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WO1994019439A1 - Utilisation d'une composition assouplissante pour tissus - Google Patents

Utilisation d'une composition assouplissante pour tissus Download PDF

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Publication number
WO1994019439A1
WO1994019439A1 PCT/EP1994/000468 EP9400468W WO9419439A1 WO 1994019439 A1 WO1994019439 A1 WO 1994019439A1 EP 9400468 W EP9400468 W EP 9400468W WO 9419439 A1 WO9419439 A1 WO 9419439A1
Authority
WO
WIPO (PCT)
Prior art keywords
ester
fabric softening
carbon atoms
quaternary ammonium
ester oil
Prior art date
Application number
PCT/EP1994/000468
Other languages
English (en)
Inventor
Simon Richard Ellis
Christopher Whaley
Original Assignee
Unilever Plc
Unilever N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB939303814A external-priority patent/GB9303814D0/en
Priority claimed from GB939307032A external-priority patent/GB9307032D0/en
Application filed by Unilever Plc, Unilever N.V. filed Critical Unilever Plc
Priority to AU62036/94A priority Critical patent/AU6203694A/en
Publication of WO1994019439A1 publication Critical patent/WO1994019439A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/46—Esters of carboxylic acids with amino alcohols; Esters of amino carboxylic acids with alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease

Definitions

  • This invention relates to the use of an ester oil, in a fabric softening composition comprising a quaternary ammonium or a ine fabric softening material, to impart ease of iron and anti-crease benefits to fabric treated with the softening composition.
  • Rinse added fabric softener compositions are well known. Typically such compositions contain a water insoluble amine salt and/or a quaternary ammonium fabric softening agent dispersed in water at a level of softening agent up to 7% by weight in which case the compositions are considered dilute, or at levels from 7% to 50% in which case the compositions are considered concentrates. Quaternary ammonium materials with long chain substituents have been used in fabric softening compositions for many years. Often they are used in conjunction with co-actives such as fatty acids or other relatively cheap materials which also provide softening benefits.
  • fabric softening compositions desirably have other benefits.
  • GB 1 601 359 ( Procter and Gamble ) describes the use of esters as an ingredient in a fabric softening composition which also comprises a cationic surfactant selected from various specified groups.
  • the ester is one of a number of nonionic fabric lubricants suggested.
  • the esters are esters °f C 12 _ 24 fatty alcohols and mono or polycarboxylic acids, whereby the total number of carbon atoms in the ester is equal to or greater than 16.
  • the specification makes no mention of ease of iron or anti-crease benefits.
  • GB 1 550 205 (Procter and Gamble) disclose formulations containing silicones, cat.ionics and glycerol monostearate. The specification states that ease of ironing and softening benefits may be obtained without the ester oil when other nonionic softeners are substituted for the glycerol monostearate.
  • EP 0 000 406 ( Procter and Gamble ) describes a concentrated liquid fabric softener comprising a fabric substantive agent and a fabric softening component.
  • One of the fabric softening components claimed is a fatty ester of a mono or polyhydric alcohol having from 1 to about 24 carbon atoms in the hydrocarbon chain, and mono or polycarboxylic acids having from 1 to about 24 carbon atoms in the hydrocarbon chain with the proviso that the total number of carbon atoms in the ester is equal to or greater than 16 and that at least one of the hydrocarbon radicals in the ester has 12 or more carbon atoms.
  • ester oil is to deliver fabric softening
  • the abstract contains the unsupported statement that the fabric softener can deposit onto fibres to provide textile handling benefits inclusive of softening, static control, ease-of-ironing, fluffiness, pliability and smoothness.
  • an ester oil in a fabric softening composition comprising a quaternary ammonium or amine fabric softening material to impart ease of iron and/or anti-crease benefits to fabric treated with the fabric softening composition.
  • the softening material is a quaternary ammonium or amine compound with two long chain groups connected to the quaternary or amine compound with two long chain groups connected to nitrogen via ester links.
  • the presence of the ester oil increases the anti-crease and/or ease of iron benefits that may derive from use of the fabric softerming material without the presence of ester oil.
  • the ester oil is a fatty ester of a mono or polyhydric alcohol having from 1 to about 24 carbon atoms in the hydrocarbon chain, and mono or polycarboxylic acids having from 1 to about 24 carbon atoms in the hydrocarbon chain with the proviso that the total number of carbon atoms in the ester oil is equal to or greater than 16 and that at least one of the hydrocarbon radicals in the ester oil has 12 or more carbon atoms.
  • the fatty acid is a naturally occurring one, such as rape oil.
  • Ester oils most suitable for use in the present invention are the PRIOLUBES from Unichema.
  • PRIOLUBE is the PRIOLUBES from Unichema.
  • PRIOLUBE 1407 which is a neopentyl glycol monomerate, is particularly useful.
  • the fatty acid mixture for this ester is called in the oleochemical industry "monomer fatty acid" and derives from the dimerisation of rape oil (eruca low) fatty acid or oleine from tallow. In the dimerisation process, dimer, trimer acids and so called monomeric acids are formed.
  • a fabric softening composition comprising a softening material and a material which can deliver ease of iron benefits to a fabric in the rinse stage of a fabric washing process characterised in that the softening component is a quaternary ammonium or amine salt material with two long chain groups connected to the quaternary nitrogen via ester links and the ease of iron benefit is imparted by an ester oil both the softening material and the ester oil having excellent biodegradability.
  • the fabric softening composition comprises a water insoluble cationic which is a compound having two C 12 _ 28 alkyl or alkenyl groups connected to the N atom via one or more ester links.
  • ester-linked quaternary ammonium material for use in the compositions according to the invention can be represented by the formula:
  • each R x group is independently selected from C ⁇ alkyl, hydroxyalkyl groups or C 2 _ 4 alkenyl groups; and wherein each R 2 group is independently selected from C 8 _ 28 alkyl or alkenyl groups; and n is an integer from 0-5.
  • the level of ester linked quaternary ammonium compounds is at least 1% by weight of the composition, more preferably more than 3% by weight of the composition; especially interesting are concentrated compositions which comprise more than 7% of ester-linked quaternary ammonium compound.
  • the level of ester-linked quaternary ammonium compounds preferably is between 1% and 80% by weight, more preferably 4% to 32%, most preferably 6% to 22%.
  • the level of ester oil is preferably 4 to 32 wt%, most preferably 5 to 15%.
  • the ratio of quaternary ammonium/amine to ester oil is preferably in the range 1:10 to 4.5:1.
  • the softening composition may also comprise a nonionic stabilising agent selected from:
