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WO1996001394A1 - An electrode arrangement for use in a combustion chamber - Google Patents

An electrode arrangement for use in a combustion chamber Download PDF

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Publication number
WO1996001394A1
WO1996001394A1 PCT/NO1995/000118 NO9500118W WO9601394A1 WO 1996001394 A1 WO1996001394 A1 WO 1996001394A1 NO 9500118 W NO9500118 W NO 9500118W WO 9601394 A1 WO9601394 A1 WO 9601394A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrodes
combustion
combustion chamber
electrode
combustion chambers
Prior art date
Application number
PCT/NO1995/000118
Other languages
French (fr)
Inventor
Torfinn Johnsen
Original Assignee
Torfinn Johnsen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Torfinn Johnsen filed Critical Torfinn Johnsen
Priority to AU29386/95A priority Critical patent/AU2938695A/en
Publication of WO1996001394A1 publication Critical patent/WO1996001394A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C99/00Subject-matter not provided for in other groups of this subclass
    • F23C99/001Applying electric means or magnetism to combustion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B5/00Combustion apparatus with arrangements for burning uncombusted material from primary combustion
    • F23B5/04Combustion apparatus with arrangements for burning uncombusted material from primary combustion in separate combustion chamber; on separate grate
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L1/00Passages or apertures for delivering primary air for combustion 
    • F23L1/02Passages or apertures for delivering primary air for combustion  by discharging the air below the fire
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L9/00Passages or apertures for delivering secondary air for completing combustion of fuel 
    • F23L9/02Passages or apertures for delivering secondary air for completing combustion of fuel  by discharging the air above the fire
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24BDOMESTIC STOVES OR RANGES FOR SOLID FUELS; IMPLEMENTS FOR USE IN CONNECTION WITH STOVES OR RANGES
    • F24B1/00Stoves or ranges
    • F24B1/18Stoves with open fires, e.g. fireplaces
    • F24B1/185Stoves with open fires, e.g. fireplaces with air-handling means, heat exchange means, or additional provisions for convection heating ; Controlling combustion
    • F24B1/189Stoves with open fires, e.g. fireplaces with air-handling means, heat exchange means, or additional provisions for convection heating ; Controlling combustion characterised by air-handling means, i.e. of combustion-air, heated-air, or flue-gases, e.g. draught control dampers 
    • F24B1/19Supplying combustion-air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24BDOMESTIC STOVES OR RANGES FOR SOLID FUELS; IMPLEMENTS FOR USE IN CONNECTION WITH STOVES OR RANGES
    • F24B5/00Combustion-air or flue-gas circulation in or around stoves or ranges
    • F24B5/02Combustion-air or flue-gas circulation in or around stoves or ranges in or around stoves
    • F24B5/021Combustion-air or flue-gas circulation in or around stoves or ranges in or around stoves combustion-air circulation
    • F24B5/025Supply of secondary air for completing combustion of fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24BDOMESTIC STOVES OR RANGES FOR SOLID FUELS; IMPLEMENTS FOR USE IN CONNECTION WITH STOVES OR RANGES
    • F24B5/00Combustion-air or flue-gas circulation in or around stoves or ranges
    • F24B5/02Combustion-air or flue-gas circulation in or around stoves or ranges in or around stoves
    • F24B5/021Combustion-air or flue-gas circulation in or around stoves or ranges in or around stoves combustion-air circulation
    • F24B5/026Supply of primary and secondary air for combustion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23BMETHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
    • F23B2900/00Special features of, or arrangements for combustion apparatus using solid fuels; Combustion processes therefor
    • F23B2900/00006Means for applying electricity to flame, e.g. an electric field

Definitions

  • the present invention concerns an electrode device for use in combustion chambers.
  • the combustion chamber can be any type and size of stove and fireplace, designed as a container with an inlet for the supply of fuel and an oxidation means in the form of air and with an outlet for exhaust gas.
  • the invention is especially concerned with electrodes and discharge factors which when tested have been shown to be capable of acting efficiently as control systems for combustion processes, the electrical system affecting the entire combustion process including air. fuel, smouldering, flame, exhaust gas. particles and chamber surfaces such as walls, top and bottom.
  • the object of the present invention is to obtain devices which provide efficient combustion in a combustion chamber with open flame combustion.
  • a further object is to reduce harmful substances in the exhaust gas.
  • the invention concerns an electrode and discharge system, the effect of which, when used in or in connection with combustion chambers, is that the normally fixed combustion conditions do not follow traditional physical and chemical patterns, but deviate in such a manner that it becomes possible to perform combustion, for example, at a low temperature while still keeping the emissions of harmful substances to a minimum or completely eliminating them.
  • the invention is described in the patent claims and in the figures.
  • the object of the electrode system which forms part of the invention is to form electrical and electromagnetic fields, discharges and conditions which influence combustion reactions to proceed in an optimum manner with reduced emissions of undesirable products such as. for example, particulate material (PM), carbon monoxide gas (CO), environmentally harmful, uncombusted organic material (HC) and nitrous compounds.
  • discharges does not principally refer to processes such as jump sparks, but. for example, discharges such as corona discharge or electrode discharges without a spark ("silent discharge").
  • the effect of the reaction pattern on the combustion process is determined by voltage, frequency and type of discharge. It has also been observed that the exhaust gas can be affected and controlled by the influence of electricity. since the exhaust gas can be conveyed back to the combustion zone and participate in a more complete combustion reaction.
  • Tests show that emissions of uncombusted hydrocarbons, carbon monoxide and particulate material are reduced by means of the invention and that nitrous compounds become less unstable with less of the natural nitrogen component in the combustion air being converted to NOx.
