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WO1996015308A1 - Procede de nettoyage de moquette - Google Patents

Procede de nettoyage de moquette

Info

Publication number
WO1996015308A1
WO1996015308A1 PCT/US1995/013995 US9513995W WO9615308A1 WO 1996015308 A1 WO1996015308 A1 WO 1996015308A1 US 9513995 W US9513995 W US 9513995W WO 9615308 A1 WO9615308 A1 WO 9615308A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
carpet
compositions
cleaning
chelant
Prior art date
Application number
PCT/US1995/013995
Other languages
English (en)
Inventor
Stefano Scialla
Floriana Raso
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to MX9703486A priority Critical patent/MX9703486A/es
Priority to US08/836,299 priority patent/US5928384A/en
Priority to AU40154/95A priority patent/AU706010B2/en
Priority to EP95938967A priority patent/EP0791095A4/fr
Priority to CA002204631A priority patent/CA2204631C/fr
Priority to JP8516091A priority patent/JPH10509191A/ja
Publication of WO1996015308A1 publication Critical patent/WO1996015308A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0031—Carpet, upholstery, fur or leather cleansers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/364—Organic compounds containing phosphorus containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions

Definitions

  • the present invention relates to the use of compositions for cleaning carpets.
  • Carpets produced from synthetic or natural fibers and mixtures thereof are commonly used in residential and commercial applications as a floor covering.
  • Various types of fibers can be used in making carpets such as pol ⁇ amide and wool.
  • carpets irrespective of whether they are made from natural or synthetic fibers are all prone to soiling and staining when contacted with many household items.
  • Foods, grease, oils, beverages such as coffee, tea and soft drinks especially those containing acidic dyes can cause unsightly, often dark stains on carpets.
  • fibers may become soiled as a result of dirt particles, clay, dust, particulate soils in general, coming into contact with, and adhering to the fibers of the carpet. These latter soils often appear in the form of a diffuse layer of soils rather than in the form of spots and tend to accumulate particularly in the so called "high traffic areas" such as near doors as a result of intensive use of the carpets in such areas.
  • carpet cleaning compositions described in the art for removing stains and soils. However, these compositions do not satisfactorily meet the consumer's needs as regards their cleaning performance on different types of stains and soils. Indeed, these carpet cleaner compositions are not fully satisfactory for removing particulate soils, especially in the so called "high traffic areas”.
  • the object of the present invention is to provide improved removal of particulate soils from carpets, in a manner which is applicable to a variety of carpet cleaning compositions, i.e. compositions being either in a liquid form or in a powder form or in a granular form.
  • compositions which comprise a chelant in combination with a soil suspending polycarboxylate or polyamine polymer.
  • a composition allows to obtain excellent particulate soil removal performance especially on diffuse layers of stains and soils which occur in the so called " high traffic areas", i.e. on stains and soils which have become otherwise extremely difficult to remove.
  • a composition comprising a chelant, or a combination of chelants, together with a soil suspending polycarboxylate or polyamine polymer, or mixtures thereof, results in a synergistic effect on the removal of particulate soils from carpets.
  • said combination of a chelant with a soil suspending polycarboxylate or polyamine polymer is particularly suitable to be used in aqueous carpet cleaning compositions which further comprise a source of active oxygen, thereby providing excellent particulate soil removal performance while delivering also good cleaning performance on other types of soils and stains like bleachable stains.
  • An advantage of the present invention is that it is applicable to all carpet types, especially delicate natural fibers and is also safe to all carpet dye types, particularly sensitive natural dyes used therein.
  • Another advantage of the present invention is that it may be applied directly on the carpet without causing damage to the carpet.
  • the cleaning action of the invention commences as soon as the carpet cleaning composition has been applied to the surface.
  • the use of the carpet cleaning composition of the present invention does not necessarily require rubbing or/and brushing of the carpet.
  • This patent application nowhere mentions the use of any chelant or soil suspending polycarboxylate or polyamine polymer, let alone the benefit resulting from their combined use, in a composition for cleaning carpets, i.e. the improved particulate soil removing performance of said composition.
  • US 3 607 760 discloses an aqueous carpet cleaner particularly suitable for removing pet stains, said carpet cleaner comprising hydrogen peroxide, hydrocarbon ether of ethylene or diethylene glycols, hydrocarbon monohydric alcohols and EDTA. No soil suspending polymer is disclosed.
  • EP-A-346 835 discloses an aqueous carpet cleaner at pH 7-12 comprising a water-soluble alcohol (C1-C5) and an oxidizing agent (hydrogen peroxide). No chelants, no soil suspending polymers are described.
  • European patent application 93870161.2 discloses the use of stable aqueous compositions comprising a source of active oxygen, having a pH of from 1 to 6, for the cleaning of carpets. More particularly this European patent application discloses that such compositions may further comprise from 1 % to 7% by weight of the total composition of a builder system, e.g. aminopolyphosphonates. No soil suspending polymers are disclosed.