  • the nonionic stabilising agent is a linear C 8 to C 22 alcohol alkoxylated with 10 to 20 moles of alkylene oxide.
  • the nonionic stabiliser has an HLB of between 10 and 20, more preferably between 12 and 20.
  • the level of nonionic stabiliser is within the range from 0 to 10% by weight, more preferably from 0 to 5% by weight, most preferably from 0 to 4% by weight.
  • the mole ratio of the quaternary ammonium compound to the nonionic stabilising agent is within the range from 40:1 to about 1:1, preferably within the range from 18:1 to about 3:1.
  • compositions of the invention are liquids comprising an aqueous base.
  • the composition can also contain a co-active for example C 8 - C 24 alkyl or alkenyl monocarboxylic acids or polymers thereof.
  • a co-active for example C 8 - C 24 alkyl or alkenyl monocarboxylic acids or polymers thereof.
  • saturated fatty acids are used, in particular, hardened tallow C 16 -C 18 fatty acids.
  • the fatty acid is non-saponified, for example free oleic acid, lauric acid or tallow fatty acid.
  • Lanolin or other nonionic fabric softening agents may also be used as co- actives.
  • the level of co-active material is preferably more than 0.1% by weight, more preferably more than 0.2% by weight.
  • concentrates comprising from 0.5 to 20% by weight of co-active, more preferably 1% to 10% by weight.
  • the weight ratio of quaternary ammonium/amine material to co-active material is preferably from 10:1 to 1:10.
  • the composition can also contain one or more optional ingredients, selected from non-aqueous solvents, pH buffering agents, perfumes, perfume carriers, fluorescers, colourants, hydrotropes, antifoaming agents, soil release agents, enzymes, optical brightening agents, opacifiers, anti-shrinking agents, anti-spotting agents, germicides, fungicides, anti-oxidants, anti-corrosion agents, and antistatic agents.
  • optional ingredients selected from non-aqueous solvents, pH buffering agents, perfumes, perfume carriers, fluorescers, colourants, hydrotropes, antifoaming agents, soil release agents, enzymes, optical brightening agents, opacifiers, anti-shrinking agents, anti-spotting agents, germicides, fungicides, anti-oxidants, anti-corrosion agents, and antistatic agents.
  • a fabric softening composition comprising:
  • the oil was prepared by adding the oil to the water as follows.
  • the cationic and fatty acid is obtained in admixture and added to the ester oil.
  • the cationic is melted by heating to above 70°C.
  • the oil mixture is then added to the water over several minutes with vigorous mixing.
  • Hoeschst 1 is 1,2 bis[hardened tallowoyloxy]-3-trimethylammonium propane chloride - ex
  • Hoeschst 2 is Hardened tallow fatty acid - ex Hoeschst
  • NPG neopentyl glycol
  • Example 1 Two comparative tests are performed using the compositions of Example 1 and comparative example A. One measures 'Anti- crease' and the other 'Ease-of-ironing" .
  • Example 1 The composition of example 1 and the control of Comparative example A was tested in a tergotometer containing 1 litre of wash liquor.
  • the fabric softening composition was then added at the usual concentration and the wash process continued for a further five minutes.
  • the monitors were then removed from the tergotometer, spun until most dry and squeezed by hand for five seconds.
  • the monitors were then line dried overnight and assessed visually by a four person panel : votes being awarded to the monitors judged to be the least creased.
  • the dosage of fabric softener used was adjusted to give equivalent amounts of cationic quaternary ammonium.
  • Example 1 The frictional resistance to the passage of the iron over the monitor is expressed as the tension response from the load cell at the front of the iron (in V) ; low values indicate low friction and hence easier ironing.
  • Application of the test product of Example 1 was found to give significantly easier ironing than the control of Example A:
  • a fabric softening composition comprising:
  • Example 1 was made by phase inversion, ie by adding water to a pre-mix of quaternary, fatty acid, ester oil and nonionic.
  • the materials used were the same as for Example 1 and comparative example A.
  • the water and the oil are first heated to 70°C, then the water is added to the oil with mixing. Once all the water was added intense mixing was carried out for about 30 minutes before perfume and dye was added.
  • the viscosity after 5 days storage was determined to be about 45cP at 110s "1 .
  • a fabric softener composition comprising:
  • a fabric softener composition similar to example 4 was prepared by the method given in example 4 with the exception that the composition comprised 1.0% of the nonionic and the amount of water was reduced accordingly.
  • a fabric softener composition was prepared as for example 5, with the exception that 2.0% nonionic was used.
  • Fabric softening compositions were prepared comprising
  • compositions were prepared according to the method in Example 1. All the examples had acceptable viscosities ( ⁇ 100 cPa) and were stable at ambient temperature for at least 3 weeks.
  • a concentrated fabric softening composition was prepared comprising
  • Example 1 The method of preparation was as for Example 1. As above, this example had an acceptable viscosities ( ⁇ 100 cP) and was stable at room temperature for at least 3 weeks.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Des compositions assouplissantes pour tissus, ajoutées au rinçage, présentent une bonne stabilité tout en rendant les tissus plus faciles à repasser. La composition comprend un composé d'ammonium quaternaire assouplissant et biodégradable, contenant deux groupes à chaîne longue reliés à l'azote quaternaire par des liaisons ester et une huile ester.
PCT/EP1994/000468 1993-02-25 1994-02-17 Utilisation d'une composition assouplissante pour tissus WO1994019439A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU62036/94A AU6203694A (en) 1993-02-25 1994-02-17 Use of fabric softening composition