  • the total electrical influence leads to conditions which increase the potential for influencing the combustion pattern in a positive direction, since the incandescence, the flame intensity and the flame pattern, together with the exhaust gas can be controlled to a very great extent by means of the described influences.
  • Figure 1 is a section of a combustion chamber preferably intended for liquid and gaseous fuels.
  • Figure 2 is a section of a combustion chamber preferably intended for solid fuels.
  • Figure 3 is a section of a combustion chamber with an outlet for exhaust gas in one of the sides.
  • FIG. 4 illustrates various forms of electrodes.
  • Figure 1 illustrates a combustion chamber 1 with an inlet 2 for fuel in the lower part of the combustion chamber.
  • the fuel can be gaseous or liquid, but all types of fuel can be employed.
  • Around the fuel inlet 2 there is coaxially located an inlet 3 for an oxidation means such as air.
  • the air inlet 3 may also be located beside the fuel inlet 2.
  • the reference numeral 4 indicates the flame zone.
  • In the upper part of the combustion chamber is an outlet 5 for exhaust gas.
  • the electrode 6 is electrically insulated from the combustion chamber by means of insulation material which can be in the form of a ring 10.
  • electrodes 7 which are electrically insulated from the combustion chamber by means of electrical insulation material 10.
  • the electrodes 6 and 7 are connected to a voltage generator 1 1 which supplies voltage to the electrodes, either direct voltage, pulsating direct voltage or alternating voltage.
  • electrodes 6 and 7 are coupled to a voltage generator 1 1 via tem ⁇ perature-resistant cables 9 which are inserted into the combustion chamber 1 through an insulator 10.
  • the electrodes 6 and 7 are coupled to voltage with opposite polarity, thus forming an electrical field between the electrodes 6 and 7.
  • Figure 2 illustrates a combustion chamber 1 preferably for solid fuels.
  • a fuel inlet 2 and an air inlet 3 are located in the side wall of the combustion chamber 1.
  • An electrically conducting grate 13 forms the base for the fuel 16.
  • the grate 13 is insulated from the combustion chamber 1 by means of heat- resistant insulators 15 which can be constructed in one piece as a ring. Ceramics can be used as insulation material.
  • the grate 13 permits the through-flow of air and ash to fall through. For practical reasons the entire cross section of the combustion chamber 1 can be in the form of a grate.
  • the grate 13 can also be made of an electrically neutral material. When such an embodiment is utilized, an electrode 6 is located under the grate.
  • the reference numeral 4 indicates the flame zone.
  • an outlet 5 for exhaust gas In the upper part of the combustion chamber 1 is an outlet 5 for exhaust gas. At the outlet area for exhaust gas in the upper part of the combustion chamber 1 there are located one or more electrodes 7 at or above the flame zone 4.
  • the electrode 7 is electrically insulated from the combustion chamber 1 by means of electrical insulation material 10.
  • the electrodes 7. 14. the grate 13 and possibly the electrode 6 are coupled to the voltage generator 1 1 by means of temperature- resistant cables 9 which are inserted into the combustion chamber 1 through insulators 10.
  • the electrodes 7 and 6 are connected to voltage with opposite polarity, thus forming a field between the electrodes.
  • the electrode 6 can have an electrical earth connection.
  • An electrode 14 can be located in or immediately in front of the air inlet 3 for ionization of the inlet air and the combustion atmosphere.
  • a mixing chamber in the outlet area 5.
  • a mixing chamber When a mixing chamber is employed it can be used as an electrode 7, or be equipped with electrodes 7 which are insulated from the mixing chamber.
  • One or more electrodes 8 and 8b are located in the lower part of the combustion chamber 1 at the same height as the fuel 16 or immediately above it.
  • the electrodes 8 and 8b are preferably located at the same level at an equal distance from each other around the fuel 16.
  • Such electrodes can also be located in the combustion chamber 1 where liquid and gaseous fuel are employed. The effect on the incandescence or combustion will be strongest where the field is strongest and most concentrated. In some cases, such as.
  • the horizontal electrodes When used in practice the horizontal electrodes should be capable of acting independently of the other electrodes, since they are activated or switched off as required. In practice it can be said that the electrodes above and below the flame zone force the exhaust gas and the particles down into the combustion and the horizontal electrodes intensify the actual incandescence. This is highly effective in those cases where a rapid burning up of the combustion material is desired, for example in the case of refuse incineration.
  • Figure 3 illustrates a combustion chamber 1 with a flue outlet 5 in one of the sides.
  • the flue outlet is located at the back edge 17 of the combustion chamber 1.
  • the pair of electrodes 6 and 7 are located on each side, one on each of the chamber walls 19 and 20.
  • the actual incandescent combustion 23 takes place in the bottom 21 of the chamber and the flame combustion 4 in the central zone of the chamber.
  • Upper flames 22 pass between the electrodes 6 and 7 where they are influenced by the electrical field and the discharge between them.
  • One of the electrodes 6 and 7 may be omitted and replaced by a combustion chamber wall 20 or 19 which is then employed as an electrode.
  • the combustion chamber 1 may be used as an electrode.
  • One of the electrodes 6 or 7 or possibly both can be mounted at a certain angle in relation to the combustion chamber walls 19 and 20 in order to give the electrical field a favourable direction in relation to the flame zone 4.
  • the reference numeral 12 indicates the earthing point.
  • the electrodes 6. 7 are connected to an electrical voltage generator 1 1 by means of cables 9 which are inserted into the combustion chamber 1 through insulators 10.
  • Figure 4.1 illustrates forms of electrodes where electrodes 7 and 6 are flat and circular or oval plates which are preferably located horizontally above each other, thus forming an electrode pair.
  • a screw 9b which in the upper electrode 7 is surrounded by an insulating material 10.
  • the object of the insulator 10 is to insulate the electrode 7 from the combustion chamber 1.
