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WO1996028536A1 - Compositions de nettoyage de toilettes - Google Patents

Compositions de nettoyage de toilettes Download PDF

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Publication number
WO1996028536A1
WO1996028536A1 PCT/GB1996/000619 GB9600619W WO9628536A1 WO 1996028536 A1 WO1996028536 A1 WO 1996028536A1 GB 9600619 W GB9600619 W GB 9600619W WO 9628536 A1 WO9628536 A1 WO 9628536A1
Authority
WO
WIPO (PCT)
Prior art keywords
block according
polymer
weight
block
surfactant
Prior art date
Application number
PCT/GB1996/000619
Other languages
English (en)
Inventor
Steven John Farrell Black
Russell Norman
Brian Murie Wilson
Nigel Frederick Cooper
Original Assignee
Jeyes Group Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jeyes Group Plc filed Critical Jeyes Group Plc
Priority to GB9719051A priority Critical patent/GB2313129B/en
Priority to AU50119/96A priority patent/AU5011996A/en
Publication of WO1996028536A1 publication Critical patent/WO1996028536A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3955—Organic bleaching agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

Definitions

  • This invention is concerned with improvements in and relating to lavatory cleansing compositions. More particularly, the invention is concerned with solid lavatory cleansing compositions which may be used to impart cleansing and/or other components to the flush water of a lavatory or urinal.
  • compositions to impart cleansing and/or other components to the flush water of a lavatory or urinal are well established.
  • Such compositions may, for example, be immersed in the water of a lavatory cistern either in free-standing form or in containerised form (i.e. in a dispensing container which allows for release of components of the solid composition in solution in water in a more or less metered fashion, on flushing of the cistern).
  • the solid composition may be held under the rim of a toilet, in a suitable holder, for intermittent contact of the solid material with flush water.
  • Solid lavatory cleansing compositions typically comprise a surfactant component, generally together with one or more fillers or builders (e.g. inorganic salts such as sodium sulphate, sodium chloride etc.). Commonly, such compositions also contain a dyestuff and, frequently, a dissolution retardant material such as a hydrophobic material, difficultly soluble material or a gum The dissolution retardant is of particular importance when the solid composition is to be formulated as a free ⁇ standing block for immersion in a lavatory cistern.
  • a surfactant component generally together with one or more fillers or builders (e.g. inorganic salts such as sodium sulphate, sodium chloride etc.).
  • fillers or builders e.g. inorganic salts such as sodium sulphate, sodium chloride etc.
  • a dissolution retardant material such as a hydrophobic material, difficultly soluble material or a gum
  • a lavatory cleansing composition having mineralisation prevention properties is disclosed in US-A-4 861 511 This composition contains from 2% to 15% by weight of a polyacrylate having a molecular weight in the range 500 - 50,000
  • a polyacrylate having a molecular weight in the range 500 - 50,000 we have found that surprisingly, significantly enhanced limescale inhibition can be obtained using this and similar polymers but having higher molecular weights
  • a solid slow- release lavatory cleansing composition comprising a water-soluble polymer derived from one or more ethylenically unsaturated carboxyl group-containing monomers and having an average molecular weight of at least 50,000.
  • any reference to an average molecular weight means the weight average molecular weight, unless specifically recited to the contrary.
  • the block may optionally comprise more than one water-soluble polymer derived from one or more ethylenically unsaturated carboxyl-containing monomers and having an average molecular weight of at least 50,000
  • the water-soluble polymers used in the composition of the invention are polycarboxylic acids derived from one or more ethylenically unsaturated carboxyl group-containing monomers, especially ethylenically unsaturated carboxylic acids such as acrylic acid or maleic acid.
  • the carboxyl group-containing monomers may be polymerized alone or in combination with other ethylenically unsaturated monomers but, in general, polymers derived largely or wholly from the acidic monomers are preferred.
  • Typical polymers are polyacrylic acid and acrylic acid/maleic acid copolymers
  • the polymers are employed in the form of salts, e g alkali metal salts such as the sodium salt
  • the polymers used in accordance with the invention suitably have average molecular weights of at least 50,000, e g more than 50,000 and suitably from 60,000 to 140,000, preferably from 70,000 to 120,000, especially about 90,000
  • the polymer is suitably present in an amount of from 5 to 90% by weight, preferably from 10 to 50% by weight, most preferably from 15% to 35% by weight thereof
  • the composition will also often contain a surfactant component which may be anionic, nonionic or amphotenc in nature
  • the surfactant serves to provide a cleansing and foaming effect and may, also, act synergistically with the polymer component
  • the surfactant component comprises one or more anioninc surface active agents, optionally in combination with one or more nonionic surface active agents
  • Suitable anionic surface active agents include alkali metal or ammonium alkylaryl sulphonates (especially alkyl benzene sulphonates), alkane sulphonates, alkyl sulphates, alky I ether sulphates and sarcosinates
