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WO1996031121A1 - Composition herbicide - Google Patents

Composition herbicide Download PDF

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Publication number
WO1996031121A1
WO1996031121A1 PCT/JP1996/000922 JP9600922W WO9631121A1 WO 1996031121 A1 WO1996031121 A1 WO 1996031121A1 JP 9600922 W JP9600922 W JP 9600922W WO 9631121 A1 WO9631121 A1 WO 9631121A1
Authority
WO
WIPO (PCT)
Prior art keywords
ether
polyoxyethylene
herbicidal
dcmu
herbicidal composition
Prior art date
Application number
PCT/JP1996/000922
Other languages
English (en)
Japanese (ja)
Inventor
Shuuichi Kojima
Hideki Yamagishi
Hideo Hosaka
Original Assignee
Nippon Soda Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Soda Co., Ltd. filed Critical Nippon Soda Co., Ltd.
Publication of WO1996031121A1 publication Critical patent/WO1996031121A1/fr

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Definitions

  • the present invention relates to a herbicidal composition containing a non-selective herbicide, Kusakattosol-sapoport, which hastens the onset of action of a herbicide and enhances the herbicidal effect.
  • Kusakattosol is composed of glufosinate (ammonium-DL-homoalanine-4-yl (methyl) phosphine) with strong foliage treatment and DCMU with soil treatment effect: 3- (3.4) -dichlorophenyl
  • This is a non-selective herbicide that contains 1-dimethylurea) as an active ingredient.
  • support is viaalaphos ⁇ L12-amino_41-((hydroquinine) (methyl) phosphinoyl) butyryl L-aranyl-L-Naranium salt ⁇ It is a non-selective herbicide containing as an active ingredient, and DCMU.
  • These herbicides have the ability to kill growing weeds as well as pre-emergence weeds, and are characterized by an extremely long weeding period.
  • An object of the present invention is to provide a new herbicidal composition in which the herbicidal effect is accelerated by compensating for such a drawback and the herbicidal effect is more reliable. Disclosure of the invention:
  • the present inventors have found that the use of a non-selective herbicide, kusakattosol or a support, together with an adjuvant, a humectant, accelerates the herbicidal action to a surprising extent and increases the herbicidal effect. And completed the present invention.
  • the present invention relates to organic silicones, polyoxyethylene isodecanol ether, polyoxyethylene dodecyl ether, tallow amino ether, E0P0 procopolymer, EOZPO fat.
  • a herbicidal composition comprising an auxiliary agent of any kind and a nonselective herbicide, kusakattosol or a support.
  • “Kusakattosol” is a trade name of Nippon Soda Co., Ltd., a non-selective herbicide, and is a herbicide containing glufosinate and DCMU as its active ingredients.
  • Support wettable powder is a brand name of Meiji Seika Co., Ltd., a non-selective herbicide, and is a herbicide containing viaalaphos and DCMU as its active ingredients.
  • the adjuvant used in the present invention is generally called a wetting agent having a function of enhancing the wettability of the leaves of a plant, and is applied as an aqueous spray mixture together with a cassatum sol or a support. can do.
  • concentration of the adjuvant in this aqueous jetting mixture is usually from 0.01 to 10% by weight, preferably from 0.25 to 0% by weight.
  • the preferable water consumption is 100 to 150 L / 10a.
  • the auxiliary agent used in the present invention includes, for example, an organic silicon-based auxiliary agent: trade name Silwet L_77 (Nippon Konika Co., Ltd.) Or Silgard 309 (manufactured by Toray Industries, Inc., Dakota Silicone Co., Ltd.).
  • auxiliary substances for polyoxyethylene isotridecanol ether include [Product name: Genapor (Genap 01 X-0,600), Hextor Inc.] Hoechst AG)].
  • Examples of substances that are particularly preferred as an auxiliary substance of polyoxetylene dodecyl ether include [Sulfactant WK, Maruwa Biochemical Co., Ltd.]. BEST MODE FOR CARRYING OUT THE INVENTION (Example)
  • No. 4 pot was filled with soil, and an appropriate amount of soil mixed with crabgrass seeds was overlaid and seeded.
  • Spray water volume was set at 100 LZ 10 a.
  • the degree of weed killing was evaluated according to the criteria of 0 (no effect) to ⁇ 0 (complete mortality). The results are shown in Table 1.
  • Drug 1 Glufosinate + DCMU (Kusakattosol: Nippon Soda Co., Ltd.)
  • Drug 2 Glufosinate (Busta: Hexstar)
  • Drug 3 Vialahos DCMU (Support wettable powder: Meiji Seika Co., Ltd.)
  • Auxiliary A Silwet L-7 7
  • Auxiliary B S y l g a r d 3 0 9
  • Auxiliary agent C Genapol X-0 60
  • Auxiliary agent D Surfactant WK From Table I, these are auxiliary agents compared to the case of treatment with only Xaccat sol (glufocine citrate + DCMU) or support (bialaphos + DCMU).
  • S i 1 wet L-77, Sylgard 309, Genapo 1 X-0.60, and Surfactant WK were added, the speed of herbicidal action and the herbicidal activity were extremely remarkable. It was shown to increase to some extent. In particular, the speed of onset of herbicidal action was significantly improved, and was comparable to that of glufosinate, which is said to have an early onset of action.
  • Stages of weeds during treatment include: meadowgrass (growing stage-flowering stage, plant height 15-40 cm), nobie (growing stage-flowering stage, plant height 25-60 cm), and abyss ( The growing water was the first bud stage, the plant height was 20 to 60 cm), and the amount of water applied was 150 LZ10a (drug 4 was 100 LZOa).
  • the survey was conducted according to the standard of 0 (no effect) to 10 (complete mortality), with the degree of weed killing as the entire treatment area after 4, 15, and 29 days after chemical treatment. It is shown in the table.
  • drugs 1, 2, 4, and Agents A, B, C and D represent the following.
  • Drug 1 Glufosinate + DCMU (Kusakattosol: Nippon Soda Co., Ltd.)
  • Drug 2 Glufosinate (Pasta: Hexstar)
  • Auxiliary B S y l g a r d 3 0 9
  • Auxiliary agent C Genapol X-0 60
  • Adjuvant D Surfactant WK As shown in Table 2, the herbicidal action and herbicidal activity were exhibited by the addition of each of the four adjuvants tested in the field as in the greenhouse test. Increased. The herbicidal period of Drug 1 with the supplement is the same as that of Drug 1 without the supplement.By adding each of the supplements A, B, C, and D to the non-selective herbicide, the active ingredient of Drug 1 is obtained. It was shown that the herbicidal activity and herbicidal activity were increased to a remarkable degree without impairing the soil treatment activity by DCMU, which is one of them.
  • the herbicidal composition of the present invention contains a non-selective herbicide, kusakat sol or support, and a specific adjuvant.
  • the herbicidal action is surprisingly fast and has an excellent herbicidal effect-industrial applicability:
  • the herbicidal composition of the present invention contains a non-selective herbicide and a specific adjuvant, and exhibits a surprisingly rapid herbicidal action and an excellent herbicidal effect as compared with the case where each drug is used alone. It is useful as a herbicide because it has

