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WO1996002624A1 - Kit, composition et procedes de nettoyage - Google Patents

Kit, composition et procedes de nettoyage Download PDF

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Publication number
WO1996002624A1
WO1996002624A1 PCT/AU1995/000423 AU9500423W WO9602624A1 WO 1996002624 A1 WO1996002624 A1 WO 1996002624A1 AU 9500423 W AU9500423 W AU 9500423W WO 9602624 A1 WO9602624 A1 WO 9602624A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaning composition
cleaning
agent
oxidising
hydrogen peroxide
Prior art date
Application number
PCT/AU1995/000423
Other languages
English (en)
Inventor
Michael Jeffrey Hunter
Original Assignee
So-Safe Specialty Products Pty. Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AUPM6807A external-priority patent/AUPM680794A0/en
Priority claimed from AUPM7148A external-priority patent/AUPM714894A0/en
Priority claimed from AUPM7326A external-priority patent/AUPM732694A0/en
Priority claimed from AUPM7663A external-priority patent/AUPM766394A0/en
Priority claimed from AUPM8111A external-priority patent/AUPM811194A0/en
Priority claimed from AUPM8409A external-priority patent/AUPM840994A0/en
Application filed by So-Safe Specialty Products Pty. Ltd. filed Critical So-Safe Specialty Products Pty. Ltd.
Priority to AU29175/95A priority Critical patent/AU2917595A/en
Publication of WO1996002624A1 publication Critical patent/WO1996002624A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20—Halogens; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/004—Surface-active compounds containing F
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions

Definitions

  • This invention relates to a a cleaning composition, a cleaning kit, and methods for using the composition and kit as well as a stabilised oxidising agent in a solvent, and method of preparing a stabilised oxidising agent in a solvent.
  • Objects of the Invention are to provide a cleaning composition, a cleaning kit, and methods for using the composition and kit as well as a stabilised oxidising agent in a solvent, and method of preparing a stabilised oxidising agent in a solvent.
  • cleaning composition comprising a first component comprising an enhancing amount of an enhancing agent to enhance the oxidising ability of an oxidising agent; together with a second component comprising an oxidising amount of the oxidising agent, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent.
  • the cleaning composition further comprises a surfactant that is substantially stable in said cleaning composition and/or a stabilising agent to substantially stabilise the oxidising agent in said cleaning composition.
  • a surfactant that is substantially stable in said cleaning composition and/or a stabilising agent to substantially stabilise the oxidising agent in said cleaning composition.
  • free chlorine is not produced in the cleamng composition.
  • the enhancing agent discourages the re-establishment of microorganisms on a surface or in a liquid cleaned with said cleaning composition.
  • the cleaning composition comprises a solvent selected from the group consisting of water and high purity water.
  • the enhancing agent is an aqueous soluble alkaline earth metal halide salt and the oxidising agent is a peroxide compound and the enhancing agent is calcium chloride and the oxidising agent is hydrogen peroxide.
  • Another form of the invention is a method of cleaning/treating a surface or an aqueous liquid comprising: applying to the surface or to the aqueous liquid an effective cleaning/treating amount of the cleaning composition of the invention.
  • Another form of the invention is a method of killing a microorganism on a surface or in an aqueous liquid comprising: applying to the surface or to the aqueous liquid an effective antimicrobial amount of the cleaning composition of the invention.
  • Another form of the invention is a method of cleaning/bleaching a surface selected from a stained surface, a concrete surface, a brick surface, and a grout surface, said method comprising: applying to the surface an effective cleaning/bleaching amount of the cleaning composition of the invention; leaving the cleaning composition on the surface for a time sufficient to substantially clean/bleach the surface.
  • Another form of the invention is a method of cleaning/treating a human or animal mouth, comprising: an effective cleaning/ treating amount of the cleaning composition of the invention.
  • Another form of the invention is a method of cleaning a water in a swimming pool comprising: applying to the swimming pool water an effective cleaning/treating amount of the cleaning composition of the invention.
  • Another form of the invention is a method of cleaning human or animal skin or treating human or animal skin requiring treatment for a preventable or treatable condition, comprising: applying to the skin an effective cleaning/treating amount of the cleaning composition of the invention.
  • a two-component cleaning kit comprising: a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent; and a second component comprising an oxidising agent, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent.
  • a two-component cleaning kit for cleaning a surface or an aqueous liquid comprising: a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface or the aqueous liquid; and a second component comprising an oxidising agent to oxidise organic matter on or in the surface or the aqueous liquid, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent.
  • a cleaning composition for cleaning a surface or an aqueous liquid comprising: a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface or the aqueous liquid together with a second component comprising an oxidising agent to oxidise organic matter on or in the surface or the aqueous liquid, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent.
  • a one-component cleaning kit for cleaning a surface or an aqueous liquid comprising a mixture of: a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface or the aqueous liquid; a surfactant that is substantially stable in an oxidising agent solution; a second component comprising an oxidising agent to oxidise organic matter on or in the surface or the aqueous liquid, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and a stabilising agent to stabilise the oxidising agent.
  • a method of cleaning/ treating a surface or an aqueous liquid comprising: applying to the surface or the aqueous liquid a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface; applying to the surface or the aqueous liquid a second component comprising an oxidising agent to oxidise organic matter on or in the surface, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the surface or the aqueous liquid.
  • a method of killing a microorganism on a surface or in an aqueous liquid comprising: applying to the surface or the aqueous liquid a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface; applying to the surface or the aqueous liquid a second component comprising an oxidising agent to oxidise and kill the microorganism on or in the surface, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the surface or the aqueous liquid.
  • the enhancing agent wets the surface.
  • the cleaning kit or cleaning composition of the invention may be exemplified in the following way:
  • Enhancing agent + a cleaning additive A, - B,
  • the first and second components are generally left on the surface for a time sufficient to effectively clean/treat the surface and/or kill microorganisms on the surface.
  • the methods of the invention may include: rinsing the surface after the first and second components have been left on the surface for a time sufficient to effectively clean the surface and/or kill microorganisms on the surface.
  • the surface is rinsed with water or an aqueous based solution (which is typically in the temperature range 5-100°C.
  • aqueous liquid examples include swimming pool water, water in a toilet bowl, water in an aqueous based air conditioning system, water in a drain, bathwater, non drinking water and washing water, for example.
  • the cleaning additive or mixture of cleaning additives may be added separately to the cleaning kit/composition of the invention.
  • the cleaning additive(s) is typically at least one of known additives that can be used in cleaning formulations.
  • the first component may be separate from the second component or as already mentioned the kit may be in the form of a composition comprising the first and second components.
  • the kit When the kit is in the form of a composition comprising the first and second components it optionally also includes a stabilising agent.
  • the first component is applied to the surface as a warm aqueous solution, typically 25-100°C, and the second component is applied to the surface when covered by the warm first component.
  • the first and second components may have a pH in the range of 0.5 to 10.
  • an acid solution for example, H2SO 4 or HCl
  • an acidic buffer may be added to the first component.
  • an alkaline solution for example, sodium hydroxide, potassium hydroxide
  • an alkaline buffer may be added to the second component.
  • the second component may be made acidic by the addition of an acid solution (for example, H 2 SO 4 or HCl) or an acidic buffer.
  • the second component may be made alkaline by the addition of an alkaline solution (for example, aqueous sodium hydroxide, aqueous potassium hydroxide) or an alkaline buffer.
  • Examples of the enhancing agent are calcium chloride, calcium acetate, calcium ascorbate, calcium borogluconate, calcium citrate, calcium formate, calcium gluconate, calcium nitrate, calcium methionate, calcium nitrite, calcium oxide, calcium propionate, calcium thioglycollate, calcium thiocyanate, calcium thiosulphate, calcium phosphate monobasic, calcium bisulphite, magnesium acetate, magnesium bisulphate, magnesium carbonate hydroxide, magnesium chloride, magnesium formate, magnesium potassium selenate, magnesium sulphate, magnesium benzoate, magnesium borate, magnesium citrate, magnesium citrate dibasic, magnesium lactate, magnesium mandelate, magnesium nitrate, magnesium oxalate, magnesium oxide, magnesium phosphate monobasic, magnesium salicylate, magnesium selenate, magnesium selenide, magnesium stannide, magnesium sulphite, magnesium thiocyanate, magnesium thiosulphate, magnesium sodium carbonate, sodium acetate, sodium
  • halide fluoride, chloride, bromide, or iodide, typically chloride
  • nitrate acetate, tartrate, sorbate, thiocyanate, borate, thiosulphate, citrate, stearate, ascorbate, salicylate, phosphate, pyrophosphate, pyrosulphate or sulphate) other than those mentioned above.
  • the enhancing agent chosen may have properties such that it discourages the re-establishment of microorganisms (e.g. calcium chloride).
  • the enhancing agent is used in the form of a solution, preferably an aqueous solution, typically in the range 0.1 wt% to 70wt% or v%, more typically lwt% to 50wt% or v%, based on the total weight of the solution.
  • amount of enhancing agent used is present in a range selected from the group consisting of a - b wt (based on the weight of the first and/or second components or the kit or the composition) listed in Table X below.
  • the amount of enhancing agent used in the first component is 0.01 to 99wt% or v%, based on the total weight of the first component or the total weight of the composition.
  • the enhancing agent is an aqueous calcium chloride solution of 1 to 60wt% or v% calcium chloride.
  • the amount of calcium chloride used is present in a range selected from the group consisting of a - b (wt%) listed in Table X below where a is selected from the group consisting of a value presented in the column headed "a" in Table X below at one of entries 1-26, and b is selected from the
  • the enhancing agent is an aqueous solution of calcium chloride in the range 1 to 10 wt , more typically 1 to 7.9wt% based on the weight of the first component or the total weight of the first and second components or the total weight of the kit or composition. Typically up to 7.9wt% aqueous calcium chloride is used in the
  • the aqueous enhancing agent solution is diluted by mixing the enhancing agent, preferably calcium chloride, with water having a typical temperature range of 15-100°C, preferably 25-95°C, 50-90°C, more preferably 60-80°C.
