WO1996031590A1 - Bleaching compositions with selected perfumes for masking bleach odor - Google Patents
Bleaching compositions with selected perfumes for masking bleach odor Download PDFInfo
- Publication number
- WO1996031590A1 WO1996031590A1 PCT/US1996/004023 US9604023W WO9631590A1 WO 1996031590 A1 WO1996031590 A1 WO 1996031590A1 US 9604023 W US9604023 W US 9604023W WO 9631590 A1 WO9631590 A1 WO 9631590A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- perfume
- composition according
- bleaching composition
- bleaching
- weight
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 101
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 79
- 239000002304 perfume Substances 0.000 title claims abstract description 44
- 238000004061 bleaching Methods 0.000 title claims abstract description 42
- 230000000873 masking effect Effects 0.000 title description 6
- 239000012190 activator Substances 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 23
- 238000001514 detection method Methods 0.000 claims abstract description 14
- 150000002148 esters Chemical class 0.000 claims abstract description 9
- 150000001298 alcohols Chemical class 0.000 claims abstract description 8
- 150000001299 aldehydes Chemical class 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims description 25
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 239000003205 fragrance Substances 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- NTPLXRHDUXRPNE-UHFFFAOYSA-N 4-methoxyacetophenone Chemical compound COC1=CC=C(C(C)=O)C=C1 NTPLXRHDUXRPNE-UHFFFAOYSA-N 0.000 claims description 6
- 150000001450 anions Chemical group 0.000 claims description 6
- 238000004900 laundering Methods 0.000 claims description 6
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- BJLRAKFWOUAROE-UHFFFAOYSA-N 2500-83-6 Chemical compound C12C=CCC2C2CC(OC(=O)C)C1C2 BJLRAKFWOUAROE-UHFFFAOYSA-N 0.000 claims description 3
- LQKRYVGRPXFFAV-UHFFFAOYSA-N Phenylmethylglycidic ester Chemical compound CCOC(=O)C1OC1(C)C1=CC=CC=C1 LQKRYVGRPXFFAV-UHFFFAOYSA-N 0.000 claims description 3
- NJGBTKGETPDVIK-UHFFFAOYSA-N raspberry ketone Chemical compound CC(=O)CCC1=CC=C(O)C=C1 NJGBTKGETPDVIK-UHFFFAOYSA-N 0.000 claims description 3
- PHXATPHONSXBIL-UHFFFAOYSA-N xi-gamma-Undecalactone Chemical compound CCCCCCCC1CCC(=O)O1 PHXATPHONSXBIL-UHFFFAOYSA-N 0.000 claims description 3
- CRIGTVCBMUKRSL-FNORWQNLSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone Chemical compound C\C=C\C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-FNORWQNLSA-N 0.000 claims description 2
- HGECJFVPNUYRJZ-UHFFFAOYSA-N 2-methyl-2-(4-propan-2-ylphenyl)propanal Chemical compound CC(C)C1=CC=C(C(C)(C)C=O)C=C1 HGECJFVPNUYRJZ-UHFFFAOYSA-N 0.000 claims description 2
- IPWBXORAIBJDDQ-UHFFFAOYSA-N methyl 2-hexyl-3-oxocyclopentane-1-carboxylate Chemical compound CCCCCCC1C(C(=O)OC)CCC1=O IPWBXORAIBJDDQ-UHFFFAOYSA-N 0.000 claims description 2
- -1 agglomerates Substances 0.000 description 22
- 235000019645 odor Nutrition 0.000 description 22
- 239000011734 sodium Substances 0.000 description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- 239000004744 fabric Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- 229930002839 ionone Natural products 0.000 description 7
- VAMXMNNIEUEQDV-UHFFFAOYSA-N methyl anthranilate Chemical compound COC(=O)C1=CC=CC=C1N VAMXMNNIEUEQDV-UHFFFAOYSA-N 0.000 description 7
- 229920005646 polycarboxylate Polymers 0.000 description 7
- 150000007942 carboxylates Chemical class 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 150000002499 ionone derivatives Chemical class 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000004965 peroxy acids Chemical class 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- 102000013142 Amylases Human genes 0.000 description 4
- 108010065511 Amylases Proteins 0.000 description 4
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 4
- 229930182556 Polyacetal Natural products 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 4
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 4
- 229940102398 methyl anthranilate Drugs 0.000 description 4
- 229920006324 polyoxymethylene Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 3
- ORMHZBNNECIKOH-UHFFFAOYSA-N 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)(O)CCCC1=CCC(C=O)CC1 ORMHZBNNECIKOH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 230000000269 nucleophilic effect Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 159000000001 potassium salts Chemical class 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- QUMXDOLUJCHOAY-UHFFFAOYSA-N 1-Phenylethyl acetate Chemical compound CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 description 2
- XSNQECSCDATQEL-SECBINFHSA-N 2,6-dimethyl-7-octen-2-ol Chemical compound C=C[C@@H](C)CCCC(C)(C)O XSNQECSCDATQEL-SECBINFHSA-N 0.000 description 2
- WRFXXJKURVTLSY-UHFFFAOYSA-N 2,6-dimethyloctan-2-ol Chemical compound CCC(C)CCCC(C)(C)O WRFXXJKURVTLSY-UHFFFAOYSA-N 0.000 description 2
- LUZDYPLAQQGJEA-UHFFFAOYSA-N 2-Methoxynaphthalene Chemical compound C1=CC=CC2=CC(OC)=CC=C21 LUZDYPLAQQGJEA-UHFFFAOYSA-N 0.000 description 2
- FLUWAIIVLCVEKF-UHFFFAOYSA-N 2-Methyl-1-phenyl-2-propanyl acetate Chemical compound CC(=O)OC(C)(C)CC1=CC=CC=C1 FLUWAIIVLCVEKF-UHFFFAOYSA-N 0.000 description 2
