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WO1997000995A1 - Composition et procede permettant de conferer des proprietes repulsives durables a des substrats - Google Patents

Composition et procede permettant de conferer des proprietes repulsives durables a des substrats Download PDF

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Publication number
WO1997000995A1
WO1997000995A1 PCT/US1996/008302 US9608302W WO9700995A1 WO 1997000995 A1 WO1997000995 A1 WO 1997000995A1 US 9608302 W US9608302 W US 9608302W WO 9700995 A1 WO9700995 A1 WO 9700995A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
carpet
fluorochemical
grafted
water
Prior art date
Application number
PCT/US1996/008302
Other languages
English (en)
Inventor
Lori P. Engle
Steven J. Hamrock
Mark J. Pellerite
Original Assignee
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/653,548 external-priority patent/US5888290A/en
Application filed by Minnesota Mining And Manufacturing Company filed Critical Minnesota Mining And Manufacturing Company
Priority to EP96916933A priority Critical patent/EP0837963A1/fr
Priority to JP9503848A priority patent/JPH11509585A/ja
Priority to AU59645/96A priority patent/AU704867B2/en
Publication of WO1997000995A1 publication Critical patent/WO1997000995A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/309—Combinations of treatments provided for in groups C09C1/3009 - C09C1/3081
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D06M13/517—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond containing silicon-halogen bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/657—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C01P2004/52—Particles with a specific particle size distribution highly monodisperse size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475—Inorganic materials
    • C03C2217/478—Silica

Definitions

  • this invention provides a fluorochemical treatment composition which can be used to impart durable water and oil repellency, durable stain release, and durable dry soil resistance to substrates, e.g., carpets, fabrics (both woven and non-woven), papers, wood, concrete, and leather.
  • the composition comprises (a) a sol comprising a colloidal dispersion of substantially discrete, substantially monodisperse in size, polymer-grafted, inorganic microparticles in liquid; and (b) at least one fluorochemical. Microparticles having polymodal size distributions prepared from blends of monodisperse distributions can also be utilized in forming the sol.
  • silica microparticles can be treated with hydrolyzable, chain transfer group- containing organosilanes under conditions such that silanol groups on the surface of the particles chemically bond with hydrolyzed silane groups to produce covalent silicon-oxyge -silicon bonds.
  • Dynamic water resistance of a carpet sample was determined by inclining a test sample (15.2 cm X 30.5 cm) at an angle of 45° from horizontal and impinging deionized (D.I.) water (20 ml) onto the center of the carpet sample through a 5 mm i.d. tube positioned 45.7 cm above the sample.
  • the increase in weight of the test sample provided an indication of its ability to repel water, with lower weight gains indicating better repellency properties.
  • D.I. water 50 g was added to a Sn0 2 suspension (50 g, 88SN-123, 20% solids, ⁇ 10 nm particle size, pH 10, available from Nalco Chemical Co.) to produce an approximately 10% solids colloidal suspension.
  • Mercaptopropyl trimethoxy silane (0.25g, 0.13 mM/g) was added to this suspension and the mixture heated, with stirring, at 80°C for 16h.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Paints Or Removers (AREA)
  • Silicon Polymers (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

Cette invention concerne une composition fluorochimique de traitement, laquelle comprend (a) un sol contenant une dispersion colloïdale dans un liquide, de microparticules non organiques, à greffe polymère, sensiblement monodispersées en taille et sensiblement discrètes, et (b) au moins un produit fluorochimique. Cette composition peut être utilisée afin de conférer à des substrats divers des propriétés oléorésistantes et imperméabilisantes durables, d'aptitude au détachage et de résistance aux salissures sèches.
PCT/US1996/008302 1995-06-23 1996-06-03 Composition et procede permettant de conferer des proprietes repulsives durables a des substrats WO1997000995A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP96916933A EP0837963A1 (fr) 1995-06-23 1996-06-03 Composition et procede permettant de conferer des proprietes repulsives durables a des substrats
JP9503848A JPH11509585A (ja) 1995-06-23 1996-06-03 支持体に持続的な撥液性を付与するための組成物および方法
AU59645/96A AU704867B2 (en) 1995-06-23 1996-06-03 Composition and process for imparting durable repellency to substrates