  • the first component: second component are present in the kit/composition in a
  • the oxidising agent may be a peroxygenated compound comprising -O-O- therein, typically a peroxide, such as hydrogen peroxide, zinc peroxide, benzoyl peroxide,
  • potassium peroxide sodium perborate, potassium perborate, ammonium perborate, oxone (KHSO 5 ), sodium persulphate, sodium percarbonate, potassium percarbonate, ammonium percarbonate, ammonium persulphate, potassium persulphate, t-butyl hydroperoxide, magnesium monoperoxyphthalate, sodium peroxide, urea hydrogen peroxide, magnesium peroxide, calcium peroxide, organic hydroperoxides such as tert-butyl hydroperoxide,
  • the oxidising agent is used in the form of a solution, preferably an aqueous solution, typically in the range 0.1wt% to 70wt% (note wt% may be wt/wt% or wt/vol%) or 0.1 v% to 70v% (note v% may be v% or v/wt%), more typically lwt% to
  • the solution is an aqueous solution and the oxidising agent is present in a range selected from the group consisting of a - b wt% or v% (based on the weight or volume of the first and/or second components or the kit or the composition) where a is selected from the group consisting of a value presented in the column headed "a" in Table X below at one of entries 1-26, and b is selected from the group of the values presented in the column headed "b" adjacent the corresponding "a” entry.
  • Table X is selected from the group consisting of a value presented in the column headed "a" in Table X below at one of entries 1-26, and b is selected from the group of the values presented in the column headed "b" adjacent the corresponding "a” entry.
  • the amount of oxidising agent used in the second component is 0.01 to 99wt% or v%, preferably 0.1 to 50wt% or v%, more preferably 1 to 30wt%, even more preferably 2 to 30wt% or v , based on the total weight of the second component.
  • the oxidising agent is a peroxide, more preferably the oxidising agent is hydrogen peroxide.
  • the peroxide is an aqueous solution of hydrogen peroxide in the range 1 to 20wt% or v%, more typically 2 to 15wt% or 1 to 7.9wt% or v% or is in a v% range or a wt% range as listed in Table X.
  • aqueous hydrogen peroxide is used as the oxidising agent for non human/animal use and more typically 1 to 5% v/v and even more typically 1 to 3% v/v.
  • the enhancing agent and oxidising agent are selected so that free chlorine is not produced when the enhancing and oxidising agents are mixed.
  • free chlorine is not released because chlorine is a health risk plus it has a lingering smell and it permeates plastics.
  • a surface to be cleaned with the cleaning kit/composition of the invention may be even; uneven; untreated; or treated such as painted, coated with a resistant coating, coated with a non resistant coating, coated with an inhibitive coating or other like treatments.
  • surfaces are basins, including kitchen and bathroom; kitchen, toilet and bathroom fittings including taps and faucets, toilets; bricks; quarry tiles; mortar; shading mesh and other shading cloths; shower surfaces (for example tiles and fittings such as shower heads and taps); baths; other bathroom surfaces; bathroom tiles; contact lens, roof tiles, wall tiles, brewery floors, bars, basins, sinks, walls, benches, tables and other surfaces, hotel floors, walls, benches, bars, basins, sinks, tables and other surfaces, kitchen tiles; kitchen benches, kitchen sinks, toilet bowls, fibreglass surfaces, epoxy surfaces, adhesive surfaces, painted surfaces, glass surfaces, perspex surfaces, polymer surfaces, rubber surfaces, metal surfaces, wire mesh, metal mesh, plastic mesh, lattice including wooden lattice, concrete floors and walls and other surfaces in abattoirs especially bloodied surfaces, ceiling surfaces, surfaces in drink and food preparation and service areas, laminated surfaces (eg Laminex , plastic and wooden laminates), in cooling towers including surfaces in cooling towers (in addition, oxidising agent/enhancing
  • the surface to be cleaned with the cleaning kit/composition of the invention may be even; uneven; untreated; or treated such as painted, coated with a resistant coating, coated with a non resistant coating, coated with an inhibitive coating or other like treatments.
  • surfaces are basins, including kitchen and bathroom; kitchen, toilet and bathroom fittings including taps and faucets, toilets; bricks; quarry tiles; mortar; shading mesh and other shading cloths; shower surfaces (for example tiles and fittings such as shower heads and taps); baths; other bathroom surfaces; bathroom tiles; roof tiles, wall tiles, brewery floors, bars, basins, sinks, walls, benches, tables and other surfaces, hotel floors, walls, benches, bars, basins, sinks, tables and other surfaces, kitchen tiles; kitchen benches, kitchen sinks, toilet bowls, fibreglass surfaces, epoxy surfaces, adhesive surfaces, painted surfaces, glass surfaces, perspex surfaces, polymer surfaces, rubber surfaces, metal surfaces, wire mesh, metal mesh, plastic mesh, lattice including wooden lattice, concrete floors and walls and other surfaces in abattoirs especially
  • the surface may be human, or animal tissue or other human or animal material, including skin (including inner skin in the inside of the human or animal's mouth, or outer skin), hair, coat, eye, nails, ears, teeth, and in the case of dead animals, the flesh, skin and coat of a dead animal.
  • the animal is a mammal or vertebrate such as, bird, fish or reptile.
  • the mammal or vertebrate is a bovine, human, ovine, equine, ape, caprine, Leporine, domestic fowl, feline or canine vertebrate. More typically, the vertebrate is selected from the group consisting of sheep, cattle, deer, buffaloes, swine, pigs, ducks, chickens and goats.
  • the surface may be the surface of human tissue or other human material, and then the kit/composition typically comprises a food, pharmaceutically or cosmetically acceptable composition(s) which includes at least one food, pharmaceutically or cosmetically acceptable carrier, adjuvant and/or excipient.
  • the kit/composition typically comprises food or veterinarilly acceptable composition(s) which includes at least one food or veterinarilly acceptable carrier, adjuvant and/or excipient.
  • the food, pharmaceutical or veterinary composition(s) may be in the form of elixirs(s), solution(s), gel(s), suspension(s), emulsion(s), syrup(s) or tincture(s), for example.
  • the compositions may contain food, pharmaceutically or veterinarilly acceptable sweeteners, diluents, flavourings, and preservatives and other suitable additives.
  • Suitable sweeteners include sucrose, lactose, glucose, aspartame or saccharine.
  • Suitable flavouring agents include peppermint oil, oil of wintergreen, cherry, orange or raspberry flavouring.
  • Suitable preservatives include sodium benzoate, vitamin E, alpha- tocopherol, ascorbic acid, methyl paraben, propyl paraben or sodium bisulphite.
  • the carrier or carriers will form from 5% to 99.9% by weight of the composition.
  • Oral and other invasive kits such as kits for gargles, mouth washes, nasal washes, douches, enematas, ear washes, etc are typical forms of the invention.
  • Oral kits such as gargles and mouthwashes are particularly useful for the treatment of bad breath, gum disease and gum infections, cold sores, gingivitis, moniliasis, mouth ulcers, mouth cuts and mouth lesions, as well as for cleaning and whitening teeth and removing food from gum and teeth.
  • the food, pharmaceutical, cosmetic or veterinary composition may be in the form of a gel(s), jelly(ies), tincture(s), lotion(s), solution(s), suspension(s) or emulsion(s), or pour-on formulation(s), for example.
  • the food, pharmaceutical and veterinary composition(s) may contain food or pharmaceutically acceptable binders, diluents, disintegrating agents, preservatives, lubricants, dispersing agents, suspending agents and/or emulsifying agents as exemplified above.
  • the veterinary composition may contain veterinarilly acceptable binders, diluents, disintegrating agents, preservatives, lubricants, dispersing agents, suspending agents and/or emulsifying agents as exemplified above.
  • compositions of the invention human or animal tissue or other human or animal material, may be prepared by any suitable means known in the relevant art for the preparation of compositions (such as in the art of preparing food, veterinary, cosmetic and pharmaceutical compositions) including homogenising, suspending, dissolving, emulsifying, dispersing and mixing of the enhancing agent and/or oxidising agent together with the selected excipient(s), carrier(s), adjuvant(s) and/or diluent(s).
  • Aqueous solutions or suspensions may further comprise one or more buffering agents. Suitable buffering agents include sodium acetate, sodium citrate, sodium borate or sodium tartrate, for example.
  • Liquid forms for oral and other invasive administration, or topical administration may contain, in addition to the above agents, a liquid carrier in addition to or in place of, in some instances, water.
  • a liquid carrier in addition to or in place of, in some instances, water.
  • Illustrative of food, pharmaceutically, veterinarilly or cosmetically (for external use) acceptable carriers or diluents include lower alkanols, demineralized or distilled water; saline solution; for example ethanol, propanol, isopropanol, Ringer's solution, isotonic salt solution, 5% dextrose in water, buffered sodium or ammonium acetate solution, 1,3-butanediol, propylene glycol, polyethylene glycols acetone or mixtures thereof.
  • a suitable treatment may comprise the administration of multiple doses (or a single dose).
  • the treatment will consist of simultaneously administering from one to five doses daily of the first and second components for a period sufficient to clean the surface the microorganism (which will vary depending on the patient, type of organic matter, microorganism or fungus - e.g. 7 days - 27 days, typically 10 days - 21 days), and then used from time to time thereafter (e.g. once a day or once every three days or once a week, for example).
  • the cleaning kit/composition of the invention may comprise one or more known cleaning agents/additives such as a surfactant, an antimicrobial agent; enzyme(s); an antifungal agent; a lubricant; a preservative; a water softener; a colorant; a propellant (for aerosols); a perfume or fragrance; a defoamer; detergent builder; a disinfectant and/or a sanitiser; a surface-active agent; dispersing agent; or a thickener or gelling agent.
