WO1996040374B1 - Production de flux d'halogene et d'oxyde de carbone - Google Patents
Production de flux d'halogene et d'oxyde de carboneInfo
- Publication number
- WO1996040374B1 WO1996040374B1 PCT/US1996/008381 US9608381W WO9640374B1 WO 1996040374 B1 WO1996040374 B1 WO 1996040374B1 US 9608381 W US9608381 W US 9608381W WO 9640374 B1 WO9640374 B1 WO 9640374B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon
- molten metal
- bath
- gas
- halogenated organic
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract 51
- 229910002090 carbon oxide Inorganic materials 0.000 title claims abstract 35
- 150000002367 halogens Chemical class 0.000 title claims abstract 24
- 229910052811 halogen oxide Inorganic materials 0.000 title 1
- 239000007789 gas Substances 0.000 claims abstract 61
- 238000000034 method Methods 0.000 claims abstract 61
- 229910052751 metal Inorganic materials 0.000 claims abstract 55
- 239000002184 metal Substances 0.000 claims abstract 55
- 229910021398 atomic carbon Inorganic materials 0.000 claims abstract 25
- 229910052736 halogen Inorganic materials 0.000 claims abstract 23
- 239000010815 organic waste Substances 0.000 claims abstract 20
- 230000003647 oxidation Effects 0.000 claims abstract 19
- 238000007254 oxidation reaction Methods 0.000 claims abstract 19
- 239000007800 oxidant agent Substances 0.000 claims abstract 17
- 230000001590 oxidative effect Effects 0.000 claims abstract 17
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract 9
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract 9
- 230000015572 biosynthetic process Effects 0.000 claims abstract 7
- 239000001257 hydrogen Substances 0.000 claims abstract 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 34
- 239000012433 hydrogen halide Substances 0.000 claims 27
- 229910000039 hydrogen halide Inorganic materials 0.000 claims 27
- 229910052759 nickel Inorganic materials 0.000 claims 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 10
- 229910052802 copper Inorganic materials 0.000 claims 10
- 239000010949 copper Substances 0.000 claims 10
- 229910052799 carbon Inorganic materials 0.000 claims 9
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 8
- 239000001569 carbon dioxide Substances 0.000 claims 8
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 4
- 229910052794 bromium Inorganic materials 0.000 claims 4
- 229910052801 chlorine Inorganic materials 0.000 claims 4
- 239000000460 chlorine Substances 0.000 claims 4
- 239000011737 fluorine Substances 0.000 claims 4
- 229910052731 fluorine Inorganic materials 0.000 claims 4
- 150000008282 halocarbons Chemical class 0.000 claims 4
- 239000011630 iodine Substances 0.000 claims 4
- 229910052740 iodine Inorganic materials 0.000 claims 4
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 claims 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 claims 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 2
- 239000003638 chemical reducing agent Substances 0.000 claims 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910001882 dioxygen Inorganic materials 0.000 claims 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 239000010931 gold Substances 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 238000002347 injection Methods 0.000 claims 2
- 239000007924 injection Substances 0.000 claims 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims 2
- 150000003071 polychlorinated biphenyls Chemical class 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 229910000570 Cupronickel Inorganic materials 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims 1
