WO1993018031A1 - Pyrazole derivative - Google Patents

Pyrazole derivative Download PDF

Info

Publication number: WO1993018031A1
Authority: WO; WIPO (PCT)
Prior art keywords: alkyl; pyrazole derivative; hydrogen; halogen; integer
Prior art date: 1992-03-03

Application number

PCT/JP1993/000274

Other languages

English (en)

French (fr)

Inventor

Mitsuru Shibata

Masashi Sakamoto

Kazuyoshi Koike

Ichiro Nasuno

Original Assignee

Idemitsu Kosan Co., Ltd.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-03-03

Filing date

1993-03-03

Publication date

1993-09-16

1993-03-03 Application filed by Idemitsu Kosan Co., Ltd. filed Critical Idemitsu Kosan Co., Ltd.

1993-03-03 Priority to DE69325018T priority Critical patent/DE69325018T2/de

1993-03-03 Priority to AU36481/93A priority patent/AU3648193A/en

1993-03-03 Priority to EP93905613A priority patent/EP0629623B1/en

1993-03-03 Priority to BR9306011A priority patent/BR9306011A/pt

1993-03-03 Priority to JP05515530A priority patent/JP3089613B2/ja

1993-03-03 Priority to US08/290,943 priority patent/US5468722A/en

1993-09-16 Publication of WO1993018031A1 publication Critical patent/WO1993018031A1/ja

1995-08-01 Priority to US08/509,963 priority patent/US5587484A/en

Links

150000003217 pyrazoles Chemical class 0.000 title abstract 2
125000000217 alkyl group Chemical group 0.000 abstract 4
229910052739 hydrogen Inorganic materials 0.000 abstract 4
239000001257 hydrogen Substances 0.000 abstract 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
229910052736 halogen Inorganic materials 0.000 abstract 2
150000002367 halogens Chemical class 0.000 abstract 2
125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
241000196324 Embryophyta Species 0.000 abstract 1
240000005979 Hordeum vulgare Species 0.000 abstract 1
235000007340 Hordeum vulgare Nutrition 0.000 abstract 1
241000209140 Triticum Species 0.000 abstract 1
235000021307 Triticum Nutrition 0.000 abstract 1
240000008042 Zea mays Species 0.000 abstract 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
235000002017 Zea mays subsp mays Nutrition 0.000 abstract 1
150000001875 compounds Chemical class 0.000 abstract 1
235000005822 corn Nutrition 0.000 abstract 1
150000002431 hydrogen Chemical class 0.000 abstract 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
- C07D335/04—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D335/06—Benzothiopyrans; Hydrogenated benzothiopyrans
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Agronomy & Crop Science (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Plural Heterocyclic Compounds (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Heterocyclic Compounds Containing Sulfur Atoms (AREA)

PCT/JP1993/000274 1992-03-03 1993-03-03 Pyrazole derivative WO1993018031A1 (en)

Priority Applications (7)

Application Number	Priority Date	Filing Date	Title
DE69325018T DE69325018T2 (de)	1992-03-03	1993-03-03	Pyrazolderivate
AU36481/93A AU3648193A (en)	1992-03-03	1993-03-03	Pyrazole derivative
EP93905613A EP0629623B1 (en)	1992-03-03	1993-03-03	Pyrazole derivative
BR9306011A BR9306011A (pt)	1992-03-03	1993-03-03	Derivados de pirazol
JP05515530A JP3089613B2 (ja)	1992-03-03	1993-03-03	ピラゾール誘導体
US08/290,943 US5468722A (en)	1992-03-03	1993-03-03	Pyrazole derivatives
US08/509,963 US5587484A (en)	1992-03-03	1995-08-01	Pyrazole process and intermediates

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
JP4/45821		1992-03-03
JP4582192		1992-03-03

Publications (1)

Publication Number	Publication Date
WO1993018031A1 true WO1993018031A1 (en)	1993-09-16

Family

ID=12729920

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PCT/JP1993/000274 WO1993018031A1 (en)	1992-03-03	1993-03-03	Pyrazole derivative

Country Status (9)

Country	Link
US (2)	US5468722A (ja)
EP (1)	EP0629623B1 (ja)
JP (1)	JP3089613B2 (ja)
AT (1)	ATE180257T1 (ja)
BR (1)	BR9306011A (ja)
CA (1)	CA2131191A1 (ja)
DE (1)	DE69325018T2 (ja)
ES (1)	ES2134257T3 (ja)
WO (1)	WO1993018031A1 (ja)