- XSAYZAUNJMRRIR-UHFFFAOYSA-N 2-acetylnaphthalene Chemical compound C1=CC=CC2=CC(C(=O)C)=CC=C21 XSAYZAUNJMRRIR-UHFFFAOYSA-N 0.000 description 2
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 description 2
- HLCSDJLATUNSSI-UHFFFAOYSA-N 3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCCC(C)=CC#N HLCSDJLATUNSSI-UHFFFAOYSA-N 0.000 description 2
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 description 2
- 241001247414 Couma Species 0.000 description 2
- FKUPPRZPSYCDRS-UHFFFAOYSA-N Cyclopentadecanolide Chemical compound O=C1CCCCCCCCCCCCCCO1 FKUPPRZPSYCDRS-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DUKPKQFHJQGTGU-UHFFFAOYSA-N Hexyl salicylic acid Chemical compound CCCCCCOC(=O)C1=CC=CC=C1O DUKPKQFHJQGTGU-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 description 2
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 2
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 229940062909 amyl salicylate Drugs 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- HQKQRXZEXPXXIG-VJOHVRBBSA-N chembl2333940 Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1[C@@](OC(C)=O)(C)CC2 HQKQRXZEXPXXIG-VJOHVRBBSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- BLBJUGKATXCWET-UHFFFAOYSA-N cyclaprop Chemical compound C12CC=CC2C2CC(OC(=O)CC)C1C2 BLBJUGKATXCWET-UHFFFAOYSA-N 0.000 description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 2
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical group [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 description 2
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- NYNCZOLNVTXTTP-UHFFFAOYSA-N ethyl 2-(1,3-dioxoisoindol-2-yl)acetate Chemical compound C1=CC=C2C(=O)N(CC(=O)OCC)C(=O)C2=C1 NYNCZOLNVTXTTP-UHFFFAOYSA-N 0.000 description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 229910052700 potassium Inorganic materials 0.000 description 2
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- 150000003871 sulfonates Chemical class 0.000 description 2
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- IMRYETFJNLKUHK-SJKOYZFVSA-N 1-[(2r,3r)-1,1,2,6-tetramethyl-3-propan-2-yl-2,3-dihydroinden-5-yl]ethanone Chemical compound CC1=C(C(C)=O)C=C2[C@H](C(C)C)[C@@H](C)C(C)(C)C2=C1 IMRYETFJNLKUHK-SJKOYZFVSA-N 0.000 description 1
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- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- DNRJTBAOUJJKDY-UHFFFAOYSA-N 2-Acetyl-3,5,5,6,8,8-hexamethyl-5,6,7,8- tetrahydronaphthalene Chemical compound CC(=O)C1=C(C)C=C2C(C)(C)C(C)CC(C)(C)C2=C1 DNRJTBAOUJJKDY-UHFFFAOYSA-N 0.000 description 1
- OHQGTOVPSIVVLZ-UHFFFAOYSA-N 2-hexyl-3-methylcyclopentan-1-one Chemical compound CCCCCCC1C(C)CCC1=O OHQGTOVPSIVVLZ-UHFFFAOYSA-N 0.000 description 1
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 description 1
- MFWSZPMUSWPIFI-UHFFFAOYSA-N 2-nonoxybenzenesulfonic acid Chemical compound CCCCCCCCCOC1=CC=CC=C1S(O)(=O)=O MFWSZPMUSWPIFI-UHFFFAOYSA-N 0.000 description 1
- XYJLPCAKKYOLGU-UHFFFAOYSA-N 2-phosphonoethylphosphonic acid Chemical class OP(O)(=O)CCP(O)(O)=O XYJLPCAKKYOLGU-UHFFFAOYSA-N 0.000 description 1
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- NGYMOTOXXHCHOC-UHFFFAOYSA-N 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol Chemical compound CC(O)C(C)CCC1CC=C(C)C1(C)C NGYMOTOXXHCHOC-UHFFFAOYSA-N 0.000 description 1
- IKTHMQYJOWTSJO-UHFFFAOYSA-N 4-Acetyl-6-tert-butyl-1,1-dimethylindane Chemical compound CC(=O)C1=CC(C(C)(C)C)=CC2=C1CCC2(C)C IKTHMQYJOWTSJO-UHFFFAOYSA-N 0.000 description 1
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- YPZUZOLGGMJZJO-UHFFFAOYSA-N Ambronide Chemical compound C1CC2C(C)(C)CCCC2(C)C2C1(C)OCC2 YPZUZOLGGMJZJO-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
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- 239000004365 Protease Substances 0.000 description 1
- ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
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- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical class [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
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- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
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- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- CMFFZBGFNICZIS-UHFFFAOYSA-N butanedioic acid;2,3-dihydroxybutanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCC(O)=O.OC(=O)C(O)C(O)C(O)=O CMFFZBGFNICZIS-UHFFFAOYSA-N 0.000 description 1
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- YXZBWJWYWHRIMU-UBPCSPHJSA-I calcium trisodium 2-[bis[2-[bis(carboxylatomethyl)amino]ethyl]amino]acetate ytterbium-169 Chemical compound [Na+].[Na+].[Na+].[Ca+2].[169Yb].[O-]C(=O)CN(CC([O-])=O)CCN(CC(=O)[O-])CCN(CC([O-])=O)CC([O-])=O YXZBWJWYWHRIMU-UBPCSPHJSA-I 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 description 1
- 229940026455 cedrol Drugs 0.000 description 1
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 229940001468 citrate Drugs 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- KVFDZFBHBWTVID-UHFFFAOYSA-N cyclohexane-carboxaldehyde Natural products O=CC1CCCCC1 KVFDZFBHBWTVID-UHFFFAOYSA-N 0.000 description 1
