WO1994023006A1 - Blocs detergents a base d'enzymes pour wc - Google Patents
Blocs detergents a base d'enzymes pour wc Download PDFInfo
- Publication number
- WO1994023006A1 WO1994023006A1 PCT/US1994/003164 US9403164W WO9423006A1 WO 1994023006 A1 WO1994023006 A1 WO 1994023006A1 US 9403164 W US9403164 W US 9403164W WO 9423006 A1 WO9423006 A1 WO 9423006A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- lavatory
- block according
- cleansing block
- lavatory cleansing
- blocks
- Prior art date
Links
- 102000004190 Enzymes Human genes 0.000 title claims abstract description 24
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 24
- 229940088598 enzyme Drugs 0.000 claims description 22
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 150000004965 peroxy acids Chemical class 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 108091005804 Peptidases Proteins 0.000 claims description 6
- 102000004882 Lipase Human genes 0.000 claims description 5
- 108090001060 Lipase Proteins 0.000 claims description 5
- 239000004365 Protease Substances 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 108010065511 Amylases Proteins 0.000 claims description 4
- 102000013142 Amylases Human genes 0.000 claims description 4
- 239000004367 Lipase Substances 0.000 claims description 4
- 239000013522 chelant Substances 0.000 claims description 4
- 235000019421 lipase Nutrition 0.000 claims description 4
- 235000019418 amylase Nutrition 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- 240000008791 Antiaris toxicaria Species 0.000 claims description 2
- 108010084185 Cellulases Proteins 0.000 claims description 2
- 102000005575 Cellulases Human genes 0.000 claims description 2
- 102000035195 Peptidases Human genes 0.000 claims description 2
- 229940025131 amylases Drugs 0.000 claims description 2
- 239000007787 solid Substances 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 description 15
- -1 alkali metal salts Chemical class 0.000 description 9
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 108010059892 Cellulase Proteins 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 150000001451 organic peroxides Chemical class 0.000 description 3
- 241000194108 Bacillus licheniformis Species 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 241000223198 Humicola Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 229940106157 cellulase Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000012320 chlorinating reagent Substances 0.000 description 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 108010020132 microbial serine proteinases Proteins 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- GLVYLTSKTCWWJR-UHFFFAOYSA-N 2-carbonoperoxoylbenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1C(O)=O GLVYLTSKTCWWJR-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 1
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000223221 Fusarium oxysporum Species 0.000 description 1
- 241000055915 Heterocoma lanuginosa Species 0.000 description 1
- 241001480714 Humicola insolens Species 0.000 description 1
- 102000004157 Hydrolases Human genes 0.000 description 1
- 108090000604 Hydrolases Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical class [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 108090000637 alpha-Amylases Proteins 0.000 description 1
- 102000004139 alpha-Amylases Human genes 0.000 description 1
- 229940024171 alpha-amylase Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003625 amylolytic effect Effects 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001461 cytolytic effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- BRDYCNFHFWUBCZ-UHFFFAOYSA-N dodecaneperoxoic acid Chemical compound CCCCCCCCCCCC(=O)OO BRDYCNFHFWUBCZ-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000019626 lipase activity Nutrition 0.000 description 1
- 230000002366 lipolytic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Definitions
- the present invention relates to solid lavatory cleansing blocks containing enzymes.
- the block is designed to have good stain removal capacity.
- Lavatory blocks for cleansing and deodourizing the lavatory bowl are well known in the art.
- Such lavatory blocks typically comprise surfactants and chlorinating compounds which provide the desired cleansing and deodourizing properties.
- the lavatory blocks disclosed in the prior art do not efficiently address the problem of stain removal of physiological soils which are frequently found in the lavatory bowl.
- the surfactants contained in the lavatory blocks on the market are not present in sufficiently high concentrations in order to achieve optimum improved stain removal.
- Chlorinating agents due to their bleaching action are known for their stain removal ability.