  • cleaning agents/additives such as a surfactant, an antimicrobial agent; enzyme(s); an antifungal agent; a lubricant; a preservative; a water softener; a colorant; a propellant (for aerosols); a perfume or fragrance; a defoamer; detergent builder; a disinfectant and/or a sanitiser; a surface-active agent; dispersing agent; or a thickener
  • the amount of additive typically used in the cleaning kit/composition of the invention is 0.01 to 90wt or v%, more typically 0.1 to 15wt% or v%, even more typically 0.5 to 10wt% or v%, and even more typically 0.5 to 5wt% or v%, based on the total weight or volume of the cleaning kit/composition.
  • the additive(s) is/are in the form of a solution, preferably an aqueous solution.
  • the additive(s) may be added to the cleaning kit/composition of the invention as a separate component. Alternatively, the additive(s) may be added to the first component and/or the second component.
  • surfactants are nonionic, cationic, anionic or amphoteric surfactants especially those that are compatible with, i.e. are not oxidised by, the oxidising agent. Mixtures of surfactants may be used but some surfactants are incompatible, such as anionic and cationic surfactants.
  • non-ionic surfactants are fatty acid esters of polyoxyethylene sorbitan such as polyoxyethylene sorbitan trioleate; tributylphenoxypolyethyleneethanol; polyglycol ether derivatives of aliphatic or cycloaliphatic alcohols having approximately 3 to 30 glycol ether groups and approximately 8 to 20 carbon atoms in the (aliphatic) hydrocarbon moiety; saturated or unsaturated fatty acids and alkylphenols having approximately 6 to 18 carbon atoms in the alkyl moiety of the alkylphenols; water-soluble adducts of polyethylene oxide with ethylenediaminopolypropylene glycol, polypropylene glycol, or alkylpolypropylene glycol having approximately 1 to 10 carbon atoms in the alkyl chain, having approximately 20 to 250 ethylene glycol ether groups and approximately 10 to 100 propylene glycol ether groups in the usual ratio of 1 to 5 ethylene glycol moiety: propylene glycol moiety; octyl
  • Merpol A is an example of a surfactant that is substantially stable in an oxidising agent solution.
  • cationic surfactants are quaternary ammonium salts in the form of halides, methylsulphates or ethylsulphates which have as N-substituent at least one C 8 -C 22 alkyl radical or unsubstituted or benzyl or hydroxy-lower alkyl radicals such as stearyltrimethyl ammonium chloride.
  • anionic surfactants are water-soluble soaps or water-soluble synthetic surface active compounds.
  • the soaps are alkali metal salts, alkaline earth metal salts, unsubstituted or substituted ammonium salts of higher fatty acids (C 10 -C 22 ), such as the sodium or potassium salts of linoleic acid, palmitic, abietic or stearic acid or of natural fatty acid mixtures such as coconut oil or tallow oil, or fatty acid methyllaurin salts.
  • synthetic surfactants are sulphonated benzimidazole derivatives, alkylarylsulphonates, fatty alcohol sulphonates, or fatty alcohol sulphates.
  • Examples of sulphonated benzimidazole derivatives are 2 sulphonic acid groups and one fatty acid radical containing approximately 8 to 22 carbon atoms.
  • Examples of alkylarylsulphonates are the sodium calcium, or triethanolamine salts of dodecylbenzenesulphonic acid, dibutylnaphthalenesulphonic acid, of a condensate of naphthalenesulphonic acid and formaldehyde or the phosphate salt of the phosphoric acid ester of an adduct of p-nonylphenol with 4 to 14 moles of ethylene oxide.
  • fatty alcohol sulphates or sulphonates are unsubstituted or substituted ammonium salts such as C 8 -C 22 alkyl radical including the alkyl moiety of acyl radicals such as the calcium or sodium salt of lignosulphonic acid, of a mixture of fatty alcohol sulphates from naturally occurring fatty acids, of dodecylsulphate, alkaline earth metal salts or alkali metal salts or the salts of sulphated and sulphonated fatty alcohol/ethylene oxide adducts.
  • acyl radicals such as the calcium or sodium salt of lignosulphonic acid, of a mixture of fatty alcohol sulphates from naturally occurring fatty acids, of dodecylsulphate, alkaline earth metal salts or alkali metal salts or the salts of sulphated and sulphonated fatty alcohol/ethylene oxide adducts.
  • amphoteric surfactants are the aminocarboxylic and aminosulphonic acids and salts thereof such as alkyl and alkylamido betaines such as cocamidopropyl betaine; alkali metal 3-(dodecylamino)propionate and alkali metal 3-(dodecylamino)propane-l- sulphonate; higher fatty alkanolamides having approximately 12 to 16 carbon atoms in the acyl group which is reacted with a lower (1 to 3 carbon atoms) mono- or dialkanolamine such as lauric monoethanolamide or cocodiethanolamide.
  • surfactants are described in "Encyclopedia of Chemical Technology",
  • the amount of surfactant used in the cleaning kit/composition of the invention is typically 0.01 to 90wt% or v%, based on the total weight or volume of the cleaning kit or cleaning composition, more typically 0.1 to 50wt%, more typically 0.1 to 10wt% or v% is used in the cleaning kit/composition.
  • the amount of surfactant used is present in a range selected from the group consisting of a - b (wt% or v%) listed in Table X below where a is selected from the group consisting of a value presented in the column headed "a" in Table X below at one of entries 1-26, and b is selected from the group of the values presented in the column headed "b" adjacent the corresponding "a" entry.
  • the surfactant is used in the form of a solution, preferably an aqueous solution.
  • the surfactant is mixed with the first component or is included in the whole of the cleaning composition.
  • a non ionic surfactant is used as the surfactant in the cleaning kit/composition.
  • the nonionic surfactant is a fluorosurfactant such as Merpol A (a registered trade mark of Du Pont and obtainable from Du Pont, 1007 Market Street, Wilmington, DE 19898, United States of America).
  • the amount of Merpol A used in the cleaning kit/composition of the invention is 0.1wt% or v%, based on the total weight or volume of the cleaning kit/composition.
  • antimicrobial agents examples include potassium permanganate, potassium dichromate, cobaltous sulphate, zinc sulphate, silver, silver nitrate, strongly acidic pH, strongly alkaline pH, l-phenoxyphenyl-l-triazolylmethyl-carbinols, manganous sulphate, silver 23 oxide, colloidal silver iodide, phenol, paraben, chlorobutamol, sorbic acid, Quat 50 or mixtures thereof.
  • preservatives examples include sodium benzoate, glycerine, formalin, or lower carboxylic acids.
  • an additive is added to facilitate uptake of the preservative.
  • the usual additives are acetone, dioxane, glyme, diglyme, triglyme, or l-methyl-2-pyrrolidone.
  • the additives are generally water soluble/miscible solvents and further examples may be found below.
  • water softeners are polyphosphates such as sodium tripolyphosphate or sodium hexametaphosphate; aminocarboxylic acids such as ethylenediaminetetraacetic acid; 1,3-diketones such as acetylacetone; hydroxycarboxylic acids such as citric acid, tartaric acid or gluconic acid; polyamines such as ethylenediamine; amino alcohols such as triethanolamine.
  • polyphosphates such as sodium tripolyphosphate or sodium hexametaphosphate
  • aminocarboxylic acids such as ethylenediaminetetraacetic acid
  • 1,3-diketones such as acetylacetone
  • hydroxycarboxylic acids such as citric acid, tartaric acid or gluconic acid
  • polyamines such as ethylenediamine
  • amino alcohols such as triethanolamine.
  • perfumes or fragrances are naturally occurring oils for example lemon grass oil, clove leaf oil, ambergris, bergamot oil, benzoin oil, castoreum, civet, eucalyptus, geranium oil, jasmine absolute, lavender, myrrh, musk tonquin, mimosa, rose oil, rosemary oil, or sandal wood oil or synthetic aroma chemicals for example citronellol, benzyl acetate, geraniol, linalool, musk ambrette, or terpinyl acetate. Further examples of perfumes or fragrances are described in "The Perfume Handbook", Nigel Groom, 1st edition, Chapman & Hall 1992, the contents of which are incorporated herein by cross reference.
  • defoamers control foam formation.
  • defoamers are fatty amides, fatty acid soaps, fatty alcohols, ethoxylates, or other like defoamers.
  • detergent builders are condensed phosphates, trisodium nitrilotriacetate, polymaleates, polymethacrylates, polyacrylates or other like detergent builders.
  • disinfectants and/or sanitisers include aliphatic alcohols such as ethyl alcohol, N-chloramines such as sodium N-chloro-p-toluenesulphonamide, N,N-dichloro-p- toluenesulphonamide, N,N-dichloro-p-carboxybenzenesulphonamide, iodine and organic iodine compounds, and other like disinfectants and/or sanitisers.
  • a surface-active agent is generally a surfactant and examples of surfactants are found above.
  • dispersing agents are condensed phosphates; or organic polymers such as organic phosphonates, polyphosphates, polyacrylates, sulphonated polymers, polymethacrylates, polymaleates.
  • thickeners or gelling agents are soap gels, gums, such as Xanthan gum or Guar gum, starches such as furcellaran, hypnean, dextran, or tamarind, proteins, alginates, pectic gels such as sodium pectate, alkylcellulose hydrophilic colloids, for example, hydroxypropylmethyl cellulose, sodium carboxymethyl cellulose, hydroxymethylcellulose, ethyl succinylated Cellulose, succinylated zein, or carboxymethylcellulose, polymers such as sodium poly (styrene sulphonate) with poly (vinyl methyl pyridinium) chloride, sodium poly (styrene sulphonate) with poly (vinyl benzyl trimethyl ammonium) chloride, strongly acidic polyanion with strongly basic polycation, vinyl acetate homo
  • thickeners or gelling agents are aluminium mono-, di-, and tristearates, aluminium palmitate, aluminium octanoate, magnesium aluminium silicate, and sodium fluorosilicate. It may, in some instances, be desirable to use various thickeners or gelling agents in the first and/or second component either as a mixture or in layers. Thickeners or gelling agents which have been found to be useful for such purposes include sodium alginate, potassium alginate, polygalacturonic acid and a mixture of gelatin and sodium alginate. Other suitable thickeners or gelling agents include, but are not limited to, alginate with gelatin.