  • Sulphonate anionic surfactants are generally preferred
  • Suitable nonionic surfactants include polyethoxylated fatty alcohols, polyethoxylated fatty acids, polyethoxylated alkyl phenols and ethylene oxide/propylene oxide block copolymers
  • Suitable amphoteric surfactants include be
  • the surfactant when present, may lie within wide limits In practice, the surfactant will generally form 10 to 70% by weight of the composition, preferably from 20 to 50% by weight thereof In certain embodiments, the surfactant content may be reduced below the minimum noted above, even to zero, to provide a composition, for example in tablet form, where the principal effect is that of limescale inhibition
  • chelatmg agent sequestrant or water-softening agent such as ethylene diamine tetra- acetic acid or a derivative thereof, nitrolot ⁇ acetic acid, phosphonates of polyphosphates. metasilicates. boroheptonates, s.s-ethvlene-diamino disuccinate. dipicolinic acid. 2-phosphonobutane- 1.2.4-t ⁇ carboxvl ⁇ c acid, or lower molecular weight polymeric materials capable of inhibiting crvstal growth
  • reducing agents such as alkali metal metabisulphates may be present to assist in the reduction of staining due to metals such as iron.
  • compositions in accordance with the invention may also contain mineral fillers with builders such as sodium sulphate or sodium chloride. It is preferred that such fillers be present, suitably in amounts of from 0 to 65% by weight, preferably 15 to 50% by weight.
  • compositions of the invention include dissolution-retardant agents such as hydrophobic or difficultly water-soluble materials or gums.
  • a perfume components itself can serve to a marked extent as a dissolution retardant but other retardants may also be present, e.g. gums, such as guar gum, or difficultly soluble alkoxylated fatty alcohols, alkyl phenols, long chain alcohols, fatty acid esters e.g.
  • dissolution retardant agents are disclosed in, for example, EP-A-005 100, EP-A-018 446, EP-A-020 8725, EP-A-341 836, EP-A-0 546 839, EP-A-0 581 826 and WO 94/12612.
  • a disinfectant may also be present.
  • Suitable disinfectants include phenolic disinfectants such as orthobenzylparachlorophenol, and halogen-release agents such as those mentioned in various of the above documents.
  • the polymers used in accordance with the present invention are suitable and stable when used in conjunction with halogen release agents.
  • compositions in accordance with the invention may be produced by a variety of routes.
  • they may be prepared by a so-called "hot melt” process comprising melting the fusible constituents of the block either alone and then adding other components in admixture with non-fusible components, and subsequently casting the melt into moulds
  • compositions in accordance with the invention are formed into the desired final shape by a compression technique, i e a technique involving the steps of forming a mixture of the ingredients of the composition and then compressing that mixture into the desired shape.
  • compositions of the invention are used as free-standing lavatory cleansing blocks, these suitably have a weight from 30 to 150gms When extruding a solid composition it is generally necessary that some lubricant component be present to facilitate extrusion.
  • compositions in accordance with the invention may also be formed into the final desired shape by a tabletting technique.
  • the invention also provides a method of cleaning a lavatory or urinal using a block of a composition in accordance with the invention.
  • Ufaryl DL80CW and DL90C and DL90JM are 80% and 90% active sodium alkyl benzene sulphonates ex Unger Fabrikker AS
  • Nansa HS80SPF is an 80% active sodium alkylbenzene sulphonate ex Albright and Wilson Ltd
  • Dobunol 91 is a blend of C 9 - C ⁇ primary alcohols ex Shell Chemicals UK Ltd
  • Degapas 4104N is the sodium salt of an acrylic acid polymer with approximately 17 Wt 90,000 ex Degussa Ltd.
  • Plasthall 4141 is a triethylene glycol caprate coprylate (ex CP Hall)
  • Floral 33556 is a fragrance oil ex GIVAUDAN-ROURE
  • Lemon 0/265760 is a suitable bleach stable fragrance oil ex Dragocco
  • Herbal LQ51808 is a fragrance oil ex BB A Ltd
  • Blocks A to D, F, G, H and I were found to have an effective life and activity of about 4 weeks when tested in standard UK 9 litre toilets with blocks positioned in the cistern with 17 flushes per day typical consumer flush cycle Similarly blocks E, F and G positioned within a suitable cage in the water flow under the ⁇ m of a similar toilet bowl were found to have an effective life and activitv of about 4 weeks Block K similarly tested had an effective life and activity of about 16 weeks For the tests, the water was typically 250ppm CaCO 3 at 12-15°C Block J similarly tested at 20°-25°C has an effective life and activity of 15- 16 weeks.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Bloc de nettoyage des toilettes à dégagement lent constitué d'un ou de plusieurs polymères hydrosolubles. Ces polymères sont dérivés d'un ou de plusieurs monomères à liaison éthylène insaturée contenant un groupe carboxyle. Les polymères ont une masse moyenne supérieure à 50 000.
PCT/GB1996/000619 1995-03-15 1996-03-15 Compositions de nettoyage de toilettes WO1996028536A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB9719051A GB2313129B (en) 1995-03-15 1996-03-15 Lavatory cleansing compositions
AU50119/96A AU5011996A (en) 1995-03-15 1996-03-15 Lavatory cleansing compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9505203.1 1995-03-15
GBGB9505203.1A GB9505203D0 (en) 1995-03-15 1995-03-15 Lavatory cleansing compositions