- 229960003750 ethyl chloride Drugs 0.000 claims 1
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 claims 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Abstract
L'invention porte sur un procédé permettant de traiter des déchets organiques halogénés afin de produire des flux de gaz halogène et de gaz d'oxyde de carbone. Ce procédé consiste à amener des déchets organiques halogénés, dont le rapport atomique halogène-hydrogène est inférieur à environ 1, dans un bain de métal en fusion. Le bain de métal en fusion est inerte par rapport à l'halogène et possède une énergie d'oxydation libre supérieure à celle de la formation de monoxyde de carbone à partir de carbone atomique. La charge de déchets organiques halogénés est convertie en gaz halogène et en carbone atomique, à la suite de quoi le gaz halogène est libéré du bain de métal en fusion. On amène un agent oxydant dans un bain de métal en fusion, de manière à ce que le carbone atomique soit oxydé pour former un gaz d'oxyde de carbone, qui est émis libéré du bain de métal en fusion.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU59685/96A AU5968596A (en) | 1995-06-07 | 1996-06-03 | Production of halogen and carbon oxide streams |
| JP9500999A JPH11506720A (ja) | 1995-06-07 | 1996-06-03 | ハロゲン及び炭素酸化物流の製造 |
| EP96916979A EP0843579A1 (fr) | 1995-06-07 | 1996-06-03 | Production de flux d'halogene et d'oxyde de carbone |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/478,439 US5695732A (en) | 1995-06-07 | 1995-06-07 | Method for treating a halogenated organic waste to produce halogen gas and carbon oxide gas streams |
| US08/478,439 | 1995-06-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1996040374A1 WO1996040374A1 (fr) | 1996-12-19 |
| WO1996040374B1 true WO1996040374B1 (fr) | 1997-01-30 |
Family
ID=23899941
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1996/008381 WO1996040374A1 (fr) | 1995-06-07 | 1996-06-03 | Production de flux d'halogene et d'oxyde de carbone |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5695732A (fr) |
| EP (1) | EP0843579A1 (fr) |
| JP (1) | JPH11506720A (fr) |
| AU (1) | AU5968596A (fr) |
| TW (1) | TW350019B (fr) |
| WO (1) | WO1996040374A1 (fr) |
| ZA (1) | ZA964418B (fr) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5769924A (en) * | 1996-08-14 | 1998-06-23 | Eckert; C. Edward | Method of treating aluminum with chlorine produced from chlorocarbon compounds |
| WO2002100563A1 (fr) * | 2001-06-08 | 2002-12-19 | Hiroshi Suzuki | Procede et appareil permettant la decomposition d'une matiere contenant des substances organiques |
| US20070253807A1 (en) | 2006-04-28 | 2007-11-01 | Cooper Paul V | Gas-transfer foot |
| US7470392B2 (en) | 2003-07-14 | 2008-12-30 | Cooper Paul V | Molten metal pump components |
| US7731891B2 (en) | 2002-07-12 | 2010-06-08 | Cooper Paul V | Couplings for molten metal devices |
| US7402276B2 (en) | 2003-07-14 | 2008-07-22 | Cooper Paul V | Pump with rotating inlet |
| US20050013715A1 (en) | 2003-07-14 | 2005-01-20 | Cooper Paul V. | System for releasing gas into molten metal |
| US7507367B2 (en) | 2002-07-12 | 2009-03-24 | Cooper Paul V | Protective coatings for molten metal devices |
| US7906068B2 (en) | 2003-07-14 | 2011-03-15 | Cooper Paul V | Support post system for molten metal pump |
| US9410744B2 (en) | 2010-05-12 | 2016-08-09 | Molten Metal Equipment Innovations, Llc | Vessel transfer insert and system |
| US9643247B2 (en) | 2007-06-21 | 2017-05-09 | Molten Metal Equipment Innovations, Llc | Molten metal transfer and degassing system |
