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WO1996037594A1 - Composition nettoyante aqueuse d'usage personnel a phase huileuse dispersee comportant deux composantes huiles definies specifiquement - Google Patents

Composition nettoyante aqueuse d'usage personnel a phase huileuse dispersee comportant deux composantes huiles definies specifiquement Download PDF

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Publication number
WO1996037594A1
WO1996037594A1 PCT/US1996/006575 US9606575W WO9637594A1 WO 1996037594 A1 WO1996037594 A1 WO 1996037594A1 US 9606575 W US9606575 W US 9606575W WO 9637594 A1 WO9637594 A1 WO 9637594A1
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WIPO (PCT)
Prior art keywords
oil
composition according
surfactant
alkyl
mixtures
Prior art date
Application number
PCT/US1996/006575
Other languages
English (en)
Inventor
Gayle Marie Frankenbach
Nicola Jacqueline Phipps
Wendy Victoria J. Richardson
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP96920163A priority Critical patent/EP0828814A4/fr
Priority to US08/973,055 priority patent/US5942479A/en
Publication of WO1996037594A1 publication Critical patent/WO1996037594A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to cleansing compositions.
  • mild personal cleansing compositions with good skin feel attributes and foaming properties suitable for simultaneously cleansing and conditioning the skin and/or the hair and which may be used, for example, in the form of foam bath preparations, shower products, skin cleansers, hand, face and body cleansers, shampoos, etc.
  • Mild cosmetic compositions must satisfy a number of criteria including cleansing power, foaming properties and mildness/low irritancy/good feel with respect to the skin, hair and the ocular mucosae.
  • Skin is made up of several layers of cells which coat and protect the keratin and collagen fibrous proteins that form the skeleton of its structure. The outermost of these layers, referred to as the stratum corneum, is known to be composed of 250 A protein bundles surrounded by 80 A thick layers. Hair similarly has a protective outer coating enclosing the hair fibre which is called the cuticle.
  • Anionic surfactants can penetrate the stratum corneum membrane and the cuticle and, by delipidization destroy membrane integrity. This interference with skin and hair protective membranes can lead to a rough skin feel and eye irritation and may eventually permit the surfactant to interact with the keratin and hair proteins creating irritation and loss of barrier and water retention functions.
  • Ideal cosmetic cleansers should cleanse the skin or hair gently, without defatting and/or drying the hair and skin and without irritating the ocular mucosae or leaving skin taut after frequent use. Most lathering soaps, shower and bath products, shampoos and bars fail in this respect.
  • oils in bathing compositions can provide post-use skin feel benefits.
  • incorporation of oils at levels sufficient to deliver consumer noticeable benefits has until now proved to be a challenge, particularly with respect to the delivery of good, stable lather characteristics in the presence of oil and avoiding unpleasant 'slimy 7 'greasy' water feel or oily appearance during use while still delivering a desirable after-use soft skin feel.
  • the subject of the present invention is a mild, foam-producing cleansing product suitable for personal cleansing of the skin or hair and which may be used as foam bath and shower products, skin cleansers and shampoos etc.
  • a personal cleansing composition comprising:
  • a dispersed oil phase comprising a first oil component having an oil/surfactant solution interfacial tension (IFT) of greater than about 1.0 dynes/cm and a second oil component having an oil/surfactant solution interfacial tension (IFT) in the range of from about 0.1 to about 1.0 dynes/cm;
  • IFT oil/surfactant solution interfacial tension
  • first to second dispersed oil component is in the range from about 20 : 1 to about 1 : 20.
  • the first oil component is selected from polyol fatty acid polyesters, especially nonocclusive liquid polyol fatty acid polyesters containing at least four fatty acid ester groups and wherein the polyol moiety is selected from sugars and sugar alcohols containing from about 4 to about 8 hydroxyl groups, and wherein each carboxylic acid moiety has from about 8 to about 22 carbon atoms and wherein the liquid polyol fatty acid polyester has a complete melting point of less than about 30°C.
  • an aqueous personal cleansing composition comprising:
  • a dispersed oil phase comprising at least one nonocclusive liquid polyol fatty acid polyester containing at least four fatty acid ester groups wherein the polyol moiety is selected from sugars and sugar alcohols containing from about 4 to about 8 hydroxyl groups, and wherein each carboxylic acid moiety has from about 8 to about 22 carbon atoms and wherein the liquid polyol fatty acid polyester has a complete melting point of less than about 30°C;
  • the invention takes the form of a foam producing cleansing composition with excellent lather and stability characteristics, superior skin feel characteristics, improved perceived dryness and assessed tightness and expertly graded dryness, combined with good cleansing ability and conditioning performance.
  • the cleansing compositions herein are based on a combination of a dispersed oil phase and a water-soluble surfactant system.
  • the surfactant system comprises an oil dispersing nonionic surfactant and mild auxiliary surfactants, which in general terms can be selected from other nonionic, anionic, amphoteric and zwitterionic surfactants and mixtures thereof.
  • the total level of surfactant, inclusive of anionic, nonionic, zwitterionic, amphoteric and other surfactant components is preferably from about 5% to about 25%, more preferably from about 7% to about 20%, and especially from about 8% to about 16% by weight.
  • compositions preferably comprise a mixture of oil dispersing nonionic and anionic surfactants optionally with auxiliary nonionic, zwitterionic and/or amphoteric surfactants.
