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WO1996035771A1 - Detergent epaissi contenant des abrasifs inorganiques et un agent de blanchiment de type hypochlorite - Google Patents

Detergent epaissi contenant des abrasifs inorganiques et un agent de blanchiment de type hypochlorite Download PDF

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Publication number
WO1996035771A1
WO1996035771A1 PCT/US1996/006379 US9606379W WO9635771A1 WO 1996035771 A1 WO1996035771 A1 WO 1996035771A1 US 9606379 W US9606379 W US 9606379W WO 9635771 A1 WO9635771 A1 WO 9635771A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition according
sodium
hypochlorite
bleach
composition
Prior art date
Application number
PCT/US1996/006379
Other languages
English (en)
Inventor
A. Thomas Weibel
Original Assignee
Reckitt & Colman Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB9509519A external-priority patent/GB2300643A/en
Application filed by Reckitt & Colman Inc. filed Critical Reckitt & Colman Inc.
Priority to GB9723885A priority Critical patent/GB2315772B/en
Priority to AU58537/96A priority patent/AU705220B2/en
Publication of WO1996035771A1 publication Critical patent/WO1996035771A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus

Definitions

  • This invention relates to abrasive-containing hard surface scouring cleansers containing hypochlorite bleach which are thickened with a combination of a synthetic smectite clay and a polyacrylate resin. Ivlore particularly, it relates to such compositions containing particulate abrasives which maintain high active chlorine stability over a long period of time and have good rinsability.
  • Polymeric thickeners are often added to liquid products containing hypochlorite bleach in order to enhance their rheological properties so as to make them more suitable for use on non-horizontal surfaces.
  • problems encountered with such compositions is the fact that liquids containing hypochlorite bleach are destructive to most synthetic and natural thickeners.
  • thickened bleach products incorporating, as thickeners, certain polyacrylates and certain natural or synthetic clays of the smectite type which 'are somewhat less subject to degradation by the hypochlorite bleach.
  • these polymeric substances particularly the lower molecular weight polyacrylates, do not substantially increase viscosity.
  • these compositions may show initial stability, they tend to degrade, with a resultant loss of chlorine activity within a few months. Therefore, in commercial practice, unless these products are used within a relatively short period of time, they lose their effectiveness as cleaning agents.
  • the B.F. Goodrich Company produces and distributes a series of Carbopol polyacrylate resins and it is known that certain of these resins are useful in the formulation of thickened sodium hypochlorite cleaning compositions.
  • These Carbopol resins generally promote the degradation of the available chlorine in the solutions but, but certain specific Carbopol resins are relatively stable in chlorine bleach solutions in that the rate of chlorine loss is sufficiently slow for use in thickened bleach-containing cleaning compositions.
  • U.S. Patent No. 4,867,896 discloses cleaning compositions containing hypochlorite bleach thickened with cross-linked polyacrylate resins, which are said to provide improved characteristics over similar compositions thickened with certain commercially available Carbopol resins.
  • the compositions can also include smectite or attapulgite clays, and are liquid or gel type dishwashing products and do not contain abrasive particles.
  • U.S. Patent No. 4,911,857 (Machin et al.) teaches the use of polyacrylates or polymethacrylates in aqueous liquid cleaning compositions comprising suspended particulate abrasive materials.
  • the compositions can additionally contain a chlorine-releasing bleaching agent and certain Carbopol resins having molecular weights in the range of 500 to 3,000. These low molecular weight resins serve only as wetting agents. Viscosity is provided by a combination of surfactants.
  • European Patent Application No. 0606707 discloses thickened hypochlorite solutions in which the principal thickening agent is a high molecular weight cross-linked polyacrylate resin.
  • the compositions are intended for use in spray operations and do not contain abrasive particles.
  • the principal advantage to the new compositions is their reduced bleach odor.
  • PCT publication WO95/08619 discloses thickened aqueous abrasive cleansers having particulate abrasives and polyacrylate resin as a thickening agent and asserts that such cleansers have good rinsability. Nevertheless, there still remains a need for thickened abrasive bleach-containing cleansers with enhanced rinsability characteristics, particularly on horizontal surfaces, and improved stability.
  • Natural clays of the smectite or attapulgite type have been used as thickeners in cleaning compositions. See, for example, U.S. Patents Nos. 4,396,525 (Rubin), 4,877,544 (Gabriel), 4,772,414 (Marzec), 5,348,682 (Finley) and 4,235,732 (Beyer). None of these disclosed compositions possess the desired characteristics.
