WO1995013261A1 - Procede de neutralisation de substances a reaction acide et de saponification d'huiles, de graisses, de cires ou similaires - Google Patents
Procede de neutralisation de substances a reaction acide et de saponification d'huiles, de graisses, de cires ou similaires Download PDFInfo
- Publication number
- WO1995013261A1 WO1995013261A1 PCT/DE1994/001347 DE9401347W WO9513261A1 WO 1995013261 A1 WO1995013261 A1 WO 1995013261A1 DE 9401347 W DE9401347 W DE 9401347W WO 9513261 A1 WO9513261 A1 WO 9513261A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oils
- fats
- waxes
- saponification
- emser
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000000126 substance Substances 0.000 title claims abstract description 16
- 239000003921 oil Substances 0.000 title claims abstract description 14
- 239000003925 fat Substances 0.000 title claims abstract description 13
- 239000001993 wax Substances 0.000 title claims abstract description 13
- 238000007127 saponification reaction Methods 0.000 title claims abstract description 8
- 238000006386 neutralization reaction Methods 0.000 title abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 150000001447 alkali salts Chemical class 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 239000011833 salt mixture Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000000499 gel Substances 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000008139 complexing agent Substances 0.000 claims description 6
- 239000002537 cosmetic Substances 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000003814 drug Substances 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 150000003460 sulfonic acids Chemical class 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000000383 hazardous chemical Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- -1 EMSER SALZ® Chemical class 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 208000009043 Chemical Burns Diseases 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 201000007100 Pharyngitis Diseases 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/965—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Definitions
- the invention relates to a method for neutralizing acidic substances or for saponifying oils, fats, waxes or the like.
- the invention has for its object to provide a process for the neutralization of acidic substances or for the saponification of oils, fats, waxes or the like, which both in terms of the production and the use of the neutralizing or saponifying component, i.e. the base, is comparatively harmless and unproblematic with regard to environmental pollution.
- this object is achieved in that the acid-reacting substances or the oils, fats, waxes or the like are reacted with naturally occurring basic salts or salt mixtures under reaction conditions suitable for the corresponding reaction.
- EMSER SALZ ® The naturally occurring basic salt mixture EMSER SALZ ® has proven to be particularly preferred. This mixture is created by evaporating the thermal water and has been used extensively as a remedy for mouth and throat infections.
- a solution of the salt mixture mentioned can also be used, for example in the form of EMSER® SOLE, a 11% EMSER SALZ® solution.
- Polyvalent ions in the naturally occurring basic salts or salt mixtures - as is the case with EMSER SALZ® - are preferably complexed by a complexing agent before the start of the reaction.
- EDTA or citrate are preferred as complexing agents.
- other conventional complexing agents can also be used, depending on the intended use.
- the invention further relates to a product which can be produced using the method according to the invention. Finally, the invention relates to the method according to the invention or the product according to the invention in the
- polyacids are used as the acid-reacting substance, gels or emulsion gels can be obtained, depending on the procedure and selection of the starting materials.
- the saponification of oils, fats or waxes with the naturally occurring basic salts or salt mixtures used according to the invention can also be used for the production of emulsions and emulsifiers.
- EMSER SALZ® for example, is demonstrably nitrosamine-free compared to conventional amine bases, which is of importance not to be underestimated in view of the preferred use in the manufacture of medicines and cosmetics.
- the present invention is explained in more detail on the basis of the exemplary embodiments illustrated in more detail below.
- the product is a gel with desirable properties that can be used in particular in the manufacture of pharmaceuticals and cosmetics.
- the product was an almost quantitative emulsion gel with desirable properties for use in the manufacture of cosmetics.