- OANSOJSBHVENEI-UHFFFAOYSA-N cyclohexene-1-carbaldehyde Chemical compound O=CC1=CCCCC1 OANSOJSBHVENEI-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229960002598 fumaric acid Drugs 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical group 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical group COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical class CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- DAKZISABEDGGSV-UHFFFAOYSA-N n-(2-aminoethyl)acetamide Chemical compound CC(=O)NCCN DAKZISABEDGGSV-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229940100595 phenylacetaldehyde Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 239000001205 polyphosphate Chemical class 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- DNSWQCHBLOEFCW-UHFFFAOYSA-M sodium;2-nonoxybenzenesulfonate Chemical compound [Na+].CCCCCCCCCOC1=CC=CC=C1S([O-])(=O)=O DNSWQCHBLOEFCW-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- FUQAYSQLAOJBBC-PAPYEOQZSA-N β-caryophyllene alcohol Chemical compound C1C[C@](C2)(C)CCC[C@]2(O)[C@H]2CC(C)(C)[C@@H]21 FUQAYSQLAOJBBC-PAPYEOQZSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Definitions
- the present invention generally relates to bleaching compositions having selected perfumes especially suitable for masking the "bleach" odor associated with such compositions More particularly, the invention relates to bleaching compositions containing a bleaching agent, a bleach activator and a perfume which effectively masks the odor of the composition before and during use
- inorganic peroxygen bleaches overcome many of the disadvantages found with chlorine bleaches, they have limitations on use in that they must be used at relatively high temperatures, such as 85°C or higher This drawback becomes significant in light of the washing practices in countries where lower wash temperatures are used which are generally less than about 60°C in order to reduce energy costs and prolong the life of the fabric This problem also renders the product ineffective when used to "pre-soak" especially soiled fabrics As a consequence, it is generally necessary to improve the low temperature performances of inorganic peroxygen bleaches through the addition of peroxygen bleach activators also known as peroxyacid precursors
- peroxygen or peroxyacid bleaches either alone or in combination with a bleach activator, as an alternative to the chlorine and inorganic peroxygen bleaches described above.
- Various products including peroxygen bleaches and activators therefor have been used, for example, detergent compositions containing a bleach/bleach activator system and bleach additive products which are added separately from the detergent composition.
- Other bleaching compositions include those which are used as a "pre-soak" product for extensively soiled fabrics. The previously mentioned detergent compositions and bleaching compositions can be used in this manner, as well.
- the pre-soak products or other bleach-containing products require the user to immerse the soiled fabrics and bleach-containing product into a washing solution that is typically contained in a bucket, sink or similar open container for 20 to 30 minutes (or longer) during which a strong "bleach" odor is emitted from the washing solution.
- Consumers are offended by such readily detectable bleach odor, a problem which is exacerbated when the product contains high levels of bleach. This problem has been very noticeable in products which contain peroxygen bleach and activators therefor.
- a bleaching composition which includes a bleaching agent, a bleach activator and a perfume that effectively masks the odor of such components.
- a composition which contains a perfume that effectively masks the odor of the bleaching agent and bleach activator, even when the composition is used as a pre-soak product and contains high levels of bleach.
- the invention meets the needs identified above by providing bleaching compositions and detergent compositions containing a bleaching agent and a bleach activator which include a selected perfume particularly suitable for masking the bleach odor emitted by such compositions before and during use.
- the compositions herein can optionally contain relatively high levels of bleaching agents and activators without significant detection of undesirable odors typically associated with such compositions.
- the compositions of the invention can be used in a wide variety of applications including presoak operations wherein soiled fabrics are soaked in open containers, i.e. bucket or sink, prior to conventional laundering operations. The consumer does not notice the bleach odors of the compositions when used in the aforementioned presoaking operations because of the perfume.
- the selected perfumes used in the compositions herein unexpectedly provide masking of the harsh odors normally associated with the bleach-containing compositions described herein.
- ODT Odor Detection Threshold
- AMU atomic weight and may also be expressed as g/mole. All percentages, ratios and proportions used herein are by weight, unless otherwise specified. All documents including patents and publications cited herein are incorporated herein by reference.