  • the screw is electrically conducting and conducts electric current up to the actual electrodes 6 and 7 from cable 9.
  • the lower electrode 6 can be connected to electric earth 12 as an alternative to voltage 1 1.
  • the object of the screw arrangement 9b is that it anchors the electrode to the combustion chamber 1 and facilitates the maintenance work since the electrode 7 can easily be unscrewed and cleaned or replaced.
  • Figure 4.2 illustrates the electrode 7 supplied with discharge points 7a.
  • Figure 4.3 illustrates electrodes 7 and 7a equipped with holes 7b for gas through- flow.
  • the incandescence electrodes 8 and 8b are in the form of rods where a part of the rod is surrounded by insulating material 10.
  • the electrode is connected to an electrical conductor 9 via a screw 9b.
  • the electrodes consist of a temperature-resistant and an electrically conducting end 8c. 8d. Se and 8f against the high temperature side. This end has voltage impressed to such a degree that a discharge occurs in the direction towards the incandescence 23.
  • the end can either be in the form of a point 8d. a ball 8c. a plate 8e or a brush 8f. depending on which type of discharge is required.
  • Figure 4.5 illustrates a plate-shaped, curved plate electrode 25 as the upper electrode in combination with a flat, circular bottom electrode 6.
  • the electrode 25 can be like electrode 7 with discharge points and perforations.
  • FIG 4.6 illustrates a top electrode 7 in the form of a funnel in which the outer walls 28 of the funnel are impressed with voltage from the voltage generator 1 1 or earthed 12.
  • a current-carrying wire electrode 27 which is impressed with high voltage.
  • the wire 27 is electrically insulated from the funnel 28 by means of an insulator 10.
  • the wire 27 may be replaced by a brush or cord-shaped metallic discharger.
  • the reference numeral 24 indicates a flame zone.
  • the electrode 26 is located around the flame zone and the electrode 27 projects down into the flame zone 24.
  • Figure 4.7 consists of a funnel as described under figure 4.6. but this has a narrowing in the form of a venturi 29 in the flow passage 24.
  • the venturi 29 can either be in electrical contact with the actual funnel 26 or insulated from the funnel 26 by means of an insulator 10.
  • Figure 4.8 consists of a fan electrode 30 in which the fan blades 3 1 are impressed with electrical voltage.
  • the electrode 31 is impressed with electrical voltage from the voltage generator 1 1 with opposite polarity to the surrounding reference electrode 32. or it is connected to earth 12.
  • the fan 30 revolves due to currents from the combustion gases or it can rotate by being connected to a shaft.
  • the reference electrode 32 can either be an independent ring or the actual combustion chamber 1.
  • the fan electrode 30 is employed in the upper part of the combustion.
  • Figure 4.9 consists of a spiral-shaped electrode 32 which permits flames to flow freely between each of the spirals 33 and 34.
  • Each isolated spiral 33 and 34 is connected to the voltage generator 1 1 where one of the spiral electrodes receives the opposite electrical charge to the other.
  • an electrical insulator 10 the object of which is to insulate the electrodes from one another and to act as a suspension means for the electrode 32 in the combustion chamber 1.
  • One of the spiral electrodes 33 and 34 can be connected to earth 12.
  • Figure 4.10 consists of an electrode 39 which acts as an ion trap for use in the upper part of the combustion chamber where the combustion passes from the flame to the gas phase.
  • the electrode 39 consists of an outer ring 40 and an inner core 41 held together by insulators 10. The object of this type of electrode is to obtain a powerful discharge between the ring 40 and the core 41 where upper flames and exhaust gas have to pass. It will thereby be possible to neutralize the gas or convert it to harmless components while at the same time any particles in the exhaust gas are precipitated in the field.
  • the reference numeral 24 indicates the flow passage for combustion elements.
  • the electrodes illustrated in figures 1.2 and 3 together with the combustion chamber 1 can be individually coupled to electrical voltage and negative or positive polarity. Alternating voltage may also be employed. The voltage may be connected intermittently and it can also be reversed for periods.
  • electrodes 6 and 13 are preferably located under or at the lower part of the flame zone 4. connected to positive polarity. Electrode 7 in the upper part of the combustion chamber above or at the flame zone 4 is preferably connected to negative polarity.
  • the combustion chamber 1 is normally made of metal and can also be used as an electrode. The combustion chamber 1 may. e.g., be connected to negative polarity and is used as an electrode either alone or in addition to electrode 7.
  • the combustion chamber 1 is preferably connected to earth 12 or to a neutral point.
  • combustion chamber 1 and the lead-in pipes 2 and 3 for fuel and air respectively are connected to earth or a neutral point and electrode 7 is connected to alternating ⁇ oltage. preferably high-frequency.
  • Electrode 8b is preferably connected to negative polarity and its primary purpose is to change the flame pattern or the incandescence, thus enabling, for example, long flames with a small surface area to be altered in appearance to a plurality of small tongues of flame with a substantially greater total surface area than the long flames.
  • the electrode 14 which is located in connection with the combustion air in the air inlet 3 is preferably connected to negative polarity and should be of such a nature that it ionizes the air which is used in the combustion. This is achieved by an electrode point consisting of one or more points, preferably points in the form of a brush where the brush consists of several thin metallic wires.
  • a fuel electrode can be located in connection with liquid fuel and is employed in such a manner that the fuel has the opposite polarity to the air. the electrode being connected to the actual fuel and the fuel thereby acting as a secondary electrode since the polar electrode has no other electrically reactive components in its vicinity than the actual fuel molecules. In zones where fuel is charged, the fuel pipe should be of an insulating nature.