  • a sodium alginate solution for example, will form a gel when a complexing agent is added.
  • Calcium salts such as calcium nitrate and calcium hydroxide are useful complexing agents.
  • Copper salts particularly copper sulphate), chitosan (a deacylated chitin), potassium chloride, ammonium chloride, lanthanum chloride, ferric chloride, cobaltous chloride, sodium tetraborate, and other compounds generally with multivalent cations also are useful complexing agents.
  • the cleaning kit/composition of the invention may further comprise a corrosion inhibitor (which may be included in Part A or Part B or both Part A and Part B or the combined Part A/Part B composition).
  • a corrosion inhibitor may be selected from inorganic inhibitors, organic inhibitors or vapour-phase inhibitors.
  • Inorganic inhibitors may be classified as functioning with or without oxygen. Examples of inhibitors functioning without oxygen include chromate and nitrate, examples of inhibitors requiring oxygen include sodium phosphates and borates. Examples of inorganic inhibitors include citric acid, sodium citrate, sodium nitrate, ammonia and the like.
  • organic inhibitors include aniline, amino-polyphosphonates including nitrilotris phosphate
  • the Dequest range generally, and, in particular, including Dequest
  • Briquest range generally including BRIQUEST 221-60A, (2- Hydroxyethyliminobis(methylenephosphonic), HOCH 2 CH 2 N(CH 2 PO 3 H 2 ) 2 , BRIQUEST 231-A, iso-Propyliminobis-(methylenephosphonic) , i-PrN(CH 2 PO 3 H 2 ) 2 , BRIQUEST 2N31-A, n-Propyliminobis-(methylene ⁇ hos ⁇ honic), n-PrN(CH 2 PO 3 H 2 ) 2 , BRIQUEST 2N41-A, n-Butyliminobis-(methylenephosphonic), n-BuN(CH 2 PO 3 H 2 ) 2 , BRIQUEST 2N61-A, n-Hexyliminobis-(methylenephosphonic), n-HexylN(CH 2 PO 3 H 2 ) 2 , BRIQUEST 2N71-A, n-Heptykminobis
  • BRIQUEST 543-45 AS Diethylenetriamine- pentakis (methylenephosphonic), BRIQUEST 664-A, Triethylenetetramine- hexakis (methylenephosphonic), C 12 H 36 N 4 O 18 P 6 , BRIQUEST 785-A, Tetraethylenepentamine- heptakis (methylenephosphonic), C l5 H 44 N 5 O 21 P 7 , BRIQUEST 8106-A, Pentaethylenehexamine- octakis (methylenephosphonic), C 1 gH 52 N 6 O 24 Pg, as well as the sodium, potassium and ammonium salts of all these acids, aminophosphonate acids such as ethylene diamine tetra(methylene phosphonic acid), aminotri(methylene phosphonic acid), diethylenetriamine penta(methylene phosphonic acid), 1
  • Vapour-phase inhibitors are usually volatile compounds containing one or more functional groups capable of inhibiting corrosion.
  • these inhibitors include amine salts with nitrous or chromic acids; amine salts with carbonic, carbamic, acetic, or substituted or unsubstituted benzoic acids; organic esters of nitrous, phthalic, or carbonic acids; primary, secondary, or tertiary aliphatic amines; cycloaliphatic and aromatic amines; polymethylene amines; mixtures of nitrites with urea, urotropine, and ethanolamine; nitrobenzene and 1-nitronaphthalene.
  • Preferred corrosion inhibitors include nitrilotris phosphate, the Briquest range generally, the Dequest range generally, and in particular, Dequest 2000, 2010 or 2006, sodium gluconate, benzotriazole, or mixtures thereof. Some corrosion inhibitors may also act as stabilising agents. Typically a mixture of corrosive inhibitors is used.
  • the corrosion inhibitor is included in the solution of the first and/or second component or in the cleaning composition in an amount of 0.03 - 15wt% or v%, 0.05 - 10wt% or v%, more typically 0.1 - 5wt% or v% and even more typically 1 - 5wt% or v% and yet even more typically 1 - 3wt% or v% based on the total wt or v of the first and/or second component or the wt or v of the total composition.
  • the amount of corrosion inhibitor used in the cleaning kit/composition of the invention is 0.1-8 wt% or v% based on the total wt or v of the total composition.
  • the cleaning kit/composition of the invention may further comprise a stabiliser in the second component.
  • the stabiliser is included in the solution of the second component in an amount of 0.03 - 15wt% or v%, 0.05 - 10wt% or v%, more typically 0.1 - 5wt% or v% and even more typically 1 - 5wt% or v% and yet even more typically 1
  • the amount of stabiliser used is present in a range selected from the group consisting of a - b (wt% or v% based on the weight or volume of the first and/or second components or the kit or the cleaning composition) listed in Table X above where a is selected from the group consisting of a value presented in the column headed
  • stabilisers are silicates (including calcium silicate, magnesium silicate, sodium silicate, potassium silicate and ammonium silicate), water- soluble phosphates such as polyphosphates including tri-polyphosphate and sodium ortho- and pyro-phosphates, EDTA, tartaric acid, sodium pyrophosphate, nitrilotriacetates (NT A) including nitriloacetic acid, l-hydroxyethane-l, l-diphosphonic acid, amino-tris- (methylenephosphonic acid), gluconic acid, sodium gluconate, phosphonobutane tricarboxylic acid, ethylenediamine tetrakis-(methylenephosphonic acid), polycarboxylates, citrates, amino-polyphosphonates including nitrilotris phosphate (N(CH 2 PO 3 H 2 ) 3 ), the Dequest range generally, and, in particular, including Dequest 2000, 2010, 2016D, 2041, 2046, 20
  • BRIQUEST 543-45 AS, Diethylenetriamine- pentakis (methylenephosphonic),
  • Pentaethylenehexamine- octakis methylenephosphonic
  • C ⁇ 8 H 52 N 6 O 24 Pg as well as the sodium, potassium and ammonium salts of all these acids
  • aminophosphonate acids such as ethylene diamine tetra(methylene phosphonic acid), aminotri(methylene phosphonic acid), diethylenetriamine penta(methylene phosphonic acid), 1 -hydroxy ethylidene (1,1- diphosphonic acid), ethylene diamine tetra (methylene phosphonic acid), heaxamethylene diamine tetra (methylene phosphonic acid), diethylene triamine penta (methylene phosphonic acid), as well as the sodium, potassium and ammonium salts of all these acids), the salts of ethylenediamine tetraacetic acid (EDTA) such as ethylenediaminetetra ⁇ acetic acid disodium salt, ethylenediaminetetraacetic acid diammonium salt, ethylenediamine, ethylened
  • NTA nitrilotriacetic acid
  • stabilising agents such as triethanolamine, diethanolamine, monoethanolamine, organic carboxylic acid stabilising agents, organic aminopolycarboxylic acids, organic phosphoric acid stabling agents, inorganic phosphoric acid stabilising agents, polyhydroxy compounds, phenanthroline, ethylenediamine diorthohydroxyphenylacetic acid, diamin
  • nitrilotris phosphate eg Dequest 2000 or
  • the first and second components are generally aqueous solutions and it is particularly preferred to use high purity water as the solvent.
  • a water soluble/miscible solvent may be added to the surface prior to, at the same time as or after addition of the first and second components to the surface.
  • the solvent may be in the form of a liquid or may be in the form of a gel.
  • the solutions of the first and second components may optionally include a water soluble/miscible solvent.
  • the amount of solvent used in the first or second component is typically 99.9 to 30wt% or v%, more typically 0-35 wt% or v%, even more typically 0.5-10wt or v%, even more typically 0.5- 5wt or v%, preferably 99 to 60wt%, based on the total weight of the first or second component, respectively or the total wt or v of the composition.
  • solvents examples include: hydroxy compounds such as propanol, ethanol, methanol, isopropanol, n-butanol, sec-butanol, pentanol, cyclohexanol, hexanol, heptanol, 2-octanol, diacetone alcohol, polyvinyl alcohol, 2-ethyl hexanol, benzyl alcohol, phenol, allyl alcohol, 2-ethyl-l,3- hexanediol, bis(2-butoxyethyl) ether, butoxyethoxypropanol, propylene glycol, hexylene glycol, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol, ethyl ether, propyl ether; carbonyls such as acetone, 2-butanone, cyclopentanone, 3-pentanone,
  • R is H or a linear or branched alkyl having from 1 - 12 carbon atoms
  • R* is a linear or branched alkyl having from 1 - 12 carbon atoms, dimethyl ethanolamine, diisopropanolamine, monoethanolamine; other solvents such as 2-methoxyethanol, 2-butoxyethanol, 2-(2- methoxyethoxy)ethanol.
  • water soluble/miscible solvents are described in "Organic Solvents Physical Properties and Methods of Purification", John A. Riddick, William B. Bunger and Theodore K. Sakano, fourth edition, Volume II, John Wiley & Sons 1986, “Chemical Safety Data Sheets", David Walsh (editor), Volume I, The Royal Society of Chemistry 1989, and "Industrial Water-Based Paint Formulations", Ernest W. Flick, Noyes Publications, 1988, the contents of which are incorporated herein by cross reference.
  • water is used as the solvent of the first and second components and monoethanolamine is used as a solvent with Merpol A.
  • Preferably purified water is used as the solvent of the first and second components.
  • purified water examples are deionised water, distilled water, filtered water and other like purified waters.
  • the water used as the solvent of the first and second components is water which has been purified by degassing, boiling and distilling and cooling and condensing the water vapour.
  • the water is first degassed in a degassing chamber and then boiled at 43°C in a vacuum and the water vapour is then cooled.