  • the total level of auxiliary surfactant is in the range from about 0.5% to about 15%, preferably from about 1 % to about 10%, more preferably from about 2% to about 6% by weight of the composition, while the level of oil dispersing nonionic surfactant is from about 1 % to about 25%, preferably from about 2% to about 15%, more preferably from about 3% to about 12% by weight and especially from about 4% to about 8%.
  • the weight ratio of anionic surfactant : auxiliary nonionic, zwitterionic and/or amphoteric surfactant is preferably in the range of from about 8:1 to about 51:2.
  • the ratio of auxiliary surfactant to oil dispersing nonionic surfactant is preferably in the range of from 1:10 to about 10:1, more preferably from about 1:5 to about 5:1, most preferably from about 1:2 to about 2:1.
  • compositions within the scope of the invention comprise mixtures of nonionic surfactants, oil and auxiliary anionic, zwitterionic and/or amphoteric surfactants, wherein the level of dispersed oil phase is from about 3% to about 25%, preferably from about 8% to about 20%, more preferably from about 10% to about 15% by weight of the composition and the weight ratio of oil dispersing nonionic surfactant : dispersed oil phase is in the range of from 1:20 to about 3:2, preferably from about 1:6 to about 1:2, more preferably from about 1:4 to about 1:3.
  • the dispersed oil phase preferably comprises a mixture of first and second oil components selected on the basis of their oil/surfactant solution interfacial tension characteristics, such combinations being optimum for delivering desirable emulsion stabilisation and skin deposition characteristics.
  • Oil/surfactant interfacial tension (IFT) measurements indicate the degree to which a surfactant solution can reduce the interfacial tension (IFT) between an oil component and a water phase. IFT measurements are made using a Spinning Drop Interfacial Tensiometer and are taken at 40 - 50°C and 21 Degrees Clark water hardness (428ppm CaC03) and 75 ⁇ pm aqueous surfactant solution concentration. In this test the surfactant system preferred for use is the surfactant system of the final cleansing composition.
  • a standard aqueous surfactant solution comprising a mixture of ethoxylated alkyl sulphate having two ethoxylated groups and alkyl N-methyl glucose amide in a weight ratio of about 4 : 1. Measurements are undertaken at pH 7 and are reported as the average of the 2, 5 and 10 minute interfacial tension readings.
  • IFT interfacial tension'
  • the dispersed oil phase suitable for inclusion herein preferably comprises a mixture of a first and a second oil component wherein the first oil component comprises, in preferred embodiments, a polyol polyester and the second oil component comprises one or more oils selected from hydrocarbons, lanolin and lanolin derivatives and animal and vegetable triglycerides.
  • first oil component comprises, in preferred embodiments, a polyol polyester
  • second oil component comprises one or more oils selected from hydrocarbons, lanolin and lanolin derivatives and animal and vegetable triglycerides.
  • the total level of first and second dispersed oil component present is from about 1 % to about 30%, preferably from about 3% to about 25%, more preferably from about 8% to about 20%, most preferably from about 10% to about 15% by weight wherein the weight ratio of first oil component to second oil component is in the range of from about 20 : 1 to about 1 : 20, preferably from about 8 : 1 to about 1 : 8 , more preferably from about 4 : 1 to about 1 : 4.
  • the dispersed oil phase comprises a nonocclusive liquid or liquifiable polyol fatty acid polyester.
  • liquid polyol fatty acid polyesters containing at least four fatty acid ester groups and wherein the polyol moiety is selected from sugars and sugar alcohols containing from about 4 to about 8 hydroxyl groups, and wherein each carboxylic acid moiety has from about 8 to about 22 carbon atoms and wherein the liquid polyol fatty acid polyester has a complete melting point of less than about 30 °C.
  • the polyester also preferably has an oil/surfactant interfacial tension (IFT) of greater than about 1.0 dynes/cm, preferably from about 1.1 to about 4.0, more preferably from about 1.2 to about 3.0 and especially from about 1.3 to about 2.0 dynes/cm (as measured under the above standard conditions) and is present at a level of from about 1 % to about 10 %, preferably from about 1% to about 5%, more preferably from about 2% to about 4% by weight.
  • IFT oil/surfactant interfacial tension
  • the liquid polyol polyesters preferred for use in the present compositions comprise certain polyols, especially sugars or sugar alcohols, esterified with at least four fatty acid groups. Accordingly, preferred polyol starting material should have at least four esterifiable hydroxyl groups.
  • preferred polyols are sugars, including monosaccharaides and disaccharides, and sugar alcohols. Examples of monosaccharides containing four hydroxyl groups are xylose and arabinose and the sugar alcohol derived from xylose, which has five hydroxyl groups, i.e., xylitol.
  • the monosaccharide, erythrose is not preferred in the practice of this invention since it only contains three hydroxyl groups, but the sugar alcohol derived from erythrose, i.e., erythritol, contains four hydroxyl groups and accordingly can be used. Suitable five hydroxyl group-containing monosaccharides are galactose, fructose, and sorbose. Sugar alcohols containing six -OH groups derived from the hydrolysis products of sucrose, as well as glucose and sorbose, e.g., sorbitol, are also suitable. Examples of disaccharide polyols which can be used include maltose, lactose, and sucrose, all of which contain eight hydroxyl groups. Preferred polyols for preparing the polyesters for use in the present invention are selected from the group consisting of erythritol, xylitol, sorbitol, glucose, and sucrose. Sucrose is especially preferred.
  • the preferred polyol starting material having at least four hydroxyl groups is esterified on at least four of the -OH groups with a fatty acid containing from about 8 to about 22 carbon atoms.
  • fatty acids include caprylic, capric, lauric, myristic, myristoleic, palmitic, palmitoleic, stearic, oleic, ricinoleic, linoleic, linolenic, eleostearic, arachidic, arachidonic, behenic, and erucic acid.