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Composition herbicide qui contient au moins un adjuvant choisi dans le groupe constitué de composés d'organosilicium, éther isotridécylique de polyoxyéthylène, éther dodécylique de polyoxyéthylène, aminoéther de suif de boeuf, copolymère bloc EO/PO, éthers d'alcool aliphatique EO/PO et éther nonylphénylique de polyoxyéthylène (de préférence des composés d'organosilicium, éther isotridécylique de polyoxyéthylène et éther dodécylique de polyoxyéthylène) et un herbicide non sélectif (glyphosinate + DCMU ou Bialophos + DCMU). Dans cette composition herbicide, l'expression des effets herbicides de l'herbicide non sélectif peut être accélerée et les effets herbicides ainsi augmentés.
PCT/JP1996/000922 1995-04-06 1996-04-04 Composition herbicide WO1996031121A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP10698595 1995-04-06
JP7/106985 1995-04-06
JP7198189A JPH08333204A (ja) 1995-04-06 1995-07-11 除草性組成物
JP7/198189 1995-07-11

Publications (1)

Publication Number Publication Date
WO1996031121A1 true WO1996031121A1 (fr) 1996-10-10

Family

ID=26447069

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1996/000922 WO1996031121A1 (fr) 1995-04-06 1996-04-04 Composition herbicide

Country Status (2)

Country Link
JP (1) JPH08333204A (fr)
WO (1) WO1996031121A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000003595A1 (fr) * 1998-07-16 2000-01-27 Michigan State University Compositions et procedes permettant de proteger les plantes cultivees contre les blessures causees par les herbicides
FR2795290A1 (fr) * 1999-06-23 2000-12-29 Agronomique Inst Nat Rech Procede de traitement phytosanitaire par absorption foliaire et composition comprenant au moins un principe actif phytosanitaire hydrosoluble et au moins une huile modifiee
WO2002021924A3 (fr) * 2000-09-13 2003-01-09 Monsanto Technology Llc Compositions herbicides contenant du glyphosate et du bipyridilium
WO2003059066A1 (fr) * 2002-01-16 2003-07-24 Bayer Cropscience Ag Utilisation d'ethoxylates d'alcool en tant qu'agents favorisants la penetration
WO2003090531A1 (fr) * 2002-04-24 2003-11-06 Basf Aktiengesellschaft Utilisation d'alcoxylates definis en tant qu'adjuvants dans le domaine de la technique agricole
US7056862B2 (en) * 2000-12-20 2006-06-06 Kao Corporation Herbicide potentiators
CN109221241A (zh) * 2018-09-17 2019-01-18 深圳诺普信农化股份有限公司 一种含有草铵膦的除草组合物
CN109964938A (zh) * 2019-04-15 2019-07-05 广东省科学院产业技术育成中心 含有月桂醇醚磷酸酯的d酸草甘膦复配助剂及其制备方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1087507C (zh) * 1994-04-27 2002-07-10 富士电气化学株式会社 电池阳极锌罐、其制造方法及使用这种锌罐的锰干电池
JP5753405B2 (ja) * 2010-03-03 2015-07-22 石原産業株式会社 芝草に対する望ましくない作用を軽減する方法
TWI769184B (zh) * 2016-10-25 2022-07-01 印度商Upl有限公司 穩定除草組成物及野草控制的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5673010A (en) * 1979-11-20 1981-06-17 Sumitomo Chem Co Ltd Herbicidal suspension composition
JPS58162504A (ja) * 1982-03-23 1983-09-27 モンサント・カンパニ− 除草剤乳濁液
JPH0324004A (ja) * 1989-06-10 1991-02-01 Hoechst Ag 除草用混合物の液状配合物
JPH05294804A (ja) * 1992-04-20 1993-11-09 Sds Biotech Kk 水田用懸濁状除草組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5673010A (en) * 1979-11-20 1981-06-17 Sumitomo Chem Co Ltd Herbicidal suspension composition
JPS58162504A (ja) * 1982-03-23 1983-09-27 モンサント・カンパニ− 除草剤乳濁液
JPH0324004A (ja) * 1989-06-10 1991-02-01 Hoechst Ag 除草用混合物の液状配合物
JPH05294804A (ja) * 1992-04-20 1993-11-09 Sds Biotech Kk 水田用懸濁状除草組成物

