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WO1995013345A1 - Compositions detergentes liquides pour surfaces dures contenant un agent tensioactif detergent amphotere ainsi qu'un parfum - Google Patents

Compositions detergentes liquides pour surfaces dures contenant un agent tensioactif detergent amphotere ainsi qu'un parfum Download PDF

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Publication number
WO1995013345A1
WO1995013345A1 PCT/US1994/012744 US9412744W WO9513345A1 WO 1995013345 A1 WO1995013345 A1 WO 1995013345A1 US 9412744 W US9412744 W US 9412744W WO 9513345 A1 WO9513345 A1 WO 9513345A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
detergent
composition
detergent surfactant
ether
Prior art date
Application number
PCT/US1994/012744
Other languages
English (en)
Inventor
Ronald Anthony Masters
Michael Stephen Maile
Timothy Clair Roetker
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to EP95900535A priority Critical patent/EP0728177B1/fr
Priority to CA002173437A priority patent/CA2173437C/fr
Priority to DE69423233T priority patent/DE69423233T2/de
Priority to AU81328/94A priority patent/AU8132894A/en
Publication of WO1995013345A1 publication Critical patent/WO1995013345A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof

Definitions

  • liquid detergent compositions for hard surfaces such as metal, glass, ceramic, plastic and linoleum surfaces, are commercially available in both powdered and liquid form.
  • Liquid detergent compositions are disclosed in Australian Pat. Application 82/88168, filed Sept. 9, 1982, by The Procter & Gamble Company; U.K. Pat. Application GB 2, 166, 153 A filed Oct. 24, 1985, by The Procter & Gamble Company; and U.K. Pat. Application GB 2, 160,887A, filed June 19, 1985, by Bristol-Myers Company, all of said published applications being incorporated herein by reference.
  • These liquid detergent compositions comprise certain organic solvents, surfactant, and optional builder and/or abrasive.
  • Liquid cleaning compositions have the great advantage that they can be applied to hard surfaces in neat or concentrated form so that a relatively high level of surfactant material and organic solvent is delivered directly to the soil. Therefore, liquid cleaning compositions have the potential to provide superior soap scum, grease, and oily soil removal over dilute wash solutions prepared from powdered cleaning compositions.
  • liquid cleaning compositions and especially compositions prepared for cleaning glass, need good filming/streaking properties.
  • they can suffer problems of product form, in particular, inhomogeneity, lack of clarity, or excessive "solvent" odor for consumer use.
  • aqueous liquid detergent compositions for cleaning shiny surfaces such as glass which contain a combination of (a) amido zwitterionic detergent surfactant, (b) cosurfactant selected from the group consisting of: specific acyl, amphocarboxylate detergent surfactant, as disclosed herein, especially those having a hydrophobic group containing from about 6 to about 10 carbon atoms; anionic detergent surfactants, especially alkyl sulfates, and more especially short chain alkyl sulfates; and, less desirably, nonionic detergent surfactants, especially short chain surfactants; and (c) hydrophobic ingredient, preferably perfume, in excess of the amount that can be solubilized by the combination of (a) and (b); and (d) an ingredient selected from the group consisting of: C2.3 fatty acid (including salts thereof), preferably acetic acid, or salts thereof; C2-6 alkane diols, preferably butane diol;
  • Suitable amido zwitterionic detergent surfactants contain an amido linkage in the hydrophobic portion of the molecule, a cationic group, preferably a quaternary ammonium group, and an anionic group, preferably carboxylate, sulfate and/or sulfonate group, more preferably sulfonate.
  • Preferred zwitterionic detergent surfactants have the generic formula: R3-C(O)-N(R4)-(CR52) n N(R6)2( + )-(CR5 2 )p-Y(-) wherein each y is preferably a carboxylate (COO") or sulfonate (SO3") group, more preferably sulfonate; wherein each R ⁇ is a hydrocarbon, e.g., an alkyl, or alkylene, group containing from about 8 to about 20, preferably from about 10 to about 18, more preferably from about 12 to about 16 carbon atoms; wherein each (R ) is either hydrogen, or a short chain alkyl, or substituted (e.g., hydroxy) alkyl, containing from one to about four carbon atoms, preferably groups selected from the group consisting of methyl, ethyl, propyl, hydroxy substituted ethyl or propyl and mixtures thereof, preferably methyl; wherein each (R