  • the fatty acids can be derived from naturally occurring or synthetic fatty acids; they can be saturated or unsaturated, including positional and geometrical isomers. However, in order to provide liquid polyesters preferred for use herein, at least about 50% by weight of the fatty acid incorporated into the polyester molecule should be unsaturated. Oleic and linoleic acids, and mixtures thereof, are especially preferred.
  • the polyol fatty acid polyesters useful in this invention preferably contain at least four fatty acid ester groups. It is not necessary that all of the hydroxyl groups of the polyol be esterified with fatty acid, but it is preferable that the polyester contain no more than two unesterif ⁇ ed hydroxyl groups. Most preferably, substantially all of the hydroxyl groups of the polyol are esterified with fatty acid, i.e., the polyol moiety is substantially completely esterified.
  • the fatty acids esterified to the polyol molecule can be the same or mixed, but as noted above, a substantial amount of the unsaturated acid ester groups must be present to provide liquidity.
  • sucrose tetra-fatty acid ester would be suitable for use herein, but is not preferred because it has more than two unesterified hydroxyl groups.
  • a sucrose hexa-fatty acid ester would be preferred because it has no more than two unesterified hydroxyl groups.
  • Highly preferred compounds in which all the hydroxyl groups are esterified with fatty acids include the liquid sucrose octa-substituted fatty acid esters.
  • glucose tetraoleate the glucose tetraesters of soybean oil fatty acids (unsaturated), the mannose tetraesters of mixed soybean oil fatty acids, the galactose tetraesters of oleic acid, the arabinose tetraesters of linoleic acid, xylose tetralinoleate, galactose pentaoleate, sorbitol tetraoleate, the sorbitol hexaesters of unsaturated soybean oil fatty acids, xylitol pentaoleate, sucrose tetraoleate, sucrose pentaoletate, sucrose hexaoleate, sucrose hepatoleate, sucrose octaoleate, and mixtures thereof.
  • highly preferred polyol fatty acid esters are those wherein the fatty acids contain from about 14 to about 18 carbon atoms.
  • the preferred liquid polyol polyesters preferred for use herein have complete melting points below about 30°C, preferably below about 27.5°C, more preferably below about 25°C. Complete melting points reported herein are measured by Differential Scanning Calorimetry (DSC).
  • the polyol fatty acid polyesters suitable for use herein can be prepared by a variety of methods well known to those skilled in the art. These methods include: transesterification of the polyol with methyl, ethyl or glycerol fatty acid esters using a variety of catalysts; acylation of the polyol with a fatty acid chloride; acylation of the polyol with a fatty acid anhydride; and acylation of the polyol with a fatty acid, per se. See US-A-2,831,854; US- A-4,005,196, to Jandacek, issued January 25, 1977; US-A-4,005,196, to Jandacek, issued January 25, 1977.
  • the preferred first oil component for the compositions according to the present invention is a liquid sucrose octa-substituted fatty acid ester.
  • compositions of the present invention can also comprise further oil components in the dispersed oil phase.
  • the preferred further oil components are non-polar oils.
  • Highly preferred second oil components have an interfacial tension (IFT) in the range of from about 0.1 to about 1.0 dynes/cm, preferably from about 0.2 to about 0.9, more preferably from about 0.3 to about 0.7 dynes/cm (as measured using the above standard conditions) and are present at a level of from about 1 % to about 20%, preferably from about 5% to about 15%, more preferably from about 8% to about 15% by weight.
  • IFT interfacial tension
  • Additional oil components of the dispersed oil phase suitable for use herein include hydrocarbons, lanolin and animal and vegetable triglycerides such as mineral oils, petrolatum and squalene, fatty sorbitan esters (see US-A-3988255, Seiden, issued October 26th 1976), lanolin and oil-like lanolin derivatives, water-insoluble silicones inclusive of non ⁇ volatile polyalkyl and polyaryl siloxane gums and fluids, volatile cyclic and linear polyalkylsiloxanes, polyalkoxylated silicones, amino and quaternary ammonium modified silicones, rigid cross-linked and reinforced silicones and mixtures thereof, C1-C24 esters of Cg-C ⁇ o fatty acids such as isopropyl myristate and cetyl ricinoleate, beeswax, saturated and unsaturated fatty alcohols such as behenyl alcohol, almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oil
  • the most preferred second oil components are non-polar oils selected from mineral oil, petrolatum, water-insoluble silicones, soya bean oil and the like and mixtures thereof. Especially preferred for use herein is mineral oil.
  • compositions include an oil dispersing nonionic surfactant at a level of from about 1% to about 25%, preferably from about 2% to about 15%, more preferably from about 3% to about 12%, most preferably from about 4% to about 8% by weight.
  • Oil dispersing nonionic surfactants suitable for inclusion in the compositions according to the present invention have excellent oil dispersing characteristics as demonstrated by microscopy and Immersion tests.
  • a test matrix including the test nonionic and all other composition ingredients is prepared. A portion of this prototype is then viewed under a microscope using a Nikon Optipot-2 Videomicrowatcher.
  • Surfactants suitable for incorporation in the compositions according to the present invention typically produce homogeneous (opaque) product matrices in which the oil droplets have a mean diameter in the range of from about 1 microns to about 30 microns, preferably from about 2 microns to about 20 microns.
  • Highly preferred dispersed oil systems suitable for the compositions according to the present invention have an average oil droplet size of from about 3 microns to about 10 microns as measured by a Nikon Optipot-2 Videomicrowatcher.
  • prototype matrices In the Immersion Test, the in-use characteristics of prototype matrices are assessed. In essence, 6 ml of prototype matrix is dispersed in 20 litres of water at 40°C. The physical appearance of the resulting solution is then assessed. Compositions which result in turbid (cloudy) solutions wherein no oil droplets are visible to the naked eye are regarded as demonstrating the desired behaviour, providing they additionally deliver the required skin feel.