- a bleaching composition comprises: (a) a peroxygen bleaching agent; (b) a bleach activator; and (c) a perfume.
- the perfume contains, by weight of the perfume, (i) at least about 25% of a fragrance material selected from the group consisting of aldehydes with a molecular weight greater than 200 AMU, esters with a molecular weight above 200 AMU, alcohols with a molecular weight between 120 and 160 AMU and mixtures thereof, wherein at least about 10% by weight of the fragrance material has an Odor Detection Threshold (ODT) value of less than about 100 parts per trillion; and (ii) at least about 1.0% of an adjunct material with an Odor Detection Threshold (ODT) value of less than about 100 parts per trillion.
- the perfume is substantially free of halogenated fragrance materials and nitromusks.
- a granular detergent composition comprises: (a) from about 0.1% to about 40% by weight of a peroxygen bleaching agent selected from the group consisting of percarbonates, perborates, peroxides and mixtures thereof; (b) from about 0 1 % to about 20% by weight a bleach activator having the formula o
- R— C — LG wherein R is an alkyl group containing from about 5 to about 18 carbon atoms and LG is a leaving group, the conjugate acid of which has a pK a of from about 4 to about 13, wherein the LG has the formula
- Y is selected from the group consisting of SO ⁇ - M + , COO" M + , SO4- M + , PO4- M + PO3- M+, (N+R2 3 )X- and 0 ⁇ -N(R 2 2 ), M is a cation, X is an anion, and R 2 is an alkyl chain containing from about 1 to about 4 carbon atoms or H, and (c) from about 0 01 % to about 2% of a perfume containing, by weight of the perfume, (i) at least 25% of a fragrance material selected from the group consisting of aldehydes with a molecular weight greater than 200 AMU, esters with a molecular weight above 200 AMU, alcohols with a molecular weight between 120 and 160 AMU and mixtures thereof, wherein at least 10% by weight of the fragrance material has an Odor Detection Threshold (ODT) value of less than about 100 parts per trillion, and (u) at least 1 0% of an adjunct material with an
- a bleaching composition as described herein which is in the form of a liquid.
- a method of laundering soiled clothes comprising the step of contacting the soiled clothes with an aqueous washing solution containing a bleaching composition as described herein
- a presoaking method is also provided which comprises the steps of soaking the soiled clothes in an aqueous soaking solution of a bleaching composition as described herein and thereafter, contacting the clothes with an aqueous washing solution containing a detergent composition
- a bleaching composition which includes a bleaching agent, a bleach activator and a perfume that effectively masks the odor of such components before and during use. It is also an object of the invention to provide a bleaching composition which contains such a perfume that effectively masks the odor of the bleaching agent and bleach activator, even when the composition is used as a pre-soak product and contains high levels of bleaching agents and activators.
- compositions of the invention comprise a bleaching agent, a bleach activator and a selected perfume for masking the odor of the bleach components.
- the compositions herein can be in the form of granules, agglomerates, liquid, gel or a bar. Additionally, the. compositions can be used as a bleaching composition, fully formulated detergent composition, or as a bleach or detergent presoak product.
- Bleaching System
- the compositions of the invention must include a bleaching system comprising a bleaching agent and a bleach activator.
- the compositions preferably comprise from about 0.1% to about 40%, more preferably from about 20% to about 35%, and most preferably from about 30% to about 35%, by weight of the peroxygen bleaching agent.
- the detergent composition comprises from about 0.1 % to about 40%, more preferably from about 5% to about 15%, and most preferably from about 10% to about 15%, by weight of the bleach activator.
- one or more adjunct bleach activators may be used in the same amounts.
- the peroxygen bleaching agents can be any of those peroxygen bleaching agents useful for detergent compositions in textile cleaning that are known or become known.
- the bleaching agent is selected from the group consisting of percarbonates, perborates, peroxides and mixtures thereof. While intending not to be limiting, included within this group are sodium carbonate peroxyhydrate and equivalent "percarbonate" bleaches, sodium pyrophosphate peroxyhydrate, urea peroxyhydrate, sodium perborate (e.g. mono- or tetra-hydrate) and sodium peroxide. It should be understood that other peroxygen bleaches other than those described herein may be used in the detergent composition without departing from the scope of the invention The most preferred bleaching agent is sodium percarbonate
- the peroxygen bleaching agent used herein is combined with a bleach activator which leads to the in situ production in aqueous solution (i e during the laundering process) of the peroxy acid corresponding to the activator
- a bleach activator which leads to the in situ production in aqueous solution (i e during the laundering process) of the peroxy acid corresponding to the activator
- the bleaching mechanism generally, and the surface bleaching mechanism in particular, in the washing solution are not completely understood While not intending to be limited by theory, however, it is believed that the bleach activator undergoes nucleophilic attack by a perhydroxide anion, for example from aqueous hydrogen peroxide, to form a percarboxylic acid This reaction is commonly referenced in the art as perhydrolysis
- DAP diacylperoxide
- dingy soils are those which have built up on textiles after numerous cycles of usage and washing and thus, cause the white textile to have a gray or yellow tint
- the bleaching mechanism herein preferably produces an effective amount of peroxyacid and DAP to bleach both dingy stains as well as stains resulting from spaghetti and the like
- bleach activators within the scope of the invention render the peroxygen bleaches more efficient even at bleach solution temperatures wherein the bleach activators are not necessary to activate the bleach, for example at temperatures above 60°C As a consequence, less peroxygen bleach is required to obtain the same level of surface bleaching performance as compared with peroxygen bleach alone
- the bleach activator used in the granular detergent composition has the general formula o
- R— C — LG wherein R is an alkyl group, linear or branched, containing from about 1 to 11 carbon atoms and LG is a suitable leaving group
- a "leaving group” is any group that is displaced from the bleach activator as consequence of nucleophilic attack on the bleach activator by the perhydroxide anion, i.e. perhydrolysis reaction.