  • the present invention encompasses the use of a composition comprising a chelant, or a mixture thereof, in combination with a soil suspending polycarboxylate or polyamine polymer, or a mixture thereof, for the cleaning of carpets.
  • the present invention further encompasses a method of cleaning a carpet wherein a composition comprising a chelant in combination with a soil suspending polycarboxylate or polyamine polymer is applied to said carpet, wherein said carpet is is then optionally rubbed and/or brushed, and wherein said composition is then removed from said carpet.
  • the present invention encompasses the use of a composition comprising a chelant, or a mixture thereof, in combination with a soil suspending polycarboxylate or polyamine polymer, or a mixture thereof, for the cleaning of carpets, whereby the performance on particulate soil removal is improved.
  • the compositions used may be either in a liquid form or in a granular form or in a powder form.
  • improved particulate soil removing performance it is meant herein that the removal of particulate soils from carpets achieved by using a carpet cleaning composition comprising a chelant together with a soil suspending polycarboxylate or polyamine polymer is improved, as compared to the removal of particulate soils obtained by using said composition without any chelant and/or without any soil suspending polycarboxylate or polyamine polymer. More particularly, it has been unexpectedly found that a synergistic effect on particulate soil removing performance is associated with the combination of a chelant with a soil suspending polycarboxylate or polyamine polymer.
  • particulate soil it is meant herein any soils or stains of particulate nature that can be found on carpets, e.g. clay, dirt, dust, mud, concrete and the like.
  • compositions herein comprise, as a first essential component, a chelant or a mixture thereof.
  • Suitable chelants for use herein include phosphonate chelants, amino carboxylate chelants, and polyfunctionally-substituted aromatic chelating agents.
  • Suitable phosphonate chelants herein include organic amino phosphonate compounds, such as amino alkylene poly (alkylene phosphonate), alkali metal ethane 1-hydroxy diphosphonates, nitrilo trimethylene phosphonates, ethylene diamine tetra methylene phosphonates, and diethylene triamine penta methylene phosphonates.
  • the phosphonate compounds may be present either in their acid form or as salts of different cations on some or all of their acid functionalities.
  • Preferred phosphonate chelants to be used herein are diethylene triamine penta methylene phosphonates. Such phosphonate chelants are commercially available from Monsanto under the trade name DEQUEST.
  • Suitable aminocarboxylate chelants for use herein include ethylenediaminetetracetates, N-hydroxyethylenediaminetriacetates, nitrilotriacetates, ethylenediamine tetrapoprionates, triethylenetetra- aminehexacetates, diethyienetriaminepentaacetates, and ethanoldiglycerides, alkali metal, ammonium, and substituted ammonium salts thereof.
  • Suitable polyfunctionally-substituted aromatic chelating agents useful herein are described in U.S. Patent 3,812,044, issued May 21 , 1974, to Connor et al.
  • Preferred compounds of this type in acid form are dihydroxydisulfobenzenes such as 1 ,2-dihydroxy-3,5-disulfobenzene.
  • a preferred biodegradable chelator for use herein is ethylenediamine disuccinate ("EDDS"), especially the [S,S] isomer as described in U.S. Patent 4,704,233, November 3, 1987, to Hartman and Perkins.
  • compositions herein can comprise, in their neat form, from 0.01 % to 5% by weight of the total composition of a chelant or a mixture thereof, preferably from 0.05% to 3% and more preferably from 0.1 % to 1 % .
  • compositions herein comprise, as a second essential ingredient, a soil suspending polycarboxylate or polyamine polymer, or a mixture thereof.
  • any soil suspending polycarboxylate polymer known to those skilled in the art can be employed according to the present invention such as homo- or co-polymeric polycarboxylic acids or their salts including polyacrylates and copolymers of maleic anhydride or/and acrylic acid and the like.
  • soil suspending polycarboxylate polymers can be prepared by polymerizing or copolymerizing suitable unsaturated monomers, preferably in their acid form.
  • Unsaturated monomeric acids that can be polymerized to form suitable polymeric polycarboxylates include acrylic acid, maleic acid (or maleic anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid and methylenemaionic acid.
  • the presence in the polymeric polycarboxylates herein of monomeric segments, containing no carboxylate radicals such as vinylmethyl ether, styrene, ethylene, etc. is suitable provided that such segments do not constitute more than about 40% by weight.
  • Particularly suitable polymeric polycarboxylates can be derived from acrylic acid.
  • acrylic acid-based polymers which are useful herein are the water-soluble salts of polymerized acrylic acid.
  • the average molecular weight of such polymers in the acid form preferably ranges from about 2,000 to 10,000, more preferably from about 4,000 to 7,000 and most preferably from about 4,000 to 5,000.
  • Water-soluble salts of such acrylic acid polymers can include, for example, the alkali metal, ammonium and substituted ammonium salts. Soluble polymers of this type are known materials. Use of polyacrylates of this type in detergent compositions has been disclosed, for example, in Diehl, U.S. Patent 3,308,067, issued March 7, 1967.
