WO1996028973B1 - Compositions a liberation controlee et techniques de traitement d'organismes dans l'environnement - Google Patents
Compositions a liberation controlee et techniques de traitement d'organismes dans l'environnementInfo
- Publication number
- WO1996028973B1 WO1996028973B1 PCT/US1996/003499 US9603499W WO9628973B1 WO 1996028973 B1 WO1996028973 B1 WO 1996028973B1 US 9603499 W US9603499 W US 9603499W WO 9628973 B1 WO9628973 B1 WO 9628973B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- population
- bioactive agent
- coating
- organisms
- Prior art date
Links
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- 239000003795 chemical substances by application Substances 0.000 claims 5
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 claims 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 4
- 229920002472 Starch Polymers 0.000 claims 4
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims 4
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- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims 3
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- GXEKYRXVRROBEV-FBXFSONDSA-N (1r,2s,3r,4s)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1C[C@@H]2[C@@H](C(O)=O)[C@@H](C(=O)O)[C@H]1O2 GXEKYRXVRROBEV-FBXFSONDSA-N 0.000 claims 2
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 claims 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims 2
- GOJCZVPJCKEBQV-UHFFFAOYSA-N Butyl phthalyl butylglycolate Chemical compound CCCCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCCCC GOJCZVPJCKEBQV-UHFFFAOYSA-N 0.000 claims 2
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 claims 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims 2
- 239000000642 acaricide Substances 0.000 claims 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims 2
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- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims 2
- 239000001069 triethyl citrate Substances 0.000 claims 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims 2
- 235000013769 triethyl citrate Nutrition 0.000 claims 2
- TUUQISRYLMFKOG-UHFFFAOYSA-N trihexyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)CC(C(=O)OCCCCCC)(OC(C)=O)CC(=O)OCCCCCC TUUQISRYLMFKOG-UHFFFAOYSA-N 0.000 claims 2
- MXHBQKVKHGQWRB-UHFFFAOYSA-N trihexyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCC)C(C(=O)OCCCCCC)=C1 MXHBQKVKHGQWRB-UHFFFAOYSA-N 0.000 claims 2
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- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 claims 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims 1
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 229920001817 Agar Polymers 0.000 claims 1
- 241000609240 Ambelania acida Species 0.000 claims 1
- 241000193365 Bacillus thuringiensis serovar israelensis Species 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- 229920003043 Cellulose fiber Polymers 0.000 claims 1
- 239000005944 Chlorpyrifos Substances 0.000 claims 1
- 239000005749 Copper compound Substances 0.000 claims 1
- NDUPDOJHUQKPAG-UHFFFAOYSA-N Dalapon Chemical compound CC(Cl)(Cl)C(O)=O NDUPDOJHUQKPAG-UHFFFAOYSA-N 0.000 claims 1
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- 241000255925 Diptera Species 0.000 claims 1
- 239000005630 Diquat Substances 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- YWBVHLJPRPCRSD-UHFFFAOYSA-N Fluridone Chemical compound O=C1C(C=2C=C(C=CC=2)C(F)(F)F)=CN(C)C=C1C1=CC=CC=C1 YWBVHLJPRPCRSD-UHFFFAOYSA-N 0.000 claims 1
- 239000005562 Glyphosate Substances 0.000 claims 1
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- 241000193386 Lysinibacillus sphaericus Species 0.000 claims 1
- 241001465754 Metazoa Species 0.000 claims 1
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- REVZBRXEBPWDRA-UHFFFAOYSA-N Stearyl citrate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC(O)(C(O)=O)CC(O)=O REVZBRXEBPWDRA-UHFFFAOYSA-N 0.000 claims 1
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- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 claims 1
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- 150000001298 alcohols Chemical class 0.000 claims 1
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- 229940124323 amoebicide Drugs 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 claims 1
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- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims 1
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- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 claims 1
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- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 claims 1
- 229940019503 diflubenzuron Drugs 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 claims 1
