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WO1996016722A1 - Technique de separation des polluants gazeux des gaz chauds de processus de fabrication - Google Patents

Technique de separation des polluants gazeux des gaz chauds de processus de fabrication Download PDF

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Publication number
WO1996016722A1
WO1996016722A1 PCT/SE1995/001403 SE9501403W WO9616722A1 WO 1996016722 A1 WO1996016722 A1 WO 1996016722A1 SE 9501403 W SE9501403 W SE 9501403W WO 9616722 A1 WO9616722 A1 WO 9616722A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixer
dust
process gases
supplied
burnt lime
Prior art date
Application number
PCT/SE1995/001403
Other languages
English (en)
Inventor
Stefan Åhman
Nils Bringfors
Original Assignee
ABB Fläkt AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002205995A priority Critical patent/CA2205995C/fr
Priority to SK661-97A priority patent/SK66197A3/sk
Priority to SI9520141A priority patent/SI9520141A/sl
Priority to UA97063196A priority patent/UA52592C2/uk
Priority to AU41264/96A priority patent/AU692014B2/en
Priority to JP51717096A priority patent/JP3640674B2/ja
Priority to RO97-00951A priority patent/RO115421B1/ro
Priority to EP95939455A priority patent/EP0804273A1/fr
Priority to CZ971574A priority patent/CZ157497A3/cs
Application filed by ABB Fläkt AB filed Critical ABB Fläkt AB
Priority to HU9800501A priority patent/HU220402B/hu
Priority to EE9700215A priority patent/EE04049B1/xx
Priority to BR9509831A priority patent/BR9509831A/pt
Priority to MD97-0166A priority patent/MD1020C2/ro
Priority to PL95320426A priority patent/PL320426A1/xx
Priority to RU97111848A priority patent/RU2147919C1/ru
Publication of WO1996016722A1 publication Critical patent/WO1996016722A1/fr
Priority to FI972233A priority patent/FI972233A7/fi