  • Acr ⁇ lic/maleic-based copolymers may also be used as a preferred soil suspending poiycarboxylic polymer.
  • Such materials include the water- soluble salts of copolymers of acrylic acid and maleic acid.
  • the average molecular weight of such copolymers in the acid form preferably ranges from about 2,000 to 100,000, more preferably from about 5,000 to 75,000, most preferably from about 7,000 to 65,000.
  • the ratio of acrylate to maleate segments in such copolymers will generally range from about 30:1 to about 1 :1 , more preferably from about 10:1 to 2:1.
  • Water- soluble salts of such acrylic acid/maleic acid copolymers can include, for example, the alkali metal, ammonium and substituted ammonium salts.
  • Soluble acrylate/maleate copolymers of this type are known materials which are described in European Patent Application No. 66915, published December 15, 1982. Particularly preferred is a copolymer of maleic / acrylic acid with an average molecular weight of about 70,000. Such copolymers are commercially available from BASF under the trade name SOKALAN CP5.
  • Any soil suspending polyamine polymer can be employed herein.
  • Particularly suitable polyamine polymer for use herein are polymers having polyalkoxymoiety are alkoxylated polyamines. Such materials can conveniently be represented as molecules of the empirical structures with repeating units :
  • R is a hydrocarbyl group, usually of 2-6 carbon atoms;
  • R 1 may be a C1-C20 hydrocarbon;
  • the alkoxy groups are ethoxy, propoxy, and the like, and y is 2-30, most preferably from 10-20;
  • n is an integer of at least 2, preferably from 2-20, most preferably 3-5;
  • X" is an anion such as halide or methylsulfate, resulting from the quaternization reaction.
  • polyethylene amines i.e., the polymerized reaction product of ethylene oxide with ethyleneimine, having the general formula :
  • ethoxylated polyethylene amine in particular ethoxylated tetraethylenepentamine, and quaternized ethoxylated hexamethylene diamine.
  • compositions for the cleaning of carpets according to the present invention can comprise in their neat form of from 0.05% to 10% by weight of the total composition of a soil suspending polycarboxylate or polyamine polymer, or mixtures thereof, preferably of from 0.1 % to 5%, more preferably of from 0.1 % to 2% and most preferably of from 0.2% to 1.5% .
  • concentrations mentioned herein for the soil suspending polycarboxylate or polyamine polymers and the chelants are preferred in that, at these concentrations, maximum performance is obtained in the most economic way. Also at these concentrations the amount of residues that the compositions may leave on carpets is minimal.
  • the present invention further encompasses the use, for the cleaning of carpets, of a composition which further comprise a source of active oxygen.
  • said compositions are liquid aqueous compositions.
  • the latter aqueous compositions being particularly efficient in terms of overall cleaning performance.
  • preferred compositions for the cleaning of carpets according to the present invention are particularly efficient in cleaning diffuse soils (particulate soils) that tend to accumulate in the so called "high traffic areas" but also in delivering good cleaning performance on other types of stains or soils, i.e. on spot stains such as coffee, beverage, food and the like.
  • liquid aqueous compositions herein when they comprise a source of active oxygen, are stable. Accordignl ⁇ , said compositions are convenient for the consumer to use. Indeed, said liquid aqueous compositions for the cleaning of carpets according to the present invention do not require pH adjustment prior to use and can be stored for long periods of time prior to use.
  • an optional but highly preferred ingredient of the compositions for the cleaning of carpets according to the present invention is a source of active oxygen.
  • a preferred source according to the present invention is hydrogen peroxide or sources thereof.
  • a hydrogen peroxide source refers to any compound which produces hydrogen peroxide when said compound is in contact with water.
  • Suitable water-soluble sources of hydrogen peroxide for use herein include percarbonates, metal peroxides and perborates.
  • peroxides can be used as an alternative to hydrogen peroxide and sources thereof or in combination with hydrogen peroxide and sources thereof.
  • Suitable classes include dialkylperoxides, diacylperoxide, preformed percarboxylic acids, persulphates, organic and inorganic peroxides and/or hydroperoxides.
  • compositions herein comprise from 0.1 % to 15%, preferably from 0.5% to 10%, most preferably from 1 % to 5% by weight of the total composition of active oxygen in said composition.
  • active oxygen concentration refers to the percentage concentration of elemental oxygen, with an oxidation number zero, that being reduced to water would be stoichiometrically equivalent to a given percentage concentration of a given peroxide compound, when the peroxide functionality of the peroxide compound is completely reduced to oxides.
  • the active oxygen sources according to the present invention increase the ability of the compositions to remove colored stains, to destroy malodorous molecules and to kill germs.
  • the concentration of available oxygen can be determined by methods known in the art, such as the iodimetric method, the permanganometric method and the cerimetric method. Said methods and the criteria for the choice of the appropriate method are described for example in "Hydrogen Peroxide", W. C. Schumb, C. N. Satterfield and R. L. Wentworth, Reinhold Publishing Corporation, New York, 1955 and "Organic Peroxides", Daniel Swern, Editor Wiley Int. Science, 1970.