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9303814.9 1993-02-25
GB939303814A GB9303814D0 (en) 1993-02-25 1993-02-25 Use of fabric softening composition
GB939307032A GB9307032D0 (en) 1993-04-05 1993-04-05 Use of fabric softening composition
GB9307032.4 1993-04-05

Publications (1)

Publication Number Publication Date
WO1994019439A1 true WO1994019439A1 (fr) 1994-09-01

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Application Number Title Priority Date Filing Date
PCT/EP1994/000468 WO1994019439A1 (fr) 1993-02-25 1994-02-17 Utilisation d'une composition assouplissante pour tissus

Country Status (2)

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AU (1) AU6203694A (fr)
WO (1) WO1994019439A1 (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996015212A1 (fr) * 1994-11-14 1996-05-23 The Procter & Gamble Company Compositions concentrees biodegradables d'ammonium quaternaire pour l'assouplissement des textiles, contenant des chaines d'acide gras a indice d'iode intermediaire
EP0829531A1 (fr) * 1996-08-22 1998-03-18 Unilever Plc Composition de conditionnement de tissus
US5919751A (en) * 1996-05-23 1999-07-06 Lever Brothers Company Fabric conditioning composition
US5965517A (en) * 1996-07-25 1999-10-12 Lever Brothers Company, Division Of Conopco,Inc. Fabric treatment composition
WO2001046513A1 (fr) * 1999-12-22 2001-06-28 Unilever Plc Utilisation de compositions de conditionnement de textiles servant a ameliorer le repassage
WO2003104366A1 (fr) * 2002-06-10 2003-12-18 Unilever Plc Compositions detergentes liquides pour tissus
EP0920486B2 (fr) † 1996-06-14 2004-10-13 Cognis Deutschland GmbH & Co. KG Assouplissant textile aqueux a haut potentiel zeta
WO2011120836A1 (fr) * 2010-04-01 2011-10-06 Evonik Degussa Gmbh Composition active d'assouplissant pour textile
US8361953B2 (en) 2008-02-08 2013-01-29 Evonik Goldschmidt Corporation Rinse aid compositions with improved characteristics
US8507425B2 (en) 2010-06-29 2013-08-13 Evonik Degussa Gmbh Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making
US8569224B2 (en) 2010-04-01 2013-10-29 Evonik Degussa Gmbh Fabric softener active composition
US8883713B2 (en) 2012-01-30 2014-11-11 Evonik Industries Ag Fabric softener active composition
US8883712B2 (en) 2010-04-28 2014-11-11 Evonik Degussa Gmbh Fabric softening composition
US9441187B2 (en) 2012-05-07 2016-09-13 Evonik Degussa Gmbh Fabric softener active composition and method for making it
US10011806B2 (en) 2013-11-05 2018-07-03 Evonik Degussa Gmbh Method for making a tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid ester
US10113137B2 (en) 2014-10-08 2018-10-30 Evonik Degussa Gmbh Fabric softener active composition
EP3418353A1 (fr) * 2017-06-20 2018-12-26 Kao Corporation, S.A. Compositions actives d'adoucissants pour tissus
EP3418354A1 (fr) * 2017-06-20 2018-12-26 Kao Corporation, S.A. Compositions actives d'adoucissants pour tissus
EP3418355A1 (fr) * 2017-06-20 2018-12-26 Kao Corporation, S.A. Compositions actives d'adoucissants pour tissus
WO2022152548A1 (fr) * 2021-01-13 2022-07-21 Unilever Ip Holdings B.V. Revitalisant pour tissu
WO2023099499A1 (fr) * 2021-12-02 2023-06-08 Unilever Ip Holdings B.V. Procédé de conditionnement de tissu

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2393099A2 (fr) * 1977-05-30 1978-12-29 Procter & Gamble Composition liquide de traitement de textiles a base de polyamine substituee de lubrifiant non-ionique
EP0000406A1 (fr) * 1977-07-06 1979-01-24 Procter & Gamble European Technical Center Adoucissant liquide concentré pour textiles contenant un système actif mélangé
GB2007734A (en) * 1977-10-22 1979-05-23 Cargo Fleet Chemical Co Fabric softeners
EP0122141A2 (fr) * 1983-04-08 1984-10-17 Unilever Plc Compositions adoucissantes pour matières textiles
EP0243735A2 (fr) * 1986-04-14 1987-11-04 Henkel Kommanditgesellschaft auf Aktien Adoncissant aqueux concentré pour matières textiles
EP0387064A2 (fr) * 1989-03-10 1990-09-12 Unilever Plc Conditionnement des tissus
EP0409504A2 (fr) * 1989-07-17 1991-01-23 Unilever Plc Composition adoucissante pour textile
EP0409503A2 (fr) * 1989-07-17 1991-01-23 Unilever Plc Composition adoucissante pour textile

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2393099A2 (fr) * 1977-05-30 1978-12-29 Procter & Gamble Composition liquide de traitement de textiles a base de polyamine substituee de lubrifiant non-ionique
EP0000406A1 (fr) * 1977-07-06 1979-01-24 Procter & Gamble European Technical Center Adoucissant liquide concentré pour textiles contenant un système actif mélangé
GB2007734A (en) * 1977-10-22 1979-05-23 Cargo Fleet Chemical Co Fabric softeners
EP0122141A2 (fr) * 1983-04-08 1984-10-17 Unilever Plc Compositions adoucissantes pour matières textiles
EP0243735A2 (fr) * 1986-04-14 1987-11-04 Henkel Kommanditgesellschaft auf Aktien Adoncissant aqueux concentré pour matières textiles
EP0387064A2 (fr) * 1989-03-10 1990-09-12 Unilever Plc Conditionnement des tissus
EP0409504A2 (fr) * 1989-07-17 1991-01-23 Unilever Plc Composition adoucissante pour textile
EP0409503A2 (fr) * 1989-07-17 1991-01-23 Unilever Plc Composition adoucissante pour textile