  • the electrodes can be connected to direct voltage, preferably pulsating direct voltage, i.e. direct voltage with overlaid alternating voltage. It has been shown that the pulse frequency affects the efficiency of the system. A pulse frequency between 1 Hz and 3000 MHz has been employed and it has been shown that specific pulse frequencies give a greater reduction in harmful substances in the exhaust gas when one type of fuel is used. In table 1 below there is a list of some fuels and pulse frequencies which affect the combustion in a positive direction, thus achieving a reduction in harmful substances in the exhaust gas and better combustion in individual, special types of combustion. Results have also been obtained in the form of improved combustion of exhaust gas by means of frequencies in the gigahertz range.
  • the following table illustrates an example of some electrical parameters in the form of frequencies and discharge characteristics which are employed in experimentation with the combustion materials listed when used in combustion in small combustion chambers with a chamber volume of 0.75 m3.
  • the examples are representative of conducted experiments and should not be regarded as limiting for subsequent choice of other values, e.g. other frequencies or voltages with the said fuel types.
  • the pulse amplitude can be up to 100% of the direct voltage. A pulse amplitude between 10% and 50% is preferably employed. Alternating voltage, preferably high-frequency alternating voltage, can also be employed.
  • the magnitude of the electrical voltage which is supplied to the electrodes is dependent on the dimensions of the combustion chamber and the distance between the electrodes.
  • the combustion temperature and the natural ionization in the combustion are also important for the voltage supplied.
  • the strength of the electrical field in the flame zone between the electrodes can be in the range 0.01 to 25 kV/cm. preferably in the range between 0.2 and 1 kV/cm.
  • the power which is supplied to the electrode system is dependent on the dimensions of the combustion chamber, the design of the electrode, the fuel. the ionization of the combustion, the combustion temperature and the number of electrodes.
  • Tests in a combustion chamber whose physical measurements are: lateral surfaces 50 cm. height 68 cm. chamber width 60 cm. show that with dry wood as fuel a substantial reduction in PM. HC and CO is already obtained when power is supplied in the range 2 to 5 watts. This is one of the advantages of the invention.
  • the power supplied was in the range 10 watts with a field strength between the electrodes of 0.25 kV/cm.
  • the voltage was pulsating direct voltage with a pulse frequency in the range 12 kHz and the pulse amplitude was in the range 10% of the direct voltage.
  • frequencies above the audible range will have to be used in. for example, fireplaces with or without doors. In an industrial context the audibility of the discharge is of less importance.
  • a flame contains countless ions. These serve as electrical charge carriers.
  • chargeable flue gas particles are also ionized. Oxygen, carbon dioxide and steam normally form a majority of negative ions and the flue gas particles are probably also negatively charged in a flame. Negative particles and ions are thereby repelled by a negatively charged electrode which is above the flame zone and are thereby forced downwards in the combustion chamber by the upper electrode and pressed back into the flame zone where they are combusted.
  • the upper part of the combustion chamber acts as an afterburning zone and the content of particulate material (PM). hydrocarbons (HC) and carbon monoxide (CO) are reduced in the combustion gas.
  • PM particulate material
  • HC hydrocarbons
  • CO carbon monoxide

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Incineration Of Waste (AREA)

Abstract

An electrode device has been developed for use in combustion chambers, such as all types and sizes of stoves and fireplaces. One or more electrodes are located in such a manner that the flame zone is located between two of the electrodes. An electrode system is also located in the inlet opening for combustion air in order to inonize/excite the air which is used in the combustion process. The combustion chamber can also be employed as an electrode or be connected to one of the electrodes. The electrodes and possibly also the combustion chamber are connected to electrical voltage, thus forming poles in an electrical system. The voltage and polarity are selected in order that the combustion is affected in the flame zone, thus reducing the content of smoke particles, hydrocarbons, carbon monoxide and nitrous components in the exhaust gas.

Description

AN ELECTRODE ARRANGEMENT FOR USE IN A COMBUSTION CHAMBER
The present invention concerns an electrode device for use in combustion chambers. The combustion chamber can be any type and size of stove and fireplace, designed as a container with an inlet for the supply of fuel and an oxidation means in the form of air and with an outlet for exhaust gas.
In the context of the constant increase in requirements for improving the control of combustion processes and emissions from combustion processes, there is a need to produce new technical solutions in the form of devices whose utilization will enable combustion processes to be controlled, by achieving control of combustion rate, combustion energy and the emission of harmful components from the combustion process.
The invention is especially concerned with electrodes and discharge factors which when tested have been shown to be capable of acting efficiently as control systems for combustion processes, the electrical system affecting the entire combustion process including air. fuel, smouldering, flame, exhaust gas. particles and chamber surfaces such as walls, top and bottom.
In connection with the combustion of combustible materials in all types of combustion chamber, for example large and small stoves, fireplaces, enclosed fireplaces, smelting furnaces, boilers, etc.. the need has arisen in recent times for a reduction in the emission of harmful substances into the environment. Restrictions have been established by law in the form of international agreements in which emission norms are stipulated. It is assumed that more stringent requirements will be specified in the future, thus requiring the constant development of methods and devices which will be capable of fulfilling the future national and international conditions. The requirements are particularly concerned with the emission of substances such as hydrocarbons, carbon monoxide, nitrous gases and particulate material. This application concerns devices which when tested have proved to be capable of efficiently controlling the combustion process and/or emissions, the combustion phase or gas phase being affected by the devices as described in the claims.