  • Oil dispersing nonionic surfactants suitable for inclusion in the compositions according to the present invention are selected from C12- Cig polyhydroxy fatty acid amide surfactants, preferably C12-C16 polyhydroxy fatty acid amide surfactants, more preferably C12-C14 polyhydroxy fatty acid amide surfactants having the general formula (I).
  • N-alkyl, N-alkoxy or N-aryloxy, polyhydroxy fatty acid amide surfactants according to formula (I) are those in which R8 is C5-C31 hydrocarbyl, preferably C9-C17 hydrocarbyl, including straight-chain and branched chain alkyl and alkenyl, or mixtures thereof and R9 is typically C1-C8 alkyl or hydroxyalkyl, preferably methyl, or a group of formula -Rl- 0-R2 wherein R* is C2-C8 hydrocarbyl including straight-chain, branched- chain and cyclic (including aryl), and is preferably C2-C4 alkylene, R 2 is C ⁇ -Cg straight-chain, branched-chain and cyclic hydrocarbyl including aryl and oxyhydrocarbyl, and is preferably C1-C4 alkyl, especially methyl, or phenyl.
  • ⁇ 2 is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 2 (in the case of glyceraldehyde) or at least 3 hydroxyls (in the case of other reducing sugars) directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof.
  • ⁇ 2 preferably will be derived from a reducing sugar in a reductive amination reaction, most preferably ⁇ 2 is a glycityl moiety.
  • Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, mannose, and xylose, as well as glyceraldehyde.
  • ⁇ 2 preferably will be selected from the group consisting of -CH2-(CHOH)n-CH2 ⁇ H, - CH(CH2 ⁇ H)-(CHOH)n_ ⁇ -CH2 ⁇ H, CH2(CHOH)2(CHOR')CHOH)-
  • n is an integer from 1 to 5, inclusive, and R' is H or a cyclic mono- or poly-saccharide, and alkoxylated derivatives thereof.
  • R' is H or a cyclic mono- or poly-saccharide, and alkoxylated derivatives thereof.
  • glycityls wherein n is 4, particularly -CH2-(CHOH)4- CH2OH.
  • Rg-CO-N ⁇ can be, for example, cocoamide, stearamide, oleamide, lauramide, myristamide, capricamide, palmitamide, tallowamide, etc.
  • a preferred process for making the above compounds having formula (I) comprises reacting a fatty acid triglyceride with an N-substituted polyhydroxy amine in the substantial absence of lower (C1-C4) alcoholic solvent, but preferably with an alkoxylated alcohol or alkoxylated alkyl phenol such as NEODOL and using an alkoxide catalyst at temperatures of from about 50°C to about 140°C to provide high yields (90-98%) of the desired products.
  • Suitable processes for making the desired polyhydroxy fatty acid amide materials are outlined in US-A-5,194,639 and US-A- 5,380,891.
  • the most preferred polyhydroxy fatty acid amide has the formula Rg(CO)N(CH3)CH2(CHOH)4CH2 ⁇ H wherein Rg is a C11-C17 straight chain alkyl or alkenyl group.
  • the surfactant system comprises an oil dispersing nonionic surfactant and auxiliary surfactants wherein the auxiliary surfactant is selected from anionic, zwitterionic, amphoteric and auxiliary nonionic surfactants and mixtures thereof.
  • the level of auxiliary surfactant is from about 0.5% to about 15%, preferably from about 1 % to about 10%, more preferably from about 2% to about 6% by weight.
  • Anionic surfactants suitable for inclusion in the compositions of the invention can generally be described as mild synthetic detergent surfactants and include ethoxylated alkyl sulfates, alkyl glyceryl ether sulfonates, methyl acyl taurates, fatty acyl glycinates, N-acyl glutamates, acyl isethionates, alkyl sulfosuccinates, alpha-sulfonated fatty acids, their salts and/or their esters, alkyl ethoxy carboxylates, alkyl phosphate esters, ethoxylated alkyl phosphate esters, acyl sarcosinates and fatty acid/protein condensates, and mixtures thereof.
  • Alkyl and/or acyl chain lengths for these surfactants are Cg-C22 > preferably Cjo-Cig.
  • Particularly preferred are the alkyl sulfates containing from about 2 to 6, preferably 2 to 4 moles of ethylene oxide, such as sodium laureth-2 sulfate, sodium laureth-3 sulfate and magnesium sodium laureth- 3.6 sulfate.
  • the anionic surfactant contains at least about 50%, especially at least about 75% by weight of ethoxylated alkyl sulfate.
  • compositions for use herein suitably also contain an amphoteric surfactant.
  • Amphoteric surfactants suitable for use in the compositions of the invention include: (a) imidazolinium surfactants of formula (II)
  • Ri is C7-C22 alkyl or alkenyl
  • R2 is hydrogen or CH2Z
  • each Z is independently CO2M or CH2CO2M
  • M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium; and/or ammonium derivatives of formula (HI)
  • R ⁇ , R2 and Z are as defined above;
  • n and m are numbers from 1 to 4, and R and M are independently selected from the groups specified above;
  • Suitable amphoteric surfactants of type (a) are marketed under the trade name Miranol and Empigen and are understood to comprise a complex mixture of species. Traditionally, the Miranols have been described as 15
  • CTFA Cosmetic Ingredient Dictionary, 4th Edition indicates the non-cyclic structure III.
  • CTFA Cosmetic Ingredient Dictionary, 4th Edition indicates the non-cyclic structure III.
  • a complex mixture of cyclic and non-cyclic species is likely to exist and both definitions are given here for sake of completeness.
  • Preferred for use herein, however, are the non-cyclic species.
  • amphoteric surfactants of type (a) include compounds of formula II and/or III in which R ⁇ is C Hi (especially iso- capryl), C9H19 and C11H23 alkyl.
  • R ⁇ is C Hi (especially iso- capryl), C9H19 and C11H23 alkyl.
  • Suitable amphoteric surfactants of type (a) include compounds of formula II and/or III in which R ⁇ is C Hi (especially iso- capryl), C9H19 and C11H23 alkyl.
  • R ⁇ is C Hi (especially iso- capryl), C9H19 and C11H23 alkyl.
  • R ⁇ is C Hi (especially iso- capryl), C9H19 and C11H23 alkyl.
  • Ri is C9H19, Z is CO2M and R2 is H
  • the compounds in which Ri is C11H23, Z is CO2M and R2 is CH2CO2M
  • Rj is C11H23, Z is CO2M and R2 is H.
  • materials preferred for use in the present invention include cocoamphocarboxypropionate, cocoamphocarboxy propionic acid, and especially cocoamphoacetate and cocoamphodiacetate (otherwise referred to as cocoamphocarboxyglycinate).