| US8613884B2 (en) | 2007-06-21 | 2013-12-24 | Paul V. Cooper | Launder transfer insert and system |
| US9205490B2 (en) | 2007-06-21 | 2015-12-08 | Molten Metal Equipment Innovations, Llc | Transfer well system and method for making same |
| US8366993B2 (en) | 2007-06-21 | 2013-02-05 | Cooper Paul V | System and method for degassing molten metal |
| US8337746B2 (en) | 2007-06-21 | 2012-12-25 | Cooper Paul V | Transferring molten metal from one structure to another |
| US9409232B2 (en) | 2007-06-21 | 2016-08-09 | Molten Metal Equipment Innovations, Llc | Molten metal transfer vessel and method of construction |
| US9156087B2 (en) | 2007-06-21 | 2015-10-13 | Molten Metal Equipment Innovations, Llc | Molten metal transfer system and rotor |
| CN102387839A (zh) * | 2009-02-11 | 2012-03-21 | 自然能源系统公司 | 用于将有机物质转变成富甲烷燃料气的方法 |
| US8535603B2 (en) | 2009-08-07 | 2013-09-17 | Paul V. Cooper | Rotary degasser and rotor therefor |
| US8524146B2 (en) | 2009-08-07 | 2013-09-03 | Paul V. Cooper | Rotary degassers and components therefor |
| US8449814B2 (en) | 2009-08-07 | 2013-05-28 | Paul V. Cooper | Systems and methods for melting scrap metal |
| US8444911B2 (en) | 2009-08-07 | 2013-05-21 | Paul V. Cooper | Shaft and post tensioning device |
| US10428821B2 (en) | 2009-08-07 | 2019-10-01 | Molten Metal Equipment Innovations, Llc | Quick submergence molten metal pump |
| US8714914B2 (en) | 2009-09-08 | 2014-05-06 | Paul V. Cooper | Molten metal pump filter |
| US9108244B2 (en) | 2009-09-09 | 2015-08-18 | Paul V. Cooper | Immersion heater for molten metal |
| US8309049B2 (en) | 2009-10-19 | 2012-11-13 | Battelle Energy Alliance, Llc | Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor |
| US8128902B2 (en) * | 2011-04-12 | 2012-03-06 | Midwest Refrigerants, Llc | Method for the synthesis of anhydrous hydrogen halide and anhydrous carbon dioxide |
| US8834830B2 (en) | 2012-09-07 | 2014-09-16 | Midwest Inorganics LLC | Method for the preparation of anhydrous hydrogen halides, inorganic substances and/or inorganic hydrides by using as reactants inorganic halides and reducing agents |
| US9903383B2 (en) | 2013-03-13 | 2018-02-27 | Molten Metal Equipment Innovations, Llc | Molten metal rotor with hardened top |
| US9011761B2 (en) | 2013-03-14 | 2015-04-21 | Paul V. Cooper | Ladle with transfer conduit |
| US10052688B2 (en) | 2013-03-15 | 2018-08-21 | Molten Metal Equipment Innovations, Llc | Transfer pump launder system |
| US10138892B2 (en) | 2014-07-02 | 2018-11-27 | Molten Metal Equipment Innovations, Llc | Rotor and rotor shaft for molten metal |
| US10947980B2 (en) | 2015-02-02 | 2021-03-16 | Molten Metal Equipment Innovations, Llc | Molten metal rotor with hardened blade tips |
| US10267314B2 (en) | 2016-01-13 | 2019-04-23 | Molten Metal Equipment Innovations, Llc | Tensioned support shaft and other molten metal devices |
| US11149747B2 (en) | 2017-11-17 | 2021-10-19 | Molten Metal Equipment Innovations, Llc | Tensioned support post and other molten metal devices |
| US11358217B2 (en) | 2019-05-17 | 2022-06-14 | Molten Metal Equipment Innovations, Llc | Method for melting solid metal |
| US11873845B2 (en) | 2021-05-28 | 2024-01-16 | Molten Metal Equipment Innovations, Llc | Molten metal transfer device |
| US12146508B2 (en) | 2022-05-26 | 2024-11-19 | Molten Metal Equipment Innovations, Llc | Axial pump and riser |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3445192A (en) * | 1963-03-25 | 1969-05-20 | Hooker Chemical Corp | Apparatus for production and recovery of hydrogen halides |