  • the quality of purified water is such that it has a conductivity ⁇ S/cm at 35°C of ⁇ 2.0, the total dissolved solids are ⁇ lppm, the amount of sodium ions is ⁇ 0.1mg/L, the amount of calcium ions is ⁇ 0.01mg/L, the amount of magnesium ions is ⁇ 0.05mg/L and the amount of ammonium ions is ⁇ 0.2mg/L.
  • Typical cleaning compositions include:
  • a method of cleaning and/or bleaching a stained surface comprising: applying to the surface a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface; applying to the surface a second component comprising an oxidising agent to oxidise and bleach the stain on or in the surface, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the surface.
  • the first and second components are generally left on the stained surface for a time sufficient to effectively clean and/or bleach the stained surface.
  • a method of cleaning a concrete surface comprising: applying to the surface a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface; applying to the surface a second component comprising an oxidising agent to oxidise organic matter on or in the surface, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the surface.
  • the first and second components are generally left on the concrete surface for a time sufficient to effectively clean the concrete surface.
  • a method of cleaning a brick surface comprising: applying to the surface a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface; applying to the surface a second component comprising an oxidising agent to oxidise organic matter on or in the surface, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the surface.
  • the first and second components are generally left on the brick surface for a time sufficient to effectively clean the brick surface.
  • a method of cleaning grout comprising: applying to the grout a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the grout; applying to the grout a second component comprising an oxidising agent to oxidise organic matter on or in the grout, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the grout.
  • the first and second components are generally left on the grout for a time sufficient to effectively clean the grout.
  • a method of cleaning a human or animal mouth comprising: applying to the mouth a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the mouth; applying to the mouth a second component comprising an oxidising agent to oxidise organic matter on or in the mouth, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the mouth.
  • the first and second components are generally left in the mouth for a time sufficient to effectively clean the mouth.
  • a method of treating a human or animal mouth or treating a mouth requiring treatment for a preventable or treatable condition comprising: applying to the mouth a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the mouth; applying to the mouth a second component comprising an oxidising agent to oxidise organic matter on or in the mouth, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the mouth.
  • the first and second components are generally left in the mouth for a time sufficient to effectively treat the mouth.
  • a method of cleaning a water in a swimming pool comprising: applying to the swimming pool water a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the swimming pool water; applying to the swimming pool water a second component comprising an oxidising agent to oxidise organic matter in the swimming pool water, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the swimming pool water.
  • a method of a cleaning human or animal skin or treating human or animal skin requiring treatment for a preventable or treatable condition comprising: applying to the skin a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the skin; applying to the skin a second component comprising an oxidising agent to oxidise organic matter on or in the skin, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the first and second components prior to and/or after applying the first and second components to the skin.
  • the first and second components are generally left on the skin for a time sufficient to effectively clean/treat the skin.
  • a method of cleaning and/or bleaching a stained surface comprising: applying to the surface, optionally a dry surface, a solvent to dissolve the stain on the surface; applying to the surface a first component comprising an enhancing agent to enhance the oxidising ability of an oxidising agent applied to the surface; applying to the surface a second component comprising an oxidising agent to oxidise and bleach the stain on or in the surface, said oxidising agent being one whose oxidising ability is capable of being enhanced by said enhancing agent; and optionally mixing the solvent and the first and second components prior to and/or after applying the first and second components to the surface.
  • the solvent, first and second components are generally scrubbed separately or together on the surface and are typically left on the stained surface for a time sufficient to effectively clean and/or bleach the stained surface.
  • the solvent is applied first as a liquid or gel to a dry surface together with a surfactant (0.05-50wt%, more typically .5-5wt% of the solvent) and scrubbed on the surface and left there for a time sufficient to dissolve the stain.
  • the solvent may be left on the surface or rinsed therefrom and the first and second components are then added to the surface, scrubbed into the surface and left on the stained surface for a time sufficient to effectively clean and/or bleach the stained surface.
  • the surface is then rinsed typically with cold or hot water.
  • the first component and the second component are applied to the surface or the aqueous liquid simultaneously or in succession with the first component being applied to the surface or the aqueous liquid first, followed by the application of the second component.
  • the second component may be applied to the surface or the aqueous liquid first, followed by the application of the first component.
  • the first component is applied to the surface or the aqueous liquid first, followed by the application of the second component.
  • the first component is applied to the surface as a warm aqueous solution, typically 25-100°C, and the second component is applied to the surface when covered by the warm first component.
  • the first and second components are mixed.
  • the components may be mixed prior to application, so that only one application step takes place.
  • the components may be mixed after they have been applied to the surface. In this case, mixing usually occurs by scrubbing the components on or into the surface.
  • mixing usually occurs by scrubbing the components on or into the surface.
  • equal volumes of the first and second components are used in the cleaning kit/composition of the invention.
  • the first component is first applied to the surface.
  • the first component may be applied by spraying, pouring, painting, soaking, layering, or dipping the surface in the first component.
  • the first component may be prepared as a solution, paste, cream, gel, aerosol or other like preparation.
  • the first component is prepared as an aqueous solution.
  • the first component is diluted with water having a temperature range of 5-100°C, typically 25-100 c C, preferably 50-90°C, more preferably 60-80°C.
  • the first component is typically poured on the surface when warm (30-100°C).
  • the second component is applied to the surface by spraying, pouring, painting, layering, or dipping the surface in the second component.
  • the second component may be prepared as a solution, paste, cream, gel, aerosol or other like preparation.
  • the second component is prepared as an aqueous solution.
  • the second component is diluted with purified water. The second component is typically applied whilst the surface is covered with the warm first component.
  • the first and second components are mixed together by scrubbing the surface for a time sufficient to effect mixing. Generally scrubbing takes place for 3 seconds to 24 hours, typically 5 to 20 minutes, preferably 5 to 10 minutes and even more preferably 10 seconds to 1 minute.
  • the surface may be allowed to dry to discourage the re- establishment of microorganisms. Alternatively, the surface may be rinsed with water to remove excess first component, second component and any debris resulting from the cleansing action of the first and second components.
  • the first and second components may be allowed to stand prior to scrubbing or after scrubbing to penetrate and clean the surface, especially if the surface is porous. Generally the time is chosen such that it is sufficient to clean the surface.
  • the first and second components may be allowed to stand on the surface for 0.1 minute to 24 hours, typically
  • the additive(s) may be added before or after application of the first component, or before or after application of the second component. Alternatively the additive(s) may be added at the same time as the first and/or the second component. Generally the additive(s) is applied to the surface by spraying, pouring, painting, layering, or dipping the surface in the additive(s). Generally the additive(s) may be prepared as a solution, paste, cream, gel, aerosol or other like preparation. Usually the additive(s) is mixed with the first and/or second component before application, alternatively the additive(s) may be scrubbed on or into the surface with the first and/or second component.
  • first component and the second component may be prepared in situ or may be stored in a cool, ventilated area for several months to years and may be stored as a concentrated solution.
  • components A to A 3 and components B to B 3 may be dispensed separately from separate containers or dispensed from an integral multi-compartmented container.
  • dispensers are posi-pour measures, Emu measures, optic measures, straight through pourers such as speed pourers or tubes or other like dispensers which can deliver a predetermined amount of components A to A 3 and components B to B 3 .
  • the dispenser may or may not be integral with the container.
  • the cleaning kit/composition of the invention cleans any organic matter for example microorganisms such as algae, fungus, bacteria, yeast, lichen, moss, protozoa; excreta; food; vegetation; or other like organic matter or microorganisms or mixtures thereof.
  • microorganisms such as algae, fungus, bacteria, yeast, lichen, moss, protozoa; excreta; food; vegetation; or other like organic matter or microorganisms or mixtures thereof.
  • the stains bleached by the cleaning kit/composition of the invention are stains caused by dyes, tints, pigments, vegetable matter, excreta or other like stains or mixtures thereof.
  • a coating may be applied to the surface.
  • coatings are a reinforcing pigment such as sodium silicate, magnesium silicate, aluminium silicate, barium sulphate silica, potassium-aluminium silicate; a colour-carrying pigment coating such as toluidine red, iron oxide red, monastral red, dmium red, iron oxide, molybdenum orange, yellow iron oxide, nickel titanate, chrome yellow, phthalocyanine green, chrome oxide, phthalocyanine blue, lamp black, carbon black, titanium dioxide, aluminium flake, zinc dust, stainless-steel flake, lead flake; inhibitive pigment coating such as zinc powder, red lead, lead chromate, barium chromate, basic zinc chromate, strontium chromate, zinc chromate; vinyl coating such as vinyl chloride-vinyl acetate copolymer coating; chlorinated rubber coating; epoxy coating; amine-cured epoxy; poly
  • An advantage of the cleaning kit composition of the invention is that excesses of the oxidising agent (or hydrogen peroxide) are likely to be readily decomposed by sunlight and atmospheric exposure, or in contact with surrounding soil, leaving a residue of water and enhancing agent (or calcium chloride).
  • Another advantage is that excess calcium chloride absorbed into the surface is likely to lose water to the air until coming into balance with the hygroscopic nature of calcium chloride, leaving a concentrated solution soaked in to the surface. This will tend to discourage the re-establishment of microorganisms. This effect may be minimised if the surface is later cleaned by high pressure water to remove organic residues.
  • Further advantages are that the enhancing agent and oxidising agent are prepared in situ and excess will decompose in a relatively short time.
  • the enhancing agent and oxidising agent are not dangerous goods and final residues are not harmful to the environment, provided the surfactant used is thoroughly biodegradable. Irritating products are not released to the atmosphere, for example, a sodium hypochlorite solution is currently used to clean a concrete surface.
  • the cleaning kit/composition of the invention is a lot more pleasant to use than sodium hypochlorite solution.
  • Another advantage of the cleaning kit/composition of the invention is that it can be safely used in beer cellars because no chlorine is released.
  • a further advantage of the cleaning kit/composition of the invention is that the combination of the warmed calcium chloride solution and the hydrogen peroxide enhances the disinfecting ability of the cleaning kit.