  • a hard surface scouring cleaner composition comprising, on a weight basis.
  • a thickening system comprising a cross-linked polyacrylate resin having a molecular weight in the range of 1,000,000 to 10,000,000 and a synthetic smectite clay resembling natural clays of the hectorite class, the amount of said clay in the thickening system being from about 20% to about 80%,
  • compositions have an apparent viscosity as measured on a Brookf ⁇ eld
  • RVTDV-II with a #6 spindle at 50 rpm of 2-8 Kcps and at 1 rpm of 50-200 Kcps.
  • the abrasive component of the formulation is necessary for physically scouring the stains from surfaces.
  • the abrasive agent should be present in amounts of from about 10 to about 30% by weight of the compositions; preferably, the abrasive agent is present in amounts ranging from 15 to 25%.
  • Any suitable hard inorganic particulate base-stable abrasive agent may be used.
  • Preferred abrasives include calcium carbonate and alumina trihydrate but harder abrasives such as a perlite, silica sand and various other insoluble, inorganic particulate abrasives can be used, such as quartz, pumice, feldspar, tripoli and calcium phosphate.
  • Particle size will range from average particle size of about 10 to about 500 microns, preferably from 10 to 100 microns, and more preferably from 15 to 75 microns.
  • Particle hardness of the abrasives can range from Mohs hardness of about 2-8, more preferably 3-6.
  • Especially preferred is calcium carbonate, also known as calcite. Calcite is available from numerous commercial sources such as Georgia Marble Company, and has a Mohs hardness of about 3. Typically, a size of U.S. 140 mesh is selected, although others may be appropriate.
  • the scouring composition of this invention contains a chlorine oxidizing bleach derived from a hypochlorite.
  • the hypochlorite component may be provided by a variety of sources which include sodium, potassium, lithium and calcium hypochlorites, chlorinated trisodium phosphate dodecylhydrate, potassium and sodium dichloroisocyanurate and trichlorocyanuric acid.
  • the preferred sources are sodium or potassium hypochlorite, particularly sodium hypochlorite.
  • the hypochlorite is present in the composition in an amount equal to about 0.5 to about 2.5% by weight of the composition.
  • the hypochlorite may form 0.75 to 2.0% of the composition.
  • Interaction of the cross-linked polyacrylate resin with the hypochlorite component of the composition is particularly important for maintaining the desirable characteristics of thickening and stability.
  • hypochlorite component which is preferably present in the composition contains low levels of salts such as chlorides, which would tend to interfere with the phase stability of the composition. For this reason, the present invention avoids or minimizes the use of hypochlorite bleaches formed by methods which commonly generate large amounts of salts such as sodium chloride.
  • Ordinary sodium hypochlorite bleach sold for laundry purposes can contain, for every 100 parts of NaOCl, up to 75 parts of NaCl. For purposes of this invention, it is preferred that the amount of NaCl present be not more than 20% of the amount of NaOCl.
  • the preferred hypochlorite component is preferably selected or formed in a manner avoiding or minimizing the presence of undesirable salts.
  • ordinary sodium hypochlorite bleaches are commonly formed by bubbling chlorine gas through liquid sodium hydroxide to result in formation of the corresponding hypochlorite.
  • hypochlorite bleaches produced by such reactions are undesirable for the present unless the reaction is followed by salt separation step.
  • hypochlorites formed from the reaction of chlorine with sodium hydroxide contemplates the use of hypochlorites formed in other ways, such as by reaction of hypochlorous acid with sodium hydroxide or other metal hydroxides in order to produce the corresponding hypochlorite with water as the only substantial by-product.
  • Sodium hypochlorite bleach produced in this manner is available from a number of sources, for example Olin Corporation which produces sodium hypochlorite bleach as a 36% solution in water, and sold under the trademark Hy-Pure.
  • hypochlorite component of the invention will not include chloride salt in excess of 20% of the hypochlorite.
  • the amount of chloride will be less than 5% by weight of the hypochlorite component.
  • the ionic strength of the composition has an effect on thickening. If the total ionic strength (sum of the total alkali ions plus the negative counterions) exceeds about 5 g-ions per kilogram, it becomes difficult to achieve the desired level of thickening. Moreover, ionic strength also has some effect on stability of the composition; however, the effect of ionic strength on stability is minimal relative to the effects of the cross-linked polyacrylate polymer, the synthetic clay and the polymer stabilizer. Nevertheless, the ionic strength of the compositions of the present invention should be maintained at less than about 5 g-ions/Kg, preferably less than about 3 g-ions/Kg.