- a suitable leaving group is electrophilic and is stable such that the rate of the reverse reaction is negligible. This facilitates the nucleophilic attack by the perhydroxide anion.
- the leaving group must also be sufficiently reactive for the reaction to occur within the optimum time frame, for example during the wash cycle. However, if the leaving group is too reactive, the bleach activator will be difficult to stabilize. In the past, it has been difficult to formulate granular detergent compositions having the desired stability for a practical shelf-life.
- the conjugate acid of the leaving group in accordance with the present invention preferably has a pK a in a range from about 4 to about 13, more preferably from about 6 to about 11 , and most preferably from about 8 to about 11.
- the leaving group has the formula
- Y is selected from the group consisting of SO3" M + , COO" M + , SO4- M + , P0 4 " M + , PO3- M + , (N + R2 3 )X- and 0 ⁇ -N(R 2 2 ),
- M is a cation and X is an anion, both of which provide solubility to the bleach activator, and R 2 is an alkyl chain containing from about 1 to about 4 carbon atoms or H.
- M is preferably an alkali metal, with sodium being most preferred.
- X is a hydroxide, methylsulfate or acetate anion.
- R is an alkyl chain, linear or branched, containing from about 1 to about 11 carbon atoms
- the bleach activator has the formula
- TAED tetra acetyl ethylene diamme
- compositions of the invention preferably contain from about 0 001 % to about 5%, more preferably from about 0 01% to about 2%, and most preferably from about 0 1% to about 1 0%, by weight of a perfume as described herein
- the formulator has the luxury of choosing from a wide variety of perfume ingredients in order to arrive at a perfume formulation with the definition stated previously Several exemplary perfume formulations are set forth hereinafter
- the perfume preferably includes at least 25%, more preferably from about 40% to about 75%, and most preferably from about 60% to about 70%, by weight of the perfume, of certain aldehydes, esters, alcohols and mixtures thereof
- Suitable aldehydes with molecular weights greater than 200 AMU, esters with molecular weights greater than 200 AMU and alcohols with molecular weights between 120 - 160 AMU include, but are not limited to hexyl cinnamic aldehyde; amyl cinnamic aldehyde; amyl salicylate; hexyl salicylate; phenyl ethyl alcohol; terpineol; 3,7-dimethyl-cs-2,6-octadien-1 -ol; 2,6-dimethyl-2-octanol; 2,6-dimethyl-7- octen-2-ol, 3,7-dimethyl-3-octanol; 3,7-d
- At least about 10%, more preferably from about 15% to about 30%, and most preferably from about 20% to about 25%, by weight of the perfume, of the aformentioned aldehydes, esters, alcohols and mixtures thereof have an Odor Detection Threshold value of less than about 100 parts per trillion.
- Suitable aldehydes with molecular weights greater than 200 AMU, esters with molecular weights greater than 200 AMU and alcohols with molecular weights between 120 - 160 AMU having such- measured Odor Detection Threshold (ODT) values include but are not limited to, benzyl salicylate; 2-methyl-3-(para tert butylphenyl)- propionaldehyde; 4-(4-hydroxy-4-methyl pentyl)-3-cyclohexene-1- carboxaldehyde; tricyclodecenyl propionate.
- the perfume also comprises at least about 1%, more preferably from about 5% to about 35%, and most preferably from about 20% to about 25%, by weight of the perfume, of an adjunct fragrance material with an Odor Detection Threshold values less than or equal to 100 parts per trillion include, but are not limited to, tricyclodecenyl acetate; anisaldehyde; 2- methyl-2-(para-iso-propylphenyl)-propionaldehyde; ethyl 3-methyl-3-phenyl glycidate; 4-(para-hydroxy phenyl) butan-2-one; 1-(2,6,6-trimethyl-2- cyclohexen-1-yl)-2-buten-1 -one; para methoxy acetophenone; para- methoxy-alpha-phenyl propene; methyl 2-n-hexyl-3-oxo-cyclopentane carboxylate; undecalactone gamma.
- fragrance materials of synthetic or natural origin may be added to the perfume if desired and include but are not limited to dodecalactone gamma; methyl 2-(2- ⁇ entyl-3-oxo-cyclopentyl) acetate; beta naphthol methyl ether; methyl beta naphthyl ketone; couma n; decyl aldehyde; benzaldehyde; 4-tertiary-butyl cyclohexyl acetate; alpha, alpha- dimethyl phenethyl acetate; methyl phenyl carbinyl acetate; schiff s base of 4-(4-hydroxy-4-methyl pentyl)-3-cyclohexene-1 -carboxaldehyde and methyl anthranilate; cyclic ethylene glycol diester of tridecandioic acid; 3,7- dimethyl-2,6-octadiene-1-nitrile; ionone gamma methyl;
- adjunct ingredients can be included in the compositions disclosed herein.