- the in-bowl stain removal action of said chlorinating agents is limited at low concentrations.
- the present invention proposes to formulate a lavatory block comprising an enzyme system as a stain removal active.
- the blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution.
- a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
- An advantage of the present invention is that the enzymes are permanently active in the lavatory bowl water during the whole period in between lavatory flushes.
- the present invention is a solid lavatory block characterized in that it comprises from 0.1% to 50% of an enzyme system, whereby said lavatory block provides a permanent aqueous solution comprising an effective amount of said enzyme system as said block is progressively dissolved in said lavatory bowl water.
- the present invention relates to a solid lavatory cleansing block.
- lavatory blocks available on the market at present, in-rim and in-cistern type lavatory blocks.
- the in-rim type blocks are distinct from in-cistern type blocks in that they are designed to be hung from the rim of the lavatory bowl, in a conventional type rim cage.
- the in-cistern type blocks are designed to be placed in the cistern itself. Depending on the positioning of the block the properties of the active ingredients will vary, depending on the length of time the block is immersed in water.
- the lavatory blocks according to the present invention are designed to be used as both in-rim and in-cistern type lavatory blocks.
- the blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution.
- a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
- the lavatory blocks of the present invention comprise as an essential feature from 0.1% to 50%, preferably from 1% to 40%, more preferably from 2% to 25% of an enzyme system.
- Suitable enzymes which may be used are selected from Upases, proteases, cellulases, amylases, polysaccharide hydrolases and mixtures thereof.
- the preferred enzyme for use herein is lipase.
- lavatory blocks according to the present invention comprise a lipase enzyme such that the lipolytic activity of the lavatory block is from 0.01 to 5000 KLU, preferably from 0.1 to 1000 KLU, most preferably from 1 to 150 KLU per gram of the lavatory block.
- KLU are standard kilo units defined by Novo for measuring lipase activity.
- the lavatory blocks according to the present invention typically comprise a protease enzyme such that the protolytic activity of the lavatory block is from 0.01 to 500 KNPU, preferably from 0.05 to 200 KNPU, most preferably from 1 to 100 KNPU per gram of the lavatory block.
- KNPU denotes Kilo Novo Protease Units.
- the lavatory blocks according to the present invention typically comprise an amylase enzyme such that the amylolytic activity of the lavatory block is from 0.01 to 500 KNU, preferably from 0.1 to 250, most preferably from 1 to 100 KNPU per gram of the lavatory block.
- KNU are Kilo Novo units used for measuring amylase activity.
- lavatory blocks according to the present invention comprise a cellulase enzyme such that the cellulytic activity of the lavatory block is from 0.01 to 50 000 CEVU, preferably from 0.1 to 10 000 CEVU, more preferably from 1 to 1500 CEVU per gram of the lavatory block.
- CEVU are standard units for measuring cellulase activity.
- Commercially available enzymes for use herein include :
- Bacillus especially from B. licheniformis (e.g. Alcalase( R ) and from alkalophilic Bacillus strains according to US 3 723 250 (e.g. Savinase( R ) ) (both available from Novo Industri A/S) .
- B. licheniformis e.g. Alcalase( R )
- alkalophilic Bacillus strains e.g. Savinase( R )
- Novo Industri A/S Novo Industri A/S
- the enzyme system assists in the removal of faecal, urine and grease stains which are found in the lavatory bowl. It is believed that enzymes, especially lipases are effective in removing the stains found in the lavatory bowl by attacking the components present in faeces which represent a significant fraction of the faecal soil.
- the lavatory blocks according to the present invention may also contain a number of optional ingredients.
- One such ingredient is a surfactant system.
- the incorporation of a surfactant provides increased cleansing of the lavatory blocks and provides a solid matrix in which all the other ingredients can be incorporated.
- the block comprises at least 10% of a surfactant system.
- the surfactants that may be used herein can be anionic and nonionic surfactants or mixtures thereof.