  • Suitable organic and inorganic peroxides/hydroperoxides for use in the compositions according to the present invention include diacyl and dialkyl peroxides/hydroperoxides such as dibenzoyl peroxide, t-butyl hydroperoxide, dilauroyl peroxide, dicumyl peroxide, persulphuric acid and mixtures thereof.
  • the compositions according to the present invention comprise from 0% to 15%, preferably from 0.005% to 10% of said organic peroxides.
  • Suitable preformed peroxyacids for use in the compositions for the cleaning of carpets according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalatic acid, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof.
  • the compositions for the cleaning of carpets according to the present invention comprise in their neat form from 0% to 15%, preferably from 0.005% to 10% of said preformed peroxyacids.
  • compositions herein may additionally comprise from 0% to 30%, preferably from 2% to 20% of peracid precursors, i.e. compounds that upon reaction with hydrogen peroxide produce peroxyacids.
  • peracid precursors suitable for use in the present invention can be found among the classes of anhydrides, amides, imides and esters such as acetyl triethyl citrate (ATC), tetra acetyl ethylene diamine (TAED), succinic or maleic anhydrides.
  • the pH of the compositions herein can be from 1 to 14.
  • the recommended pH range to achieve good hydrogen peroxide stability is from 1 to 9, preferably between pH 1 and 8, and more preferably between pH 2 and 7.
  • the compositions herein may further comprise an acid to adjust pH.
  • some acids can have the advantage that they can form small concentrations of the corresponding peracids by reaction with hydrogen peroxide in-situ, thus enhancing the overall performance of the composition. These acids can be further selected so as to have chelating and/or building properties.
  • the acids of the present invention that may be used for these purposes can be organic or inorganic acids, preferably organic acids such as citric, maleic, oxalic succinic, and tartaric acids or inorganic acids such as sulphuric acid.
  • compositions herein may further comprise a number of additional compounds such as surfactants, builder system, solvents, perfumes, dyes, suds suppressing agents, enzymes, photobleaching agents and other minors.
  • additional compounds such as surfactants, builder system, solvents, perfumes, dyes, suds suppressing agents, enzymes, photobleaching agents and other minors.
  • the optional ingredients are selected so that they are compatible with said source of active oxygen.
  • dyes are used at low concentrations to prevent staining.
  • Solvents suitable for use herein may be selected from oct ⁇ l alcohol, isopropyl alcohol, propyl alcohol and furfuryl alcohol.
  • Surfactants suitable for use herein are well known in the art and include anionic, nonionic, zwitterionic and cationic surfactants and mixtures thereof.
  • the surfactants suitable for use herein are compatible with hydrogen peroxide and sources thereof.
  • the anionic surfactants which may be used herein include alkali metal salts of alk ⁇ l substituted benzene sulphonates, alkali metal alkyl sulphonates, alkali metal alkyl sulphates and alkali metal alkyl ether sulphates derived from for example fatty alcohols and alkyl phenols, alkali metal alkane sulphonates, alkali metal olefin sulphonates and alkali metal sulphosuccinates and alkyl succinates, whereby the sodium salts are preferred, alk ⁇ l carboxylates and alkyl ether carbox ⁇ lates.
  • nonionic surfactants which may be used herein include any liquid or solid ethoxylated C6-C2 fatty alcohol nonionic surfactant, alkyl propoxylates and mixtures thereof, fatty acid C6-C2 alkanolamides, CQ- C20 polyethylglycol ethers, polyethylene glycol with molecular weight 1000 to 80000 and C6-C24 amine oxides, glucose amides, alkyl pyrrolidones, betaines.
  • Suitable cationic surfactants for use herein include quaternary ammonium compounds of the formula R-
  • Zwitterionic surfactants are also suitable optionais for use herein.
  • Suitable zwitterionic surfactants include derivatives of aliphatic quaternary ammonium, phosphonium, and sulphonium compounds in which the aliphatic moiety can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 24 carbon atoms and another substituent contains, at least, an anionic water-solubilizing group.
  • Particularly preferred zwitterionic materials are the ethoxylated ammonium sulphonates and sulfates disclosed in U.S.
  • compositions according to the present invention contain from 0% to 20% of zwitterionic surfactants.
  • compositions herein comprise from 0.01 % to 70% by weight, preferably from 0.1 % to 50% by weight of the total composition of said surfactants.
  • compositions herein may further comprise a builder system.
  • Suitable builders for use herein include citric acid, preferably in the form of a water-soluble salt, derivatives of succinic acid of the formula R_CH(COOH)CH2(COOH) wherein R is C ⁇ o-20 alkyl or alkenyl, preferably C-
  • Specific examples include lauryl succinate, myristyl succinate, palmityl succinate, 2-dodecenylsuccinate, 2-tetradecenyl succinate.
  • Succinate builders are preferably used in the form of their water-soluble salts, including sodium, potassium, ammonium and alkanolammonium salts.
  • Suitable builders are oxodisuccinates and mixtures of tartrate monosuccinic and tartrate disuccinic acid such as described in US 4,663,071. 13
  • fatty acid builders including saturated or unsaturated C10-I 8 f tty acids, as well as the corresponding soaps.
  • Preferred saturated species have from 12 to 16 carbon atoms in the alkyl chain.
  • the preferred unsaturated fatty acid is oleic acid.