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US46895P 1995-06-23 1995-06-23
US60/000,468 1995-06-23
US08/653,548 1996-05-24
US08/653,548 US5888290A (en) 1996-05-24 1996-05-24 Composition and process for imparting durable repellency to substrates

Publications (1)

Publication Number Publication Date
WO1997000995A1 true WO1997000995A1 (fr) 1997-01-09

Family

ID=26667687

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/008302 WO1997000995A1 (fr) 1995-06-23 1996-06-03 Composition et procede permettant de conferer des proprietes repulsives durables a des substrats

Country Status (5)

Country Link
EP (1) EP0837963A1 (fr)
JP (1) JPH11509585A (fr)
AU (1) AU704867B2 (fr)
CA (1) CA2225526A1 (fr)
WO (1) WO1997000995A1 (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057205A1 (fr) * 1998-05-04 1999-11-11 3M Innovative Properties Company Composition de ceramere possedant des caracteristiques de resistance a l'abrasion et aux taches
WO2000009798A1 (fr) * 1998-08-17 2000-02-24 The Dow Chemical Company Dossier de tapis anti-deversement
WO2000050517A1 (fr) * 1999-02-22 2000-08-31 3M Innovative Properties Company Composition et composite de ceramere contenant une composante de compose fluore a durcissement radicalaire
WO2001075216A1 (fr) * 2000-04-04 2001-10-11 Schoeller Textil Ag Appret de fibres textiles, de tissus et de structures planes
DE10021726A1 (de) * 2000-05-04 2001-11-15 Henkel Kgaa Verwendung von nanoskaligen Teilchen zur Verbesserung der Schmutzablösung
WO2001096511A3 (fr) * 2000-06-14 2002-07-25 Procter & Gamble Compositions de revetement servant a modifier des surfaces dures
EP1245658A1 (fr) * 2001-03-30 2002-10-02 Central Glass Company, Limited Article hydrophobe
US6479612B1 (en) 1999-08-10 2002-11-12 E. I. Du Pont De Nemours And Company Fluorochemical water and oil repellents
US6743844B1 (en) 1998-08-17 2004-06-01 Dow Global Technologies Inc. Spill resistant carpet backing
WO2004074568A1 (fr) * 2003-02-18 2004-09-02 Basf Aktiengesellschaft Procede d'impermeabilisation de matieres textiles
US7115688B1 (en) 1998-11-30 2006-10-03 Nanosphere, Inc. Nanoparticles with polymer shells
US7160480B2 (en) 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
US7192986B2 (en) * 1997-03-12 2007-03-20 Catalysts & Chemicals Industries Co., Ltd. Inorganic compound sol modified by organic compound
WO2007031490A1 (fr) * 2005-09-16 2007-03-22 Basf Se Procede d'application de revetements sur des surfaces et particules adaptees a cet effet
WO2008090191A3 (fr) * 2007-01-26 2010-01-07 Basf Se Particules, procédé de fabrication et utilisation
CN103451924A (zh) * 2013-07-24 2013-12-18 吴江市七都镇庙港雅迪针织制衣厂 一种含有甘露醇的羊毛衫拒水拒油整理剂