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Birds (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4498621T DE4498621D2 (de) | 1993-11-11 | 1994-11-10 | Verfahren zur Neutralisation sauer reagierender Substanzen und zur Verseifung von Ölen, Fetten, Wachsen oder dergleichen |
AU81391/94A AU8139194A (en) | 1993-11-11 | 1994-11-10 | Process for the neutralization of acidically reacting substances and for the saponification of oils, fats, waxes and the like |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4338591.5 | 1993-11-11 | ||
DE19934338591 DE4338591A1 (de) | 1993-11-11 | 1993-11-11 | Verfahren zur Neutralisation sauer reagierender Substanzen und zur Verseifung von Ölen, Fetten, Wachsen oder dergleichen |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995013261A1 true WO1995013261A1 (fr) | 1995-05-18 |
Family
ID=6502398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1994/001347 WO1995013261A1 (fr) | 1993-11-11 | 1994-11-10 | Procede de neutralisation de substances a reaction acide et de saponification d'huiles, de graisses, de cires ou similaires |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU8139194A (fr) |
DE (2) | DE4338591A1 (fr) |
WO (1) | WO1995013261A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012098336A1 (fr) | 2011-01-19 | 2012-07-26 | Totum Bio Cosmetics | Emulsion naturelle et son procede de preparation |
US8796217B2 (en) | 2008-01-25 | 2014-08-05 | HallStar Italia S.r.l. | Use of transesterified olive oil in the cosmetic field |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20012139A1 (it) | 2001-10-16 | 2003-04-16 | B & T S R L | Emulsionante naturale per cosmetici |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB570881A (en) * | 1943-09-24 | 1945-07-26 | Norman Swindin | An improved process of and means for neutralising spent acid liquors |
DE838138C (de) * | 1952-03-27 | Badische Anilin- &. Soda-Fabrik (I. G. Farbenindustrie Aktiengesellschaft "In Auflösung"), Ludwigshafen/Rhein | Verfahren zum Neutralisieren saurer Flüssigkeiten | |
US2855437A (en) * | 1955-06-06 | 1958-10-07 | Phillips Petroleum Co | Neutralization process |
DE3809947A1 (de) * | 1987-05-12 | 1988-11-24 | Colgate Palmolive Co | Verfahren zur herstellung fluessiger seife |
US5191097A (en) * | 1991-09-17 | 1993-03-02 | Church & Dwight Co., Inc. | Production of fatty acid salts |
-
1993
- 1993-11-11 DE DE19934338591 patent/DE4338591A1/de not_active Withdrawn
-
1994
- 1994-11-10 WO PCT/DE1994/001347 patent/WO1995013261A1/fr active Application Filing
- 1994-11-10 AU AU81391/94A patent/AU8139194A/en not_active Abandoned
- 1994-11-10 DE DE4498621T patent/DE4498621D2/de not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE838138C (de) * | 1952-03-27 | Badische Anilin- &. Soda-Fabrik (I. G. Farbenindustrie Aktiengesellschaft "In Auflösung"), Ludwigshafen/Rhein | Verfahren zum Neutralisieren saurer Flüssigkeiten | |
GB570881A (en) * | 1943-09-24 | 1945-07-26 | Norman Swindin | An improved process of and means for neutralising spent acid liquors |
US2855437A (en) * | 1955-06-06 | 1958-10-07 | Phillips Petroleum Co | Neutralization process |
DE3809947A1 (de) * | 1987-05-12 | 1988-11-24 | Colgate Palmolive Co | Verfahren zur herstellung fluessiger seife |
US5191097A (en) * | 1991-09-17 | 1993-03-02 | Church & Dwight Co., Inc. | Production of fatty acid salts |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8796217B2 (en) | 2008-01-25 | 2014-08-05 | HallStar Italia S.r.l. | Use of transesterified olive oil in the cosmetic field |
WO2012098336A1 (fr) | 2011-01-19 | 2012-07-26 | Totum Bio Cosmetics | Emulsion naturelle et son procede de preparation |
Also Published As
Publication number | Publication date |
---|---|
DE4498621D2 (de) | 1996-12-19 |
DE4338591A1 (de) | 1995-05-18 |
AU8139194A (en) | 1995-05-29 |
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