  • detergent cosurfactants useful herein contain a hydrophobic group, typically containing an alkyl group in the Cg-Cjg range, and, optionally, one or more linking groups such as ether or amido, preferably amido groups.
  • the anionic detergent surfactants can be used in the form of their sodium, potassium, ammonium, and/or alkanolammonium, e.g., triethanolammonium salts; the nonionics generally contain from about 5 to about 17 ethylene oxide groups.
  • Cg-C j g paraffin-sulfonates and alkyl sulfates, and the ethoxylated alcohols and alkyl phenols are especially preferred in the compositions of the present type.
  • LAS linear Cg.jg alkyl benzene sulfonate
  • C 1 1-12 LAS the sodium salt of a coconut alkyl ether sulfate containing 3 moles of ethylene oxide
  • the adduct of a random secondary alcohol having a range of alkyl chain lengths of from 11 to 15 carbon atoms and an average of 2 to 10 ethylene oxide moieties, several commercially available examples of which are Tergitol 15-S-3, Tergitol 15-S-5, Tergitol 15-S-7, and Tergitol 15- S-9, all available from Union Carbide Corporation
  • the sodium and potassium salts of coconut fatty acids (coconut soaps) the condensation product of a straight-chain primary alcohol containing from about 8 carbons to about 16 carbon atoms and having an average carbon chain length of from about 10 to about 12 carbon atoms with from about 4 to about 8 moles of ethylene oxide per mole of
  • Examples of the highly volatile, low boiling, perfiime ingredients are: anethole, benzaldehyde, benzyl acetate, benzyl alcohol, benzyl formate, iso- bornyl acetate, camphene, cis-citral (neral), citronellal, citronellol, citronellyl acetate, para-cymene, decanal, dihydrolinalool, dihydromyrcenol, dimethyl phenyl carbinol, eucalyptol, geranial, geraniol, geranyl acetate, geranyl nitrile, cis-3-hexenyl acetate, hydroxycitronellal, d-limonene, linalool, linalool oxide, linalyl acetate, linalyl propionate, methyl anthranilate, alpha-methyl ionone, methyl nonyl acetal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Compositions liquides aqueuses pour surfaces dures dotées de bonnes propriétés contre la formation de traces et de film opaque, contenant un agent tensioactif détergent zwitterionique, un autre tensioactif linéaire, un parfum hydrophobe, un additif de stabilisation qui est un acide gras C2-3 et/ou un alcane diol C2-6 afin d'aider à stabiliser le parfum hydrophobe, particulièrement en tant que micro-émulsion, ainsi que, le cas échéant, un solvant de nettoyage, une monométhanolamine et/ou d'autres béta-aminoalcanols spécifiques, etc. Des formules préférées ne contiennent pas de quantités importantes d'adjuvants et/ou d'autres matériaux, lesquels contribuent à un mauvais détachage ou à la formation d'un film opaque, et elles sont conçues pour le nettoyage en général, y compris le nettoyage du verre.
PCT/US1994/012744 1993-11-12 1994-11-04 Compositions detergentes liquides pour surfaces dures contenant un agent tensioactif detergent amphotere ainsi qu'un parfum WO1995013345A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP95900535A EP0728177B1 (fr) 1993-11-12 1994-11-04 Compositions detergentes liquides pour surfaces dures contenant un agent tensioactif detergent amphotere ainsi qu'un parfum
CA002173437A CA2173437C (fr) 1993-11-12 1994-11-04 Compositions detergentes liquides pour surfaces dures contenant un agent tensioactif detergent amphotere ainsi qu'un parfum
DE69423233T DE69423233T2 (de) 1993-11-12 1994-11-04 Amphoterestensid und parfümenthaltende, flüssige waschmittelzusammensetzungen für harte oberflächen
AU81328/94A AU8132894A (en) 1993-11-12 1994-11-04 Liquid hard surface detergent compositions containing amphoteric detergent surfactant and perfume

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15109493A 1993-11-12 1993-11-12
US08/151,094 1993-11-12

Publications (1)