  • a preferred builder system for use herein consists of a mixture of citric acid, fatty acids and succinic acid derivatives described herein above.
  • the compositions herein preferably comprise from 0% to 10%, preferably from 1 % to 7% by weight of the neat total composition of a builder system.
  • the present invention also encompasses a method of cleaning a carpet wherein a composition comprising a chelant in combination with with a soil suspending polycarboxylate or polyamine polymer is applied to said carpet, wherein said carpet is then optionally rubbed and/or brushed, and wherein said composition is then removed from said carpet.
  • the step of applying a composition for the cleaning of carpets as described herein before may be followed by a rubbing step or/and a brushing step.
  • the carpet may be cleaned by applying onto it a composition for the cleaning of carpets according to the present invention, then rubbing and/or brushing it more or less intensively for example by means of a sponge or a brush or other mechanical/eletrical device, optionally with the aid of water.
  • the rubbing/brushing-times are between 0.1 to a few minutes per square meters.
  • compositions for the cleaning of carpets according to the present invention may be applied to the carpet to be cleaned either in neat or diluted form, this applies to compositions being either liquid compositions or granular compositions or powder compositions.
  • diluted form it is meant herein that the compositions for the cleaning of carpets as described herein before may be diluted by the user, 14
  • compositions herein can be diluted up to 150 times, preferably up to 50 times and more preferably up to 25 times.
  • the compositions for the cleaning of carpets according to the present invention are liquid aqueous compositions.
  • a liquid aqueous composition i.e. an aqueous composition for the cleaning of carpets as described herein before in its neat form or which has been diluted with water by the user or an aqueous composition resulting from the dilution of a granular composition or of a powder composition, is applied to the carpet to be cleaned, said carpet is optionally rubbed and/or brushed, then said composition is left to dry and then removed from said carpet.
  • said liquid aqueous composition is left to dry until said composition which combined with dirt has been changed into dry residues. These residues are then removed from the carpet mechanically.
  • Such liquid aqueous compositions may be applied directly onto the area to be treated or applied using a cloth or piece of material such as spraying device or aerosol can, a sponge, a brush or other mechanical/eletrical device.
  • a liquid aqueous composition is applied to the area to be treated by using a spraying device or an aerosol can.
  • a spraying device may be trigger operated or pump operated or electrically operated or operated by any source of pressurized gas such as a can or a pressurizer.
  • Such spraying devices are particularly preferable if a large area is to be treated as it facilitates the ease of use for the consumer.
  • the spraying devices ensure uniform coverage of the area to be treated and maximizes the advantage of the using liquid aqueous compositions containing peroxides. This is because the application of product by spray best allows the product to be left to dry on the area treated, even without rubbing or brushing. This optimizes the action time of the composition and allows the best exploitation of the bleaching action of peroxides.
  • compositions for the cleaning of carpets according to the present invention are granular compositions or powder compositions.
  • Such compositions for the cleaning of carpets according to the present invention may be applied directly onto the area of the carpet to be treated by for example sprinkling said composition over said area or may be applied by using a sponge, a brush, or other mechanical/eletrical device preferably in presence of water and then left to dry and then removed from said carpet.
  • the area to be treated using the compositions according to the present invention may be any size.
  • a complete section or even a whole carpet may be applied with the composition for the cleaning of carpets according to the present invention.
  • a spraying device with a pump to allow prolonged spraying is particularly useful.
  • the amount of the compositions for the cleaning of carpets according to the present invention applied will depend on the severity of the stain or soil. In the case of stubborn stains more than one application may be required to ensure complete removal of the stain.
  • the carpet cleaning compositions may also be used in order to deodorize the carpet and remove the dinginess of the carpet resulting from a diffused layer of soil which results from general wear.
  • compositions for the cleaning of carpets according to the present invention may be used both for manual carpet cleaning and carpet cleaning machines.
  • carpet cleaning machines the compositions for the cleaning of carpets according to the present invention, i.e. either liquid compositions or granular compositions or powder compositions, may be preferably diluted according to the machine operating instructions.
  • compositions to be used in such machines should be formulated to prevent high sudsing.
  • the ratio of nonionic surfactant to other surfactants should be higher. More preferably such compositions comprise suds suppressing agents.
  • compositions may be used for the removal of odors, stains and soils from carpets or upholstery.
  • compositions may be used to hygenise or disinfect carpets and exterminate microinsects from the carpet or upholstery.