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 claims 1
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 claims 1
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- 239000000417 fungicide Substances 0.000 claims 1
- MZPRYQVBGLNOOZ-UHFFFAOYSA-N furan-2,5-dione prop-2-enylbenzene Chemical class O=C1OC(=O)C=C1.C=CCc1ccccc1 MZPRYQVBGLNOOZ-UHFFFAOYSA-N 0.000 claims 1
- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical class O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 claims 1
- 229940075529 glyceryl stearate Drugs 0.000 claims 1
- 229940097068 glyphosate Drugs 0.000 claims 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims 1
- 230000012010 growth Effects 0.000 claims 1
- 239000010440 gypsum Substances 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 claims 1
- 239000011507 gypsum plaster Substances 0.000 claims 1
- 239000004009 herbicide Substances 0.000 claims 1
- 239000005556 hormone Substances 0.000 claims 1
- 229940088597 hormone Drugs 0.000 claims 1
- 239000000416 hydrocolloid Substances 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- 239000002949 juvenile hormone Substances 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 239000000787 lecithin Substances 0.000 claims 1
- 235000010445 lecithin Nutrition 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
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- 229920000609 methyl cellulose Polymers 0.000 claims 1
- 239000001923 methylcellulose Substances 0.000 claims 1
- 235000010981 methylcellulose Nutrition 0.000 claims 1
- 230000000813 microbial effect Effects 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 239000003750 molluscacide Substances 0.000 claims 1
- 230000002013 molluscicidal effect Effects 0.000 claims 1
- 229940116396 monostearyl citrate Drugs 0.000 claims 1
- 229940043348 myristyl alcohol Drugs 0.000 claims 1
- 229920001206 natural gum Polymers 0.000 claims 1
- 229920005615 natural polymer Polymers 0.000 claims 1
- 239000005645 nematicide Substances 0.000 claims 1
- 235000015097 nutrients Nutrition 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 244000045947 parasite Species 0.000 claims 1
- 244000052769 pathogen Species 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 239000003016 pheromone Substances 0.000 claims 1
- 230000003711 photoprotective effect Effects 0.000 claims 1
- QHOQHJPRIBSPCY-UHFFFAOYSA-N pirimiphos-methyl Chemical group CCN(CC)C1=NC(C)=CC(OP(=S)(OC)OC)=N1 QHOQHJPRIBSPCY-UHFFFAOYSA-N 0.000 claims 1
- 239000005648 plant growth regulator Substances 0.000 claims 1
- 229920002401 polyacrylamide Polymers 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
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- 239000011164 primary particle Substances 0.000 claims 1
- 239000003223 protective agent Substances 0.000 claims 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims 1
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- 239000002728 pyrethroid Substances 0.000 claims 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims 1
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- 150000003839 salts Chemical class 0.000 claims 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 claims 1
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- 239000008107 starch Substances 0.000 claims 1
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- 229940012831 stearyl alcohol Drugs 0.000 claims 1
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- 229920001059 synthetic polymer Polymers 0.000 claims 1
- WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 claims 1
- 231100000167 toxic agent Toxicity 0.000 claims 1
- 239000003440 toxic substance Substances 0.000 claims 1
- GWVUTNGDMGTPFE-UHFFFAOYSA-N trihexyl 2-butanoyloxypropane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)CC(C(=O)OCCCCCC)(OC(=O)CCC)CC(=O)OCCCCCC GWVUTNGDMGTPFE-UHFFFAOYSA-N 0.000 claims 1
- DCTZJRUXIXPDJP-UHFFFAOYSA-N trihexyl 2-hydroxy-4-oxoheptane-1,2,3-tricarboxylate Chemical compound CCCCCCOC(=O)CC(O)(C(=O)OCCCCCC)C(C(=O)CCC)C(=O)OCCCCCC DCTZJRUXIXPDJP-UHFFFAOYSA-N 0.000 claims 1
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- 235000019354 vermiculite Nutrition 0.000 claims 1
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Abstract