  • hypochlorite component In addition to enhancing the phase stability of the composition, provided primarily by the cross-linked polyacrylate polymers, the hypochlorite component also acts as a cleaning agent.
  • the thickening system for the compositions of this invention must include a cross-linked polyacrylate polymer of the type sold by the B. F. Goodrich Company under the trademark Carbopol and by 3 V Chemical Company under the trademark Polygel.
  • These polymeric resins should have a molecular weight in the range of from about 1,000,000 to about 10,000,000, preferably from 1,500,000 to 5,000,000. (These molecular weight figures are based on data supplied in the manufacturers' product literature.)
  • a particularly suitable polymeric resin is Carbopol 695, which has a published molecular weight of about 3,000,000.
  • cross-linked polyacrylate polymers are generally characterized as acrylic acid polymers which are non-linear and water-dispersible while being cross-linked with an additional monomer or monomers in order to exhibit a molecular weight in the desired range.
  • the polymers are cross-linked with a polyalkenyl polyether, the cross-linking agents tending to interconnect linear strands of the polymer to form the cross-linked resin. It has been found that, for the purposes of achieving good long term stability, without the loss of chlorine effectiveness, the polymeric cross-linking agent must be carefully chosen within the foregoing parameters.
  • the thickening system comprises from about 0.5% to about 3% of the composition, preferably from 1% to 2.5% thereof.
  • the thickening system also comprises, in addition to the cross-linked polyacrylate polymer, from about 20% to about 80%, preferably from 50% to 80%, of its weight of a synthetic smectite-type clay similar to hectorite in structure and composition.
  • a synthetic, rather than a natural, clay is preferably used in order to avoid degradation of the composition owing to small amounts of impurities which may be found in natural products.
  • the preferred synthetic smectite clays for use in this invention are sold under the trademark Laponite by Southern Clay Products, Inc. Particularly useful are Laponite RD and Laponite RDS with Laponite RD being especially preferred because it contains no phosphates.
  • the preferred amount of synthetic smectite clay is from about 0.25 to about 2.0 weight %, more preferably about 1.0% to about 2.0%.
  • the addition of the synthetic smectite clay provides both improved rinsability, and improved stability, particularly over long time periods.
  • Surfactants are added to the composition for supplemental thickening and/or for non-thickening purposes such as cleaning, improved stability, etc. Stability in the presence of the hypochlorite component is the basic criterion for selecting the surfactants to be included in the composition.
  • surfactants may be sufficiently stable in the presence of hypochlorite bleaches and these include betaines, sarcosinates, taurates, alkyl sulphates, alkyl sulphonates, alkyl acyl sulphonates, alkylphenol ether sulphates, alkyl diphenyl oxide sulphonates, alkyl phosphate esters, etc.
  • the surfactant systems will comprise principally anionic surfactants, but they may also include up to about 20% of non-ionics and/or amphoterics .
  • Bleach-stable anionic surfactants useful in the present invention and which are especially stable in the presence of hypochlorite include water soluble alkali metal alkyl sulphates, alkyl sulphonates, alkylbenzene sulphonates, alkyldiphenyl oxide sulphonates particularly the sodium salts of those having from 8 to 18 carbon atoms in the alkyl group, and sodium alkyl sarcosinate salts in which the alkyl group is a saturated hydrocarbon chain having from 7 to 17 carbon atoms.
  • a preferred alkyl sulphate is lauryl sulphate.
  • a preferred sarcosinate is sodium lauroyl sarcosinate, sold by W.R. Grace & Co.
  • Preferred alkyl sulphonates are the secondary alkyl products sold as Hostapur SAS by Hoechst in formulations containing 30% and 60% active ingredient.
  • Preferred alkyldiphenyl oxide sulphonates are the products sold by Dow Chemical Company under the name Dowfax 2A1 and by Olin Corporation under the name Polytergent 2A1; both products are aqueous based and contain about 45% active ingredient which is principally sodium dodecyl diphenyl oxide disulphonate.
  • organic anionic non-soap surfactants include: sodium C 10 -Ci 8 alkylsulphates such as sodium dodecylsulphate and sodium tallow alcoholsulphate; sodium C 10 -C ⁇ g alkanesulphonates such as sodium hexadecyl -1,1- sulphonate, and sodium C 12 -C 18 alkylbenzenesulphona.es such as sodium dodecylbenzenesulphonate.
  • the corresponding potassium salts may also be employed.
  • the amount of surfactant in the compositions of this invention ranges from about 0.25% to about 3%, preferably from 0.5 to 2.0%.
  • a sufficient amount of sodium or potassium hydroxide should be added to provide a pH in the range of from 11.5 to 13.5, preferably from 12 to 13.