  • compositions are made by combining the listed ingredients in the listed proportions (weight % unless otherwise specified).
  • Nonionic Surfactant 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0
  • DETPMP diethylene triamine penta methylene phosphonic acid available from Monsanto under the trade name Dequest 2060 or Dequest 4060.
  • MA/AA is copolymer of maleic/ acrylic acid, average molecular weight about 70,000.
  • PA is an ethoxylated tetraethylenepentamine, everage molecular weight about 70,000.
  • EDDS is trisodium salt solution of [S,S]- Ethylenediamine-N,N'-disuccinic Acid.
  • DTPA is pentasodium diethylenetriaminepentaacetate.
  • Composition 1 is taken as reference, i.e. it comprises no chelant and no soil suspending polycarboxylate or polyamine polymer.
  • Compositions 2 to 4 comprise diethylene triamine penta methylene phosphonic acid, respectively, at different levels.
  • Compositions 4, 5 and 6 comprise a copolymer of maleic/ acrylic acid as the soil suspending polycarboxylate polymer of the present invention, at different levels.
  • Composition 7 is representative of the compositions for the cleaning of carpets according to the present invention and comprises diethylene triamine penta methylene phosphonic acid together with a copolymer of maleic/ acrylic acid.
  • compositions 8, 9 and 10 comprise a copolymer of maleic/acrylic acid as the soil suspending polycarboxylate polymer, and a non phosphonate chelant (EDDS) at different levels.
  • Composition 1 1 comprises a copolymer of maleic/acrylic acid as the soil suspending polycarboxylate polymer, and a non phosphonate chelant (DTPA).
  • Compositions 12 comprises ethoxylated tetraethylenepentamine as the soil suspending polyamine of the present invention.
  • compositions 1 to 7 20 ml of each of the compositions 1 to 7 was sprayed separately onto an artificial soiled carpet sample (40cm x 40cm) with a trigger sprayer. All the resulting samples were left to dry for about 2 hours and then vacuum cleaned.
  • composition 1 was taken as a reference and compared to compositions 2 to 7, to evaluate their particulate soil removing performance.
  • composition 7 was taken as a reference to grade compositions 8 to 16.
  • a composition graded 0 is a composition for which no difference was observed versus the reference composition (composition 1).
  • a composition graded 4 is a composition for which a very large difference was observed versus the reference composition, i.e. important particulate soil removal was observed.
  • the results in the following table are average results over 3 replicates test and on observations of 2 persons.
  • composition 7,8,9,10,11 a composition according to the present invention
  • a plateau concentration value is reached and, beyond this concentration, no further improvement is observed.
  • the results show that there is a synergistic effect associated with the use of a carpet cleaning composition comprising a chelant together with a soil suspending polycarboxylate or polyamine polymer. This synergistic effect is even stronger with a combination of chelants and a polyamine polymer in terms of particulate soil removing performance. In fact, particulate soil removal is observed even immediatelly after application, even before vacuum cleaning.
  • compositions 1 2 3 4 Compositions 1 2 3 4
  • DETPMP diethylene triamine penta methylene phosphonic acid available from Monsanto under the trade name Dequest 2060 or Dequest 4060.
  • MA/AA is copolymer of maleic/ acrylic acid, average molecular weight about 70,000.
  • PA is an ethoxylated tetraethylenepentamine, everage molecular weight about 70,000.
  • EDDS is trisodium salt solution of [S,S]- Ethylenediamine-N,N'-disuccinic Acid.
  • compositions in the examples are compositions for the cleaning of carpets according to the present invention, i.e. they exhibit excellent particulate soil removing performance while providing also good cleaning performance on other types of soils such as coffee, beverages and the like.
  • Compositions 1 and 2 are preferably used in manual carpet cleaning applications.
  • Compositions 3 and 4 are preferably used in carpet cleaning machines.
  • Compositions 5 and 6 can be used for both application, diluted if used in carpet cleaning machines.
  • Compositions 3 and 4 are prepared by mixing together separately all the water soluble ingredients on one hand, and all the water insoluble ingredients on the other hand, as follows: Premix 1 is Water, H2 ⁇ 2» Dob. 45-7, citric acid, MA/AA and DETPMP, and Premix 2 is Dob. 23-2, Acetyl triethyl citrate. Premix 1 is then poured into premix 2 (or viceversa) and vigorously stirred until a stable emulsion is obtained, typically for 30 minutes to 1 hour.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Utilisation de compositions comprenant un chélateur ainsi qu'un polycarboxylate ou une polyamine constituant une suspension avec les salissures particulaires, pour nettoyer des moquettes, l'efficacité d'élimination des salissures particulaires étant améliorée.
PCT/US1995/013995 1994-11-10 1995-10-31 Procede de nettoyage de moquette WO1996015308A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
MX9703486A MX9703486A (es) 1994-11-10 1995-10-31 Metodo para limpiar alfombras.
US08/836,299 US5928384A (en) 1994-11-10 1995-10-31 Method of cleaning carpets
AU40154/95A AU706010B2 (en) 1994-11-10 1995-10-31 Method of cleaning carpets
EP95938967A EP0791095A4 (fr) 1994-11-10 1995-10-31 Procede de nettoyage de moquette
CA002204631A CA2204631C (fr) 1994-11-10 1995-10-31 Procede de nettoyage de moquette
JP8516091A JPH10509191A (ja) 1994-11-10 1995-10-31 カーペットのクリーニング法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP94870175.0 1994-11-10
EP94870175 1994-11-10