  • Specific commercial products include those sold under the trade names of Empigen CDL60 and CDR 60 (Albright & Wilson), Miranol H2M Cone. Miranol C2M Cone. N.P., Miranol C2M Cone.
  • Miranol C2M SF Miranol CM Special (Rh ⁇ ne-Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); and Schercotic MS-2 (Scher Chemicals).
  • amphoteric surfactants of this type are manufactured and sold in the form of electroneutral complexes with, for example, hydroxide counterions or with anionic sulfate or sulfonate surfactants, especially those of the sulfated Cg-Cig alcohol, Cg-Cig ethoxylated alcohol or Cg-C ⁇ g acyl glyceride types.
  • anionic sulfate or sulfonate surfactants especially those of the sulfated Cg-Cig alcohol, Cg-Cig ethoxylated alcohol or Cg-C ⁇ g acyl glyceride types.
  • compositions which are essentially free of (non- ethoxylated) sulfated alcohol surfactants are essentially free of (non- ethoxylated) sulfated alcohol surfactants.
  • amphoteric surfactants are based herein on the uncomplexed forms of the surfactants, any anionic surfactant counterions being considered as part of the overall anionic surfactant component content.
  • suitable amphoteric surfactants of type (b) include salts, especially the triethanolammonium salts and salts of N-lauryl-beta-amino propionic acid and N-lauryl-imino-dipropionic acid. Such materials are sold under the trade name Deriphat by Henkel and Mirataine by Rh ⁇ ne- Poulenc.
  • Amphoterics preferred for use herein, however, are those of formula II and/or III.
  • compositions of the invention may also include auxiliary nonionic surfactants.
  • auxiliary nonionic surfactants for use herein can be selected from C12-C14 fatty acid mono-and diethanolamides and sucrose polyester surfactants, water soluble vegetable and animal-derived emollients (oil derived) such as triglycerides with a polyglycol chain inserted; ethoxylated mono and di-glycerides, polyethoxylated lanolins and shea butter derivatives and mixtures thereof.
  • oil-derived auxiliary nonionic surfactants for use herein have the general formula (VI)
  • n is from about 5 to about 200, preferably from about 20 to about 100, more preferably from about 30 to about 85, and wherein R comprises an aliphatic radical having on average from about 5 to 20 carbon atoms, preferably from about 9 to 18 carbon atoms.
  • Suitable ethoxylated oils and fats of this class include polyethyleneglycol derivatives of glyceryl cocoate, glyceryl caproate, glyceryl caprylate, glyceryl tallowate, glyceryl palmate, glyceryl stearate, glyceryl laurate, glyceryl oleate, glyceryl ricinoleate, and glyceryl fatty esters derived from triglycerides, such as palm oil, almond oil, and corn oil, preferably glyceryl tallowate and glyceryl cocoate.
  • Suitable oil derived auxiliary nonionic surfactants of this class are available from Croda Inc. (New York, USA) under their Crovol line of materials such as Crovol EP40 (PEG 20 evening primrose glyceride), Crovol EP 70 (PEG 60 evening primrose glyceride) Crovol A-40 (PEG 20 almond glyceride), Crovol A-70 (PEG 60 almond glyceride), Crovol M-40 (PEG 20 maize glyceride), Crovol M-70 (PEG 60 maize glyceride), Crovol PK-40 (PEG 12 palm kernel glyceride), and Crovol PK-70 (PEG 45 palm kernel glyceride) and under their Solan range of materials such as Solan E, E50 and X polyethoxylated lanolins.
  • Crovol EP40 PEG 20 evening primrose glyceride
  • Crovol EP 70 PEG 60 evening primrose glyceride
  • Crovol A-40 PEG 20 almond glyceride
  • PEG (6) capric/caprylic glyceride (Softigen 767).
  • Varonic LI 2 PEG 28 glyceryl tallowate
  • Varonic LI 420 PEG 200 glyceryl tallowate
  • auxiliary nonionic surfactants derived from composite vegetable fats extracted from the fruit of the Shea Tree (Butyrospermum Karkii Kotschy) and derivatives thereof.
  • This vegetable fat, known as Shea Butter is widely used in Central Africa for a variety of means such as soap making and as a barrier cream, it is marketed by Sederma (78610 Le Perray En Yvelines, France).
  • ethoxylated derivatives of Shea butter available from Karlshamn Chemical Co. (Columbos, Ohio, USA) under their Lipex range of chemicals, such as Lipex 102 E-75 (ethoxylated mono, di-glycerides of Shea butter) and from Croda Inc.
  • Crovol SB70 ethoxylated Shea butter
  • ethoxylated derivatives of Mango, Cocoa and Illipe butter may be used in compositions according to the invention. Although these are classified as ethoxylated nonionic surfactants it is understood that a certain proportion may remain as non-ethoxylated vegetable oil or fat.
  • auxiliary oil-derived nonionic surfactants include ethoxylated derivatives of almond oil, peanut oil, wheat germ oil, linseed oil, jojoba oil, oil of apricot pits, walnuts, palm nuts, pistachio nuts, sesame seeds, rapeseed, cade oil, corn oil, peach pit oil, poppy seed oil, pine oil, castor oil, soybean oil, avocado oil, safflower oil, coconut oil, hazelnut oil, olive oil, grapeseed oil, and sunflower seed oil.
  • Oil derived auxiliary nonionic surfactants highly preferred for use herein from the viewpoint of optimum mildness and skin feel characteristics are PEG 60 evening primrose triglycerides; PEG 55 lanolin polyethoxylated derivatives and ethoxylated derivatives of Shea butter.
  • compositions herein preferably also contain a zwitterionic surfactant.
  • Betaine surfactants suitable for inclusion in the composition of the invention include alkyl betaines of the formula R5R6R7N + (CH2)nM (VII) and amido betaines of the formula (VIII)
  • R5 is C11-C22 a ⁇ or ⁇ en yl> ⁇ 6 an ⁇ ⁇ 7 are independently C1-C3 alkyl
  • M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium
  • n, m are each numbers from 1 to 4.
  • Preferred betaines include cocoamidopropyldimethylcarboxymethyl betaine, laurylamidopropyldimethylcarboxymethyl betaine and Tego betaine.
  • Water-soluble auxiliary sultaine surfactants suitable for inclusion in the compositions of the present invention include alkyl sultaines of the formula
  • Ri is C7 to C22 alkyl or alkenyl
  • R2 and R3 are independantly C ⁇ to C3 alkyl
  • M is H
  • m and n are numbers from 1 to 4.
  • Preferred for use herein is coco amido propylhydroxy sultaine.