- the levels of the ingredients will vary depending upon the context, e.g. liquid or granular, bleaching or detergent composition, etc.
- the bleaching or granular detergent compositions of the invention can include a wide variety of additional ingredients typically used in the art of detergency.
- the detergent composition can include from about 1% to about 80%, more preferably from about 5% to about 20%, and most preferably from about 10% to about 30%, by weight of a builder.
- the builder can be selected from the various water-soluble, alkali metal, ammonium or substituted ammonium phosphates, polyphosphates, phosphonates, polyphosphonates, carbonates, crystalline layered and amorphous silicates, borates, polyhydroxy sulfonates, polyacetates, carboxylates, and polycarboxylates.
- the alkali metal especially sodium, salts of the above.
- Preferred for use herein are the phosphates, carbonates, silicates, C 10 _ 1 g fatty acids, polycarboxylates, and mixtures thereof. More preferred are sodium tripolyphosphate, tetrasodium pyrophosphate, citrate, tartrate mono- and di-succinates, sodium silicate, and mixtures thereof (see below).
- inorganic phosphate builders are sodium and potassium tripolyphosphate, pyrophosphate, polymeric metaphosphate having a degree of polymerization of from about 6 to 21 , and orthophosphates.
- polyphosphonate builders are the sodium and potassium salts of ethylene diphosphonic acid, the sodium and potassium salts of ethane 1-hydroxy-1 , 1 -diphosphonic acid and the sodium and potassium salts of ethane, 1 ,1 ,2-triphosphonic acid.
- Other phosphorus builder compounds are disclosed in U.S. Patents 3,159,581 ; 3,213,030; 3,422,021 ; 3,422,137; 3,400,176 and 3,400,148, all of which are incorporated herein by reference.
- nonphosphorus, inorganic builders are sodium and. potassium carbonate, bicarbonate, sesquicarbonate, tetraborate decahydrate, and silicates having a weight ratio of Si0 2 to alkali metal oxide of from about 0.5 to about 4.0, preferably from about 1.0 to about 2.4.
- Water-soluble, nonphosphorus organic builders useful herein include the various alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxy sulfonates.
- polyacetate and polycarboxylate builders are the sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylene diamine tetraacetic acid, nitrilotriacetic acid, oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, and citric acid.
- Polymeric polycarboxylate builders are set forth in U.S. Patent 3,308,067, Diehl, issued March 7, 1967, the disclosure of which is incorporated herein by reference.
- Such materials include the water-soluble salts of homo- and copolymers of aliphatic carboxylic acids such as maleic acid, itaconic acid, mesaconic acid, fumaric acid, aconitic acid, citraconic acid and methylenemalonic acid.
- Some of these materials are useful as the water-soluble anionic polymer as hereinafter described, but only if in intimate admixture with the non-soap anionic surfactant.
- polycarboxylates for use herein are the polyacetal carboxylates described in U.S. Patent 4,144,226, issued March 13, 1979 to Crutchfield et al, and U.S. Patent 4,246,495, issued March 27, 1979 to Crutchfield et al, both of which are incorporated herein by reference. These polyacetal carboxylates can be prepared by bringing together under polymerization conditions an ester of glyoxylic acid and a polymerization 96/31590 PC17US96/04023
- polyacetal carboxylate ester is then attached to chemically stable end groups to stabilize the polyacetal carboxylate against rapid depolyme ⁇ zation in alkaline solution, converted to the corresponding salt, and added to a detergent composition.
- Particularly preferred polycarboxylate builders are the ether carboxylate builder compositions comprising a combination of tartrate monosuccinate and tartrate disuccinate described in U.S. Patent 4,663,071 , Bush et al., issued May 5, 1987, the disclosure of which is incorporated herein by reference.
- Water-soluble silicate solids represented by the formula Si ⁇ 2»M 2 0, M being an alkali metal, and having a SiO ⁇ M ⁇ O weight ratio of from about 0.5 to about 4.0, are useful salts in the compositions of the invention at levels of from about 0.1% to about 15%, more preferably from about 0.5% to about 2%, on an anhydrous weight basis.
- Anhydrous or hydrated paniculate silicate can be utilized, as well.
- the detergent composition of the invention optionally can contain various anionic, nonionic, zwitte ⁇ onic, etc. surfactants. If used, such surfactants are typically present at levels of from about 1 % to about 50%, more preferably from about 3% to about 35%, and most preferably from about 5% to about 25%, by weight of the composition.
