17 à la faveur du jeu annulaire 20 ménagé entre le perçage 18 et l'extrémité inférieure de la tige de commande 3, passe dans l'intervalle ménagé entre la lèvre annulaire 16a et la face frontale inférieure de la rondelle 6, dans l'orifice 14, et quitte la tige de commande par le conduit 12 pour être acheminé vers une buse de distribution connue en elle-même et non représentée, par exemple fixée sur un poussoir emmanché à l'extrémité supérieure de la tige de commande 3. La bille 5, qui repose dans le fond de la gorge annulaire formée entre les surfaces 27 et 29 ne gêne pas l'écoulement du produit.In the normal position of use of the container, when the control rod 3 is pressed into the valve body 2, the orifice 14 opens out under the sealing washer 6 and allows a product to flow out along the arrowed path P in the figure 2. The product coming from the dip tube fixed to the end piece 22 passes through the supply orifice 31, then the wall 17 thanks to the annular clearance 20 formed between the bore 18 and the lower end of the control rod 3 , passes in the interval formed between the annular lip 16a and the lower front face of the washer 6, in the orifice 14, and leaves the control rod through the conduit 12 to be routed to a distribution nozzle known in it- same and not shown, for example fixed on a pusher fitted to the upper end of the control rod 3. The ball 5, which rests in the bottom of the annular groove formed between the surfaces 27 and 29 does not impede the flow of the product.

Lorsque le récipient est retourné avec la valve au repos, comme représenté sur la figure 3, la bille 5 est guidée par la surface conique 27 et la surface concave 28 vers le perçage 18 et, l'extrémité — O —When the container is turned over with the valve at rest, as shown in FIG. 3, the ball 5 is guided by the conical surface 27 and the concave surface 28 towards the bore 18 and, the end - O -

19 de la tige 3 venant au niveau des bords du perçage 18 adjacents à la cavité 26, la bille 5 se loge dans la concavité de l'extrémité 19. Si l'utilisateur enfonce la tige de commande 3 dans le corps 2, la bille 5 se déplace avec la tige de commande 3 et elle est appliquée par cette dernière contre les bords de l'orifice 31 qu'elle vient obturer, comme représenté sur la figure 4. La bille 5 s'oppose ainsi au passage de produit et la valve est inopérante.19 of the rod 3 coming at the edges of the bore 18 adjacent to the cavity 26, the ball 5 is housed in the concavity of the end 19. If the user pushes the control rod 3 into the body 2, the ball 5 moves with the control rod 3 and it is applied by the latter against the edges of the orifice 31 which it comes to close, as shown in FIG. 4. The ball 5 thus opposes the passage of product and the valve is inoperative.

Dans l'exemple décrit, la course de la tige de commande qui est nécessaire pour appliquer la bille 5 contre l'orifice 31 et obturer ce dernier, est supérieure à la course nécessaire pour dégager l'orifice 14.In the example described, the stroke of the control rod which is necessary to apply the ball 5 against the orifice 31 and to close the latter, is greater than the stroke necessary to clear the orifice 14.

En variante, dans un exemple de réalisation non représenté, on pourrait rapprocher l'orifice 31 et l'extrémité 19 de la tige de commande 3 de manière à ce que, lorsque la tige de commande 3 applique la bille 5 contre l'orifice 31, l'orifice 14 se trouve toujours obturé par la rondelle d'étanchéité 6. La bille 5 agirait alors simplement pour limiter la course en déplacement de la tige de commande 3 afin de l'empêcher d'atteindre l'enfoncement nécessaire pour dégager l'orifice 14 et ouvrir la valve.As a variant, in an embodiment not shown, the orifice 31 and the end 19 of the control rod 3 could be brought closer so that, when the control rod 3 applies the ball 5 against the orifice 31 , the orifice 14 is always closed by the sealing washer 6. The ball 5 would then act simply to limit the displacement travel of the control rod 3 in order to prevent it from reaching the depression necessary to release the orifice 14 and open the valve.