If combustible materials are burned in traditional combustion chambers, the quality of combustion is to a great extent left to chance. It has been shown that the often random access of the combustion mass and the exhaust gas to oxygen does not permit a maximum degree of combustion of the fuel and the exhaust gases. This applies particularly during the period before the actual main combustion occurs, i.e. during the first combustion phase and during the period when there is characteristic smouldering in the combustion chamber. Measurements have established that the emission of uncombusted organic material in the form of hydrocarbons and the poisonous gas carbon monoxide increases when the flame intensity and the rate of combustion decrease. Point measurement of the oxygen content in and around the combustion shows that the flame receives most oxygen in the part which is closest to the opening for air input and least at the back of the flame. An analysis of the proportion of the mixture of air/combustible gas in the zone above the flame shoλvs that the proportions of the mixture are uneven when efficient afterburning of the gases is not achieved. The upper combustion zone lacks oxygen and has too low a temperature.
Traditional combustion chambers are normally equipped with inlets for combustion air. combustion mass and outlets for flue gas. In most cases the degree of combustion is regulated by altering the proportions of the mixture of combustible material and air. As a rule the optimum conditions in the actual combustion centre cannot be altered in order to obtain a combustion pattern which is environmentally and economically attractive. In most cases one factor increases if the other is reduced. An example of this is the relationship between a low degree of combustion and the emission of harmful components from the combustion process. If the combustion temperature is reduced, the flue gas temperature drops and the proportion of uncombusted volatile harmful substances in the exhaust gas is increased with the consequence that substances are passed into the natural environment which are invidious and difficult to break down.
The object of the present invention is to obtain devices which provide efficient combustion in a combustion chamber with open flame combustion. A further object is to reduce harmful substances in the exhaust gas.
The invention concerns an electrode and discharge system, the effect of which, when used in or in connection with combustion chambers, is that the normally fixed combustion conditions do not follow traditional physical and chemical patterns, but deviate in such a manner that it becomes possible to perform combustion, for example, at a low temperature while still keeping the emissions of harmful substances to a minimum or completely eliminating them. The invention is described in the patent claims and in the figures.
The object of the electrode system which forms part of the invention is to form electrical and electromagnetic fields, discharges and conditions which influence combustion reactions to proceed in an optimum manner with reduced emissions of undesirable products such as. for example, particulate material (PM), carbon monoxide gas (CO), environmentally harmful, uncombusted organic material (HC) and nitrous compounds. In this context the term "discharges" does not principally refer to processes such as jump sparks, but. for example, discharges such as corona discharge or electrode discharges without a spark ("silent discharge"). The type of discharge with be determined by the form of electrode, where pointed or thin electrodes will substantially give corona discharges, while flat electrodes will give spark-free discharges characterized as "silent discharge".
By employing pulsed direct current, it is possible to impress a higher voltage and thereby a stronger electrical field without the formation of jump sparks between the electrodes. Thus the frequency of the current is important for controlling the discharge process. The frequency also gives rise to electromagnetic conditions which can influence the combustion in a positive direction.
It is assumed that the discharges and the electrical field affect the reactants in the combustion process by excitation, dissociation, ionizing, dissociative ionization. or by the formation of free radicals. Each of these processes separately can contributes to increasing the efficiency of the combustion reaction.
The effect of the reaction pattern on the combustion process is determined by voltage, frequency and type of discharge. It has also been observed that the exhaust gas can be affected and controlled by the influence of electricity. since the exhaust gas can be conveyed back to the combustion zone and participate in a more complete combustion reaction.
Tests show that emissions of uncombusted hydrocarbons, carbon monoxide and particulate material are reduced by means of the invention and that nitrous compounds become less unstable with less of the natural nitrogen component in the combustion air being converted to NOx. The total electrical influence leads to conditions which increase the potential for influencing the combustion pattern in a positive direction, since the incandescence, the flame intensity and the flame pattern, together with the exhaust gas can be controlled to a very great extent by means of the described influences.
The invention will now be explained in more detail by means of embodiments which are disclosed in the attached drawings, which illustrate in purely schematic form the principle of a design of the invention. Other embodiments may also be used.
Figure 1 is a section of a combustion chamber preferably intended for liquid and gaseous fuels.
Figure 2 is a section of a combustion chamber preferably intended for solid fuels.
Figure 3 is a section of a combustion chamber with an outlet for exhaust gas in one of the sides.
Figure 4 illustrates various forms of electrodes.
Figure 1 illustrates a combustion chamber 1 with an inlet 2 for fuel in the lower part of the combustion chamber. The fuel can be gaseous or liquid, but all types of fuel can be employed. Around the fuel inlet 2 there is coaxially located an inlet 3 for an oxidation means such as air. The air inlet 3 may also be located beside the fuel inlet 2. The reference numeral 4 indicates the flame zone. In the upper part of the combustion chamber is an outlet 5 for exhaust gas. At the fuel inlet 2 and the air inlet 3 or at the start of the flame zone 4 there are located one or more electrodes 6. The electrode 6 is electrically insulated from the combustion chamber by means of insulation material which can be in the form of a ring 10. In the upper part of the combustion chamber 1 over or around the flame zone there are located one or more electrodes 7 which are electrically insulated from the combustion chamber by means of electrical insulation material 10. The electrodes 6 and 7 are connected to a voltage generator 1 1 which supplies voltage to the electrodes, either direct voltage, pulsating direct voltage or alternating voltage. In the figure electrodes 6 and 7 are coupled to a voltage generator 1 1 via tem¬ perature-resistant cables 9 which are inserted into the combustion chamber 1 through an insulator 10. The electrodes 6 and 7 are coupled to voltage with opposite polarity, thus forming an electrical field between the electrodes 6 and 7. There is a choice of either connecting one of the electrodes 6. 7 to the combustion chamber 1 or using the combustion chamber 1 as an electrode.