Publications (1)

Publication Number Publication Date
WO1996028536A1 true WO1996028536A1 (fr) 1996-09-19

Family

ID=10771227

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1996/000619 WO1996028536A1 (fr) 1995-03-15 1996-03-15 Compositions de nettoyage de toilettes

Country Status (3)

Country Link
AU (1) AU5011996A (fr)
GB (2) GB9505203D0 (fr)
WO (1) WO1996028536A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997020029A1 (fr) * 1995-12-01 1997-06-05 S.C. Johnson & Son, Inc. Composition pour nettoyer les toilettes
WO1998035008A1 (fr) * 1997-02-11 1998-08-13 S. C. Johnson & Son, Inc. Bloc de nettoyage pour cabinets immerge dans le reservoir de chasse d'eau
WO1999040170A1 (fr) * 1998-02-04 1999-08-12 Unilever Plc Compositions de nettoyage de toilettes
AU725381B2 (en) * 1997-03-14 2000-10-12 Unilever Plc Lavatory cleansing blocks
WO2008100393A1 (fr) * 2007-02-12 2008-08-21 S. C. Johnson & Son, Inc. Bloc désintégrant auto-adhésif pour toilettes ou urinoir
WO2013083929A1 (fr) * 2011-12-07 2013-06-13 Eurotab Produit solide compacté pour désinfecter des toilettes

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6051797A (ja) * 1983-08-31 1985-03-23 ライオン株式会社 清浄剤組成物
US4861511A (en) * 1987-06-26 1989-08-29 Nalco Chemical Company Toilet bowl cleaner and stain-inhibiting composition
JPH07331284A (ja) * 1994-06-13 1995-12-19 Kao Corp 水洗トイレ用洗浄剤組成物
JPH0860186A (ja) * 1994-06-13 1996-03-05 Kao Corp 水洗トイレ用洗浄剤組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6051797A (ja) * 1983-08-31 1985-03-23 ライオン株式会社 清浄剤組成物
US4861511A (en) * 1987-06-26 1989-08-29 Nalco Chemical Company Toilet bowl cleaner and stain-inhibiting composition
JPH07331284A (ja) * 1994-06-13 1995-12-19 Kao Corp 水洗トイレ用洗浄剤組成物
JPH0860186A (ja) * 1994-06-13 1996-03-05 Kao Corp 水洗トイレ用洗浄剤組成物

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8518, Derwent World Patents Index; Class A97, AN 85-107791, XP002006172 *
DATABASE WPI Section Ch Week 9619, Derwent World Patents Index; Class A97, AN 96-185169, XP002006170 *
PATENT ABSTRACTS OF JAPAN vol. 95, no. 12 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997020029A1 (fr) * 1995-12-01 1997-06-05 S.C. Johnson & Son, Inc. Composition pour nettoyer les toilettes
WO1998035008A1 (fr) * 1997-02-11 1998-08-13 S. C. Johnson & Son, Inc. Bloc de nettoyage pour cabinets immerge dans le reservoir de chasse d'eau
US5863876A (en) * 1997-02-11 1999-01-26 S. C. Johnson & Son, Inc. In-tank toilet cleansing block having polyacrylic acid/acrylate
AU725381B2 (en) * 1997-03-14 2000-10-12 Unilever Plc Lavatory cleansing blocks
EP0972009B1 (fr) * 1997-03-14 2002-06-26 Unilever Plc Compositions de nettoyage pour w.c.
WO1999040170A1 (fr) * 1998-02-04 1999-08-12 Unilever Plc Compositions de nettoyage de toilettes
WO2008100393A1 (fr) * 2007-02-12 2008-08-21 S. C. Johnson & Son, Inc. Bloc désintégrant auto-adhésif pour toilettes ou urinoir
US7709433B2 (en) 2007-02-12 2010-05-04 S.C. Johnson & Son, Inc. Self-sticking disintegrating block for toilet or urinal
EP2363457A1 (fr) * 2007-02-12 2011-09-07 S.C. Johnson & Son, Inc. Block désintégrant auto-adhésif pour toilettes ou urinoir
AU2008216848B2 (en) * 2007-02-12 2013-07-04 S. C. Johnson & Son, Inc. Self-sticking disintegrating block for toilet or urinal
US8664172B2 (en) 2007-02-12 2014-03-04 S.C. Johnson & Son, Inc. Self-sticking disintegrating block for toilet or urinal
WO2013083929A1 (fr) * 2011-12-07 2013-06-13 Eurotab Produit solide compacté pour désinfecter des toilettes

Also Published As

Publication number Publication date
GB9719051D0 (en) 1997-11-12
GB2313129A (en) 1997-11-19
GB2313129B (en) 1999-03-24
GB9505203D0 (en) 1995-05-03
AU5011996A (en) 1996-10-02

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