La présente invention concerne des compositions à libération contrôlée comprenant des complexes pour le traitement d'une population d'un ou plusieurs organismes aquatiques dans une colonne d'eau. Ces complexes contiennent au moins un système, lequel comprend au moins un agent bioactif comme composant choisi pour traiter une population d'organismes aquatiques, au moins un composant vecteur et au moins un composant de revêtement pour régulariser la libération contrôlée et le profil de libération de l'agent bioactif dans l'eau ou au moins un agent bioactif et un composant à fonction mixte, qui peut faire office aussi bien de vecteur que de revêtement pour régulariser la libération contrôlée et le profil de libération de l'agent bioactif dans l'eau, avec ou sans composant fixateur optionnel et/ou matériaux de formulation supplémentaire. Les composants sont choisis de manière à couler ou à flotter de sorte que les complexes passeront au travers et/ou resteront dans tout segment plan ou volumétrique d'une colonne d'eau pendant une période suffisamment longue pour traiter efficacement une population d'organismes aquatiques. La présente invention concerne aussi des techniques de traitement d'une colonne d'eau qui consistent à libérer lesdites compositions dans ladite colonne d'eau ou dans une zone asséchée après avoir été recouverte d'eau (prétraitement) et qui se transformera en colonne d'eau ou en zone inondée. La composition et le procédé peuvent également servir à traiter des organismes terrestres.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU53640/96A AU689716C (en) | 1995-03-17 | 1996-03-15 | Controlled delivery compositions and processes for treating organisms in the environment |
CA002215377A CA2215377C (fr) | 1995-03-17 | 1996-03-15 | Compositions a liberation controlee et techniques de traitement d'organismes dans l'environnement |
DE69635045T DE69635045T2 (de) | 1995-03-17 | 1996-03-15 | Zusammensetzungen mit kontrollierter freigabe und verfahren zur behandlung von organismen in der umwelt |
AT96910449T ATE301395T1 (de) | 1995-03-17 | 1996-03-15 | Zusammensetzungen mit kontrollierter freigabe und verfahren zur behandlung von organismen in der umwelt |
EP96910449A EP0814659B1 (fr) | 1995-03-17 | 1996-03-15 | Compositions a liberation controlee et techniques de traitement d'organismes dans l'environnement |
JP8528500A JPH11502229A (ja) | 1995-03-17 | 1996-03-15 | 制御供給組成物及び環境中の生物処理方法 |
MXPA/A/1997/007049A MXPA97007049A (en) | 1995-03-17 | 1997-09-17 | Compositions of controlled release and process for the treatment of organisms in the environment |
Applications Claiming Priority (6)
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US40634495A | 1995-03-17 | 1995-03-17 | |
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US08/434,313 US5698210A (en) | 1995-03-17 | 1995-05-02 | Controlled delivery compositions and processes for treating organisms in a column of water or on land |
US08/434,313 | 1995-05-02 |
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WO1996028973A1 WO1996028973A1 (fr) | 1996-09-26 |
WO1996028973B1 true WO1996028973B1 (fr) | 1996-10-31 |
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PCT/US1996/003499 WO1996028973A1 (fr) | 1995-03-17 | 1996-03-15 | Compositions a liberation controlee et techniques de traitement d'organismes dans l'environnement |
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US (14) | US5698210A (fr) |
EP (1) | EP0814659B1 (fr) |
JP (1) | JPH11502229A (fr) |
AT (1) | ATE301395T1 (fr) |
CA (1) | CA2215377C (fr) |
DE (1) | DE69635045T2 (fr) |
DK (1) | DK0814659T3 (fr) |
ES (1) | ES2246494T3 (fr) |
PT (1) | PT814659E (fr) |
WO (1) | WO1996028973A1 (fr) |
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- 1996-03-15 WO PCT/US1996/003499 patent/WO1996028973A1/fr active IP Right Grant
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- 1996-03-15 DE DE69635045T patent/DE69635045T2/de not_active Expired - Lifetime
- 1996-03-15 DK DK96910449T patent/DK0814659T3/da active
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- 1996-03-15 JP JP8528500A patent/JPH11502229A/ja active Pending
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-
1997
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1999
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- 1999-12-10 US US09/457,897 patent/US6350461B1/en not_active Expired - Fee Related
- 1999-12-10 US US09/458,045 patent/US6335027B1/en not_active Expired - Fee Related
- 1999-12-10 US US09/458,652 patent/US6391328B1/en not_active Expired - Fee Related
- 1999-12-10 US US09/458,023 patent/US6337078B1/en not_active Expired - Fee Related
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Cited By (2)
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US6852328B1 (en) | 1989-09-01 | 2005-02-08 | Battelle Memorial Institute K1-53 | Method and device for protection of wooden objects proximate soil from pest invasion |
US7335374B2 (en) | 1998-02-25 | 2008-02-26 | Battelle Memorial Institute K1-53 | Multi-layer barrier preventing wood pest access to wooden structures |
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