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes

Definitions

  • the present invention relates to a method for sepa ⁇ rating gaseous pollutants, such as sulphur dioxide, from hot process gases, such as flue gases, in which method the process gases are passed through a contact reactor, in which a particulate absorbent material, which is reac ⁇ tive with the gaseous pollutants, is introduced in mois ⁇ tened state into the process gases for converting the gaseous pollutants into separable dust, whereupon the process gases are passed through a dust separator, in which dust is separated from the process gases and from which the cleaned process gases are discharged, part of the dust separated in the dust separator being passed to a mixer, in which it is mixed and supplied with water so as to be moistened, whereupon it is recirculated as ab- sorbent material by being introduced into the process gases together with an addition of fresh absorbent.
  • a contact reactor in which a particulate absorbent material, which is reac ⁇ tive with the gaseous pollutants, is introduced in mois ⁇ tened state into the process gases for
  • the above-described method for separating gaseous pollutants from hot process gases is known from e.g. SE 8504675-3 and SE 8904106-5.
  • use is preferably made of slaked lime (calcium hydroxide) in particle form as fresh absorbent.
  • This absorbent is mixed with dust which has been separated from the process gases in the dust separator, whereupon the mixture is supplied with water to be introduced, in moistened state, into the flue gases in the contact reac ⁇ tor.
  • the slaked lime is comparatively expensive, and so various experiments have been made to use burnt lime (calcium oxide) instead, which is considerably less ex ⁇ pensive.
  • the object of the present invention is to provide a method for separating gaseous pollutants from hot process gases, in which the slaked lime can be replaced by burnt lime, without necessitating an expensive, separate plant for slaking the burnt lime.
  • this object is achieved by a method which is of the type mentioned by way of in- troduction and is characterised in that burnt lime is added as fresh absorbent, and that the major part of the dust separated in the dust separator is supplied to and discharged from the mixer in a substantially continuous flow, the dust being kept so long in the mixer and being recirculated so many times that the total residence time of the burnt lime in the mixer in moistened state is suf ⁇ ficiently long for the burnt lime to have time to react substantially completely with water supplied to the mixer and form slaked lime.
  • the fresh absorbent in the form of burnt lime is supplied preferably to the mixer, but it may also be added to that part of the dust separated in the dust separator which is supplied to the mixer. Alternatively, the burnt lime can be introduced directly into the flue gases in the contact reactor.
  • An air flow is suitably supplied to the mixer in order to fluidise the dust mixed therein and thus improve the mixture.
  • FIG. 1 Schematically illustrates a plant for cleaning flue gases from a coal-fired central heating plant, the cleaning plant being provided with equipment for carrying out the method according to the present invention.
  • the drawing schematically illustrates a plant for cleaning flue gases from a coal-fired central heating plant 1, said flue gases containing dust, such as fly ash, and gaseous pollutants, such as sulphur dioxide.
  • a preheating device 2 is arranged to transmit heat from the hot flue gases to combustion air, which via a duct 2a is supplied to the central heating plant 1 by means of a fan 3.
  • the hot flue gases are conveyed through a duct 4 to a dust separator 5, which in the embodiment shown is an electrostatic precipitator having three successive preci- pitator units, through which the flue gases are passed to be cleaned.
  • the flue gases cleaned in this manner are via a duct 6 passed to a flue gas fan 7, which via a duct 8 feeds them on to a chimney 9 to be emitted into the at ⁇ mosphere.
  • the dust separator can also be a bag filter.
  • the duct 4 comprises a vertical portion which forms a contact reactor 10.
  • a mixer 11 communicates with the contact reactor 10 in the lower part thereof.
  • the mixer 11 introduces a particulate absorbent material, which is reactive with the gaseous pollutants in the flue gases, in moistened state into the flue gases in the lower part of the contact reactor 10. This absorbent material con ⁇ verts the gaseous pollutants into dust, which is separat ⁇ ed in the precipitator 5.
  • the dust particles separated in the precipitator 5 are collected in the hoppers 12 of the precipitator units.
  • the major part of the collected dust particles is recirculated in the system in a manner which will be described in detail below.
  • the remainder of the collect ⁇ ed dust particles are transported away in a manner which will not be described in detail, for instance by means of a worm conveyor.
  • the mixer 11 is of the type as described in SE- 9404104-3.
  • the mixer 11 has essentially the shape of a double-bottom box. Between the two bottoms, the upper of which consists of a tensioned fluidising cloth 13 of polyester, there is a chamber 14, to which air for fluidising the particulate absorbent material in the mixer 11 is conducted through an air supply conduct 15.
  • Water is supplied to the mixer 11 through a water supply conduit 16 and nozzles 17, which are arranged in the upper portion of the mixer.
  • the particulate material which is to be mixed is supplied to the mixer 11 through two material inlets 18 and 19 at the inlet end of the mixer.
  • the mixer 11 further comprises a mechanical mixing mechanism 20 consisting of two cooperating, parallel agi ⁇ tators (of which only one is shown in the drawing), each having a horizontal shaft and, mounted thereon, a plura- lity of inclined elliptic plates.
  • the outlet end of the mixer 11 extends into the contact reactor 10 in order to continuously supply thereto through an overflow 21 well- mixed, moistened absorbent material.
  • That part of the dust particles collected in the hoppers 12 of the precipitator units which is to be recirculated in the system is supplied to the mixer 11 through the inlet 19.
  • Particulate burnt lime (calcium oxide) is supplied to the mixer 11 through the inlet 18 to be mixed with the dust particles supplied through the inlet 19.
  • the mixture is moistened with water supplied through the nozzles 17.
  • Water is supplied through the nozzles 17 also in order to slake the burnt lime supplied to the mixer 11.
  • the mixer produces a homogeneously moistened, homogeneous mixture of material particles, which are, through the overflow 21 of the mixer 11, continuously supplied to the contact reactor 10 as absorbent material.
  • the residence time of the material particles in the mixer 11 is in the order of 5-60 s, especially 10-20 s.
  • the residence time as stated above (10-20 s) of the material particles in the mixer 11, i.e. the time during which the lime particles are in moistened state, is in- sufficient for the burnt lime to have time to react com ⁇ pletely with the water added for slaking and form slaked lime. Such a reaction is relatively slow and takes seve ⁇ ral minutes.
  • the Exam- pie states the conditions prevailing at points A, B and C in the drawing, i.e. in the duct 4 before the mixer 11, in the reactor 10 after the mixer 11 at the inlet of the precipitator 5 and at the outlet of the precipitator 5, respectively.
  • the dust at A is substantially fly ash, whereas the dust at B is fly ash and absorbent material.
  • the particulate absorbent mate ⁇ rial including the burnt lime, which is being slaked, is thus circulated on the average about 35 times (1.0 x 103,933 / 2,930 * 35) in the system before being discharged at D.
  • the total residence time of the absor ⁇ bent material in the mixer 11 thus is 350-700 s, i.e. in the order of 6-12 min, which is sufficient for the burnt lime to have time to be slaked.
  • the total consumption of water in the above Example is 3,366 1/h, of which 152 1/h is required for the slak ⁇ ing of lime.
  • the moisture content of the absorbent material discharged from the mixer 11 is about 6%.
  • the moisture con ⁇ tent can, according to the composition of the mixture, suitably be varied in the range 2-15%.
  • the circulation number will, by analogy with that stated above, be about 110 (0.980 x 103,993 / 930 * 110), which in turn yields a residence time of 1,100-2,200 s, i.e. in the order of 18-37 min.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Les gaz chauds de processus de fabrication passent par un four de contact (10) dans lequel des particules absorbantes, qui réagissent avec les polluants gazeux contenus dans les gaz de fabrication, sont introduites dans ces gaz pour transformer les gaz polluants en poussière séparable. Les gaz de fabrication passent ensuite par un séparateur de poussière (5). La plus grande partie de la poussière séparée dans le séparateur (5) passe alors dans un mélangeur (11), où elle est mélangée et humidifiée avant d'être recyclée comme matière absorbante par introduction dans les gaz de fabrication en même temps qu'un absorbant frais. L'absorbant frais ajouté est de la chaux vive. La poussière reste si longtemps dans le mélangeur et elle est recyclée tellement de fois que la durée de séjour de la chaux vive à l'état humide dans le mélangeur suffit à ce que celle-ci réagisse de façon assez complète avec l'eau alimentant le mélangeur pour se transformer en chaux éteinte.
PCT/SE1995/001403 1994-11-28 1995-11-24 Technique de separation des polluants gazeux des gaz chauds de processus de fabrication WO1996016722A1 (fr)