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6235682B1 (en) * 1998-07-16 2001-05-22 Board Of Trustees Operating Michigan State University Compositions and methods for protecting cultivated plants from herbicidal injury
WO2000003595A1 (fr) * 1998-07-16 2000-01-27 Michigan State University Compositions et procedes permettant de proteger les plantes cultivees contre les blessures causees par les herbicides
FR2795290A1 (fr) * 1999-06-23 2000-12-29 Agronomique Inst Nat Rech Procede de traitement phytosanitaire par absorption foliaire et composition comprenant au moins un principe actif phytosanitaire hydrosoluble et au moins une huile modifiee
WO2001000028A1 (fr) * 1999-06-23 2001-01-04 Institut National De La Recherche Agronomique Composition phytosanitaire comprenant un agent hydrosoluble et une huile modifiee
US6737381B1 (en) 1999-06-23 2004-05-18 Institut National De La Recherche Agronomique Phytosanitary composition comprising at least a water soluble agent and a modified oil
EP1491092A3 (fr) * 1999-06-23 2005-02-16 Societe D'exploitation De Produits Pour Les Industries Chimiques, S.E.P.P.I.C. Procédé phytosanitaire mettant en oeuvre une composition comprenant au moins un principe actif hydrosoluble et au moins une huile modifiée
WO2002021924A3 (fr) * 2000-09-13 2003-01-09 Monsanto Technology Llc Compositions herbicides contenant du glyphosate et du bipyridilium
US7989392B2 (en) * 2000-09-13 2011-08-02 Monsanto Technology, Llc Herbicidal compositions containing glyphosate bipyridilium
US7008904B2 (en) 2000-09-13 2006-03-07 Monsanto Technology, Llc Herbicidal compositions containing glyphosate and bipyridilium
US7056862B2 (en) * 2000-12-20 2006-06-06 Kao Corporation Herbicide potentiators
WO2003059066A1 (fr) * 2002-01-16 2003-07-24 Bayer Cropscience Ag Utilisation d'ethoxylates d'alcool en tant qu'agents favorisants la penetration
US7723268B2 (en) 2002-01-16 2010-05-25 Bayer Cropscience Ag Use of alcohol ethoxylates as penetration enhancers
EA011649B1 (ru) * 2002-04-24 2009-04-28 Басф Акциенгезельшафт Композиция на основе алкоксилатов спиртов и их применение в качестве адъюванта в области агротехники
EP2181593A1 (fr) * 2002-04-24 2010-05-05 Basf Se Utilisation d'alkoxylates d'alcool définis comme adjuvants pour le domaine agrotechnique
WO2003090531A1 (fr) * 2002-04-24 2003-11-06 Basf Aktiengesellschaft Utilisation d'alcoxylates definis en tant qu'adjuvants dans le domaine de la technique agricole
EA015423B1 (ru) * 2002-04-24 2011-08-30 Басф Се Применение определенных алкоксилатов спиртов в качестве адъюванта в области агротехники
US8129312B2 (en) 2002-04-24 2012-03-06 Basf Se Use of defined alcohol alkoxylates as adjuvants in the agrotechnical field
US8877681B2 (en) 2002-04-24 2014-11-04 Basf Se Use of specific alcohol alkoxylates as an adjuvant for agrotechnical applications
CN109221241A (zh) * 2018-09-17 2019-01-18 深圳诺普信农化股份有限公司 一种含有草铵膦的除草组合物
CN109964938A (zh) * 2019-04-15 2019-07-05 广东省科学院产业技术育成中心 含有月桂醇醚磷酸酯的d酸草甘膦复配助剂及其制备方法

Also Published As

Publication number Publication date
JPH08333204A (ja) 1996-12-17

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