| DE2261795C3 (de) * | 1972-12-16 | 1975-05-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Chlorwasserstoff durch thermische Spaltung organischer chlorenthaltender Stoffe |
| BE817313A (fr) * | 1974-07-05 | 1974-11-04 | Procede de desoxydation du cuivre et de ses alliages. | |
| JPS5573835A (en) * | 1978-11-21 | 1980-06-03 | Fuji Electric Co Ltd | Metal recovering method |
| US4246255A (en) * | 1979-04-02 | 1981-01-20 | Rockwell International Corporation | Disposal of PCB |
| US4337368A (en) * | 1980-04-21 | 1982-06-29 | The Franklin Institute | Reagent and method for decomposing halogenated organic compounds |
| US4469661A (en) * | 1982-04-06 | 1984-09-04 | Shultz Clifford G | Destruction of polychlorinated biphenyls and other hazardous halogenated hydrocarbons |
| US4497782A (en) * | 1982-10-28 | 1985-02-05 | S. Garry Howell | Method for destroying toxic organic chemical products |
| US4447262A (en) * | 1983-05-16 | 1984-05-08 | Rockwell International Corporation | Destruction of halogen-containing materials |
| US4552667A (en) * | 1984-06-25 | 1985-11-12 | Shultz Clifford G | Destruction of organic hazardous wastes |
| US4574714A (en) * | 1984-11-08 | 1986-03-11 | United States Steel Corporation | Destruction of toxic chemicals |
| US4602574A (en) * | 1984-11-08 | 1986-07-29 | United States Steel Corporation | Destruction of toxic organic chemicals |
| EP0371201A1 (fr) * | 1988-12-01 | 1990-06-06 | Ruhrkohle Aktiengesellschaft | Procédé d'hydrogénation des composés organochlorés et de neutralisation du gaz chlorhydrique en résultant ainsi qu'un agent de neutralisation pour le gaz chlorhydrique résultant des composés organochlorés |
| SE467483B (sv) * | 1989-11-24 | 1992-07-27 | Ips Interproject Service Ab | Foerfarande foer destruktion av halogenhaltiga substanser |
| US5084264A (en) * | 1989-12-12 | 1992-01-28 | Battelle Memorial Institute | Process for oxidation of hydrogen halides to elemental halogens |
| US5177304A (en) * | 1990-07-24 | 1993-01-05 | Molten Metal Technology, Inc. | Method and system for forming carbon dioxide from carbon-containing materials in a molten bath of immiscible metals |
| CA2113174A1 (fr) * | 1991-07-29 | 1993-02-18 | Casey E. Mcgeever | Methode et systeme d'oxydation en bain de fusion |
| US5191154A (en) * | 1991-07-29 | 1993-03-02 | Molten Metal Technology, Inc. | Method and system for controlling chemical reaction in a molten bath |
| GB9216666D0 (en) * | 1992-08-06 | 1992-09-23 | Electricity Ass Tech | A process for the destruction of halocarbons |
| US5435982A (en) * | 1993-03-31 | 1995-07-25 | Molten Metal Technology, Inc. | Method for dissociating waste in a packed bed reactor |
| US5301620A (en) * | 1993-04-01 | 1994-04-12 | Molten Metal Technology, Inc. | Reactor and method for disassociating waste |
| US5537940A (en) * | 1993-06-08 | 1996-07-23 | Molten Metal Technology, Inc. | Method for treating organic waste |
-
1995
- 1995-06-07 US US08/478,439 patent/US5695732A/en not_active Expired - Lifetime
-
1996
- 1996-05-30 ZA ZA964418A patent/ZA964418B/xx unknown
- 1996-06-03 WO PCT/US1996/008381 patent/WO1996040374A1/fr not_active Application Discontinuation
- 1996-06-03 JP JP9500999A patent/JPH11506720A/ja active Pending
- 1996-06-03 AU AU59685/96A patent/AU5968596A/en not_active Abandoned
- 1996-06-03 EP EP96916979A patent/EP0843579A1/fr not_active Withdrawn
- 1996-06-04 TW TW085106641A patent/TW350019B/zh active
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