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996015212A1 (fr) * 1994-11-14 1996-05-23 The Procter & Gamble Company Compositions concentrees biodegradables d'ammonium quaternaire pour l'assouplissement des textiles, contenant des chaines d'acide gras a indice d'iode intermediaire
US5919751A (en) * 1996-05-23 1999-07-06 Lever Brothers Company Fabric conditioning composition
EP0920486B2 (fr) † 1996-06-14 2004-10-13 Cognis Deutschland GmbH & Co. KG Assouplissant textile aqueux a haut potentiel zeta
US5965517A (en) * 1996-07-25 1999-10-12 Lever Brothers Company, Division Of Conopco,Inc. Fabric treatment composition
EP0829531A1 (fr) * 1996-08-22 1998-03-18 Unilever Plc Composition de conditionnement de tissus
WO2001046513A1 (fr) * 1999-12-22 2001-06-28 Unilever Plc Utilisation de compositions de conditionnement de textiles servant a ameliorer le repassage
WO2003104366A1 (fr) * 2002-06-10 2003-12-18 Unilever Plc Compositions detergentes liquides pour tissus
US7012059B2 (en) 2002-06-10 2006-03-14 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Fabric detergent compositions
US8361953B2 (en) 2008-02-08 2013-01-29 Evonik Goldschmidt Corporation Rinse aid compositions with improved characteristics
CN102803456B (zh) * 2010-04-01 2014-06-11 赢创德固赛有限公司 织物柔软剂活性组合物
AP4034A (en) * 2010-04-01 2017-02-12 Evonik Degussa Gmbh Fabric softener active composition
CN102803456A (zh) * 2010-04-01 2012-11-28 赢创德固赛有限公司 织物柔软剂活性组合物
US8563499B2 (en) 2010-04-01 2013-10-22 Evonik Degussa Gmbh Fabric softener active composition
US8569224B2 (en) 2010-04-01 2013-10-29 Evonik Degussa Gmbh Fabric softener active composition
WO2011120836A1 (fr) * 2010-04-01 2011-10-06 Evonik Degussa Gmbh Composition active d'assouplissant pour textile
US8883712B2 (en) 2010-04-28 2014-11-11 Evonik Degussa Gmbh Fabric softening composition
US8507425B2 (en) 2010-06-29 2013-08-13 Evonik Degussa Gmbh Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making
US8883713B2 (en) 2012-01-30 2014-11-11 Evonik Industries Ag Fabric softener active composition
RU2612130C2 (ru) * 2012-01-30 2017-03-02 Эвоник Дегусса Гмбх Активная композиция мягчителя ткани
US9441187B2 (en) 2012-05-07 2016-09-13 Evonik Degussa Gmbh Fabric softener active composition and method for making it
US10011806B2 (en) 2013-11-05 2018-07-03 Evonik Degussa Gmbh Method for making a tris-(2-hydroxyethyl)-methylammonium methylsulfate fatty acid ester
US10113137B2 (en) 2014-10-08 2018-10-30 Evonik Degussa Gmbh Fabric softener active composition
EP3418353A1 (fr) * 2017-06-20 2018-12-26 Kao Corporation, S.A. Compositions actives d'adoucissants pour tissus
EP3418354A1 (fr) * 2017-06-20 2018-12-26 Kao Corporation, S.A. Compositions actives d'adoucissants pour tissus
EP3418355A1 (fr) * 2017-06-20 2018-12-26 Kao Corporation, S.A. Compositions actives d'adoucissants pour tissus
WO2018234294A1 (fr) * 2017-06-20 2018-12-27 Kao Corporation S.A. Compositions actives d'adoucissant pour textiles
US10570354B2 (en) 2017-06-20 2020-02-25 Kao Corporation S.A. Fabric softener active compositions
WO2022152548A1 (fr) * 2021-01-13 2022-07-21 Unilever Ip Holdings B.V. Revitalisant pour tissu
WO2023099499A1 (fr) * 2021-12-02 2023-06-08 Unilever Ip Holdings B.V. Procédé de conditionnement de tissu

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AU6203694A (en) 1994-09-14

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