On a représenté sur les figures 5 à 8, une valve l' conforme à un deuxième exemple de réalisation de l'invention, la valve l' fonctionnant normalement lorsque le récipient est tête en bas, et étant rendue inopérante lorsque le récipient est retourné.There is shown in Figures 5 to 8, a valve according to a second embodiment of the invention, the valve operating normally when the container is upside down, and being rendered inoperative when the container is inverted.

La valve l' comporte une partie 2a, identique à celle de l'exemple de réalisation précédent, et fixée de manière semblable sur la coupelle 10 du récipient.The valve 1a has a part 2a , identical to that of the previous embodiment, and similarly fixed to the cup 10 of the container.

Des signes de référence identiques ont été employés pour désigner des éléments communs aux deux exemples de réalisation représentés sur les figures, et dont la description ne sera pas reprise dans le détail.Identical reference signs have been used to designate elements common to the two embodiments shown in the figures, the description of which will not be repeated in detail.

La valve l' comporte une tige de commande 3' qui diffère de la tige de commande 3 précédemment décrite par le fait qu'elle se prolonge au-delà du perçage 18 pour faire saillie à l'intérieur d'une deuxième partie 2b' du corps de valve 2 ' . La partie 2b' est identique extérieurement à la partie 2b précédemment décrite, mais définit une cavité 26', dans laquelle se déplace la bille 5, de forme différente. La cavité 26' est délimitée latéralement par une surface conique 27' convergeant en éloignement de la tige de commande 3', de génératrice faisant un angle de quelques degrés avec l'axe X. Cette surface conique 27' est raccordée supérieurement à une surface 28' concave vers la tige de commande 3', constituée dans l'exemple décrit par une calotte sphérique. La cavité 26' est délimitée à l'opposé de la surface 28' par la paroi transversale 17 de la partie 2a. du corps de valve 2'. La surface 28' est traversée en son sommet par un perçage 31' débouchant à l'intérieur de la tubulure 22, qui est dépourvue de tube plongeur dans cette réalisation et qui pourrait être supprimée. La partie 2b' comporte intérieurement un voile de matière 24' de forme tronconique, définissant avec la surface 27' une gorge annulaire dont la largeur d'ouverture est légèrement supérieure au diamètre de la bille 5. Lorsque la tige de commande 3' est au repos, son extrémité 19' se situe au niveau de l'extrémité supérieure du voile 24'. Le diamètre du perçage 31' est inférieur au diamètre de la bille 5. L'extrémité 19' présente une forme sphérique convexe en direction du perçage 31' .The valve 1 'comprises a control rod 3' which differs from the control rod 3 previously described in that it extends beyond the bore 18 to protrude inside a second part 2b 'of the valve body 2 '. Part 2b 'is identical externally to part 2b previously described, but defines a cavity 26', in which the ball 5 moves, of different shape. The cavity 26 'is delimited laterally by a surface conical 27 ′ converging away from the control rod 3 ′, of generatrix making an angle of a few degrees with the axis X. This conical surface 27 ′ is connected above a surface 28 ′ concave towards the control rod 3 ′, constituted in the example described by a spherical cap. The cavity 26 'is delimited opposite the surface 28' by the transverse wall 17 of the part 2a. valve body 2 '. The surface 28 'is crossed at its top by a bore 31' opening into the interior of the tube 22, which is devoid of dip tube in this embodiment and which could be omitted. The part 2b 'internally comprises a web of material 24' of frustoconical shape, defining with the surface 27 'an annular groove whose opening width is slightly greater than the diameter of the ball 5. When the control rod 3' is at rest, its end 19 'is located at the upper end of the web 24'. The diameter of the bore 31 'is less than the diameter of the ball 5. The end 19' has a convex spherical shape in the direction of the bore 31 '.

Le fonctionnement de la valve l' est le suivant.The operation of the valve is as follows.