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1996000008A1 (fr) *	1994-06-27	1996-01-04	Idemitsu Kosan Co., Ltd.	Composition herbicide
WO1996016962A1 (fr) *	1994-12-02	1996-06-06	Idemitsu Kosan Co., Ltd.	Procede de production de derives de pyrazole
WO1996030368A1 (en) *	1995-03-28	1996-10-03	Idemitsu Kosan Co., Ltd.	Pyrazole derivatives
WO1996031507A1 (fr) *	1995-04-05	1996-10-10	Idemitsu Kosan Co., Ltd.	Derives de pyrazole
EP0728756A4 (en) *	1993-11-09	1996-11-13	Idemitsu Kosan Co	PYRAZOLE DERIVATIVES AND HERBICIDE CONTAINING THEM
WO1997003064A1 (fr) *	1995-07-12	1997-01-30	Idemitsu Kosan Co., Ltd.	Derives de tricetone
WO1997008163A1 (fr) *	1995-08-31	1997-03-06	Idemitsu Kosan Co., Ltd.	Procede de production de derives thiochromane
WO1997008164A1 (en) *	1995-08-25	1997-03-06	E.I. Du Pont De Nemours And Company	Bicyclic herbicides
WO1997009327A1 (de) *	1995-09-01	1997-03-13	Basf Aktiengesellschaft	Pyrazol-4-yl-benzoylderivate und ihre verwendung als herbizide
WO1997012885A1 (fr) *	1995-10-04	1997-04-10	Idemitsu Kosan Co., Ltd.	Derives de pyrazole
WO1997023135A1 (fr) *	1995-12-25	1997-07-03	Idemitsu Kosan Co., Ltd.	Composition herbicide
WO1997041116A1 (fr) *	1996-04-26	1997-11-06	Nippon Soda Co., Ltd.	Derives du benzene substitues par des heterocycles, et herbicides
WO1997041118A1 (fr) *	1996-04-26	1997-11-06	Nippon Soda Co., Ltd.	Derives du benzene substitues par des heterocycles, et herbicides
WO1997041117A1 (fr) *	1996-04-26	1997-11-06	Nippon Soda Co., Ltd.	Nouveaux derives du benzene substitues par des heterocycles, et herbicides
WO1997049679A1 (fr) *	1996-06-27	1997-12-31	Ono Pharmaceutical Co., Ltd.	Derives d'aryle (sulfure, oxyde sulfonique et sulfone) et medicaments les contenant en tant que principe actif
EP0810227A4 (en) *	1995-02-15	1998-05-13	Idemitsu Kosan Co	ISOXAZOLE DERIVATIVES
WO1998029406A1 (fr) *	1996-12-27	1998-07-09	Idemitsu Kosan Co., Ltd.	Derives cyclohexanedione et herbicides obtenus a partir de ces derives
WO1999023094A1 (fr)	1997-10-30	1999-05-14	Nippon Soda Co., Ltd.	Nouveaux composes, produits intermediaires, et desherbants de benzoylpyrazole
US5939360A (en) *	1997-07-08	1999-08-17	Nippon Soda Co., Ltd.	Compound and herbicidal composition for weed control
US5981439A (en) *	1996-12-27	1999-11-09	Idemitsu Kosan Co., Ltd.	Cyclohexanedione derivatives and herbicides containing them
US5990049A (en) *	1997-12-19	1999-11-23	Idemitsu Kosan Co., Ltd.	Triketone derivatives
US6037312A (en) *	1996-05-23	2000-03-14	Idemitsu Kosan Co., Ltd.	Isoxazole derivatives
WO2000014087A1 (de) *	1998-09-04	2000-03-16	Aventis Cropscience Gmbh	Benzoylderivate, verfahren zu ihrer herstellung und ihre verwendung als herbizide und pflanzenwachstumsregulatoren
RU2162849C2 (ru) *	1996-12-27	2001-02-10	Ниппон Сода Ко., Лтд	Производное бензола, замещенное гетероциклом, и гербицид
WO2008043456A1 (en) *	2006-10-13	2008-04-17	Bayer Cropscience Ag	Benzoylpyrazoles, their use as as herbicides, and intermediates