Figure 2 illustrates a combustion chamber 1 preferably for solid fuels. A fuel inlet 2 and an air inlet 3 are located in the side wall of the combustion chamber 1. An electrically conducting grate 13 forms the base for the fuel 16. The grate 13 is insulated from the combustion chamber 1 by means of heat- resistant insulators 15 which can be constructed in one piece as a ring. Ceramics can be used as insulation material. The grate 13 permits the through-flow of air and ash to fall through. For practical reasons the entire cross section of the combustion chamber 1 can be in the form of a grate. The grate 13 can also be made of an electrically neutral material. When such an embodiment is utilized, an electrode 6 is located under the grate. The reference numeral 4 indicates the flame zone. In the upper part of the combustion chamber 1 is an outlet 5 for exhaust gas. At the outlet area for exhaust gas in the upper part of the combustion chamber 1 there are located one or more electrodes 7 at or above the flame zone 4. The electrode 7 is electrically insulated from the combustion chamber 1 by means of electrical insulation material 10. The electrodes 7. 14. the grate 13 and possibly the electrode 6 are coupled to the voltage generator 1 1 by means of temperature- resistant cables 9 which are inserted into the combustion chamber 1 through insulators 10. The electrodes 7 and 6 are connected to voltage with opposite polarity, thus forming a field between the electrodes. The electrode 6 can have an electrical earth connection. An electrode 14 can be located in or immediately in front of the air inlet 3 for ionization of the inlet air and the combustion atmosphere. In patent application xxx from the same applicant reference is made to the use of a mixing chamber in the outlet area 5. When a mixing chamber is employed it can be used as an electrode 7, or be equipped with electrodes 7 which are insulated from the mixing chamber. One or more electrodes 8 and 8b are located in the lower part of the combustion chamber 1 at the same height as the fuel 16 or immediately above it. The electrodes 8 and 8b are preferably located at the same level at an equal distance from each other around the fuel 16. Such electrodes can also be located in the combustion chamber 1 where liquid and gaseous fuel are employed. The effect on the incandescence or combustion will be strongest where the field is strongest and most concentrated. In some cases, such as. for example, during heating, a slow combustion is desirable and two horizontal electrodes 8 and 8b have therefore been inserted with the object of increasing the intensity of incandescence in the combustion as required. This electrode arrangement is a kind of replacement for the effect of a traditional bellows. The obvious effect of using an electrode system of this kind is the creation of a wind-like atmosphere which blows life into the incandescence. The phenomenon can be characterized as an electron wind where the air masses are not moved in a traditional manner, but the practical effect of an electron wind is obtained between the electrodes. The object of the horizontal electrodes is to shorten the heating phase, thus reducing the period between ignition and steady combustion. As previously mentioned, it is the heating period which is the most unstable and polluting. When used in practice the horizontal electrodes should be capable of acting independently of the other electrodes, since they are activated or switched off as required. In practice it can be said that the electrodes above and below the flame zone force the exhaust gas and the particles down into the combustion and the horizontal electrodes intensify the actual incandescence. This is highly effective in those cases where a rapid burning up of the combustion material is desired, for example in the case of refuse incineration.
Figure 3 illustrates a combustion chamber 1 with a flue outlet 5 in one of the sides. In the figure the flue outlet is located at the back edge 17 of the combustion chamber 1. In the example the pair of electrodes 6 and 7 are located on each side, one on each of the chamber walls 19 and 20. The actual incandescent combustion 23 takes place in the bottom 21 of the chamber and the flame combustion 4 in the central zone of the chamber. Upper flames 22 pass between the electrodes 6 and 7 where they are influenced by the electrical field and the discharge between them. One of the electrodes 6 and 7 may be omitted and replaced by a combustion chamber wall 20 or 19 which is then employed as an electrode. The combustion chamber 1 may be used as an electrode. One of the electrodes 6 or 7 or possibly both can be mounted at a certain angle in relation to the combustion chamber walls 19 and 20 in order to give the electrical field a favourable direction in relation to the flame zone 4. The reference numeral 12 indicates the earthing point. The electrodes 6. 7 are connected to an electrical voltage generator 1 1 by means of cables 9 which are inserted into the combustion chamber 1 through insulators 10. Figure 4.1 illustrates forms of electrodes where electrodes 7 and 6 are flat and circular or oval plates which are preferably located horizontally above each other, thus forming an electrode pair. In the centre of the upper and lower electrodes 7 and 6 there is located a screw 9b. which in the upper electrode 7 is surrounded by an insulating material 10. The object of the insulator 10 is to insulate the electrode 7 from the combustion chamber 1. The screw is electrically conducting and conducts electric current up to the actual electrodes 6 and 7 from cable 9. The lower electrode 6 can be connected to electric earth 12 as an alternative to voltage 1 1. The object of the screw arrangement 9b is that it anchors the electrode to the combustion chamber 1 and facilitates the maintenance work since the electrode 7 can easily be unscrewed and cleaned or replaced.
Figure 4.2 illustrates the electrode 7 supplied with discharge points 7a.
Figure 4.3 illustrates electrodes 7 and 7a equipped with holes 7b for gas through- flow.
Figure 4.4. The incandescence electrodes 8 and 8b are in the form of rods where a part of the rod is surrounded by insulating material 10. The electrode is connected to an electrical conductor 9 via a screw 9b. The electrodes consist of a temperature-resistant and an electrically conducting end 8c. 8d. Se and 8f against the high temperature side. This end has voltage impressed to such a degree that a discharge occurs in the direction towards the incandescence 23. The end can either be in the form of a point 8d. a ball 8c. a plate 8e or a brush 8f. depending on which type of discharge is required.
Figure 4.5 illustrates a plate-shaped, curved plate electrode 25 as the upper electrode in combination with a flat, circular bottom electrode 6. In addition the electrode 25 can be like electrode 7 with discharge points and perforations.