  • Optional ingredients in the composition include an electrolyte such as sodium or potassium carbonate or silicate, in amounts ranging up to about 3% of the composition.
  • an electrolyte such as sodium or potassium carbonate or silicate
  • the principal purpose of these carbonates and silicates is to act as a buffer in order to maintain the proper pH.
  • the presence of a small amount of sodium or potassium silicate results in somewhat improved stability.
  • compositions which contain both potassium and sodium ions, derived from the various ingredients have a somewhat higher viscosity than analogous compositions with sodium as the sole alkali metal action.
  • the hypochlorite composition preferably includes a bleach stable fragrance component and more preferably a bleach stable fragrance component which is relatively more volatile than the oxidants included in the hypochlorite component of the composition which are responsible for bleach odors.
  • the scouring compositions of the present invention together with the preferred cross-linked polyacrylate polymers for achieving combined thickening and stability may also include other components, either for enhancing one or more of these effect or for other purposes.
  • additional adjuncts in the composition may include buffers, builders, colorants, fluorescent whitening agents, pigments, etc.
  • additional adjuncts in the composition may include buffers, builders, colorants, fluorescent whitening agents, pigments, etc.
  • additional adjuncts in the composition may include buffers, builders, colorants, fluorescent whitening agents, pigments, etc.
  • additional adjuncts in the composition may include buffers, builders, colorants, fluorescent whitening agents, pigments, etc.
  • Such adjuncts must be selected to the extent that they not substantially interfere with the preferred characteristics of the present invention as described above.
  • the scouring composition of the instant invention can be prepared by admixing the above-described essential and optional components together in the appropriate concentrations by any conventional means normally used to form thickened compositions. Some shear agitation is, of course, necessary to ensure preparation
  • a scouring cleanser containing the following ingredients was prepared.
  • a 2% Carbopol gel was prepared by adding 9.0g Carbopol 695 to 44 lg of stirred deionized water over a ten-minute period. Agitation was provided with an overhead stirrer to provide a deep vortex and minimize clumping of Carbopol particles. Total mixing time was extended to about one hour.
  • a scouring cleanser containing Laponite RDS clay is prepared.
  • the ingredients of the composition are:
  • Example 3-12 additional compositions according to this invention were prepared according to the method of Example 1 and their viscosities and bleach stabilities were measured.
  • the sodium silicate and potassium silicate were obtained from PQ Corporation as PQ "N" Silicate and Kasil 6, respectively.
  • the sodium hypochlorite used was Hy-Pure N, obtained from Olin Corporation, which 0 contains 16% NaOCl, and 0.5% each of NaCl and NaOH.
  • the pH level was measured after one day at ambient temperatures (22°C).
  • the viscosity was also measured after one day at ambient temperatures on a 5 Brookfield #6 spindle, at 50 RPM after 30 seconds, and is given in units of Kcps.
  • the stability of NaOCl was measured in terms of (1) the number of days required for the composition to show 40% loss of chlorine activity on storage at 49°C, and (2) percent of available chlorine after storage for ten months at ambient temperatures (about 22°C).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Un détergent stable, épaissi, pour surfaces dures, comprend, en poids, (a) environ 10 à environ 30 % de particules abrasives, (b) environ 0,5 à environ 2,5 % d'un agent de blanchiment contenant du chlore, (c) environ 0,5 à environ 3 % d'un système épaississant comprenant une résine de polyacrylate réticulé dont le poids moléculaire est compris entre 1 000 000 et 10 000 000 et une argile à smectite synthétique ressemblant à de l'argile naturelle de la classe hectorite, cette argile se trouvant dans le système épaississant à raison d'environ 20 à environ 80 %, de préférence entre 50 et 80 %, (d) environ 0,25 à environ 2 % d'un système de tensioactifs stable à l'agent de blanchiment composé principalement de tensioactifs anioniques, (e) environ 0 à environ 3 % d'un électrolyte sélectionné dans le groupe comprenant des carbonates ou des silicates de sodium ou de potassium, et (f) une quantité suffisante d'hydroxyde de sodium ou de potassium pour obtenir un pH compris entre 11,5 et 13,5.
PCT/US1996/006379 1995-05-11 1996-05-02 Detergent epaissi contenant des abrasifs inorganiques et un agent de blanchiment de type hypochlorite WO1996035771A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB9723885A GB2315772B (en) 1995-05-11 1996-05-02 Thickened scouring cleanser containing inorganic abrasives and hypochlorite bleach
AU58537/96A AU705220B2 (en) 1995-05-11 1996-05-02 Thickened scouring cleanser containing inorganic abrasives and hypochlorite bleach