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001012166A2 (fr) 1999-08-17 2001-02-22 University Of Saskatchewan Technologies Inc. Traitement ameliore de troubles physiques aigus du systeme nerveux central
EP1277766B1 (fr) * 2001-07-20 2009-06-24 Rohm And Haas Company Composé polymère contenant des groupes d'ester de silicium et compositions les contenant
DE102004020112A1 (de) * 2003-07-04 2005-01-20 Bayer Chemicals Ag Papierherstellung mit modifizierten Kieselsolen als Mikropartikel
EP1533356A1 (fr) * 2003-11-24 2005-05-25 3M Innovative Properties Company Composition fluorochimique pour rendre des substrats oléophobes et/ou hydrophobes
ES2302199T3 (es) * 2004-05-19 2008-07-01 Basf Se Procedimiento para el acabado de materiales absorbentes.
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US7192986B2 (en) * 1997-03-12 2007-03-20 Catalysts & Chemicals Industries Co., Ltd. Inorganic compound sol modified by organic compound
WO1999057205A1 (fr) * 1998-05-04 1999-11-11 3M Innovative Properties Company Composition de ceramere possedant des caracteristiques de resistance a l'abrasion et aux taches
WO2000009798A1 (fr) * 1998-08-17 2000-02-24 The Dow Chemical Company Dossier de tapis anti-deversement
US6743844B1 (en) 1998-08-17 2004-06-01 Dow Global Technologies Inc. Spill resistant carpet backing
US7115688B1 (en) 1998-11-30 2006-10-03 Nanosphere, Inc. Nanoparticles with polymer shells
US6497961B2 (en) 1999-02-22 2002-12-24 3M Innovative Properties Company Ceramer composition and composite comprising free radically curable fluorochemical component
US6238798B1 (en) 1999-02-22 2001-05-29 3M Innovative Properties Company Ceramer composition and composite comprising free radically curable fluorochemical component
WO2000050517A1 (fr) * 1999-02-22 2000-08-31 3M Innovative Properties Company Composition et composite de ceramere contenant une composante de compose fluore a durcissement radicalaire
US6479612B1 (en) 1999-08-10 2002-11-12 E. I. Du Pont De Nemours And Company Fluorochemical water and oil repellents
US7056845B2 (en) * 2000-04-04 2006-06-06 Schoeller Textil Ag Finishing of textile fibers, tissues and fabrics
WO2001075216A1 (fr) * 2000-04-04 2001-10-11 Schoeller Textil Ag Appret de fibres textiles, de tissus et de structures planes
DE10021726A1 (de) * 2000-05-04 2001-11-15 Henkel Kgaa Verwendung von nanoskaligen Teilchen zur Verbesserung der Schmutzablösung
WO2001096511A3 (fr) * 2000-06-14 2002-07-25 Procter & Gamble Compositions de revetement servant a modifier des surfaces dures
US7452605B2 (en) 2001-03-30 2008-11-18 Central Glass Company, Limited Article superior in slipping waterdrops down surface thereof
EP1398362A1 (fr) * 2001-03-30 2004-03-17 Central Glass Company, Limited Article hydrophobe
EP1245658A1 (fr) * 2001-03-30 2002-10-02 Central Glass Company, Limited Article hydrophobe
WO2004074568A1 (fr) * 2003-02-18 2004-09-02 Basf Aktiengesellschaft Procede d'impermeabilisation de matieres textiles
US7790238B2 (en) 2003-02-18 2010-09-07 Basf Aktiengesellschaft Method for hydrophobing textile materials
US7955518B2 (en) 2003-02-18 2011-06-07 Basf Aktiengesellschaft Method for hydrophobing textile materials
US7160480B2 (en) 2005-02-22 2007-01-09 E. I. Du Pont De Nemours And Company Leather treated with fluorochemicals
WO2007031490A1 (fr) * 2005-09-16 2007-03-22 Basf Se Procede d'application de revetements sur des surfaces et particules adaptees a cet effet
US7906172B2 (en) 2005-09-16 2011-03-15 Basf Aktiengesellschaft Method for coating surfaces and suitable particles therefor
WO2008090191A3 (fr) * 2007-01-26 2010-01-07 Basf Se Particules, procédé de fabrication et utilisation
CN103451924A (zh) * 2013-07-24 2013-12-18 吴江市七都镇庙港雅迪针织制衣厂 一种含有甘露醇的羊毛衫拒水拒油整理剂

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EP0837963A1 (fr) 1998-04-29
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AU5964596A (en) 1997-01-22
AU704867B2 (en) 1999-05-06

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