Figure 4.6 illustrates a top electrode 7 in the form of a funnel in which the outer walls 28 of the funnel are impressed with voltage from the voltage generator 1 1 or earthed 12. In the centre of the funnel 26 there is located a current-carrying wire electrode 27 which is impressed with high voltage. The wire 27 is electrically insulated from the funnel 28 by means of an insulator 10. The wire 27 may be replaced by a brush or cord-shaped metallic discharger. The reference numeral 24 indicates a flame zone. The electrode 26 is located around the flame zone and the electrode 27 projects down into the flame zone 24.
Figure 4.7 consists of a funnel as described under figure 4.6. but this has a narrowing in the form of a venturi 29 in the flow passage 24. The venturi 29 can either be in electrical contact with the actual funnel 26 or insulated from the funnel 26 by means of an insulator 10.
Figure 4.8 consists of a fan electrode 30 in which the fan blades 3 1 are impressed with electrical voltage. The electrode 31 is impressed with electrical voltage from the voltage generator 1 1 with opposite polarity to the surrounding reference electrode 32. or it is connected to earth 12. The fan 30 revolves due to currents from the combustion gases or it can rotate by being connected to a shaft. The reference electrode 32 can either be an independent ring or the actual combustion chamber 1. The fan electrode 30 is employed in the upper part of the combustion.
Figure 4.9 consists of a spiral-shaped electrode 32 which permits flames to flow freely between each of the spirals 33 and 34. Each isolated spiral 33 and 34 is connected to the voltage generator 1 1 where one of the spiral electrodes receives the opposite electrical charge to the other. In the centre of the spirals 33 and 34 there is located an electrical insulator 10 the object of which is to insulate the electrodes from one another and to act as a suspension means for the electrode 32 in the combustion chamber 1. One of the spiral electrodes 33 and 34 can be connected to earth 12.
Figure 4.10 consists of an electrode 39 which acts as an ion trap for use in the upper part of the combustion chamber where the combustion passes from the flame to the gas phase. The electrode 39 consists of an outer ring 40 and an inner core 41 held together by insulators 10. The object of this type of electrode is to obtain a powerful discharge between the ring 40 and the core 41 where upper flames and exhaust gas have to pass. It will thereby be possible to neutralize the gas or convert it to harmless components while at the same time any particles in the exhaust gas are precipitated in the field. The reference numeral 24 indicates the flow passage for combustion elements. The electrodes illustrated in figures 1.2 and 3 together with the combustion chamber 1 can be individually coupled to electrical voltage and negative or positive polarity. Alternating voltage may also be employed. The voltage may be connected intermittently and it can also be reversed for periods.
In figures 1 and 2 electrodes 6 and 13 are preferably located under or at the lower part of the flame zone 4. connected to positive polarity. Electrode 7 in the upper part of the combustion chamber above or at the flame zone 4 is preferably connected to negative polarity. The combustion chamber 1 is normally made of metal and can also be used as an electrode. The combustion chamber 1 may. e.g., be connected to negative polarity and is used as an electrode either alone or in addition to electrode 7. The combustion chamber 1 is preferably connected to earth 12 or to a neutral point.
Other connections are also possible. For instance, the combustion chamber 1 and the lead-in pipes 2 and 3 for fuel and air respectively are connected to earth or a neutral point and electrode 7 is connected to alternating λ oltage. preferably high-frequency.
In figure 2 the electrodes 8 and 8b are located horizontally on the same level as the incandescent zone, thus forming a field between them. Electrode 8b is preferably connected to negative polarity and its primary purpose is to change the flame pattern or the incandescence, thus enabling, for example, long flames with a small surface area to be altered in appearance to a plurality of small tongues of flame with a substantially greater total surface area than the long flames.
The electrode 14 which is located in connection with the combustion air in the air inlet 3 is preferably connected to negative polarity and should be of such a nature that it ionizes the air which is used in the combustion. This is achieved by an electrode point consisting of one or more points, preferably points in the form of a brush where the brush consists of several thin metallic wires.
A fuel electrode can be located in connection with liquid fuel and is employed in such a manner that the fuel has the opposite polarity to the air. the electrode being connected to the actual fuel and the fuel thereby acting as a secondary electrode since the polar electrode has no other electrically reactive components in its vicinity than the actual fuel molecules. In zones where fuel is charged, the fuel pipe should be of an insulating nature.
The electrodes can be connected to direct voltage, preferably pulsating direct voltage, i.e. direct voltage with overlaid alternating voltage. It has been shown that the pulse frequency affects the efficiency of the system. A pulse frequency between 1 Hz and 3000 MHz has been employed and it has been shown that specific pulse frequencies give a greater reduction in harmful substances in the exhaust gas when one type of fuel is used. In table 1 below there is a list of some fuels and pulse frequencies which affect the combustion in a positive direction, thus achieving a reduction in harmful substances in the exhaust gas and better combustion in individual, special types of combustion. Results have also been obtained in the form of improved combustion of exhaust gas by means of frequencies in the gigahertz range.
In future applications, a decision will have to be taken on the choice of fre- quency. voltage and type of discharge dependent on the nature of the fuel and the combustion chamber. It should be possible to choose any combination of electrical parameters for specific purposes without being confined to the individual values which are expressed in table 1.
The following table illustrates an example of some electrical parameters in the form of frequencies and discharge characteristics which are employed in experimentation with the combustion materials listed when used in combustion in small combustion chambers with a chamber volume of 0.75 m3. The examples are representative of conducted experiments and should not be regarded as limiting for subsequent choice of other values, e.g. other frequencies or voltages with the said fuel types.
TABLE 1
Fuel Electrode voltage Frequency Polarity Earth conductor to
Light oil: 20 KV per electrode 8 KHz Pos.Neg. Combustion chamber
Gas: 5 KV per electrode 8 KHz Pos.Neg. Combustion chamber Charcoal: 10 KV per electrode 13.5 KHz Neg. Grate
Coal: 30 KV per electrode 12.5 KHz Neg. Grate The pulse amplitude can be up to 100% of the direct voltage. A pulse amplitude between 10% and 50% is preferably employed. Alternating voltage, preferably high-frequency alternating voltage, can also be employed.