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9509519A GB2300643A (en) 1995-05-11 1995-05-11 Hard Surface Cleaners
GB9509519.6 1995-05-11
US63435896A 1996-04-18 1996-04-18
US08/634,358 1996-04-18

Publications (1)

Publication Number Publication Date
WO1996035771A1 true WO1996035771A1 (fr) 1996-11-14

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AU (1) AU705220B2 (fr)
CA (1) CA2219679A1 (fr)
GB (1) GB2315772B (fr)
WO (1) WO1996035771A1 (fr)

Cited By (15)

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WO1997039099A1 (fr) * 1996-04-12 1997-10-23 Reckitt & Colman Inc. Compositions de nettoyage stables contenant un agent blanchissant et des abrasifs doux
WO1998030672A1 (fr) * 1997-01-10 1998-07-16 Reckitt & Colman South Africa (Pty) Limited Compositions organiques ameliorees ou ameliorations relatives a ces compositions
US5985817A (en) * 1997-02-24 1999-11-16 Reckitt & Colman South Africa Ltd. Pourable, thickened aqueous bleach and abrasive containing compositions
WO2000011128A1 (fr) * 1998-08-19 2000-03-02 Jeyes Group Limited Compositions liquides de blanchiment
WO2000055291A1 (fr) * 1999-03-17 2000-09-21 R.T. Vanderbilt Company, Inc. Stabilisant pour produits de nettoyage contenant des agents de blanchiment
WO2001005931A1 (fr) * 1999-07-16 2001-01-25 Unilever N.V. Compositions nettoyantes abrasives liquides
US6380151B1 (en) * 1997-03-20 2002-04-30 The Procter & Gamble Company Detergent composition for use with a cleaning implement comprising a superabsorbent material and kits comprising both
WO2003027218A1 (fr) * 2001-09-24 2003-04-03 The Procter & Gamble Company Composition de nettoyage
WO2004035727A1 (fr) * 2002-10-12 2004-04-29 Reckitt Benckiser Inc Composition de blanchiment liquide
WO2007126922A1 (fr) * 2006-03-29 2007-11-08 Douglas Howard Phillips Agent nettoyant pour la peau
EP1911832A1 (fr) * 2006-10-13 2008-04-16 Unilever N.V. Composition de blanchiment
GB2508177A (en) * 2012-11-22 2014-05-28 Jeyes Group Ltd Spray apparatus and cleaning composition
EP2800472A4 (fr) * 2012-01-06 2015-09-09 Puricore Inc Solutions de nutriments traitées électrochimiquement
WO2016096328A1 (fr) 2014-12-18 2016-06-23 Unilever N.V. Composition en poudre pour le nettoyage de surfaces dures
DE102013220893B4 (de) 2013-10-15 2024-01-04 Ika Innovative Kunststoffaufbereitung Gmbh & Co. Kg Thermoplastische Reinigungsmasse für die Thermoplastverarbeitung, Verfahren zum Entfernen von thermoplastischem Kunststoff, Verwendung der Reinigungsmasse