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5607898A (en) *	1993-08-02	1997-03-04	Idemitsu Kosan Company, Ltd.	Pyrazole derivatives
ES2194971T3 (es) *	1995-02-13	2003-12-01	Idemitsu Kosan Co	Derivados del pirazol.
US5952266A (en) *	1995-06-29	1999-09-14	E. I. Du Pont De Nemours And Company	Herbicidal ketals and spirocycles
DE19543640A1 (de) *	1995-11-23	1997-05-28	Basf Ag	Isoxazol-4-yl-benzoylderivate
SK283200B6 (sk) *	1996-02-24	2003-03-04	Basf Aktiengesellschaft	Pyrazol-4-ylhetaroylderiváty ako herbicídy
US5631210A (en) *	1996-06-14	1997-05-20	E. I. Du Pont De Nemours And Company	Herbicidal thiophene ketones
DE19638484A1 (de) *	1996-09-20	1998-03-26	Basf Ag	Hetaroylderivate
US5885936A (en) *	1997-02-24	1999-03-23	E. I. Du Pont De Nemours And Company	Heterotricyclic herbicides
US6300514B1 (en)	1997-06-25	2001-10-09	Ono Pharmaceutical Co., Ltd.	Aryl (sulfide, sulfoxide and sulfone) derivatives and drugs containing the same as the active ingredient
KR19990036764A (ko)	1997-10-08	1999-05-25	이데미츠 고산 캄파니 리미티드	6-(아릴카보닐)-4-옥시모-디하이드로벤조티오피란 제초제제조방법 및 이에 유용한 중간체
US20020016262A1 (en) *	1998-03-02	2002-02-07	Idemitsu Kosan Co., Ltd.	Pyrazole derivatives and herbicides containing the same
EP1080089B1 (de) *	1998-05-18	2003-11-05	Basf Aktiengesellschaft	Pyrazolyldioxothiochromanoyl-derivate
BR0013075A (pt) *	1999-08-10	2002-05-21	Bayer Agrochem Kk	Derivados de tetrazolinona
US6413913B1 (en)	1999-10-22	2002-07-02	Basf Corporation	Thiono-thiochroman and -dihydrobenzothiophene compounds as herbicidal agents
JP2002080460A (ja)	2000-07-06	2002-03-19	Nippon Bayer Agrochem Co Ltd	除草性テトラゾール誘導体
JP2003238540A (ja) *	2002-02-08	2003-08-27	Bayer Ag	テトラゾール誘導体及び除草剤
US8841334B2 (en) *	2006-05-31	2014-09-23	Abbvie Inc.	Compounds as cannabinoid receptor ligands and uses thereof
EP2024349B1 (en) *	2006-05-31	2017-08-02	AbbVie Inc.	Compounds as cannabinoid receptor ligands and uses thereof
EP2142522A1 (en)	2007-03-28	2010-01-13	Abbott Laboratories	1, 3-thiazol-2 (3h) -ylidene compounds as cannabinoid receptor ligands
US7872033B2 (en) *	2007-04-17	2011-01-18	Abbott Laboratories	Compounds as cannabinoid receptor ligands
JP2010527929A (ja) *	2007-05-18	2010-08-19	アボット・ラボラトリーズ	カンナビノイド受容体リガンドとしての新規な化合物
US9193713B2 (en)	2007-10-12	2015-11-24	Abbvie Inc.	Compounds as cannabinoid receptor ligands
WO2009114566A1 (en)	2008-03-11	2009-09-17	Abbott Laboratories	Novel compounds as cannabinoid receptor ligands
US8846730B2 (en) *	2008-09-08	2014-09-30	Abbvie Inc.	Compounds as cannabinoid receptor ligands
JP2012502917A (ja) *	2008-09-16	2012-02-02	アボット・ラボラトリーズ	カンナビノイド受容体リガンドとしての置換ベンズアミド類
PA8854001A1 (es) *	2008-12-16	2010-07-27	Abbott Lab	Compuestos novedosos como ligandos de receptores de canabinoides
WO2010111572A1 (en) *	2009-03-27	2010-09-30	Abbott Laboratories	Compounds as cannabinoid receptor ligands

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS49116071A (ja) *	1973-02-24	1974-11-06
JPH02173A (ja) *	1987-03-17	1990-01-05	Nissan Chem Ind Ltd	ピラゾール誘導体及び選択性除草剤
JPH02288866A (ja) *	1988-07-15	1990-11-28	Nissan Chem Ind Ltd	ピラゾール誘動体及び選択性除草剤