- the anionic surfactants which may be used in the present invention include for example alkali metal salts of alkyl substituted benzene sulphonates, alkali metal alkyl sulphonates, alkali metal alkyl sulphonates and alkali metal alkyl ether sulphates derived for example from fatty alcohols and alkyl phenols, alkali metal alkane sulphonates, alkali metal olefin sulphonates and alkali metal sulphosuccinates, whereby the sodium salts are preferred. Most preferred are sodium alkyl metal sulphonates and sulphates.
- nonionic surfactants which may be used can be chosen from any liquid or solid ethoxylated Cg-C 2 fatty alcohol nonionic surfactant, fatty acid C 6 -C 24 alkanolamides, C 6 -C 20 polyethylglycol ethers, polyethyleneglycol with molecular weight 1000 to 80000 and Cg-C 24 amine oxides.
- the lavatory blocks of the present invention may further comprise from 0.001% to 10%, preferably from 0.001% to 3% soluble calcium salts.
- the calcium salts can be used to stabilize the enzymes.
- the lavatory blocks of the invention may further comprise 0% to 50%, preferably from 5% to 39%, fillers of inorganic salts such as sodium sulphate, sodium carbonate, sodium silicate and less preferably phosphorous sodium salts, for example sodium triphosphate, or inert fillers such as clay, urea or calcite.
- the fillers can be used to adjust the mechanistic properties of the lavatory blocks so that the active ingredients are released in the desired manner.
- the differences in the composition of the in-rim and in- cistern type lavatory blocks of the present invention can be exclusively but not necessarily dependant upon the type of surfactants, fillers and polymers used therein, to determine the dissolution rate. The composition differences are well known in the art.
- In-cistern type lavatory blocks can preferably contain surfactants with a lower solubilization rate and may be chosen from long chain higher anionics or nonionics with a high degree of ethoxylation. In-cistern type lavatory blocks may also contain specific ingredients to decrease the solubilization rate such as slowly dissolving polymers or oils.
- the lavatory blocks of the present invention may further comprise as an optional feature from lppm to 500ppm, preferably from 5ppm to 300ppm, more preferably from lOppm to 200ppm active oxygen in the lavatory bowl water.
- the source of active oxygen can be selected from hydrogen peroxide or sources thereof, preformed peroxyacids, organic peroxides and mixtures thereof.
- active oxygen concentration refers to the percentage concentration of elemental oxygen, with an oxidation number zero, that being reduced to water would be stoichiometrically equivalent to a given percentage concentration of a given peroxide compound, when the peroxide functionality of the peroxide compound is completely reduced to oxides.
- a hydrogen peroxide source according to the present invention refers to any compound which produces hydrogen peroxide when said compound is in contact with water.
- Suitable water-soluble sources of hydrogen peroxide for use herein include persul- phates, percarbonates, metal oxides and perborates.
- Suitable preformed peroxyacids for use in the lavatory blocks according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalate, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof.
- the blocks according to the present invention comprise from 0.01% to 30% of said preformed peroxyacids.
- Suitable organic peroxides for use in the lavatory blocks according to the present invention include diacyl and dialkyl peroxides such as dibenzoyl peroxide, dilauroyl peroxide, dicumyl peroxide and mixtures thereof.
- the blocks according to the present invention comprise from 0.01% to 30% of said organic peroxides.
- the lavatory blocks may additionally comprise peracid precursors, i.e. compounds that upon reaction with hydrogen peroxide produce peroxyacids.
- peracid precursors suitable for use in the present invention can be found among the classes of esters, amides, imides and anhydrides such as acetyl triethyl citrate (ATC) , tetra acetyl ethylene diamine (TAED) , succinic or maleic anhydrides. All of these bleaching agents are environmentally compatible and odourless.
- Another optional component of said system is an acid or alkali.
- the acid or alkali is used to ensure that the pH of the lavatory bowl water is in the range of pH 4 to pH 10.