  • Water-soluble auxiliary amine oxide surfactants suitable for inclusion in the compoisitions of the present invention include alkyl amine oxide R5R-6R7NO and amido amine oxides of the formula (X)
  • R5 is Cn to C22 alkyl or alkenyl
  • R6 and R7 are independantly Ci to C3 alkyl
  • M is H
  • alkali metal alkaline earth metal
  • m is a number from 1 to 4.
  • Preferred amine oxides include cocoamidopropylamine oxide, lauryl dimethyl amine oxide and myristyl dimethyl amine oxide.
  • compositions of the invention may also contain a cationic or nonionic polymeric skin or hair conditioning agent at a level from about 0.01 % to about 5%, preferably from about 0.04% to about 2% and especially from about 0.05% to about 1 % by weight.
  • the polymer is found to be valuable for enhancing the creaminess and quality of the foam as well as providing a hair or skin conditioning utility.
  • Suitable polymers are high molecular weight materials (mass-average molecular weight determined, for instance, by light scattering, being generally from about 2,000 to about 3,000,000, preferably from about 5,000 to about 1,000,000).
  • Useful polymers are the cationic, nonionic, amphoteric, and anionic polymers useful in the cosmetic field.
  • Representative classes of polymers include cationic and nonionic polysaccharides; cationic and nonionic homopolymers and copolymers derived from acrylic and/or methacrylic acid; cationic and nonionic cellulose resins; cationic copolymers of dimethyldiallylammonium chloride and acrylic acid; cationic homopolymers of dimethyldiallylammonium chloride; cationic polyalkylene and ethoxypolyalkylene imines; quatemized silicones, and mixtures thereof.
  • cationic polymers suitable for use herein include cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.11 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents (d.s. of from 0.8- 1.1) in addition to the above-specified cationic groups, and quatemized cellulose ethers available commercially under the trade names Ucare Polymer JR and Celquat.
  • cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.11 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents (d.s. of from 0.8- 1.1) in addition to the above-specified cationic groups, and
  • Suitable cationic polymers are homopolymers of dimethyldiallylammonium chloride available commercially under the trade name Merquat 100, copolymers of dimethyl aminoethylmethacrylate and acrylamide, copolymers of dimethyldiallylammonium chloride and acrylamide, available commercially under the trade names Merquat 550 and Merquat S, quatemized vinyl pyrrolidone acrylate or methacrylate copolymers of amino alcohol available commercially under the trade name Gafquat, and polyalkyleneimines such as polyethylenimine and ethoxylated polyethylenimine.
  • Nonionic polymers suitable for use in the compositions according to the present invention include any conventionally used nonionic polymer and preferably those of the Pluronic and Synperonic group of polyoxyethylene polyoxypropylene block copolymers available from BASF, such as Pluronic L-121 and ICI, such as synperonic PE-F127.
  • Anionic polymers suitable herein include hydrophobically-modified cross- linked polymers of acrylic acid having amphipathic properties as marketed by B F Goodrich under the trade name Pemulen TRI and Pemulen TR2; and the carboxyvinyl polymers sold by B F Goodrich under the trade mark Carbopol and which consist of polymers of acrylic acid cross-linked with polyallyl sucrose or polyallyl pentaeyrthritol, for example, Carbopol 934, 940 and 950.
  • the viscosity of the final composition is preferably at least about 500 cps, more preferably from about 1,000 to about 10,000 cps, especially from about 1,000 to about 5,000 cps.
  • the cleansing compositions can optionally include a hair or skin moisturizer which is soluble in the cleansing composition matrix.
  • the preferred level of moisturizer is from about 0.5% to about 20% by weight.
  • the moisturizer is selected from:
  • nonocclusive moisturizers are glycerine, polyethylene glycol, propylene glycol, sorbitol, polyethylene glycol and propylene glycol ethers of methyl glucose (e.g. methyl gluceth- 20), polyethylene glycol and propylene glycol ethers of lanolin alcohol (e.g. Solulan-75), sodium pyrrolidone carboxylic acid, lactic acid, urea, L-proline, guanidine, pyrrolidone, hydrolyzed protein and other collagen- derived proteins, aloe vera gel and acetamide ME A and mixtures thereof.
  • glycerine is highly preferred.
  • composition of the invention is an adduct prepared from vegetable oils containing non-conjugated polyunsaturated fatty acid esters which are conjugated and elaidinized and then modified via Diels-Alder addition with a member of the goup consisting of acrylic acid, fumaric acid and maleic anhydride.
  • the vegetable oil adduct preferably has the general formula (X).
  • R3 and R4 are independently selected from saturated and unsaturated C7-C22 hydrocarbyl, each Z being CO2M and wherein M is H, or a salt forming cation, preferably alkalimetal, ammonium or alkanol ammonium.
  • the adducts and their preparation are described in US-A-4740367, the adducts being marketed under the trade name Ceraphyl GA (Van Dyke).
  • the vegetable oil adduct is preferably added from about 0.01 % to about 5%, preferably from about 0.05% to about 2%, more preferably from about 0.1 % to about 1% by weight of the composition.
  • compositions according to the present invention can also include a stabilising system.
  • Preferred stabilising systems suitable for inclusion in the compositions according to the present invention comprise a primary and secondary stabilising agent wherein the primary stabilising agent is an optionally modified clay or clay like material and the secondary stabilising agent is a hetero polysaccharide gum.
  • Use of a mixed stabilising system is valuable for the delivery of lather having good volume, stability and appearance characteristics in combination with improvements in skin feel.
  • the total level of primary and secondary stabilising agent present is from about 0.01% to about 15%, preferably from about 0.05% to about 12%, more preferably from about 0.1% to about 10% most preferably from about 0.5% to about 5% by weight wherein the ratio of primary stabiliser to secondary stabiliser is in the range of from about 32:1 to about 1:1, preferably from about 16:1 to about 1:1, more preferably from about 4:1 to about 2:1.