Priority Applications (16)

Application Number Priority Date Filing Date Title
CZ971574A CZ157497A3 (en) 1994-11-28 1995-11-24 Method of separating gaseous contaminants from hot processing gases
SI9520141A SI9520141A (en) 1994-11-28 1995-11-24 Method for separating gaseous pollutants from hot process gases
UA97063196A UA52592C2 (uk) 1994-11-28 1995-11-24 Спосіб відокремлення газоподібних забруднювань від гарячих процесних газів
AU41264/96A AU692014B2 (en) 1994-11-28 1995-11-24 Method for separating gaseous pollutants from hot process gases
JP51717096A JP3640674B2 (ja) 1994-11-28 1995-11-24 熱処理ガスからガス状の汚染物質を分離する方法
RO97-00951A RO115421B1 (ro) 1994-11-28 1995-11-24 Procedeu de separare a poluantilor gazosi din gazele de ardere fierbinti ale instalatiilor de incalzire
EP95939455A EP0804273A1 (fr) 1994-11-28 1995-11-24 Technique de separation des polluants gazeux des gaz chauds de processus de fabrication
CA002205995A CA2205995C (fr) 1994-11-28 1995-11-24 Technique de separation des polluants gazeux des gaz chauds de processus de fabrication
HU9800501A HU220402B (hu) 1994-11-28 1995-11-24 Eljárás gáznemű szennyezők leválasztására forró folyamatgázokból
SK661-97A SK66197A3 (en) 1994-11-28 1995-11-24 Method for separating gaseous pollutants from hot process gases
EE9700215A EE04049B1 (et) 1994-11-28 1995-11-24 Meetod gaasiliste saastainete eraldamiseks termilise protsessi gaasidest
BR9509831A BR9509831A (pt) 1994-11-28 1995-11-24 Método para a separação de poluentes gasosos a partir de gases de processo quentes
MD97-0166A MD1020C2 (ro) 1994-11-28 1995-11-24 Procedeu de separare a poluanţilor gazoşi din gazele tehnologice flierbinţi
PL95320426A PL320426A1 (en) 1994-11-28 1995-11-24 Method of removing gaseous pollutants from hot process gases
RU97111848A RU2147919C1 (ru) 1994-11-28 1995-11-24 Способ отделения газообразных загрязнений от горячих процессных газов
FI972233A FI972233A7 (fi) 1994-11-28 1997-05-27 Menetelmä kaasumaisten saastuttavien aineiden erottamiseksi kuumista prosessikaasuista