En position normale d'utilisation du récipient, la bille 5 repose dans le fond de la gorge annulaire délimitée par le voile de matière 24' et la surface 27'. Lorsque l'utilisateur enfonce la tige de commande 3' dans le corps de valve 2', l'orifice 14 est dégagé, et du produit peut s'écouler selon le trajet fléché P sur la figure 6, à travers le perçage 31', le jeu annulaire ménagé entre le perçage 18 et la tige de commande 3', l'intervalle annulaire entre la lèvre 16a et la rondelle d'étanchéité 6, pour quitter la tige de commande 3' par le conduit 12.In the normal position of use of the container, the ball 5 rests in the bottom of the annular groove delimited by the web of material 24 'and the surface 27'. When the user pushes the control rod 3 ′ into the valve body 2 ′, the orifice 14 is released, and the product can flow along the arrowed path P in FIG. 6, through the bore 31 ′, the annular clearance formed between the bore 18 and the control rod 3 ', the annular gap between the lip 16a and the sealing washer 6, to leave the control rod 3' through the conduit 12.

Lorsque le récipient est retourné, la bille 5 tombe dans le fond de la surface concave 28' et se positionne dans l'orifice 31', comme représenté sur la figure 7.When the container is inverted, the ball 5 falls into the bottom of the concave surface 28 'and is positioned in the orifice 31', as shown in FIG. 7.

Lorsque l'utilisateur enfonce la tige de commande 3', l'extrémité 19' vient appuyer sur la bille 5 et la maintient plaquée contre les bords de l'orifice 31' qu'elle obture, comme représenté sur la figure 8. La valve l' est ainsi rendue inopérante.When the user pushes the control rod 3 ′, the end 19 ′ presses on the ball 5 and keeps it pressed against the edges of the orifice 31 ′ which it closes, as shown in FIG. 8. The valve it is thus rendered inoperative.

Finalement, l'invention permet de rendre inopérante ou non une valve d'un récipient pressurisé selon la position tête en haut ou tête en bas de celui-ci, sans toutefois faire subir une perte de charge excessive à l'écoulement du produit quittant le récipient. La structure d'une valve selon l'invention est simple, et elle est peu coûteuse à réaliser. Le maintien par la tige de commande de la bille en position d'obturation permet d'utiliser une bille de faibles dimensions et de faible poids, et d'obtenir des déplacements rapides de la bille vers les positions rendant inopérante la valve ou au contraire autorisant son fonctionnement normal.Finally, the invention makes it possible to make a valve of a pressurized container inoperative or not depending on the head-up or head-down position of the latter, without however causing a pressure drop excessive flow of product leaving the container. The structure of a valve according to the invention is simple, and it is inexpensive to produce. Holding the ball control rod in the closed position allows the use of a ball of small dimensions and low weight, and to obtain rapid movements of the ball towards the positions rendering the valve inoperative or on the contrary allowing its normal operation.

Bien entendu, on peut apporter diverses modifications aux exemples de réalisation décrits sans sortir du cadre de la présente invention.Of course, various modifications can be made to the embodiments described without departing from the scope of the present invention.

On peut ainsi modifier la forme de la tige de commande ou celle du corps de valve, ou encore remplacer le ressort de rappel par un organe de rappel élastique venu de moulage avec la tige de commande. On peut encore utiliser une bille 5 en métal, en matière plastique rigide ou élastomère. It is thus possible to modify the shape of the control rod or that of the valve body, or even to replace the return spring with an elastic return member molded with the control rod. It is also possible to use a metal ball 5, made of rigid plastic or elastomer.