  • the primary stabiliser is a modified clay based material.
  • Suitable primary suspending agents for the compositions of the present invention include magnesium aluminium silicate (Al2MggSi2), bentonite, hectorite and derivatives thereof.
  • Magnesium aluminium silicate occurs naturally in such smectite materials as colerainite, saponite and sapphire.
  • Refined magnesium aluminium silicate useful herein is available from the R.T. Vanderbilt Company, Inc. under the trade name Veegum (RTM) and from ECC America under the trade name Gelwhite MAS-H (RTM).
  • Modified magnesium aluminium silicate materials such as magnesium aluminium silicate mineral / CMC are available from the R.T Vanderbilt Company, Inc. under the trade name Veegum Plus (RTM).
  • This modified clay material contains smectite clay with sodium carboxymethylcellulose and titanium dioxide.
  • Bentonite is a native hydrated colloidal aluminium silicate clay available from ECC America under the trade name Bentonite H (RTM) and from Whittaker, Clark and Daniels under the trade name Mineral Colloid BP 2430 (RTM).
  • Hectorite is one of the montmorillonite minerals that is a principal constituent of bentonite clay. Hectorite is available from Rheox Inc. under the trade names Bentone EW (RTM) and Macaloid (RTM).
  • the preferred primary stabilising agent is magnesium aluminium silicate mineral / CMC available from the R.T. Vanderbilt Company, Inc. under the trade name Veegum Plus (RTM).
  • the preferred secondary stabilising agent in the compositions according to the invention is xanthan gum (xanthan / com sugar gum) which is a heteropolysaccaride gum produced by a pure-culture fermentation of a carbohydrate with Xanthomonas campestris having a molecular weight of greater than about 1,000,000. It is believed to contain D-glucose, D- mannose and D-glucoronate in the molar ratios of 2.8 : 2.0 : 2.0. The polysaccharide is partially acetylated with 4.7% acetyl.
  • This biosynthetic gum material is commercially available from Calgon under the trade name Kelgum CG (RTM) and from Kelko (a division of Merck & Co., Inc.) , Meer and Vanderbilt under the respective trade names Keltrol (RTM), Merezan 8 (RTM) and Rhodigel (RTM) as well as from a variety of other sources.
  • Xanthan gum mixtures are also available from Calgon, Alban Muller and others and are also suitable for inclusion in the compositions of the present invention. Further information on xanthan gum is to be found in Whistler, Roy L. (Editor) Industrial Gums - Polysaccharides and Their Derivatives New York: Academic Press, 1973.
  • the compositions according to the present invention can also contain hydrotropes to impart improved low temperature stability characteristics.
  • a suitable low temperature hydrotrope for the present compositions is sodium Cg alkyl sulphate.
  • a number of additional optional materials can be added to the cleansing compositions.
  • Such materials include proteins and polypeptides and derivatives thereof; water- solubilizable preservatives such as DMDM Hydantoin, Germall 115, methyl, ethyl, propyl and butyl esters of hydroxybenzoic acid, EDTA, Euxyl (RTM) K400, Bronopol (2-bromo-2- nitropropane-l,3-diol), sodium benzoate, potassium sorbate and 2- phenoxyethanol; other moisturizing agents such as hyaluronic acid, chitin and starch-grafted sodium polyacrylates such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 available from Celanese Superabsorbent Materials, Portsmith, VA, USA and described in US-A-4,076,663; solvents such as hexylene glycol and propylene glycol; anti-bacterial agents such as Oxeco (phenoxy is
  • viscosity control agents such as magnesium sulfate, citrate salts and other electrolytes; colouring agents; pearlescers and opacifiers such as styrene PVP polymers such as Lytron 631 (RTM), Ti ⁇ 2 and Ti ⁇ 2-coated mica; perfumes and perfume solubilizers; and zeolites such as Valfour BV400 and derivatives thereof and Ca 2 +/Mg2+ sequestrants such as polycarboxylates, amino polycarboxylates, polyphosphates, polyphosphonates, amino polyphosphonates and gluconates etc and pH adjusting agents such as citric acid and salts thereof.
  • Water is also present at a level preferably of from about 40% to about 94% preferably at least about 50% by weight of the compositions herein.
  • the pH of the compositions is preferably from about 4 to about 8.
  • the invention is illustrated by the following non-limiting examples.
  • Oil l Liquid sucrose octaoleate having a complete melting point of less than about 30°C and an IFT of about 1.45 dynes/cm ( on a 4:1 anionic : GA aqueous solution basis ) wherein IFT is measured as described herein.
  • Oil 2 Mineral Oil having an IFT of about 0.38 (measured as detailed for Oil 1).
  • Amphoteric Empigen CDL 60 an aqueous mixture of 23.5% cocoamphoacetate (in which R ⁇ is coconut alkyl, R2 is H, and Z is C ⁇ 2Na) and 1.35% cocoamphodiacetate (in which R ⁇ is coconut alkyl, R2 is CH2C02Na and Z is C ⁇ 2Na).
  • Solan Solan (RTM) E PEG 55 lanolin
  • Compositions I to VII are prepared by first hydrating any Veegum type material as a pre-mix. Next all of the oil materials are separately blended together using by stirring with water at ambient temperature. If xanthan gum type material is present it may be slurried by stirring with this mixture. Separately, the surfactant materials are hydrated along with any additional skin feel agents, preservatives and hydrotropes by mixing with water and heating to between about 20°C and about 90°C. Finally, the oil blend is added to the hydrated Veegum pre-mix (if present) and then the stirred surfactant mixture is added to the combined mixture and this final blend is stirred and cooled to ambient temperature and the remaining water, preservatives, perfume and any other materials are added.
  • compositions have a viscosity (Helipath,. Spindle A, 10 rpm, 25°C, neat) in the range from 1,000 to 10,000 cps.
  • the products provide excellent in-use and efficacy benefits including excellent skin feel during and after use, good lather volume and stability characteristics, skin conditioning, mildness, stability, cleansing, good water-feel and appearance.