  • a stabilised oxidising agent in a solvent comprising: an oxidising agent dissolved in the solvent; and an effective stabilising amount of a stabilising agent dissolved in the solvent to stabilise the oxidising agent.
  • a stabilised oxidising agent in a solvent comprising: dissolving an oxidising agent in the solvent; and dissolving an effective stabilising amount of a stabilising agent in the solvent to stabilise the oxidising agent.
  • the oxidising agent may be dissolved in the solvent prior to, at the same time or after the stabilising agent is dissolved in the solvent.
  • the stabilising agent comprises at least one amino-polyphosphonate.
  • the amino- polyphosphonate may be, for instance, nitrilotris phosphate (N(CH 2 PO 3 H 2 ) 3 ) and in particular, the Briquest range generally, the Dequest range generally, and, in particular,
  • the solvent comprises water, especially highly purified water including high purity deionised and distilled water and in particular high purity water containing low levels of metal ions.
  • the oxidising agent is a peroxide such as hydrogen peroxide, zinc peroxide, benzoyl peroxide, potassium peroxide, t-butyl hydroperoxide, sodium peroxide, urea hydrogen peroxide, magnesium peroxide, or calcium peroxide.
  • the peroxide is hydrogen peroxide.
  • oxidising agent is in the range
  • oxidising agent:solvent is 0.005: 1 to 0.75: 1, typically 0.01:1 to 0.35:1, more typically 0.02:1 to 0.05:1, and yet even more typically
  • stabilising agent:solvent is 0.001: 1 to 0.50: 1, typically 0.003: 1 to 0.25: 1, more typically 0.005: 1 to 0.05: 1, and yet even more typically
  • a cleaning kit/composition for cleaning a surface generally comprises 50wt% of a first component, based on the total weight of the cleaning kit/composition and 50wt% or v% of a second component, based on the total weight of the cleaning kit/composition.
  • 0.1-10wt% or v% more typically
  • 0.5-5wt% or v% and even more typically lwt% or ⁇ % fluorosurfactant, based on the total weight of the cleaning kit/composition is preferably added to the first component.
  • the preferred fluorosurfactant is Merpol A.
  • the calcium chloride solution contains 0.1wt% Merpol A.
  • 0.5 to lwt% stabiliser, based on the total weight of the second component is preferably added to the second component.
  • the preferred stabiliser is Dequest 2000 or Dequest 2006.
  • the hydrogen peroxide solution contains 0.5 to lwt% Dequest 2000.
  • the pH of the first and second components ranges from 2 to 13, more typically 2.0 to 9.0.
  • Approximately equal volumes of the calcium chloride and hydrogen peroxide solutions are used.
  • Use of calcium chloride is particularly advantageous as it is a hygroscopic material. Thus large areas of concrete or cement, for example, can be covered on a hot day without drying out prior to application of the hydrogen peroxide aqueous solution.
  • an aqueous solution of 50wt% calcium chloride is diluted to 10 to 25wt%, preferably 20wt%, based on the total weight of the first component.
  • the calcium chloride solution is preferably diluted with water having a temperature range of 35-90°C.
  • the diluted aqueous calcium chloride solution is applied to the surface by spraying or pouring it onto the surface.
  • the diluted calcium chloride solution is sprayed or poured whilst still warm (30-90°C).
  • An aqueous solution of 3 to 20wt% or v%, more typically 5 to 7.9wt% or v hydrogen peroxide, preferably 7.9wt% or v%, based on the total weight of the second component is diluted with purified water.
  • the diluted aqueous hydrogen peroxide solution is applied to the surface covered with the diluted warm aqueous calcium chloride solution.
  • the diluted aqueous hydrogen peroxide solution is typically applied by spraying or pouring it onto the surface.
  • the aqueous calcium chloride/hydrogen peroxide is scrubbed on or into the surface. Scrubbing in this way mixes the hydrogen peroxide with the calcium chloride.
  • the aqueous calcium chloride/hydrogen peroxide mixture is allowed to remain on the surface for 1 minute to 24 hours, typically 5 to 20 minutes, preferably
  • An alternative cleaning kit/composition for cleaning a surface generally comprises
  • the first component comprises 50wt%, preferably 20wt , of an aqueous solution of calcium chloride and the second component comprises 50wt% or v%, typically 20wt% or v%, preferably 7.9wt% or v%, of an aqueous solution of hydrogen peroxide.
  • lwt% fluorosurfactant based on the total weight of the cleaning kit/composition is preferably added to the first component.
  • the preferred fluorosurfactant is Merpol A.
  • the calcium chloride solution contains 0.1wt% Merpol A.
  • the pH of the first and second components ranges from 7 to 10.
  • an aqueous solution of 50wt% calcium chloride is diluted to 10 to 25wt%, preferably 20wt%, based on the total weight of the first component.
  • the diluted aqueous calcium chloride solution is applied to the surface by spraying or pouring it onto the surface.
  • An aqueous solution of 30wt% or v%, more typically 20wt% or v%, hydrogen peroxide is diluted to 5 to 7.9wt% or ⁇ % , preferably 7.9wt% or v%, based on the total weight of the second component.
  • the diluted aqueous hydrogen peroxide solution is applied to the surface covered with the diluted aqueous calcium chloride solution.
  • the diluted aqueous hydrogen peroxide solution is typically applied by spraying or pouring it onto the surface.
  • aqueous calcium chloride/hydrogen peroxide is scrubbed on or into the surface. Scrubbing in this way mixes the hydrogen peroxide with the calcium chloride.
  • the aqueous calcium chloride/hydrogen peroxide mixture is allowed to remain on the surface for 1 minute to 24 hours, typically 5 to 20 minutes, preferably 10 to 15 minutes.
  • the surface is rinsed with water to remove excess hydrogen peroxide, calcium chloride and any debris resulting from the cleansing action of the cleaning kit.
  • a 20wt% aqueous calcium chloride solution is sprayed or poured onto the concrete surface so that it thoroughly wets the concrete and penetrates a little into the surface, especially, if the surface is porous.
  • the aqueous calcium chloride solution contains 0.1wt% Merpol A.
  • a 7.9wt% aqueous hydrogen peroxide solution is sprayed or poured onto the concrete surface.
  • the aqueous hydrogen peroxide solution is scrubbed into the concrete and this causes the hydrogen peroxide to mix with the calcium chloride.
  • the concrete surface is scrubbed for approximately 10 to 15 minutes.
  • the calcium chloride and hydrogen peroxide may be left on the concrete surface to discourage the re-establishment of microorganisms.
  • the calcium chloride and hydrogen peroxide is rinsed with water to remove excess hydrogen peroxide, calcium chloride and any debris resulting from the cleansing action.
  • a warm (40-50°C) 20wt% aqueous calcium chloride solution was poured onto a concrete surface to be cleaned so that it thoroughly wetted the concrete.
  • a warm (30-40°C) aqueous 3wt% calcium chloride/3v% hydrogen peroxide composition was administered topically to human scaly skin so that it thoroughly wetted the affected area on the skin and was left there for 5 minutes, whereupon it visibly reacted with the scaly skin but did not visibly react with the healthy skin surrounding the scaly skin.
  • the composition was then washed thoroughly from the skin with water. The treated skin did not have the scales that were present prior to treatment and the sunounding healthy skin that had been contacted by the composition appeared unchanged.
  • aqueous 3wt% calcium chloride (food grade)/3v% hydrogen peroxide (food grade) composition was administered orally to a person's mouth and was left there for 1-2 minutes. The composition was removed from the mouth and the mouth rinsed with water. The teeth in the treated mouth were visibly whiter and the user's mouth felt clean and fresh.
  • Example 5 Calcium chloride 0.005wt% - 0.1wt% is dissolved in the swimming pool water and up 1- 500ppm hydrogen peroxide is added to the water and maintained at that level by periodically adding hydrogen peroxide to the water.
  • Example 6 Dequest 2000 or 2006 (nitrilotris 301-50A, N CH 2 PO 3 H 2 ) 3 ) up to 0.01 - lv% and 0.5 - 3% v/v hydrogen peroxide is dissolved in high purity water which has been purified by degassing, boiling and distilling and cooling and condensing the water vapour.
  • the water is first degassed in a degassing chamber and then boiled at 43°C in a vacuum and the water vapour is then cooled.
  • the quality of purified water is such that it has a conductivity ⁇ S/cm at 35°C of ⁇ 2.0, the total dissolved solids are ⁇ lppm, the amount of sodium ions is ⁇ 0.1mg/L, the amount of calcium ions is ⁇ 0.01mg/L, the amount of magnesium ions is ⁇ 0.05mg/L and the amount of ammonium ions is ⁇ 0.2mg/L.
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 7 (a) A one part aqueous cleaning composition of the following was found to have an effective shelf life: 2.5-7.9wt% or v:v% hydrogen peroxide; 0.25 to 2wt% Dequest 2000; 2.5-7.9wt% or v:v% calcium chloride;
  • NMP Gelled N-methyl pyrrolidone
  • 1.0v:v% surfactant was applied to a surface marked with graffiti, scrubbed into the graffiti, left for 5-10 minutes. The surface was then rinsed with warm water.
  • a one part cleaning composition of 7.9v:v% hydrogen peroxide, 0.1v:v% Dequest 2000, 15.8 v:v% calcium chloride; and 0.2v:v% Merpol was applied to the surface, scrubbed into the surface and let there for 5-10 minutes before being rinsed off with warm water with the result that the graffiti had been substantially removed from the surface.
  • Dequest 2000, Dequest 2010, or Dequest 2006 0.5 - 1.5v% and 0.5 - 7%v/v hydrogen peroxide is dissolved in high purity distilled water.