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GB2305434B (en) 1995-09-19 1999-03-10 Reckitt & Colmann Sa Abrasive cleaning composition

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US4248728A (en) * 1979-02-28 1981-02-03 Chemed Corporation Liquid scouring cleanser
US4911857A (en) * 1987-07-31 1990-03-27 Lever Brothers Company Aqueous liquid abrasive cleaning composition: particulate abrasive suspended in aqueous medium
US5160448A (en) * 1987-12-30 1992-11-03 Lever Brothers Company, Division Of Conopco, Inc. Gel detergent compositions containing a clay and a cross-linked polycarboxylic polymer
US5470499A (en) * 1993-09-23 1995-11-28 The Clorox Company Thickened aqueous abrasive cleanser with improved rinsability

Cited By (16)

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Publication number Priority date Publication date Assignee Title
WO1997039099A1 (fr) * 1996-04-12 1997-10-23 Reckitt & Colman Inc. Compositions de nettoyage stables contenant un agent blanchissant et des abrasifs doux
US5821214A (en) * 1996-04-12 1998-10-13 Reckitt & Colman Inc. Stable bleach-containing cleansing compositions with soft abrasives
WO1998030672A1 (fr) * 1997-01-10 1998-07-16 Reckitt & Colman South Africa (Pty) Limited Compositions organiques ameliorees ou ameliorations relatives a ces compositions
US5985817A (en) * 1997-02-24 1999-11-16 Reckitt & Colman South Africa Ltd. Pourable, thickened aqueous bleach and abrasive containing compositions
US6380151B1 (en) * 1997-03-20 2002-04-30 The Procter & Gamble Company Detergent composition for use with a cleaning implement comprising a superabsorbent material and kits comprising both
WO2000011128A1 (fr) * 1998-08-19 2000-03-02 Jeyes Group Limited Compositions liquides de blanchiment
WO2000055291A1 (fr) * 1999-03-17 2000-09-21 R.T. Vanderbilt Company, Inc. Stabilisant pour produits de nettoyage contenant des agents de blanchiment
WO2001005931A1 (fr) * 1999-07-16 2001-01-25 Unilever N.V. Compositions nettoyantes abrasives liquides
WO2003027218A1 (fr) * 2001-09-24 2003-04-03 The Procter & Gamble Company Composition de nettoyage
WO2004035727A1 (fr) * 2002-10-12 2004-04-29 Reckitt Benckiser Inc Composition de blanchiment liquide
WO2007126922A1 (fr) * 2006-03-29 2007-11-08 Douglas Howard Phillips Agent nettoyant pour la peau
EP1911832A1 (fr) * 2006-10-13 2008-04-16 Unilever N.V. Composition de blanchiment
EP2800472A4 (fr) * 2012-01-06 2015-09-09 Puricore Inc Solutions de nutriments traitées électrochimiquement
GB2508177A (en) * 2012-11-22 2014-05-28 Jeyes Group Ltd Spray apparatus and cleaning composition
DE102013220893B4 (de) 2013-10-15 2024-01-04 Ika Innovative Kunststoffaufbereitung Gmbh & Co. Kg Thermoplastische Reinigungsmasse für die Thermoplastverarbeitung, Verfahren zum Entfernen von thermoplastischem Kunststoff, Verwendung der Reinigungsmasse
WO2016096328A1 (fr) 2014-12-18 2016-06-23 Unilever N.V. Composition en poudre pour le nettoyage de surfaces dures

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GB2315772A (en) 1998-02-11
GB9723885D0 (en) 1998-01-07
GB2315772B (en) 1999-11-24
CA2219679A1 (fr) 1996-11-14
AU705220B2 (en) 1999-05-20
AU5853796A (en) 1996-11-29

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