Publication Number Publication Date
WO1995013345A1 true WO1995013345A1 (fr) 1995-05-18

Family

ID=22537294

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1994/012744 WO1995013345A1 (fr) 1993-11-12 1994-11-04 Compositions detergentes liquides pour surfaces dures contenant un agent tensioactif detergent amphotere ainsi qu'un parfum

Country Status (7)

Country Link
US (1) US5536450A (fr)
EP (1) EP0728177B1 (fr)
AU (1) AU8132894A (fr)
CA (1) CA2173437C (fr)
DE (1) DE69423233T2 (fr)
ES (1) ES2143030T3 (fr)
WO (1) WO1995013345A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997004059A1 (fr) * 1995-07-20 1997-02-06 Colgate-Palmolive Company Compositions detergentes liquides
GB2311296A (en) * 1996-03-19 1997-09-24 Procter & Gamble Perfumed particulate detergent compositions for hand dishwashing
WO1999006520A1 (fr) * 1997-07-31 1999-02-11 E.I. Du Pont De Nemours And Company Microemulsions aqueuses
WO1999031216A1 (fr) * 1997-12-12 1999-06-24 Colgate-Palmolive Company Microemulsion antimicrobienne multifonction renfermant un tensio-actif cationique
US10433545B2 (en) 2016-07-11 2019-10-08 Ecolab Usa Inc. Non-streaking durable composition for cleaning and disinfecting hard surfaces

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ZA925727B (en) * 1991-08-09 1993-03-10 Bristol Myers Squibb Co Glass cleaning composition.
ES2123131T3 (es) * 1993-03-19 1999-01-01 Procter & Gamble Composiciones de detergente acidas, liquidas, para cuartos de baño.
US5770554A (en) * 1995-07-20 1998-06-23 Colgate-Palmolive Co. Liquid cleaning compositions
US6277808B1 (en) * 1995-11-27 2001-08-21 The Procter & Gamble Company Composition for treating stains on laundry items and method of treatment
US5726139A (en) * 1996-03-14 1998-03-10 The Procter & Gamble Company Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality
US5851980A (en) * 1996-07-10 1998-12-22 S. C. Johnson & Sons, Inc. Liquid hard surface cleaner comprising a monocarboxylate acid and an ampholytic surfactant having no carboxyl groups
US6881711B1 (en) 2001-10-26 2005-04-19 Prestone Products Corporation Low VOC cleaning compositions for hard surfaces
CN1813059A (zh) * 2003-05-02 2006-08-02 西格玛-奥尔德利希公司 固相细胞裂解和捕获平台
US20050227898A1 (en) * 2004-04-09 2005-10-13 Leskowicz James J Zero to low VOC glass and general purpose cleaner
WO2006026248A1 (fr) * 2004-08-25 2006-03-09 Sigma-Aldrich Co. Compositions et procedes faisant appel a des combinaisons de detergents zwitterioniques
US7258878B2 (en) * 2004-12-20 2007-08-21 Kimberly-Clark Worldwide, Inc. Anti-microbial composition and methods of use thereof
ATE554743T1 (de) * 2007-09-19 2012-05-15 Bubbles & Beyond Gmbh Reinigungsmittel zur entfernung von farbschichten von oberflächen, verfahren zur herstellung des mittels und verfahren zur reinigung
WO2009105453A1 (fr) * 2008-02-20 2009-08-27 Johnsondiversey, Inc. Composition de nettoyage à faible teneur en composés organiques volatils
EP2661471A4 (fr) * 2011-01-06 2014-06-11 Diversey Inc Compositions de décapage non corrosives et procédés pour les préparer et les utiliser
JP6052957B2 (ja) * 2012-07-03 2016-12-27 花王株式会社 水洗トイレ用液体芳香組成物

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CA2173437A1 (fr) 1995-05-18
EP0728177A1 (fr) 1996-08-28
CA2173437C (fr) 1999-08-31
AU8132894A (en) 1995-05-29
US5536450A (en) 1996-07-16
EP0728177B1 (fr) 2000-03-01
DE69423233D1 (de) 2000-04-06
ES2143030T3 (es) 2000-05-01
DE69423233T2 (de) 2000-10-26

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