  • quality of purified water is such that it has a conductivity ⁇ S/cm at 35°C of ⁇ 2.0, the total dissolved solids are ⁇ lppm, the amount of sodium ions is ⁇ 0.1mg/L, the amount of calcium ions is
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 11 Nitrilotris phosphate (N(CH 2 PO 3 H 2 ) 3 ), 0.25 - 2.5v% and 0.25 - 7%v/v hydrogen peroxide is dissolved in high purity distilled water. Typically the quality of purified water is such that it has a conductivity ⁇ S/cm at 35°C of ⁇ 2.0, the total dissolved solids are
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 12 Dequest 2000, Dequest 2010, or Dequest 2006, 0.3 - 3.5v% and 0.2 - 7%v/v hydrogen peroxide is dissolved in high purity deionised water.
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 13 Dequest 2000, Dequest 2010, or Dequest 2006, 0.3 - 3.5v% and 0.2 - 7%v/v hydrogen peroxide is dissolved in high purity deionised water.
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 13 Example 13
  • Nitrilotris phosphate (N(CH 2 PO 3 H 2 ) 3 ), 0.1 - 4.5v% and 0.2 - 7%v/v hydrogen peroxide is dissolved in high purity deionised water.
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 14 Dequest 2000, Dequest 2010, or Dequest 2006, 0.3 - 3.5v% and 0.2 - 7%v/v hydrogen peroxide is dissolved in deionised and distilled water.
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • Example 15 Nitrilotris phosphate (N(CH 2 PO 3 H 2 ) 3 ), 0.1 - 4.5v% and 0.2 - 7%v/v hydrogen peroxide is dissolved in high purity deionised and distilled water.
  • the aqueous composition may be stored in an air tight container with minimal degassing of the peroxide.
  • the cleaning kit/composition of the invention can be readily utilised for cleaning a surface, killing microorganisms, oY bleaching stains from a surface.

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Abstract

L'invention décrit une composition de nettoyage, un kit de nettoyage, et des procédés d'utilisation de la composition et du kit. La composition de nettoyage comprend un premier composant consistant en un agent d'augmentation de la capacité d'oxydation d'un agent d'oxydation, ainsi qu'un second composant comprenant une quantité de l'oxydant dont les caractéristiques d'oxydation ont été améliorées par l'agent d'amélioration.
PCT/AU1995/000423 1994-07-13 1995-07-13 Kit, composition et procedes de nettoyage WO1996002624A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU29175/95A AU2917595A (en) 1994-07-13 1995-07-13 A cleaning kit and a cleaning composition and methods of use

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
AUPM6807A AUPM680794A0 (en) 1994-07-13 1994-07-13 A cleaning kit
AUPM6807 1994-07-13
AUPM7148A AUPM714894A0 (en) 1994-07-29 1994-07-29 A cleaning kit
AUPM7148 1994-07-29
AUPM7326A AUPM732694A0 (en) 1994-08-08 1994-08-08 A cleaning kit
AUPM7326 1994-08-08
AUPM7663 1994-08-24
AUPM7663A AUPM766394A0 (en) 1994-08-24 1994-08-24 A cleaning kit
AUPM8111A AUPM811194A0 (en) 1994-09-13 1994-09-13 A cleaning kit
AUPM8111 1994-09-13
AUPM8409A AUPM840994A0 (en) 1994-09-26 1994-09-26 A cleaning kit
AUPM8409 1994-09-26

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Publication Number Publication Date
WO1996002624A1 true WO1996002624A1 (fr) 1996-02-01

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Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998040047A1 (fr) * 1997-03-12 1998-09-17 Axel Kramer Agents favorisant l'hygiene et la sante buccales
EP0997523A1 (fr) * 1998-10-27 2000-05-03 CHT R. BEITLICH GmbH Solutions aqueuses d'acides phosphoniques
US6090765A (en) * 1997-12-12 2000-07-18 Church & Dwight Co., Inc. Composition for cleaning hard surfaces
WO2001026699A1 (fr) * 1999-10-14 2001-04-19 Saftair Industries Sa Procede, installation et agent de decontamination
GB2381531A (en) * 2001-11-02 2003-05-07 Reckitt Benckiser Inc Hard surface cleaning and disinfecting compositions
WO2005073130A1 (fr) * 2004-02-02 2005-08-11 Giovanni Bozzetto S.P.A. Utilisation de polyaminomethylenephosphonates en tant qu'agents dispersants
EP1576880A1 (fr) * 2004-03-16 2005-09-21 Well-being Biochemical Corp. Composition antibactérienne, antivirale et antifongique, sa préparation et utilisation
US6949218B2 (en) 1996-12-13 2005-09-27 Alcon Manufacturing, Ltd. Use of low molecular weight amino alcohols in ophthalmic compositions
WO2005094768A1 (fr) * 2004-03-29 2005-10-13 Colgate-Palmolive Company Methode de blanchiment des dents amelioree
WO2006038802A1 (fr) * 2004-10-07 2006-04-13 Ngen Pharmaceuticals N.V. Composition stabilisee liberant de l’oxygene
WO2006073559A1 (fr) * 2004-11-09 2006-07-13 Discus Dental Impressions Inc Preparations dentaires blanchissantes bicomposant
US7387799B2 (en) 2003-05-19 2008-06-17 Well-Being Biochemical Corp. Anti-bacterial, anti-viral, and anti-fungus composition, its preparation and use
DE102007034639A1 (de) * 2007-07-23 2009-01-29 Antiseptica Chemisch-Pharmazeutische Produkte Gmbh Mehrteiliges Medizinprodukt
EP0888780B2 (fr) † 1996-11-13 2009-08-19 Menicon Co., Ltd. Composition de traitement pour lentilles de contact et procede de traitement de lentilles de contact au moyen de ladite composition
US7858124B2 (en) 2003-07-29 2010-12-28 Well-Being Biochemical Corp. Anti-bacterial, anti-virus, and anti-fungus composition, its preparation and use
WO2017063817A1 (fr) 2015-10-13 2017-04-20 Unilever N.V. Procédé et kit de désinfection de surfaces
CN107383997A (zh) * 2017-08-17 2017-11-24 广州玮弘祺生物科技有限公司 一种环保型的玻璃脱墨剂
WO2018098474A1 (fr) * 2016-11-28 2018-05-31 2G Protectants, Llc Composition pour le traitement de substrats poreux
CN111850482A (zh) * 2020-07-06 2020-10-30 昆山金百辰金属科技有限公司 一种真空电镀pvd镀膜工艺
US11129385B2 (en) 2018-12-04 2021-09-28 Virox Technologies Inc. C3-C5 N-alkyl-gamma-butyrolactam-containing antimicrobial compositions and uses thereof
CN113605999A (zh) * 2017-06-13 2021-11-05 通用电气公司 用于选择性清洁涡轮发动机构件的系统和方法
US20220000108A1 (en) * 2018-11-12 2022-01-06 Diversey, Inc. C3-c6 n-alkyl-gamma-butyrolactam- and peroyxgen-containing antimicrobial compositions
US12052990B2 (en) 2018-12-04 2024-08-06 Virox Technologies Inc. C3-C5 n-alkyl-gamma-butyrolactam containing antimicrobial compositions and methods of using same
US12053540B2 (en) 2018-12-04 2024-08-06 Virox Technologies Inc. Antimicrobial compositions containing solvents including a C3-C5 N-alkyl-gamma-butyrolactam

Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4634368A (en) * 1967-11-16 1970-05-21 RECKITT & COLMAN i PRODUCTS LIMITED Cleaning compositions
US3574516A (en) * 1966-03-28 1971-04-13 Degussa Dehairing of hides and skins
US3740187A (en) * 1971-06-03 1973-06-19 Monsanto Co Processes for bleaching textiles
AU3780472A (en) * 1971-01-15 1973-07-12 Ab Helios, Kamiar-Tekniska Laderer Detergent composition
AU5435373A (en) * 1972-05-12 1974-10-17 Colgate-Palmolive Company, The Scouring cleanser
JPS54112557A (en) * 1978-02-22 1979-09-03 Ebara Infilco Co Ltd Treatment of sludge
JPS58205599A (ja) * 1982-05-25 1983-11-30 Nippon Peroxide Co Ltd し尿の処理方法およびし尿処理剤
AU3273884A (en) * 1983-09-06 1985-03-14 Occidental Chemical Corporation Disinfectant composition comprising dichloro-isocyanuric acid salts
AU5260286A (en) * 1985-01-30 1986-08-07 Interox Chemicals Limited A process and composition for the activation of hydrogen peroxide or a hydrogen perioxide-developing persalt with a mixed oxide
US4699623A (en) * 1984-11-21 1987-10-13 Atochem Process of bleaching laundry
JPS62280298A (ja) * 1986-05-28 1987-12-05 花王株式会社 粉末状漂白剤組成物
JPH01301798A (ja) * 1988-05-30 1989-12-05 Lion Corp 固型状漂白剤組成物の製造方法
KR900003010B1 (ko) * 1987-12-07 1990-05-04 윤 선 저온열처리와 겨자유 첨가의 병용효과를 이용한 김치류의 보존 연장방법
AU3873789A (en) * 1988-12-22 1990-07-10 Alfred R. Globus Stable, active chlorine-containing anti-microbial compositions
AU6870691A (en) * 1989-12-06 1991-06-26 Previsan S.A. Active agent against retrovirus group viruses, compositions containing same and their use
JPH03202193A (ja) * 1989-10-30 1991-09-03 Shigeo Kido 水の消毒剤及び消毒方法
AU7210991A (en) * 1990-02-08 1991-09-03 Unilever Plc Liquid bleach composition
