WO1995027036A1 - Detergent en pains de lessive contenant de l'argile adoucissant le tissu et de la cellulase - Google Patents
Detergent en pains de lessive contenant de l'argile adoucissant le tissu et de la cellulase Download PDFInfo
- Publication number
- WO1995027036A1 WO1995027036A1 PCT/US1995/002733 US9502733W WO9527036A1 WO 1995027036 A1 WO1995027036 A1 WO 1995027036A1 US 9502733 W US9502733 W US 9502733W WO 9527036 A1 WO9527036 A1 WO 9527036A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- clay
- weight
- laundry
- detergent
- bar
- Prior art date
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- 239000004927 clay Substances 0.000 title claims abstract description 86
- 239000003599 detergent Substances 0.000 title claims abstract description 70
- 239000004744 fabric Substances 0.000 title claims abstract description 39
- 108010059892 Cellulase Proteins 0.000 title claims abstract description 30
- 239000000203 mixture Chemical class 0.000 claims abstract description 77
- -1 poly(ethylene oxide) Polymers 0.000 claims abstract description 72
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- 239000003945 anionic surfactant Substances 0.000 claims abstract description 18
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- 239000004094 surface-active agent Substances 0.000 claims description 40
- 125000000217 alkyl group Chemical group 0.000 claims description 32
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 12
- 238000012423 maintenance Methods 0.000 claims description 8
- 235000011180 diphosphates Nutrition 0.000 claims description 5
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 abstract description 17
- 239000013522 chelant Substances 0.000 abstract description 15
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 10
- 150000001340 alkali metals Chemical group 0.000 abstract description 7
- QTONSPKDOKVNBJ-UHFFFAOYSA-N acetic acid;n'-(2-aminoethyl)ethane-1,2-diamine Chemical class CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCNCCN QTONSPKDOKVNBJ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract description 2
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical class OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 abstract description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical class OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- FRTNIYVUDIHXPG-UHFFFAOYSA-N acetic acid;ethane-1,2-diamine Chemical class CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN FRTNIYVUDIHXPG-UHFFFAOYSA-N 0.000 abstract 1
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 8
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- 239000011591 potassium Substances 0.000 description 6
- 108090001060 Lipase Proteins 0.000 description 5
- 102000004882 Lipase Human genes 0.000 description 5
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- 239000011575 calcium Substances 0.000 description 5
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
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- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 235000019698 starch Nutrition 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0069—Laundry bars
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Un pain de lessive contient d'environ 10 % à environ 60 % en poids de tensioactif anionique, d'environ 5 % à environ 60 % en poids d'un adjuvant au pouvoir détergent, et d'environ 0,02 % à environ 2 % en poids de cellulases. Selon un mode de réalisation préféré, un pain de lessive comprend également d'environ 0,5 % à environ 30 % d'une argile adoucissante de type smectite, et éventuellement un agent polymère séparant l'argile en flocons à un niveau d'environ 0,001 % à environ 30 % en poids d'argile adoucissant le tissu. Un agent préféré séparant l'argile en flocons est un poly(éthylène oxyde) ayant un poids moléculaire moyen de 100 000 à environ 10 millions. Un agent de chélation détergent éventuellement ajouté est de préférence un sel de métal alcalin, de métal alcalino-terreux, de métal lourd de diéthylènetriamine penta (acide méthylène phosphonique), diéthylènetriamine penta (acide acétique), éthylènediamine tétra (acide méthylène phosphonique), éthylènediamine tétra (acide acétique), et des mélanges de ceux-ci.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| MX9604431A MX9604431A (es) | 1994-03-30 | 1995-03-30 | Barras detergentes para lavanderia que contienen arcilla suavizadora de telas y enzima celulasa. |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PH48019 | 1994-03-30 | ||
| PH4801994 | 1994-03-30 | ||
| PH50203 | 1995-03-28 | ||
| PH5020395 | 1995-03-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1995027036A1 true WO1995027036A1 (fr) | 1995-10-12 |
Family