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS63122672A (ja) *	1986-11-10	1988-05-26	Nissan Chem Ind Ltd	ピラゾ−ル誘導体および選択性除草剤
US5175299A (en) *	1987-03-17	1992-12-29	Nissan Chemical Industries, Ltd.	Benzoic acid derivatives useful as intermediates for the preparation of herbicidal 4-benzoylpyrazoles
US4885022A (en) *	1987-03-17	1989-12-05	Nissan Chemical Industries Ltd.	Herbicidal pyrazole derivatives
US4986845A (en) *	1988-07-15	1991-01-22	Nissan Chemical Industries Ltd.	Pyrazole derivatives and herbicides containing them
JP3245421B2 (ja) *	1992-08-18	2002-01-15	出光興産株式会社	シクロヘキサンジオン誘導体

1993
- 1993-03-03 JP JP05515530A patent/JP3089613B2/ja not_active Expired - Fee Related
- 1993-03-03 ES ES93905613T patent/ES2134257T3/es not_active Expired - Lifetime
- 1993-03-03 EP EP93905613A patent/EP0629623B1/en not_active Expired - Lifetime
- 1993-03-03 DE DE69325018T patent/DE69325018T2/de not_active Expired - Fee Related
- 1993-03-03 US US08/290,943 patent/US5468722A/en not_active Expired - Fee Related
- 1993-03-03 CA CA002131191A patent/CA2131191A1/en not_active Abandoned
- 1993-03-03 BR BR9306011A patent/BR9306011A/pt not_active IP Right Cessation
- 1993-03-03 WO PCT/JP1993/000274 patent/WO1993018031A1/ja active IP Right Grant
- 1993-03-03 AT AT93905613T patent/ATE180257T1/de not_active IP Right Cessation
1995
- 1995-08-01 US US08/509,963 patent/US5587484A/en not_active Expired - Fee Related

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS49116071A (ja) *	1973-02-24	1974-11-06
JPH02173A (ja) *	1987-03-17	1990-01-05	Nissan Chem Ind Ltd	ピラゾール誘導体及び選択性除草剤
JPH02288866A (ja) *	1988-07-15	1990-11-28	Nissan Chem Ind Ltd	ピラゾール誘動体及び選択性除草剤