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9404105-0 1994-11-28
SE9404105A SE504440C2 (sv) 1994-11-28 1994-11-28 Sätt att avskilja gasformiga föroreningar från varma processgaser

Publications (1)

Publication Number Publication Date
WO1996016722A1 true WO1996016722A1 (fr) 1996-06-06

Family

ID=20396125

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1995/001403 WO1996016722A1 (fr) 1994-11-28 1995-11-24 Technique de separation des polluants gazeux des gaz chauds de processus de fabrication

Country Status (20)

Country Link
EP (1) EP0804273A1 (fr)
JP (1) JP3640674B2 (fr)
KR (1) KR100384589B1 (fr)
CN (1) CN1080137C (fr)
AU (1) AU692014B2 (fr)
BR (1) BR9509831A (fr)
CZ (1) CZ157497A3 (fr)
EE (1) EE04049B1 (fr)
FI (1) FI972233A7 (fr)
HU (1) HU220402B (fr)
MD (1) MD1020C2 (fr)
PL (1) PL320426A1 (fr)
RO (1) RO115421B1 (fr)
RU (1) RU2147919C1 (fr)
SE (1) SE504440C2 (fr)
SI (1) SI9520141A (fr)
SK (1) SK66197A3 (fr)
UA (1) UA52592C2 (fr)
WO (1) WO1996016722A1 (fr)
ZA (1) ZA959876B (fr)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0882490A1 (fr) * 1997-06-05 1998-12-09 ALOIS SCHEUCH GESELLSCHAFT m.b.H. Méthode pour purifier des gaz chargés de polluants
WO1999059704A1 (fr) * 1998-05-18 1999-11-25 ABB Fläkt AB Procede et appareil pour epurer des gaz de combustion
WO2001032296A1 (fr) * 1999-11-03 2001-05-10 Foster Wheeler Energia Oy Procede et appareil pour la fixation des polluants dans des gaz de fumee
JP2002518168A (ja) * 1998-06-24 2002-06-25 エービービー フラクト アクチボラグ 煙道ガス清浄方法
JP3395036B2 (ja) 1997-10-06 2003-04-07 日立造船株式会社 排ガス中の酸性ガス除去方法および装置
JP3395035B2 (ja) 1997-10-06 2003-04-07 日立造船株式会社 排ガス中の酸性ガス除去方法および装置
WO2004026443A1 (fr) 2002-09-20 2004-04-01 Alstom Technology Ltd Procede et dispositif de separation de polluants gazeux de gaz de transformation chauds par absorption et melangeur d'humidification de poussiere particulaire
EP1815903A1 (fr) 2006-02-06 2007-08-08 ALSTOM Technology Ltd Procédé et dispositif pour contrôler l'absorption de polluants gazeux de gaz chauds
EP1875953A1 (fr) 2006-07-04 2008-01-09 ALSTOM Technology Ltd Méthode et dispositif associé pour la séparation de composés gazeux de gaz de procédés chauds
DE102007045751B4 (de) * 2006-10-24 2010-01-21 Scheuch Gmbh Vorrichtung und Verfahren zum Befeuchten eines Sorptionsmittels
US7766997B2 (en) 2007-12-21 2010-08-03 Alstom Technology Ltd Method of reducing an amount of mercury in a flue gas
US7850936B2 (en) 2008-02-18 2010-12-14 Alstom Technology Ltd Dry sulfur dioxide (SO2) scrubbing
EP2457637A1 (fr) 2010-11-24 2012-05-30 Alstom Technology Ltd Système de chaudière et procédé de nettoyage de gaz combustible riche en dioxyde de carbone et système de chaudière
EP2684611A2 (fr) * 2012-07-13 2014-01-15 Alstom Technology Ltd Agencement de lance de pulvérisation
EP2695659A1 (fr) 2012-08-07 2014-02-12 Alstom Technology Ltd Capture de mercure à haute performance
US8728211B2 (en) 2012-03-30 2014-05-20 Alstom Technology Ltd Nozzle for spraying liquid and a mixer comprising the nozzle
EP2878889A1 (fr) * 2013-11-27 2015-06-03 Alstom Technology Ltd Système d'épuration à sec avec protection de réchauffeur d'air
CN105617851A (zh) * 2016-03-16 2016-06-01 中国科学院城市环境研究所 一种高效双塔半干法脱硫的方法及其装置
WO2019048582A1 (fr) 2017-09-06 2019-03-14 S.A. Lhoist Recherche Et Developpement Procédé de traitement de gaz de combustion dans un traitement de gaz de combustion à épurateur à sec à lit circulant (cds)

