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WO1995026991A1 - Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine - Google Patents

Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine Download PDF

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Publication number
WO1995026991A1
WO1995026991A1 PCT/FI1995/000176 FI9500176W WO9526991A1 WO 1995026991 A1 WO1995026991 A1 WO 1995026991A1 FI 9500176 W FI9500176 W FI 9500176W WO 9526991 A1 WO9526991 A1 WO 9526991A1
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WO
WIPO (PCT)
Prior art keywords
olefins
sep
process according
butene
butenes
Prior art date
Application number
PCT/FI1995/000176
Other languages
English (en)
Inventor
Frantis^¿ek MIKES^¿
Vlastimil HALAS^¿KA
Jan Pecka
Miroslav Marek
Erkki Halme
Salme Koskimies
Original Assignee
Neste Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oy filed Critical Neste Oy
Priority to AU21395/95A priority Critical patent/AU2139595A/en
Publication of WO1995026991A1 publication Critical patent/WO1995026991A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C07C2/22—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/10—Chlorides
    • C07C2527/11—Hydrogen chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un procédé de production d'huiles synthétiques et d'un produit à base de polymère oléfinique utile en tant qu'huile synthétique ou en tant que partie de celle-ci. Selon ce procédé, des hydrocarbures oléfiniques sont polymérisés de manière à former une huile possédant un index élevé de viscosité ainsi qu'un bas point d'écoulement. Selon l'invention, les hydrocarbures oléfiniques utilisés comprennent des oléfines C8-24 possédant une liaison interne double, lesquelles sont soumises à une réaction de polymérisation avec des oléfines inférieures, en particulier des 1- et 2-butènes. On effectue cette réaction en présence d'un initiateur de réaction contenant un composé de la formule générale (I) R2AlCl dans laquelle R représente halogène ou un groupe alcoyle contenant 1 à 6 atomes de carbone, de manière à obtenir un produit de polymérisation, puis on sépare le produit de polymérisation du mélange de réaction de manière à former une huile synthétique.
PCT/FI1995/000176 1994-03-31 1995-03-31 Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine WO1995026991A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU21395/95A AU2139595A (en) 1994-03-31 1995-03-31 A method to oligomerize c4 olefins together with long chain olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI941529 1994-03-31
FI941529A FI941529A7 (fi) 1994-03-31 1994-03-31 Menetelmä C4-öljyjen oligomeroimiseksi pitkäketjuisten olefiinien kanssa

Publications (1)

Publication Number Publication Date
WO1995026991A1 true WO1995026991A1 (fr) 1995-10-12

Family

ID=8540435

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1995/000176 WO1995026991A1 (fr) 1994-03-31 1995-03-31 Procede d'oligomerisation d'olefines c4 en meme temps que d'olefines a longue chaine

Country Status (3)

Country Link
AU (1) AU2139595A (fr)
FI (1) FI941529A7 (fr)
WO (1) WO1995026991A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735366B (zh) * 2009-12-17 2011-09-14 中国石油化工股份有限公司 一种用于减阻剂聚合用的复合给电子体
CN103289731A (zh) * 2012-02-28 2013-09-11 赵阳 一种内烯烃制备含芳烃合成烃的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3330883A (en) * 1964-04-06 1967-07-11 Gulf Research Development Co Copolymerization of low carbon number and high carbon number olefin fractions
US4311864A (en) * 1980-07-14 1982-01-19 Gulf Research & Development Company Method for preparing synthetic hydrocarbon fluids
US4434308A (en) * 1982-04-28 1984-02-28 Texaco Inc. Manufacture of synthetic lubricant additives from internal olefins using boron trifluoride catalysis
EP0337737A2 (fr) * 1988-04-15 1989-10-18 Neste Oy Procédé de préparation d'huiles de poly-N-butène d'une fraction-C4 résiduelle
EP0449453A2 (fr) * 1990-03-28 1991-10-02 Texaco Chemical Company Procédé pour l'oligomérisation d'oléfines pour préparer un matériau de base pour des lubrifiants synthétiques
WO1994015894A1 (fr) * 1992-12-30 1994-07-21 Neste Oy Procede d'oligomerisation d'olefines c4 avec des alpha-olefines lineaires

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3330883A (en) * 1964-04-06 1967-07-11 Gulf Research Development Co Copolymerization of low carbon number and high carbon number olefin fractions
US4311864A (en) * 1980-07-14 1982-01-19 Gulf Research & Development Company Method for preparing synthetic hydrocarbon fluids
US4434308A (en) * 1982-04-28 1984-02-28 Texaco Inc. Manufacture of synthetic lubricant additives from internal olefins using boron trifluoride catalysis
EP0337737A2 (fr) * 1988-04-15 1989-10-18 Neste Oy Procédé de préparation d'huiles de poly-N-butène d'une fraction-C4 résiduelle
EP0449453A2 (fr) * 1990-03-28 1991-10-02 Texaco Chemical Company Procédé pour l'oligomérisation d'oléfines pour préparer un matériau de base pour des lubrifiants synthétiques
WO1994015894A1 (fr) * 1992-12-30 1994-07-21 Neste Oy Procede d'oligomerisation d'olefines c4 avec des alpha-olefines lineaires

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735366B (zh) * 2009-12-17 2011-09-14 中国石油化工股份有限公司 一种用于减阻剂聚合用的复合给电子体
CN103289731A (zh) * 2012-02-28 2013-09-11 赵阳 一种内烯烃制备含芳烃合成烃的方法

Also Published As

Publication number Publication date
FI941529A0 (fi) 1994-03-31
FI941529A7 (fi) 1995-10-01
AU2139595A (en) 1995-10-23

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