Publications (1)

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WO1996015308A1 true WO1996015308A1 (fr) 1996-05-23

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PCT/US1995/013995 WO1996015308A1 (fr) 1994-11-10 1995-10-31 Procede de nettoyage de moquette

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EP (1) EP0791095A4 (fr)
JP (1) JPH10509191A (fr)
AR (1) AR000116A1 (fr)
AU (1) AU706010B2 (fr)
CA (1) CA2204631C (fr)
CO (1) CO4520249A1 (fr)
MX (1) MX9703486A (fr)
TW (1) TW297067B (fr)
WO (1) WO1996015308A1 (fr)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0751213A1 (fr) * 1995-06-27 1997-01-02 The Procter & Gamble Company Compositions pour le nettoyage de tapis et méthode de nettoyage
GB2321252A (en) * 1997-01-16 1998-07-22 Reckitt & Colman Inc Carpet cleaning compositions
EP0906950A1 (fr) * 1997-10-03 1999-04-07 The Procter & Gamble Company Compositions contenant des agents de blanchiment péroxydés comprenant un système d'agent chélatant particulier
US5905065A (en) * 1995-06-27 1999-05-18 The Procter & Gamble Company Carpet cleaning compositions and method for cleaning carpets
WO1999029817A1 (fr) * 1997-12-04 1999-06-17 Henkel Kommanditgesellschaft Auf Aktien Nettoyant pulverulent pour tapis, a source d'oxygene actif
EP0949325A1 (fr) * 1998-04-08 1999-10-13 The Procter & Gamble Company Compositions pour le nettoyage de tapis et méthode de nettoyage
EP0949326A1 (fr) * 1998-04-08 1999-10-13 The Procter & Gamble Company Procédé pour le nettoyage de tapis
EP0997526A1 (fr) * 1998-10-30 2000-05-03 The Procter & Gamble Company Procédé de nettoyage de tapis avec une composition contenant un agent de blanchiment peroxydé
EP0997525A1 (fr) * 1998-10-30 2000-05-03 The Procter & Gamble Company Procédé de nettoyage de tapis avec une composition contenant un copolymère de poly ( éther de vinyle et de méthyle / acide maléique )
US6113654A (en) * 1996-09-12 2000-09-05 Peterson; David Carpet cleaning composition
US6403547B1 (en) * 1998-10-30 2002-06-11 The Procter & Gamble Company Process of cleaning carpets with a composition comprising peroxygen bleach
EP0988361B1 (fr) * 1998-04-08 2002-12-11 The Procter & Gamble Company Compositions et procede de nettoyage de tapis
WO2005066323A1 (fr) * 2004-01-06 2005-07-21 Reckitt Benckiser N.V. Composition de traitement de tapis
US7261742B2 (en) 2005-10-13 2007-08-28 S.C. Johnson & Son, Inc. Method of deodorizing a textile
US7407922B2 (en) 2005-10-13 2008-08-05 S.C. Johnson & Son, Inc. Deodorizing compositions
WO2011088089A1 (fr) 2010-01-12 2011-07-21 The Procter & Gamble Company Intermédiaires et tensioactifs utiles dans des compositions de nettoyage ménager et d'hygiène personnelle, et leurs procédés de fabrication
WO2012112828A1 (fr) 2011-02-17 2012-08-23 The Procter & Gamble Company Sulfonates d'alkylphényle linéaires d'origine biologique
WO2012138423A1 (fr) 2011-02-17 2012-10-11 The Procter & Gamble Company Compositions comprenant des mélanges de sulfonates d'alkylphényle c10-c13
WO2014138141A1 (fr) 2013-03-05 2014-09-12 The Procter & Gamble Company Compositions de sucre mélangées
WO2016200440A1 (fr) 2015-06-11 2016-12-15 The Procter & Gamble Company Dispositif et procédés pour l'application de compositions sur des surfaces

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EP3004310B1 (fr) * 2013-05-24 2021-07-14 The Procter & Gamble Company Composition de détergent à faible ph

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EP0346835A2 (fr) * 1988-06-14 1989-12-20 BASF Corporation Procédé de nettoyer des tapis et l'application d'une composition
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US3723323A (en) * 1971-04-22 1973-03-27 Johnson & Son Inc S C Fabric treating shampoo compositions
US4648882A (en) * 1984-12-10 1987-03-10 Henkel Kommanditgesellschaft Auf Aktien Powdery carpet cleaning preparation containing zeolite granulate
US4652389A (en) * 1984-12-14 1987-03-24 The Clorox Company Carpet cleaner
US4820450A (en) * 1986-06-26 1989-04-11 E And R Investments Composition for precipitating dirt and other contaminants from wash water and method of cleaning
US4797223A (en) * 1988-01-11 1989-01-10 Rohm And Haas Company Water soluble polymers for detergent compositions
EP0346835A2 (fr) * 1988-06-14 1989-12-20 BASF Corporation Procédé de nettoyer des tapis et l'application d'une composition
US5395555A (en) * 1993-11-22 1995-03-07 Eastman Kodak Company Cleaning composition for animal urine removal