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* Cited by examiner, † Cited by third party
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RU2286836C1 (ru) * 2005-04-11 2006-11-10 Константин Владимирович Зелинский Способ очистки технологического газа от диоксида серы
CN101513589B (zh) * 2009-03-03 2011-07-20 桑德环境资源股份有限公司 半干法烟气净化方法及装置
US8192529B2 (en) * 2009-03-10 2012-06-05 Gatton Jr Lawrence H Integrated dry scrubber system
US9108152B2 (en) * 2013-11-26 2015-08-18 Alstom Technology Ltd Dry scrubber system with low load distributor device

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SE453570B (sv) * 1985-10-09 1988-02-15 Flaekt Ab Forfarande for att ur en gasblandning avskilja sura komponenter samt anordning for genomforande av forfarandet
WO1988004196A1 (fr) * 1986-12-12 1988-06-16 Imatran Voima Oy Procede de purification de gaz de fumee
SE458095B (sv) * 1986-06-27 1989-02-27 Flaekt Ab Anlaeggning foer att avskilja foeroreningar ur ett gasformigt medium

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DE3308927A1 (de) 1983-03-12 1984-09-13 L. & C. Steinmüller GmbH, 5270 Gummersbach Verfahren zur bindung von in rauchgasen enthaltenen gasfoermigen schadstoffen
FI78401B (fi) * 1985-04-24 1989-04-28 Tampella Oy Ab Foerfarande och anordning foer att bringa roekgasernas gasformiga svavelfoereningar saosom svaveldioxid att reagera till fasta foereningar som separeras fraon roekgaserna.
JP3035015B2 (ja) * 1991-08-13 2000-04-17 三菱重工業株式会社 脱硫方法

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SE453570B (sv) * 1985-10-09 1988-02-15 Flaekt Ab Forfarande for att ur en gasblandning avskilja sura komponenter samt anordning for genomforande av forfarandet
SE458095B (sv) * 1986-06-27 1989-02-27 Flaekt Ab Anlaeggning foer att avskilja foeroreningar ur ett gasformigt medium
WO1988004196A1 (fr) * 1986-12-12 1988-06-16 Imatran Voima Oy Procede de purification de gaz de fumee