- Nonlimiting examples of surfactants useful herein include the conventional Cn-Ci ⁇ alkyl benzene sulfonates ("LAS") and primary, branched-cham and random C10-C20 alk yl sulfates (“AS”), the C10-C18 secondary (2,3) alkyl sulfates of the formula CH 3 (CH2) ⁇ (CHOS0 3 " M + ) CH3 and CH3 (CH 2 )y(CHOS ⁇ 3 " M + ) CH2CH3 where x and (y + 1 ) are integers of at least about 7, preferably at least about 9, and M is a water-solubilizing cation, especially sodium, unsaturated sulfates such as oleyl sulfate, the C10- 18 alkyl alkoxy sulfates (“AE X S”; especially EO 0.1-7 ethoxy sulfates), C10-C18 alkyl alkoxy carboxylates (especially the EO 1-5 ethoxycar
- the conventional nonionic and amphote ⁇ c surfactants such as the C12-C18 alkyl ethoxylates ("AE") including the so-called narrow peaked alkyl ethoxylates and C6-C12 alkyl phenol alkoxylates (especially ethoxylates and mixed ethoxy/propoxy), Ci2 _c 18 betames and sulfobetames (“sultaines”), C10-C18 am ⁇ ne oxides, and the like, can also be included in the overall compositions.
- the C10-C18 N-alkyl polyhydroxy fatty acid amides can also be used. Typical examples include the C12-C18 N-methylglucamides. See WO 9,206,154.
- sugar-derived surfactants include the N-alkoxy polyhydroxy fatty acid amides, such as C10-C18 N-(3-methoxypropyl) glucamide.
- the N-propyl through N-hexyl Ci2 _c 18 glucamides can be used for low sudsing.
- o _c 20 conventional soaps may also be used. If high sudsing is desired, the branched-chain C10-C16 soa P s ma y De used. Mixtures of anionic and nonionic surfactants are especially useful. Other conventional useful surfactants are listed in standard texts.
- AE X S C10-C18 alkyl alkoxy sulfates
- AE C-12-C18 alkyl ethoxylates
- the detergent composition can also include suds boosters or suds, suppresses, anti-tarnish and anticorrosion agents, soil suspending agents, soil release agents, germicides, pH adjusting agents, non-builder alkalinity sources, chelating agents, smectite clays, enzymes (e.g. cellulases, proteases, lipases and amylases), and enzyme-stabilizing agents. See U.S. Patent 3,936,537, issued February 3, 1976 to Baskerville, Jr. et al., incorporated herein by reference.
- a polymeric dispersant such as polyaspartic acid, may also be included in the detergent composition disclosed herein.
- Chelating agents are also described in U.S. Patent 4,663,071 , Bush et al., from Column 17, line 54 through Column 18, line 68, incorporated herein by reference.
- Suds modifiers are also optional ingredients and are described in U.S. Patents 3,933,672, issued January 20, 1976 to Bartoletta et al., and 4,136,045, issued January 23, 1979 to Gault et al., both incorporated herein by reference.
- Suitable smectite clays for use herein are described in U.S. Patent 4,762,645, Tucker et al, issued August 9, 1988, Column 6, line 3 through Column 7, line 24, incorporated herein by reference.
- Suitable additional detergency builders for use herein are enumerated in the Baskerville patent, Column 13, line 54 through Column 16, line 16, and in U.S. Patent 4,663,071 , Bush et al, issued May 5, 1987, both incorporated herein by reference.
- Fillers such as sulfates may be included at levels of from about 5% to about 50%, more preferably from about 10% to about 30%, by weight of the composition.
- This Example illustrates three perfume formulations in accordance with the invention. Specifically, Table I sets forth perfume formulations A, B and C which are suitable for use in the compositions of the invention.
- compositions set forth in Table II are made by conventional detergent processing techniques.
- the base granule ingredients are mixed together as a slurry and spray dried in a tower to produce granules.
- the dry ingredients are then admixed with the granules and the liquid ingredients are spray thereon to provide the finished composition.
- various liquid and dry ingredients can be agglomerated to provide high density agglomerates to which the remaining ingredients can be sprayed on or admixed as appropriate.
- Polyethylene glycol (M.W. 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8
- Protease enzyme 04 0.5 0.4 0.4 0.5 0.5
- Nonionic 3 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
- Neodol (23-9) commercially available from Shell Chemical Co.