ID=26652401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1995/002733 WO1995027036A1 (fr) | 1994-03-30 | 1995-03-30 | Detergent en pains de lessive contenant de l'argile adoucissant le tissu et de la cellulase |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN1145094A (fr) |
| MA (1) | MA23492A1 (fr) |
| MX (1) | MX9604431A (fr) |
| WO (1) | WO1995027036A1 (fr) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997036985A1 (fr) * | 1996-03-29 | 1997-10-09 | The Procter & Gamble Company | Pain de detergent pour lessive, presentant une faible teneur en humidite et une stabilite d'enzyme amelioree |
| WO1998018897A1 (fr) * | 1996-10-31 | 1998-05-07 | The Procter & Gamble Company | Procede pour incorporer des enzymes dans des produits lessiviels en barre |
| WO1998054285A1 (fr) * | 1997-05-30 | 1998-12-03 | The Procter & Gamble Company | Barre de lessive contenant une protease d'une plus grande stabilite |
| WO1999020729A1 (fr) * | 1997-10-21 | 1999-04-29 | Stepan Company | Compositions pour pain de savon a base d'ester d'alkyle sulfone alpha et d'acide gras sulfone, et acides gras a chaine longue |
| WO2000040685A1 (fr) * | 1999-01-05 | 2000-07-13 | Unilever Plc | Traitement pour textiles |
| US6878680B2 (en) | 2002-05-02 | 2005-04-12 | Procter & Gamble | Detergent compositions and components thereof |
| US6916769B2 (en) | 2001-12-03 | 2005-07-12 | The Procter & Gamble Company | Fabric treatment composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2653880C (fr) * | 2006-05-31 | 2014-08-05 | Basf Se | Polymeres greffes amphiphiles a base d'oxydes de polyalkylene et esters vinyliques |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3798181A (en) * | 1970-11-03 | 1974-03-19 | Colgate Palmolive Co | Enzymatic detergent bar |
| JPS57108199A (en) * | 1980-12-24 | 1982-07-06 | Kao Corp | Detergent composition |
| EP0177165A2 (fr) * | 1984-08-29 | 1986-04-09 | Unilever Plc | Composition détergente |
| EP0495258A1 (fr) * | 1991-01-16 | 1992-07-22 | The Procter & Gamble Company | Compositions de détergent contenant de la cellulase de haute activité et de l'argile adoucissant |
| JPH05331497A (ja) * | 1992-05-29 | 1993-12-14 | Lion Corp | タブレット型洗剤組成物 |
| GB2278124A (en) * | 1993-05-17 | 1994-11-23 | Unilever Plc | Detergent composition |
-
1995
- 1995-03-30 CN CN 95192355 patent/CN1145094A/zh active Pending
- 1995-03-30 MA MA23821A patent/MA23492A1/fr unknown
- 1995-03-30 MX MX9604431A patent/MX9604431A/es unknown
- 1995-03-30 WO PCT/US1995/002733 patent/WO1995027036A1/fr active Application Filing
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3798181A (en) * | 1970-11-03 | 1974-03-19 | Colgate Palmolive Co | Enzymatic detergent bar |
| JPS57108199A (en) * | 1980-12-24 | 1982-07-06 | Kao Corp | Detergent composition |
| EP0177165A2 (fr) * | 1984-08-29 | 1986-04-09 | Unilever Plc | Composition détergente |
| EP0495258A1 (fr) * | 1991-01-16 | 1992-07-22 | The Procter & Gamble Company | Compositions de détergent contenant de la cellulase de haute activité et de l'argile adoucissant |
| JPH05331497A (ja) * | 1992-05-29 | 1993-12-14 | Lion Corp | タブレット型洗剤組成物 |
| GB2278124A (en) * | 1993-05-17 | 1994-11-23 | Unilever Plc | Detergent composition |
Non-Patent Citations (2)
| Title |
|---|
| DATABASE WPI Week 8232, Derwent World Patents Index; AN 82-67228E * |
| DATABASE WPI Week 9403, Derwent World Patents Index; AN 94-023143 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997036985A1 (fr) * | 1996-03-29 | 1997-10-09 | The Procter & Gamble Company | Pain de detergent pour lessive, presentant une faible teneur en humidite et une stabilite d'enzyme amelioree |
| WO1998018897A1 (fr) * | 1996-10-31 | 1998-05-07 | The Procter & Gamble Company | Procede pour incorporer des enzymes dans des produits lessiviels en barre |
| WO1998054285A1 (fr) * | 1997-05-30 | 1998-12-03 | The Procter & Gamble Company | Barre de lessive contenant une protease d'une plus grande stabilite |
| WO1999020729A1 (fr) * | 1997-10-21 | 1999-04-29 | Stepan Company | Compositions pour pain de savon a base d'ester d'alkyle sulfone alpha et d'acide gras sulfone, et acides gras a chaine longue |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| US6172026B1 (en) | 1997-10-21 | 2001-01-09 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| WO2000040685A1 (fr) * | 1999-01-05 | 2000-07-13 | Unilever Plc | Traitement pour textiles |
| US6916769B2 (en) | 2001-12-03 | 2005-07-12 | The Procter & Gamble Company | Fabric treatment composition |
| US6878680B2 (en) | 2002-05-02 | 2005-04-12 | Procter & Gamble | Detergent compositions and components thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| MX9604431A (es) | 1997-12-31 |
| MA23492A1 (fr) | 1995-10-01 |
| CN1145094A (zh) | 1997-03-12 |
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