Claims

REVENDICATIONS 1. Valve pour récipient apte à contenir un produit pressurisé, cette valve comportant un corps de valve et une tige de commande, mobile dans ledit corps de valve lorsque le récipient est dans une position normale d'utilisation, entre une position d'ouverture de la valve et une position de fermeture de celle-ci, la valve comportant en outre un organe mobile sensible à l'action de la pesanteur, apte à rendre la valve inopérante lorsque le récipient est écarté, au-delà d'une limite prédéterminée, de sa position normale d'utilisation, caractérisée par le fait que ledit organe mobile (5) est apte à coopérer avec la tige de commande (3; 3') lorsque ledit récipient est écarté, au-delà de ladite limite prédéterminée, de sa position normale d'utilisation pour s'interposer entre le corps de valve et la tige de commande lorsque cette dernière est sollicitée en déplacement vers ladite position d'ouverture.1. Valve for container capable of containing a pressurized product, this valve comprising a valve body and a control rod, movable in said valve body when the container is in a normal position of use, between an open position of the valve and a closed position thereof, the valve further comprising a movable member sensitive to the action of gravity, capable of rendering the valve inoperative when the container is moved aside, beyond a predetermined limit, from its normal position of use, characterized in that said movable member (5) is able to cooperate with the control rod (3; 3 ') when said container is moved, beyond said predetermined limit, from its normal position of use for interposing between the valve body and the control rod when the latter is urged to move towards said open position. 2. Valve selon la revendication 1, caractérisée par le fait que ledit organe mobile est apte à s'interposer entre le corps de valve et la tige de commande pour empêcher cette dernière d'atteindre ladite position d'ouverture.2. Valve according to claim 1, characterized in that said movable member is capable of interposing between the valve body and the control rod to prevent the latter from reaching said open position. 3. Valve selon la revendication 1 ou la revendication 2, caractérisée par le fait que l'intérieur du corps de valve (2; 2') communique par un orifice d'alimentation en produit (31; 31') avec l'intérieur du récipient, et par le fait que la tige de commande est apte à maintenir ledit organe mobile dans une position d'obturation dudit orifice.3. Valve according to claim 1 or claim 2, characterized in that the interior of the valve body (2; 2 ') communicates through a product supply orifice (31; 31') with the interior of the container, and by the fact that the control rod is able to maintain said movable member in a closed position of said orifice. 4. Valve selon la revendication 3, caractérisée par le fait que ledit orifice d'alimentation en produit (31) débouche à l'extrémité d'une tubulure (24) formant saillie à l'intérieur d'une cavité (26) du corps de valve (2) en ménageant avec la paroi dudit corps de valve une gorge annulaire apte à loger ledit organe mobile (5) en position normale d'utilisation du récipient, et par le fait que la paroi de ladite cavité faisant face audit orifice d'alimentation (7) est généralement concave vers ladite tubulure (24) et ajourée en son sommet (18) pour le passage d'une extrémité (19) de la tige de commande (3), cette dernière étant en outre conformée de manière à transporter ledit organe mobile pour l'appliquer contre ledit orifice (31) lorsqu'elle est déplacée depuis ladite position de fermeture vers ladite position d'ouverture et que le récipient est dans ladite position écartée de sa position normale d'utilisation.4. Valve according to claim 3, characterized in that said product supply orifice (31) opens at the end of a tube (24) projecting inside a cavity (26) of the body valve (2) by providing with the wall of said valve body an annular groove capable of accommodating said movable member (5) in the normal position of use of the container, and by the fact that the wall of said cavity facing said orifice 'supply (7) is generally concave towards said tube (24) and perforated at its top (18) for the passage of one end (19) of the control rod (3), the latter being further shaped so as to transporting said movable member to apply it against said orifice (31) when it is moved from said position of closing towards said open position and the container is in said position away from its normal position of use. 5. Valve selon la revendication 4, caractérisée par le fait que la tubulure (24) présente à son extrémité par laquelle débouche ledit orifice d'alimentation (31) une forme généralement convexe vers ladite tige de commande (3) .5. Valve according to claim 4, characterized in that the tubing (24) has at its end through which said feed orifice (31) opens a generally convex shape towards said control rod (3). 6. Valve selon la revendication 4 ou la revendication 5, caractérisée par le fait que ladite extrémité (19) de la tige de commande (3) est concave vers ladite tubulure (24).6. Valve according to claim 4 or claim 5, characterized in that said end (19) of the control rod (3) is concave towards said tube (24). 7. Valve selon la revendication 3, caractérisée par le fait que ledit orifice d'alimentation en produit (31') débouche dans le fond d'une surface (28') concave en direction de la tige de commande (3') d'une cavité (26') du corps de valve (2') dans laquelle ledit organe mobile (5) est retenu, et par le fait que ladite tige de commande (3') débouche dans ladite cavité (26') à l'opposé dudit orifice (31').7. Valve according to claim 3, characterized in that said product supply orifice (31 ') opens into the bottom of a concave surface (28') in the direction of the control rod (3 ') of a cavity (26 ') of the valve body (2') in which said movable member (5) is retained, and by the fact that said control rod (3 ') opens into said cavity (26') opposite of said orifice (31 '). 8. Valve selon l'une quelconque des revendications 1 à 7, caractérisée par le fait que ledit organe mobile est constitué par une bille (5).8. Valve according to any one of claims 1 to 7, characterized in that said movable member is constituted by a ball (5). 9. Récipient pressurisé, caractérisé par le fait qu'il est équipé d'une valve conforme à l'une quelconque des revendications précédentes. 9. Pressurized container, characterized in that it is equipped with a valve according to any one of the preceding claims.
PCT/FR1996/001082 1995-07-11 1996-07-11 Valve for a pressurised container and container provided therewith WO1997003000A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9508355A FR2736702B1 (en) 1995-07-11 1995-07-11 VALVE FOR PRESSURIZED CONTAINER AND CONTAINER THUS EQUIPPED
FR95/08355 1995-07-11