The magnitude of the electrical voltage which is supplied to the electrodes is dependent on the dimensions of the combustion chamber and the distance between the electrodes. The combustion temperature and the natural ionization in the combustion are also important for the voltage supplied. The strength of the electrical field in the flame zone between the electrodes can be in the range 0.01 to 25 kV/cm. preferably in the range between 0.2 and 1 kV/cm.
The power which is supplied to the electrode system is dependent on the dimensions of the combustion chamber, the design of the electrode, the fuel. the ionization of the combustion, the combustion temperature and the number of electrodes. Tests in a combustion chamber whose physical measurements are: lateral surfaces 50 cm. height 68 cm. chamber width 60 cm. show that with dry wood as fuel a substantial reduction in PM. HC and CO is already obtained when power is supplied in the range 2 to 5 watts. This is one of the advantages of the invention. During normal operation the power supplied was in the range 10 watts with a field strength between the electrodes of 0.25 kV/cm. The voltage was pulsating direct voltage with a pulse frequency in the range 12 kHz and the pulse amplitude was in the range 10% of the direct voltage. In a practical application of the invention, frequencies above the audible range will have to be used in. for example, fireplaces with or without doors. In an industrial context the audibility of the discharge is of less importance.
A flame contains countless ions. These serve as electrical charge carriers. In a flame chargeable flue gas particles are also ionized. Oxygen, carbon dioxide and steam normally form a majority of negative ions and the flue gas particles are probably also negatively charged in a flame. Negative particles and ions are thereby repelled by a negatively charged electrode which is above the flame zone and are thereby forced downwards in the combustion chamber by the upper electrode and pressed back into the flame zone where they are combusted. The upper part of the combustion chamber acts as an afterburning zone and the content of particulate material (PM). hydrocarbons (HC) and carbon monoxide (CO) are reduced in the combustion gas. This is also one of the advantages of the invention. Table 2 illustrates the content of these substances without and with electrical influence on the combustion in a combustion chamber as mentioned above with a lateral surface of 50 cm. height of 68 cm and chamber width of 60 cm.
TABLE 2
Particles per kg combusted mass, spruce ace. to NS 3058 HC ppm CO vol.%
Without influence 9-12 g/kg 150-210 1 ,2-2,3 With influence 1 -5 ε/kε 20-50 0.1-0.5

Claims

PATENT CLAIMS
1. A device for use in combustion chambers, such as all types and sizes of stove and fireplace, designed as a container with an inlet for the supply of a fuel and an oxidation means in the form of air and with an outlet for exhaust gas, characterized in that one or more electrodes are located in such a manner that the flame zone is located between two of the electrodes or between one electrode and a combustion chamber wall and that the electrodes and possibly also the combustion chamber are connected to electrical voltage, thus forming poles in an electrical system.
2. A device for use in combustion chambers according to claim 1. characterized in that one or more electrodes are located in the low er part of the combustion chamber at or under the flame zone and that one or more electrodes are located in the upper part of the combustion chamber at or above the flame zone.
3. A device for use in combustion chambers according to one of the preceding claims. characterized in that two or more electrodes are located in the upper part of the combustion chamber in such a manner that the flame zone is located between the electrodes, or between one electrode and a combustion chamber wall.
4. A device for use in combustion chambers according to one of the preceding claims. characterized in that one or more electrodes are located at the inlet for or under the fuel or the grate.
5. A device for use in combustion chambers according to one of the preceding claims. characterized in that one or more electrodes are located at or in the inlet for air.
6. A device for use in combustion chambers according to one of the preceding claims. characterized in that one or more electrodes are located at the outlet area for exhaust gas.
7. A device for use in combustion chambers according to one of the preceding claims. characterized in that electrodes and combustion chamber can be coupled individually to electrical voltage and negative or positive polarity and that the voltage direction can be reversed for periods, and that the voltage may be connected intermittently.
8. A device for use in combustion chambers according to one of the preceding claims. characterized in that the voltage which is supplied is direct voltage or pulsating direct voltage with a pulse frequency in the range 1 Hz to 3000 MHz.
9. A device for use in combustion chambers according to one of the preceding claims. characterized in that the field strength in the flame zone is in the range 0.01 kV/cm to 30 kV/cm.
10. A device for use in combustion chambers according to one of the preceding claims. characterized in that one or more electrodes in the lower part of the combustion chamber at or under the flame zone are preferably coupled to positive polarity and one or more electrodes in the upper part of the combustion chamber at or above the flame zone and/or the combustion chamber are preferably coupled to negative polarity.
1 1. A device for use in combustion chambers according to one of the preceding claims. characterized in that one or more electrodes are provided around the fuel in the lower part of the combustion chamber.
12. A device for use in combustion chambers according to one of the preceding claims when a mixing chamber is used, thus forming one or more afterburninε zones. characterized in that the mixing chamber is equipped with electrodes or is employed as an electrode.
13. A device for use in combustion chambers according to one of the preceding claims. characterized in that the electrodes on each side of the flame zone can be located at any angle whatever in relation to one another and the flame zone, preferably parallel to one another.
PCT/NO1995/000118 1994-07-01 1995-06-30 An electrode arrangement for use in a combustion chamber WO1996001394A1 (en)

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NO942504A NO180315C (en) 1994-07-01 1994-07-01 Combustion chamber with equipment to improve combustion and reduce harmful substances in the exhaust gas

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NO942504L (en) 1996-01-02
AU2938695A (en) 1996-01-25

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