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Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0882490A1 (fr) * 1997-06-05 1998-12-09 ALOIS SCHEUCH GESELLSCHAFT m.b.H. Méthode pour purifier des gaz chargés de polluants
JP3395036B2 (ja) 1997-10-06 2003-04-07 日立造船株式会社 排ガス中の酸性ガス除去方法および装置
JP3395035B2 (ja) 1997-10-06 2003-04-07 日立造船株式会社 排ガス中の酸性ガス除去方法および装置
RU2209657C2 (ru) * 1998-05-18 2003-08-10 АББ Флэкт АБ Способ и устройство для очистки дымовых газов
AU738601B2 (en) * 1998-05-18 2001-09-20 General Electric Technology Gmbh Method and apparatus for cleaning flue gases
US6508994B1 (en) 1998-05-18 2003-01-21 ABB Fläkt AB Method and apparatus for cleaning flue gases
CZ300312B6 (cs) * 1998-05-18 2009-04-15 ABB Fläkt AB Zpusob cištení kourových plynu a zarízení k jeho provádení
EP1857167A1 (fr) 1998-05-18 2007-11-21 Alstom Procede et appareil pour epurer des gaz de combustion.
WO1999059704A1 (fr) * 1998-05-18 1999-11-25 ABB Fläkt AB Procede et appareil pour epurer des gaz de combustion
JP2002518168A (ja) * 1998-06-24 2002-06-25 エービービー フラクト アクチボラグ 煙道ガス清浄方法
JP2011085386A (ja) * 1998-06-24 2011-04-28 Alstom Technology Ltd 煙道ガス清浄方法
JP4990432B2 (ja) * 1998-06-24 2012-08-01 アルストム テクノロジー リミテッド 煙道ガス清浄方法
US6290921B1 (en) 1999-11-03 2001-09-18 Foster Wheeler Enegeria Oy Method and apparatus for binding pollutants in flue gas
WO2001032296A1 (fr) * 1999-11-03 2001-05-10 Foster Wheeler Energia Oy Procede et appareil pour la fixation des polluants dans des gaz de fumee
CZ297595B6 (cs) * 1999-11-03 2007-02-07 Foster Wheeler Energia Oy Zpusob a zarízení pro vázání necistot v kourovýchplynech
WO2004026443A1 (fr) 2002-09-20 2004-04-01 Alstom Technology Ltd Procede et dispositif de separation de polluants gazeux de gaz de transformation chauds par absorption et melangeur d'humidification de poussiere particulaire
US7387662B2 (en) 2002-09-20 2008-06-17 Alstom Technology Ltd Method and device for separating gaseous pollutants from hot process gases by absorption and a mixer for moistening particulate dust
CN100354027C (zh) * 2002-09-20 2007-12-12 阿尔斯托姆科技有限公司 用于通过吸收来从高温工艺气体中分离气体污染物的方法和设备以及用于润湿粒状粉尘的混合器
EP2295128A1 (fr) 2002-09-20 2011-03-16 Alstom Technology Ltd Procédé et dispositif de séparation de polluants gazeux de gaz de transformation chauds par absorption et melangeur d'humidification de poussiere particulaire
EP1815903A1 (fr) 2006-02-06 2007-08-08 ALSTOM Technology Ltd Procédé et dispositif pour contrôler l'absorption de polluants gazeux de gaz chauds
EP1875953A1 (fr) 2006-07-04 2008-01-09 ALSTOM Technology Ltd Méthode et dispositif associé pour la séparation de composés gazeux de gaz de procédés chauds
DE102007045751B4 (de) * 2006-10-24 2010-01-21 Scheuch Gmbh Vorrichtung und Verfahren zum Befeuchten eines Sorptionsmittels
US7766997B2 (en) 2007-12-21 2010-08-03 Alstom Technology Ltd Method of reducing an amount of mercury in a flue gas
US8277545B2 (en) 2007-12-21 2012-10-02 Alstom Technology Ltd Method of reducing an amount of mercury in a flue gas
US7850936B2 (en) 2008-02-18 2010-12-14 Alstom Technology Ltd Dry sulfur dioxide (SO2) scrubbing
EP2990094A1 (fr) 2010-11-24 2016-03-02 Alstom Technology Ltd Procédé de nettoyage de gaz combustible riche en dioxyde de carbone et système de chaudière
EP2457637A1 (fr) 2010-11-24 2012-05-30 Alstom Technology Ltd Système de chaudière et procédé de nettoyage de gaz combustible riche en dioxyde de carbone et système de chaudière
US9638416B2 (en) 2010-11-24 2017-05-02 General Electric Technology Gmbh Method of cleaning a carbon dioxide rich flue gas and a boiler system
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FI972233A0 (fi) 1997-05-27
JPH10509914A (ja) 1998-09-29
SI9520141A (en) 1997-10-31
EE04049B1 (et) 2003-06-16
HU220402B (hu) 2002-01-28
ZA959876B (en) 1996-07-15
EP0804273A1 (fr) 1997-11-05
AU4126496A (en) 1996-06-19
SE504440C2 (sv) 1997-02-10
HUT77637A (hu) 1998-06-29
RU2147919C1 (ru) 2000-04-27
SE9404105L (sv) 1996-05-29
MD1020C2 (ro) 1999-07-31
JP3640674B2 (ja) 2005-04-20
PL320426A1 (en) 1997-09-29
SE9404105D0 (sv) 1994-11-28
CN1167450A (zh) 1997-12-10
RO115421B1 (ro) 2000-02-28
EE9700215A (et) 1998-02-16
AU692014B2 (en) 1998-05-28
SK66197A3 (en) 1997-10-08
UA52592C2 (uk) 2003-01-15
BR9509831A (pt) 1997-09-30
CZ157497A3 (en) 1997-11-12
FI972233A7 (fi) 1997-05-27
KR100384589B1 (ko) 2003-08-21
CN1080137C (zh) 2002-03-06

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