- the stability and activity of the enzymes of the present invention can be optimized by ensuring that the pH of said lavatory bowl water is at the optimum level for the enzyme used herein.
- the acids of the present invention may in addition have the advantage that they can form small concentrations of the corresponding peracids by reaction with hydrogen peroxide in-situ, thus enhancing the overall performance of the lavatory block. These acids can be further selected so as to have chelating and/or building properties, which results in limescale removal.
- the acids that can be used in the present invention are organic or inorganic acids, preferably organic acids such as citric, maleic, oxalic succinic and tartaric acids, more preferably citric and maleic acids.
- the alkalis that may be used in the present invention include sodium hydroxide, potassium hydroxide, alkali metal hydroxides, alkaline earth metal hydroxides and amines, for example monoethylamine, monoethanola ine and triethanolamine.
- a chelant system improves the overall limescale/rust removal performance. Furthermore, the chelant system may improve the stability of the bleaching agent in the formulation. Suitable chelants may be chosen from EDTA, NTA or preferably from biodegradable chelants such as s,s-ethylene dia ino disuccinate and dipicolinic acid.
- perfumes and dyes used to improve the aesthetics of the lavatory block.
- perfumes and dyes contained in the lavatory block are selected for their stability in the presence of the source of active oxygen.
- said blocks comprise perfumes and dyes
- the lavatory cleansing block is formed by conventional methods well known in the art as described for instance in EP-A 462 643.
- the ingredients are mixed to form a dough of suitable consistency which can then be extruded and cut into lengths to form blocks.
- the extrusion process can be carried out by using simple conventional extrusion equipment such as usually used for manufacturing soap bars.
- the lavatory blocks may be prepared by compressing all of the ingredients into a block.
- compositions are made by combining the listed ingredients, in the listed proportions.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Blocs détergents pleins pour WC comportant un système d'enzymes. Lesdits blocs sont non polluants et dotés d'un pouvoir détachant renforcé.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6522179A JPH08508770A (ja) | 1993-04-06 | 1994-03-23 | 酵素を含有したラバトリーブロック |
AU65516/94A AU6551694A (en) | 1993-04-06 | 1994-03-23 | Lavatory blocks containing enzymes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93201007.7 | 1993-04-06 | ||
EP93201007A EP0619367A1 (fr) | 1993-04-06 | 1993-04-06 | Blocs pour toilettes contenant des enzymes |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994023006A1 true WO1994023006A1 (fr) | 1994-10-13 |
Family
ID=8213747
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/003164 WO1994023006A1 (fr) | 1993-04-06 | 1994-03-23 | Blocs detergents a base d'enzymes pour wc |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0619367A1 (fr) |
JP (1) | JPH08508770A (fr) |
AU (1) | AU6551694A (fr) |
CA (1) | CA2159820A1 (fr) |
WO (1) | WO1994023006A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3310985B2 (ja) | 1996-06-12 | 2002-08-05 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 便所清浄用ブロックに関する改善 |
US8795740B2 (en) | 2003-10-24 | 2014-08-05 | Novapharm Research (Australia) Pty Ltd | Drip tray tablet |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4337032C1 (de) * | 1993-10-29 | 1995-05-24 | Henkel Kgaa | Verwendung von Detergensgemischen zur Herstellung von Toilettensteinen |