- compositions set forth in Table III are made in accordance with the processes described with respect to Examples ll-IV hereinabove.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96910538A EP0821723A1 (en) | 1995-04-03 | 1996-03-25 | Bleaching compositions with selected perfumes for masking bleach odor |
JP8530341A JPH11503192A (en) | 1995-04-03 | 1996-03-25 | Bleaching compositions containing fragrances selected to mask bleach odor |
BR9604793A BR9604793A (en) | 1995-04-03 | 1996-03-25 | Bleach compositions with selected perfumes to mask the bleach odor |
MX9707588A MX9707588A (en) | 1995-04-03 | 1996-03-25 | Bleaching compositions with selected perfumes for masking bleach odor. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US41590595A | 1995-04-03 | 1995-04-03 | |
US08/415,905 | 1995-04-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996031590A1 true WO1996031590A1 (en) | 1996-10-10 |
Family
ID=23647715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/004023 WO1996031590A1 (en) | 1995-04-03 | 1996-03-25 | Bleaching compositions with selected perfumes for masking bleach odor |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0821723A1 (en) |
JP (1) | JPH11503192A (en) |
CN (1) | CN1185804A (en) |
BR (1) | BR9604793A (en) |
CA (1) | CA2216778A1 (en) |
CZ (1) | CZ308797A3 (en) |
HU (1) | HUP9801774A3 (en) |
MX (1) | MX9707588A (en) |
WO (1) | WO1996031590A1 (en) |
ZA (1) | ZA962667B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001000775A1 (en) * | 1999-06-28 | 2001-01-04 | U.S. Borax Inc. | Benzolactones as bleach activators |
JP2002539322A (en) * | 1999-03-15 | 2002-11-19 | ザ、プロクター、エンド、ギャンブル、カンパニー | Perfume composition and method for masking malodor of amine |
US7157411B2 (en) | 1999-12-13 | 2007-01-02 | Symrise Gmbh & Co. Kg | Odor neutralizers |
EP2226063A2 (en) | 2009-03-04 | 2010-09-08 | Takasago International Corporation | High intensity fragrances |
EP2449082A2 (en) * | 2009-06-30 | 2012-05-09 | The Procter & Gamble Company | Bleaching compositions comprising a perfume delivery system |
DE102014205860A1 (en) | 2014-03-28 | 2015-10-01 | Henkel Ag & Co. Kgaa | Olfactory amplifiers |
EP3546560A1 (en) * | 2018-03-28 | 2019-10-02 | The Procter & Gamble Company | Laundry detergent composition |
US11008271B2 (en) * | 2016-09-08 | 2021-05-18 | P2 Science, Inc. | Methods for the continuous alkoxylation and derivatization of terpenes |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0147191A2 (en) * | 1983-12-22 | 1985-07-03 | Unilever N.V. | Perfume and compositions containing perfume |
EP0404470A1 (en) * | 1989-06-19 | 1990-12-27 | Quest International B.V. | Fragrance compositions and their use in detergent products |
WO1992008780A1 (en) * | 1990-11-14 | 1992-05-29 | The Procter & Gamble Company | Granular detergent or bleaching compositions containing amidoperoxyacid bleach and perfume |
-
1996
- 1996-03-25 WO PCT/US1996/004023 patent/WO1996031590A1/en not_active Application Discontinuation
- 1996-03-25 EP EP96910538A patent/EP0821723A1/en not_active Withdrawn
- 1996-03-25 JP JP8530341A patent/JPH11503192A/en active Pending
- 1996-03-25 CN CN96194278A patent/CN1185804A/en active Pending
- 1996-03-25 CA CA002216778A patent/CA2216778A1/en not_active Abandoned
- 1996-03-25 BR BR9604793A patent/BR9604793A/en not_active Application Discontinuation
- 1996-03-25 MX MX9707588A patent/MX9707588A/en unknown
- 1996-03-25 HU HU9801774A patent/HUP9801774A3/en unknown
- 1996-03-25 CZ CZ973087A patent/CZ308797A3/en unknown
- 1996-04-03 ZA ZA962667A patent/ZA962667B/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0147191A2 (en) * | 1983-12-22 | 1985-07-03 | Unilever N.V. | Perfume and compositions containing perfume |
EP0404470A1 (en) * | 1989-06-19 | 1990-12-27 | Quest International B.V. | Fragrance compositions and their use in detergent products |
WO1992008780A1 (en) * | 1990-11-14 | 1992-05-29 | The Procter & Gamble Company | Granular detergent or bleaching compositions containing amidoperoxyacid bleach and perfume |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002539322A (en) * | 1999-03-15 | 2002-11-19 | ザ、プロクター、エンド、ギャンブル、カンパニー | Perfume composition and method for masking malodor of amine |
WO2001000775A1 (en) * | 1999-06-28 | 2001-01-04 | U.S. Borax Inc. | Benzolactones as bleach activators |
US7157411B2 (en) | 1999-12-13 | 2007-01-02 | Symrise Gmbh & Co. Kg | Odor neutralizers |
EP2226063A2 (en) | 2009-03-04 | 2010-09-08 | Takasago International Corporation | High intensity fragrances |
US9222055B2 (en) | 2009-03-04 | 2015-12-29 | Takasago International Corporation | High intensity fragrances |
EP2449082A2 (en) * | 2009-06-30 | 2012-05-09 | The Procter & Gamble Company | Bleaching compositions comprising a perfume delivery system |
EP2537916B1 (en) * | 2009-06-30 | 2017-11-29 | The Procter and Gamble Company | Bleaching compositions comprising a perfume delivery system |
DE102014205860A1 (en) | 2014-03-28 | 2015-10-01 | Henkel Ag & Co. Kgaa | Olfactory amplifiers |
US11008271B2 (en) * | 2016-09-08 | 2021-05-18 | P2 Science, Inc. | Methods for the continuous alkoxylation and derivatization of terpenes |
EP3546560A1 (en) * | 2018-03-28 | 2019-10-02 | The Procter & Gamble Company | Laundry detergent composition |
WO2019191171A1 (en) * | 2018-03-28 | 2019-10-03 | The Procter & Gamble Company | Laundry detergent composition |
Also Published As
Publication number | Publication date |
---|---|
CA2216778A1 (en) | 1996-10-10 |
MX9707588A (en) | 1997-12-31 |
CN1185804A (en) | 1998-06-24 |
BR9604793A (en) | 1998-07-07 |
CZ308797A3 (en) | 1998-03-18 |
ZA962667B (en) | 1996-10-09 |
HUP9801774A3 (en) | 1999-03-01 |
EP0821723A1 (en) | 1998-02-04 |
HUP9801774A2 (en) | 1999-01-28 |
JPH11503192A (en) | 1999-03-23 |
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