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Abstract

L'invention porte sur une composition nettoyante d'usage personnel comprenant: a) environ 1 à environ 30 % en poids d'une phase huileuse dispersée comportant une première composante huileuse d'une tension interfaciale (IFT) huile/solution tensioactive supérieure à environ 1,0 dyne-cm et une seconde composante huileuse d'une tension interfaciale (IFT) comprise entre environ 0,1 et environ 1,0 dyne-cm, b) environ 5 à environ 30 % en poids d'un agent tensioactif hydrosoluble choisi parmi des agents tensioactifs et leurs mélanges, anioniques, non-ioniques, zwittérioniques et amphotériques et c) de l'eau; le rapport de la première à la seconde composante huileuse dispersées est compris entre environ 20/1 et environ 1/20. Ces produits de nettoyage offrent de remarquables avantages sur le plan de l'efficacité à l'usage, y compris une sensation notable de bien-être de la peau durant et après usage, un important volume de mousse, de bonnes caractéristiques de stabilité et d'aspect, un bon conditionnement de la peau, une grande douceur, une bonne stabilité, un bon pouvoir nettoyant ainsi qu'une consistance et une apparence agréables de l'eau qui les véhicule.
PCT/US1996/006575 1995-05-27 1996-05-09 Composition nettoyante aqueuse d'usage personnel a phase huileuse dispersee comportant deux composantes huiles definies specifiquement WO1996037594A1 (fr)

Priority Applications (2)

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EP96920163A EP0828814A4 (fr) 1995-05-27 1996-05-09 Composition nettoyante aqueuse d'usage personnel a phase huileuse dispersee comportant deux composantes huiles definies specifiquement
US08/973,055 US5942479A (en) 1995-05-27 1996-05-23 Aqueous personal cleansing composition with a dispersed oil phase comprising two specifically defined oil components

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GBGB9510837.9A GB9510837D0 (en) 1995-05-27 1995-05-27 Cleansing compositions
GB9510837.9 1995-05-27

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Cited By (4)

* Cited by examiner, † Cited by third party
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WO1998004241A3 (fr) * 1996-07-25 1998-03-12 Procter & Gamble Compositions pour shampooing
EP1205538A1 (fr) * 2000-11-10 2002-05-15 Unilever Plc Composition pour l'entretien des tissus
US6727220B1 (en) * 1999-05-17 2004-04-27 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Fabric softening compositions
US7799748B2 (en) 2005-12-01 2010-09-21 Conopco, Inc. Method of selecting benefit agents/oils suitable for reducing surfactant damage

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CN107405284B (zh) * 2014-12-23 2020-11-24 莱雅公司 用于调理角蛋白纤维的组合物
BR112019020034B1 (pt) 2017-04-07 2023-09-26 Unilever Ip Holdings B.V Composição de limpeza, método para preparar uma composição de limpeza e uso de material da parede celular
CN107095807B (zh) * 2017-06-30 2020-06-16 广州澳希亚实业有限公司 一种双层沐浴液及其制备方法
US12274770B2 (en) 2019-03-13 2025-04-15 Basf Se Stabilizer concentrates for wax dispersions

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US4446165A (en) * 1979-06-08 1984-05-01 The Procter & Gamble Company Oleaginous compositions
US5160738A (en) * 1990-07-09 1992-11-03 Chesebrough-Pond's U.S.A. Co., Division Of Conopco Inc. Cosmetic composition

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GB9113484D0 (en) * 1991-06-21 1991-08-07 Unilever Plc Cosmetic composition
JPH07501077A (ja) * 1991-11-22 1995-02-02 リチャードソン、ビックス、インコーポレーテッド 組合せパーソナルクレンジング及びモイスチャライジング組成物
WO1993019149A1 (fr) * 1992-03-25 1993-09-30 The Procter & Gamble Company Compositions de nettoyage
JP2736486B2 (ja) * 1992-07-03 1998-04-02 花王株式会社 クレンジング用組成物

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US4446165A (en) * 1979-06-08 1984-05-01 The Procter & Gamble Company Oleaginous compositions
US4368213A (en) * 1981-06-23 1983-01-11 The Procter & Gamble Company Emulsion concentrate for palatable polyester beverage
US5160738A (en) * 1990-07-09 1992-11-03 Chesebrough-Pond's U.S.A. Co., Division Of Conopco Inc. Cosmetic composition

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998004241A3 (fr) * 1996-07-25 1998-03-12 Procter & Gamble Compositions pour shampooing
US6727220B1 (en) * 1999-05-17 2004-04-27 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Fabric softening compositions
EP1205538A1 (fr) * 2000-11-10 2002-05-15 Unilever Plc Composition pour l'entretien des tissus
US7799748B2 (en) 2005-12-01 2010-09-21 Conopco, Inc. Method of selecting benefit agents/oils suitable for reducing surfactant damage

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MX9709178A (es) 1998-07-31
CN1190431A (zh) 1998-08-12
EP0828814A1 (fr) 1998-03-18
GB9510837D0 (en) 1995-07-19
CN1100862C (zh) 2003-02-05
EP0828814A4 (fr) 1999-09-15

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