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5756759A (en) *	1993-11-09	1998-05-26	Idemitsu Kosan Co., Ltd.	Pyrazole compounds having a thiochroman ring and pesticides containing such compounds
EP0728756A4 (en) *	1993-11-09	1996-11-13	Idemitsu Kosan Co	PYRAZOLE DERIVATIVES AND HERBICIDE CONTAINING THEM
US5849926A (en) *	1993-11-09	1998-12-15	Idemitsu Kosan Co., Ltd.	Pyrazole derivatives and herbicides containing the same
US5723408A (en) *	1994-06-27	1998-03-03	Idemitsu Kosan Co., Ltd.	Herbicide composition comprising 4-(benzothiopyran-6-carbonyl) pyrazoles
WO1996000008A1 (fr) *	1994-06-27	1996-01-04	Idemitsu Kosan Co., Ltd.	Composition herbicide
WO1996016962A1 (fr) *	1994-12-02	1996-06-06	Idemitsu Kosan Co., Ltd.	Procede de production de derives de pyrazole
EP0810227A4 (en) *	1995-02-15	1998-05-13	Idemitsu Kosan Co	ISOXAZOLE DERIVATIVES
WO1996030368A1 (en) *	1995-03-28	1996-10-03	Idemitsu Kosan Co., Ltd.	Pyrazole derivatives
EA000179B1 (ru) *	1995-03-28	1998-12-24	Идемицу Козан Ко., Лтд.	Производные пиразола
WO1996031507A1 (fr) *	1995-04-05	1996-10-10	Idemitsu Kosan Co., Ltd.	Derives de pyrazole
US5863866A (en) *	1995-04-05	1999-01-26	Idemitsu Kosan Co., Ltd.	Pyrazole derivatives
WO1997003064A1 (fr) *	1995-07-12	1997-01-30	Idemitsu Kosan Co., Ltd.	Derives de tricetone
WO1997008164A1 (en) *	1995-08-25	1997-03-06	E.I. Du Pont De Nemours And Company	Bicyclic herbicides
WO1997008163A1 (fr) *	1995-08-31	1997-03-06	Idemitsu Kosan Co., Ltd.	Procede de production de derives thiochromane
WO1997009327A1 (de) *	1995-09-01	1997-03-13	Basf Aktiengesellschaft	Pyrazol-4-yl-benzoylderivate und ihre verwendung als herbizide
AU710278B2 (en) *	1995-09-01	1999-09-16	Basf Aktiengesellschaft	Pyrazol-4-ylbenzoyl derivatives
EA000753B1 (ru) *	1995-09-01	2000-04-24	Басф Акциенгезельшафт	Производные пиразол-4-илбензоила и их применение в качестве гербицидов
US6291682B1 (en) *	1995-09-01	2001-09-18	Basf Aktiengesellschaft	Pyrazol-4-ylbenzoyl derivatives and their use as herbicides
EP0970956A4 (en) *	1995-10-04	2000-01-12	Idemitsu Kosan Co	PYRAZOLE DERIVATIVES
WO1997012885A1 (fr) *	1995-10-04	1997-04-10	Idemitsu Kosan Co., Ltd.	Derives de pyrazole
US6159904A (en) *	1995-10-04	2000-12-12	Idemitsu Kosan Co., Ltd.	Pyrazole derivatives
WO1997023135A1 (fr) *	1995-12-25	1997-07-03	Idemitsu Kosan Co., Ltd.	Composition herbicide
WO1997041116A1 (fr) *	1996-04-26	1997-11-06	Nippon Soda Co., Ltd.	Derives du benzene substitues par des heterocycles, et herbicides
WO1997041118A1 (fr) *	1996-04-26	1997-11-06	Nippon Soda Co., Ltd.	Derives du benzene substitues par des heterocycles, et herbicides
WO1997041117A1 (fr) *	1996-04-26	1997-11-06	Nippon Soda Co., Ltd.	Nouveaux derives du benzene substitues par des heterocycles, et herbicides
US6037312A (en) *	1996-05-23	2000-03-14	Idemitsu Kosan Co., Ltd.	Isoxazole derivatives
WO1997049679A1 (fr) *	1996-06-27	1997-12-31	Ono Pharmaceutical Co., Ltd.	Derives d'aryle (sulfure, oxyde sulfonique et sulfone) et medicaments les contenant en tant que principe actif
RU2162849C2 (ru) *	1996-12-27	2001-02-10	Ниппон Сода Ко., Лтд	Производное бензола, замещенное гетероциклом, и гербицид
US5981439A (en) *	1996-12-27	1999-11-09	Idemitsu Kosan Co., Ltd.	Cyclohexanedione derivatives and herbicides containing them
WO1998029406A1 (fr) *	1996-12-27	1998-07-09	Idemitsu Kosan Co., Ltd.	Derives cyclohexanedione et herbicides obtenus a partir de ces derives
US5939360A (en) *	1997-07-08	1999-08-17	Nippon Soda Co., Ltd.	Compound and herbicidal composition for weed control
WO1999023094A1 (fr)	1997-10-30	1999-05-14	Nippon Soda Co., Ltd.	Nouveaux composes, produits intermediaires, et desherbants de benzoylpyrazole
US5990049A (en) *	1997-12-19	1999-11-23	Idemitsu Kosan Co., Ltd.	Triketone derivatives
WO2000014087A1 (de) *	1998-09-04	2000-03-16	Aventis Cropscience Gmbh	Benzoylderivate, verfahren zu ihrer herstellung und ihre verwendung als herbizide und pflanzenwachstumsregulatoren
US6297196B1 (en)	1998-09-04	2001-10-02	Hoechst Schering Agrevo Gmbh	Benzoyl derivatives, process for their preparation and their use as herbicides and plant growth regulators
WO2008043456A1 (en) *	2006-10-13	2008-04-17	Bayer Cropscience Ag	Benzoylpyrazoles, their use as as herbicides, and intermediates

Also Published As

Publication number	Publication date
EP0629623A4 (en)	1995-02-08
US5468722A (en)	1995-11-21
DE69325018D1 (en)	1999-06-24
ATE180257T1 (de)	1999-06-15
JP3089613B2 (ja)	2000-09-18
EP0629623B1 (en)	1999-05-19
CA2131191A1 (en)	1993-09-04
ES2134257T3 (es)	1999-10-01
DE69325018T2 (de)	1999-09-16
EP0629623A1 (en)	1994-12-21
BR9306011A (pt)	1997-10-21
US5587484A (en)	1996-12-24

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