AU8939491A (en) * 1990-11-02 1992-05-26 Michael J. Arnold Plaque adsorbent oral composition and method
SU1740628A1 (ru) * 1990-01-03 1992-06-15 Волго-Уральский научно-исследовательский и проектный институт по добыче и переработке сероводородсодержащих газов Буферна жидкость на водной основе
EP0623283A1 (fr) * 1993-04-26 1994-11-09 Kemira Kemi Aktiebolag Agent pour enlever les algues
WO1995008917A1 (fr) * 1993-09-30 1995-04-06 Spruegel Friedrich A Desinfectant/nettoyant a usage superficiel

Patent Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3574516A (en) * 1966-03-28 1971-04-13 Degussa Dehairing of hides and skins
AU4634368A (en) * 1967-11-16 1970-05-21 RECKITT & COLMAN i PRODUCTS LIMITED Cleaning compositions
AU3780472A (en) * 1971-01-15 1973-07-12 Ab Helios, Kamiar-Tekniska Laderer Detergent composition
US3740187A (en) * 1971-06-03 1973-06-19 Monsanto Co Processes for bleaching textiles
AU5435373A (en) * 1972-05-12 1974-10-17 Colgate-Palmolive Company, The Scouring cleanser
JPS54112557A (en) * 1978-02-22 1979-09-03 Ebara Infilco Co Ltd Treatment of sludge
JPS58205599A (ja) * 1982-05-25 1983-11-30 Nippon Peroxide Co Ltd し尿の処理方法およびし尿処理剤
AU3273884A (en) * 1983-09-06 1985-03-14 Occidental Chemical Corporation Disinfectant composition comprising dichloro-isocyanuric acid salts
US4699623A (en) * 1984-11-21 1987-10-13 Atochem Process of bleaching laundry
AU5260286A (en) * 1985-01-30 1986-08-07 Interox Chemicals Limited A process and composition for the activation of hydrogen peroxide or a hydrogen perioxide-developing persalt with a mixed oxide
JPS62280298A (ja) * 1986-05-28 1987-12-05 花王株式会社 粉末状漂白剤組成物
KR900003010B1 (ko) * 1987-12-07 1990-05-04 윤 선 저온열처리와 겨자유 첨가의 병용효과를 이용한 김치류의 보존 연장방법
JPH01301798A (ja) * 1988-05-30 1989-12-05 Lion Corp 固型状漂白剤組成物の製造方法
AU3873789A (en) * 1988-12-22 1990-07-10 Alfred R. Globus Stable, active chlorine-containing anti-microbial compositions
JPH03202193A (ja) * 1989-10-30 1991-09-03 Shigeo Kido 水の消毒剤及び消毒方法
AU6870691A (en) * 1989-12-06 1991-06-26 Previsan S.A. Active agent against retrovirus group viruses, compositions containing same and their use
SU1740628A1 (ru) * 1990-01-03 1992-06-15 Волго-Уральский научно-исследовательский и проектный институт по добыче и переработке сероводородсодержащих газов Буферна жидкость на водной основе
AU7210991A (en) * 1990-02-08 1991-09-03 Unilever Plc Liquid bleach composition
AU8939491A (en) * 1990-11-02 1992-05-26 Michael J. Arnold Plaque adsorbent oral composition and method
EP0623283A1 (fr) * 1993-04-26 1994-11-09 Kemira Kemi Aktiebolag Agent pour enlever les algues
WO1995008917A1 (fr) * 1993-09-30 1995-04-06 Spruegel Friedrich A Desinfectant/nettoyant a usage superficiel

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
DERWENT ABSTRACT, Accession No. 74404B/41, Class D15; & JP,A,54 112 557 (EBARA INFILCO KK), 3 September 1979. *
DERWENT ABSTRACT, Accession No. 84-013824/03, Class D15; & JP,A,58 205 599 (NIPPON CALOXIDE KK), 30 November 1983. *
DERWENT ABSTRACT, Accession No. 88-017994/03, Classes D25, E16; & JP,A,62 280 298 (KAO CORP), 12 May 1987. *
DERWENT ABSTRACT, Accession No. 90-020354/03, Classes A97, D25, E37; & JP,A,01 301 798 (LION), 5 December 1989. *
DERWENT ABSTRACT, Accession No. 91-146324/20, Class D13; & KR,B,9003010 (YUN) 4 May 1990. *
DERWENT ABSTRACT, Accession No. 91-301051/41, Class P34; & JP,A,03 202 193 (KIDO), 3 september 1991. *
DERWENT ABSTRACT, Accession No. 93-187425/23, Class Q49; & SU,A,1 740 628 (VOLGA URALS HYDROCARBON RAW MAT), 15 June 1992. *
DERWENT ABSTRACT, Accession No. 94-207329/25 Classes B04, C03; & SU,A,1 808 323 (NONBLACK SOIL REG VETERINARY RES INST), 15 April 1994. *

Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0888780B2 (fr) † 1996-11-13 2009-08-19 Menicon Co., Ltd. Composition de traitement pour lentilles de contact et procede de traitement de lentilles de contact au moyen de ladite composition
US6949218B2 (en) 1996-12-13 2005-09-27 Alcon Manufacturing, Ltd. Use of low molecular weight amino alcohols in ophthalmic compositions
US8563011B2 (en) 1996-12-13 2013-10-22 Alcon Research, Ltd. Use of low molecular weight amino alcohols in ophthalmic compositions
US7045095B2 (en) 1996-12-13 2006-05-16 Alcon Manufacturing, Ltd. Use of low molecular weight amino alcohols in ophthalmic compositions
WO1998040047A1 (fr) * 1997-03-12 1998-09-17 Axel Kramer Agents favorisant l'hygiene et la sante buccales
US6090765A (en) * 1997-12-12 2000-07-18 Church & Dwight Co., Inc. Composition for cleaning hard surfaces
EP0997523A1 (fr) * 1998-10-27 2000-05-03 CHT R. BEITLICH GmbH Solutions aqueuses d'acides phosphoniques
WO2001026699A1 (fr) * 1999-10-14 2001-04-19 Saftair Industries Sa Procede, installation et agent de decontamination
FR2799653A1 (fr) * 1999-10-14 2001-04-20 Saftair Ind S A Procede, installation et agent de decontamination, desinfection et/ou desinsectisation par voie aerienne d'un volume a traiter, notamment pour traiter un local et/ou des conduites aerauliques et gaines de ventilation
GB2381531A (en) * 2001-11-02 2003-05-07 Reckitt Benckiser Inc Hard surface cleaning and disinfecting compositions
US7387799B2 (en) 2003-05-19 2008-06-17 Well-Being Biochemical Corp. Anti-bacterial, anti-viral, and anti-fungus composition, its preparation and use
US7976876B2 (en) 2003-05-19 2011-07-12 Well-Being Biochemical Corp. Anti-bacterial, anti-virus, and anti-fungus composition, its preparation and use
US7858124B2 (en) 2003-07-29 2010-12-28 Well-Being Biochemical Corp. Anti-bacterial, anti-virus, and anti-fungus composition, its preparation and use
US7659315B2 (en) 2004-02-02 2010-02-09 Giovanni Bozzetto S.P.A. Use of polyaminomethylenephosphonates as dispersing agents
WO2005073130A1 (fr) * 2004-02-02 2005-08-11 Giovanni Bozzetto S.P.A. Utilisation de polyaminomethylenephosphonates en tant qu'agents dispersants
EP1576880A1 (fr) * 2004-03-16 2005-09-21 Well-being Biochemical Corp. Composition antibactérienne, antivirale et antifongique, sa préparation et utilisation
WO2005094768A1 (fr) * 2004-03-29 2005-10-13 Colgate-Palmolive Company Methode de blanchiment des dents amelioree
US7601002B2 (en) 2004-03-29 2009-10-13 Colgate-Palmolive Co Dental whitening method
WO2006038802A1 (fr) * 2004-10-07 2006-04-13 Ngen Pharmaceuticals N.V. Composition stabilisee liberant de l’oxygene
JP2008515881A (ja) * 2004-10-07 2008-05-15 エヌジーイーエヌ・ファーマソーティカルズ・エヌ．ブイ． 安定化酸素放出組成物
WO2006073559A1 (fr) * 2004-11-09 2006-07-13 Discus Dental Impressions Inc Preparations dentaires blanchissantes bicomposant
US9138386B2 (en) 2004-11-09 2015-09-22 Discus Dental, Llc Dental whitening compositions
DE102007034639A1 (de) * 2007-07-23 2009-01-29 Antiseptica Chemisch-Pharmazeutische Produkte Gmbh Mehrteiliges Medizinprodukt
WO2017063817A1 (fr) 2015-10-13 2017-04-20 Unilever N.V. Procédé et kit de désinfection de surfaces
WO2018098474A1 (fr) * 2016-11-28 2018-05-31 2G Protectants, Llc Composition pour le traitement de substrats poreux
CN113605999A (zh) * 2017-06-13 2021-11-05 通用电气公司 用于选择性清洁涡轮发动机构件的系统和方法
CN113605999B (zh) * 2017-06-13 2023-09-12 通用电气公司 用于选择性地清洁涡轮发动机构件的表面的方法
CN107383997A (zh) * 2017-08-17 2017-11-24 广州玮弘祺生物科技有限公司 一种环保型的玻璃脱墨剂
US20220000108A1 (en) * 2018-11-12 2022-01-06 Diversey, Inc. C3-c6 n-alkyl-gamma-butyrolactam- and peroyxgen-containing antimicrobial compositions
US12150446B2 (en) * 2018-11-12 2024-11-26 Diversey, Inc C3-C6 N-alkyl-gamma-butyrolactam- and peroyxgen-containing antimicrobial compositions
US11129385B2 (en) 2018-12-04 2021-09-28 Virox Technologies Inc. C3-C5 N-alkyl-gamma-butyrolactam-containing antimicrobial compositions and uses thereof
US12052990B2 (en) 2018-12-04 2024-08-06 Virox Technologies Inc. C3-C5 n-alkyl-gamma-butyrolactam containing antimicrobial compositions and methods of using same
US12053540B2 (en) 2018-12-04 2024-08-06 Virox Technologies Inc. Antimicrobial compositions containing solvents including a C3-C5 N-alkyl-gamma-butyrolactam
CN111850482A (zh) * 2020-07-06 2020-10-30 昆山金百辰金属科技有限公司 一种真空电镀pvd镀膜工艺

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