US5858117A (en) | 1994-08-31 | 1999-01-12 | Ecolab Inc. | Proteolytic enzyme cleaner |
US5830839A (en) * | 1995-05-17 | 1998-11-03 | Sunburst Chemicals, Inc. | Solid detergents with active enzymes and bleach |
HUP0101314A3 (en) * | 1998-04-09 | 2002-02-28 | Unilever Nv | Toilet cleaning blocks and method prevent the heat-developing therein |
CA2320776A1 (fr) * | 1998-04-09 | 1999-10-21 | Unilever Plc | Blocs nettoyants pour w-c |
DE19850896A1 (de) * | 1998-11-05 | 2000-05-11 | Buck Chemie Gmbh | Stückförmiges Mittel für den Toilettenbereich |
GB0004130D0 (en) * | 2000-02-23 | 2000-04-12 | Procter & Gamble | Detergent tablet |
AU2004284836B2 (en) * | 2003-10-24 | 2010-08-05 | Novapharm Research (Australia) Pty Ltd | Drip tray tablet |
JP5047385B1 (ja) * | 2011-08-26 | 2012-10-10 | 都市拡業株式会社 | 尿石除去剤 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3798181A (en) * | 1970-11-03 | 1974-03-19 | Colgate Palmolive Co | Enzymatic detergent bar |
US4248827A (en) * | 1978-06-12 | 1981-02-03 | The Procter & Gamble Company | Method for sanitizing toilets |
US4842762A (en) * | 1985-06-07 | 1989-06-27 | The Dow Chemical Company | Laundry soil and stain remover in applicator stick form |
WO1989012090A1 (fr) * | 1988-06-09 | 1989-12-14 | Unilever Plc | Composition enzymatique de lavage et de rinçage de vaisselle |
EP0466484A2 (fr) * | 1990-07-13 | 1992-01-15 | Unilever Plc | Compositions détergentes |
US5178787A (en) * | 1991-03-11 | 1993-01-12 | Block Drug Company, Inc. | Lavatory cleaning block comprising n,n-dichloro dialkyl hydantoin and aluminum hydroxide |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2058119T3 (es) * | 1986-08-29 | 1994-11-01 | Novo Nordisk As | Aditivo detergente enzimatico. |
GB8629534D0 (en) * | 1986-12-10 | 1987-01-21 | Unilever Plc | Enzymatic detergent & bleaching composition |
GB9013539D0 (en) * | 1990-06-18 | 1990-08-08 | Unilever Plc | Lavatory cleansing block |
-
1993
- 1993-04-06 EP EP93201007A patent/EP0619367A1/fr not_active Withdrawn
-
1994
- 1994-03-23 WO PCT/US1994/003164 patent/WO1994023006A1/fr active Application Filing
- 1994-03-23 AU AU65516/94A patent/AU6551694A/en not_active Abandoned
- 1994-03-23 JP JP6522179A patent/JPH08508770A/ja active Pending
- 1994-03-23 CA CA 2159820 patent/CA2159820A1/fr not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3798181A (en) * | 1970-11-03 | 1974-03-19 | Colgate Palmolive Co | Enzymatic detergent bar |
US4248827A (en) * | 1978-06-12 | 1981-02-03 | The Procter & Gamble Company | Method for sanitizing toilets |
US4842762A (en) * | 1985-06-07 | 1989-06-27 | The Dow Chemical Company | Laundry soil and stain remover in applicator stick form |
WO1989012090A1 (fr) * | 1988-06-09 | 1989-12-14 | Unilever Plc | Composition enzymatique de lavage et de rinçage de vaisselle |
EP0466484A2 (fr) * | 1990-07-13 | 1992-01-15 | Unilever Plc | Compositions détergentes |
US5178787A (en) * | 1991-03-11 | 1993-01-12 | Block Drug Company, Inc. | Lavatory cleaning block comprising n,n-dichloro dialkyl hydantoin and aluminum hydroxide |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3310985B2 (ja) | 1996-06-12 | 2002-08-05 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 便所清浄用ブロックに関する改善 |
US8795740B2 (en) | 2003-10-24 | 2014-08-05 | Novapharm Research (Australia) Pty Ltd | Drip tray tablet |
Also Published As
Publication number | Publication date |
---|---|
JPH08508770A (ja) | 1996-09-17 |
AU6551694A (en) | 1994-10-24 |
CA2159820A1 (fr) | 1994-10-13 |
EP0619367A1 (fr) | 1994-10-12 |
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