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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0751213A1 (fr) * 1995-06-27 1997-01-02 The Procter & Gamble Company Compositions pour le nettoyage de tapis et méthode de nettoyage
US5905065A (en) * 1995-06-27 1999-05-18 The Procter & Gamble Company Carpet cleaning compositions and method for cleaning carpets
US6113654A (en) * 1996-09-12 2000-09-05 Peterson; David Carpet cleaning composition
GB2321252A (en) * 1997-01-16 1998-07-22 Reckitt & Colman Inc Carpet cleaning compositions
EP0906950A1 (fr) * 1997-10-03 1999-04-07 The Procter & Gamble Company Compositions contenant des agents de blanchiment péroxydés comprenant un système d'agent chélatant particulier
WO1999018180A1 (fr) * 1997-10-03 1999-04-15 The Procter & Gamble Company Compositions contenant un agent de blanchiment peroxyde qui comportent un systeme d'agent chelatant particulier
WO1999029817A1 (fr) * 1997-12-04 1999-06-17 Henkel Kommanditgesellschaft Auf Aktien Nettoyant pulverulent pour tapis, a source d'oxygene actif
EP0949325A1 (fr) * 1998-04-08 1999-10-13 The Procter & Gamble Company Compositions pour le nettoyage de tapis et méthode de nettoyage
EP0949326A1 (fr) * 1998-04-08 1999-10-13 The Procter & Gamble Company Procédé pour le nettoyage de tapis
WO1999053007A1 (fr) * 1998-04-08 1999-10-21 The Procter & Gamble Company Procede de nettoyage de tapis
WO1999053006A1 (fr) * 1998-04-08 1999-10-21 The Procter & Gamble Company Compositions de nettoyage de tapis et procede de nettoyage de tapis
EP0988361B1 (fr) * 1998-04-08 2002-12-11 The Procter & Gamble Company Compositions et procede de nettoyage de tapis
WO2000026330A1 (fr) * 1998-10-30 2000-05-11 The Procter & Gamble Company Procede de nettoyage de tapis de sol a l'aide d'une composition comprenant un copolymere de poly(ether methylvinylique/acide maleique)
WO2000026333A1 (fr) * 1998-10-30 2000-05-11 The Procter & Gamble Company Procede de nettoyage de tapis de sol a l'aide d'une composition comprenant un agent de blanchiment peroxygene
EP0997525A1 (fr) * 1998-10-30 2000-05-03 The Procter & Gamble Company Procédé de nettoyage de tapis avec une composition contenant un copolymère de poly ( éther de vinyle et de méthyle / acide maléique )
US6403547B1 (en) * 1998-10-30 2002-06-11 The Procter & Gamble Company Process of cleaning carpets with a composition comprising peroxygen bleach
EP0997526A1 (fr) * 1998-10-30 2000-05-03 The Procter & Gamble Company Procédé de nettoyage de tapis avec une composition contenant un agent de blanchiment peroxydé
WO2005066323A1 (fr) * 2004-01-06 2005-07-21 Reckitt Benckiser N.V. Composition de traitement de tapis
US7407922B2 (en) 2005-10-13 2008-08-05 S.C. Johnson & Son, Inc. Deodorizing compositions
US7261742B2 (en) 2005-10-13 2007-08-28 S.C. Johnson & Son, Inc. Method of deodorizing a textile
WO2011088089A1 (fr) 2010-01-12 2011-07-21 The Procter & Gamble Company Intermédiaires et tensioactifs utiles dans des compositions de nettoyage ménager et d'hygiène personnelle, et leurs procédés de fabrication
WO2012112828A1 (fr) 2011-02-17 2012-08-23 The Procter & Gamble Company Sulfonates d'alkylphényle linéaires d'origine biologique
WO2012138423A1 (fr) 2011-02-17 2012-10-11 The Procter & Gamble Company Compositions comprenant des mélanges de sulfonates d'alkylphényle c10-c13
US9193937B2 (en) 2011-02-17 2015-11-24 The Procter & Gamble Company Mixtures of C10-C13 alkylphenyl sulfonates
WO2014138141A1 (fr) 2013-03-05 2014-09-12 The Procter & Gamble Company Compositions de sucre mélangées
WO2016200440A1 (fr) 2015-06-11 2016-12-15 The Procter & Gamble Company Dispositif et procédés pour l'application de compositions sur des surfaces

Also Published As

Publication number Publication date
CA2204631C (fr) 2001-02-06
MX9703486A (es) 1997-08-30
JPH10509191A (ja) 1998-09-08
AU4015495A (en) 1996-06-06
EP0791095A4 (fr) 1997-10-15
AR000116A1 (es) 1997-05-21
AU706010B2 (en) 1999-06-03
CO4520249A1 (es) 1997-10-15
TW297067B (fr) 1997-02-01
EP0791095A1 (fr) 1997-08-27

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