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999010254A1 (en) 1997-08-27 1999-03-04 The Procter & Gamble Company Process for filling pressurised containers and valve therefor
GB2474576A (en) * 2009-10-16 2011-04-20 Ian Hill Coupler with gravity operated safety valve

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2843949B1 (en) * 2002-08-30 2004-11-19 Oreal VALVE FOR PRESSURIZED CONTAINER
US7014072B2 (en) 2002-08-30 2006-03-21 L'oreal Valve for a pressurized receptacle

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2295332A1 (en) * 1974-12-18 1976-07-16 Aerosol Inventions Dev VALVES FOR PRESSURE DISTRIBUTORS
FR2375111A1 (en) * 1976-12-27 1978-07-21 Spitzer Joseph G SAFETY CONTAINER WITH AEROSOL VALVE
JPS5761874A (en) * 1980-10-02 1982-04-14 Nakamura Seitai Ginou Kenkyusho:Kk Safety device for combustion gas
FR2680161A1 (en) * 1991-08-07 1993-02-12 Oreal Valve for pressurised container of the aerosol can type, and pressurised can fitted with such a valve

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2295332A1 (en) * 1974-12-18 1976-07-16 Aerosol Inventions Dev VALVES FOR PRESSURE DISTRIBUTORS
FR2375111A1 (en) * 1976-12-27 1978-07-21 Spitzer Joseph G SAFETY CONTAINER WITH AEROSOL VALVE
JPS5761874A (en) * 1980-10-02 1982-04-14 Nakamura Seitai Ginou Kenkyusho:Kk Safety device for combustion gas
FR2680161A1 (en) * 1991-08-07 1993-02-12 Oreal Valve for pressurised container of the aerosol can type, and pressurised can fitted with such a valve

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 006, no. 138 (M - 145) 27 July 1982 (1982-07-27) *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999010254A1 (en) 1997-08-27 1999-03-04 The Procter & Gamble Company Process for filling pressurised containers and valve therefor
GB2474576A (en) * 2009-10-16 2011-04-20 Ian Hill Coupler with gravity operated safety valve
GB2474576B (en) * 2009-10-16 2014-03-19 Ian Hill Coupler
US9297141B2 (en) 2009-10-16 2016-03-29 Ian Hill Coupler

Also Published As

Publication number Publication date
FR2736702B1 (en) 1997-08-22
FR2736702A1 (en) 1997-01-17

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