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WO1992011347A3 - Enzyme preparation for washing and cleansing agents - Google Patents

Enzyme preparation for washing and cleansing agents Download PDF

Info

Publication number
WO1992011347A3
WO1992011347A3 PCT/EP1991/002340 EP9102340W WO9211347A3 WO 1992011347 A3 WO1992011347 A3 WO 1992011347A3 EP 9102340 W EP9102340 W EP 9102340W WO 9211347 A3 WO9211347 A3 WO 9211347A3
Authority
WO
WIPO (PCT)
Prior art keywords
washing
fermentation
additives
mixing
water
Prior art date
Application number
PCT/EP1991/002340
Other languages
German (de)
French (fr)
Other versions
WO1992011347A2 (en
Inventor
Hubert Pawelczyk
Wilfried Raehse
Franz-Josef Carduck
Norbert Kuehne
Volker Runge
Horst Upadek
Original Assignee
Henkel Kgaa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kgaa filed Critical Henkel Kgaa
Priority to DE59105338T priority Critical patent/DE59105338D1/en
Priority to EP92900162A priority patent/EP0564476B1/en
Publication of WO1992011347A2 publication Critical patent/WO1992011347A2/en
Publication of WO1992011347A3 publication Critical patent/WO1992011347A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38672—Granulated or coated enzymes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

In the production of enzyme granulates with grain sizes from 0.1 to 2 mm, containing 2 to 20 % wt. proteases, lipases, amylases and/or cellulases, 10 to 50 % wt. swellable starch, 5 to 50 % wt. granulating agent, 3 to 12 % wt. water and not more than 10 % wt. water-soluble salt, by extruding an enzyme pre-mixture obtained by mixing a fermentation liquor cleared of insoluble components and concentrated with additives and spheroidizing the extrudate in a rounder, the use of relatively highly concentrated fermentation liquours has previously been necessary. By removing the insoluble components from the fermentation liquor by micro-filtration and mixing with additives which, in relation to the finished granulate, contains 10 to 35 % wt. cereal flour, it is possible, by the use of low-concentration fermentation liquors, to obtain highly active enzyme granulates with a long shelf life which are suitable for inclusion in washing and cleansing agents and are distinguished by uniform solubility properties in aqueous washing and cleansing baths.
PCT/EP1991/002340 1990-12-24 1991-12-06 Enzyme preparation for washing and cleansing agents WO1992011347A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE59105338T DE59105338D1 (en) 1990-12-24 1991-12-06 ENZYME PREPARATION FOR DETERGENT AND CLEANING AGENT.
EP92900162A EP0564476B1 (en) 1990-12-24 1991-12-06 Enzyme preparation for washing and cleansing agents

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4041752.2 1990-12-24
DE4041752A DE4041752A1 (en) 1990-12-24 1990-12-24 ENZYME PREPARATION FOR WASHING AND CLEANING AGENTS

Publications (2)

Publication Number Publication Date
WO1992011347A2 WO1992011347A2 (en) 1992-07-09
WO1992011347A3 true WO1992011347A3 (en) 1992-08-06

Family

ID=6421424

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1991/002340 WO1992011347A2 (en) 1990-12-24 1991-12-06 Enzyme preparation for washing and cleansing agents

Country Status (6)

Country Link
EP (1) EP0564476B1 (en)
AT (1) ATE121770T1 (en)
DE (2) DE4041752A1 (en)
DK (1) DK0564476T3 (en)
ES (1) ES2071478T3 (en)
WO (1) WO1992011347A2 (en)

Families Citing this family (75)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994004665A1 (en) * 1992-08-14 1994-03-03 Solvay Enzymes Gmbh & Co. Kg Novel enzyme granulates
DE4310506A1 (en) * 1993-03-31 1994-10-06 Cognis Bio Umwelt Enzyme preparation for detergents and cleaning agents
DE4322229A1 (en) * 1993-07-05 1995-01-12 Cognis Bio Umwelt Enveloped enzyme preparation for detergents and cleaners
DE4329463A1 (en) * 1993-09-01 1995-03-02 Cognis Bio Umwelt More enzyme granules
DE4344215A1 (en) * 1993-12-23 1995-06-29 Cognis Bio Umwelt Silver corrosion inhibitor-containing enzyme preparation
DE4420730A1 (en) * 1994-06-15 1995-12-21 Henkel Kgaa Process for the deodorization and stabilization of biotechnologically obtained valuable substances and their aqueous preparations
DE4422609A1 (en) * 1994-06-28 1996-01-04 Cognis Bio Umwelt Multi-enzyme granules
DE4422433A1 (en) 1994-06-28 1996-01-04 Cognis Bio Umwelt Multi-enzyme granules
DE69519944T2 (en) * 1994-11-18 2001-06-13 Genencor International, Inc. COATED ENZYME GRANULATES
DE19521371A1 (en) * 1995-06-12 1996-12-19 Henkel Kgaa Enzyme granules containing silver corrosion inhibitor
US5571446A (en) * 1995-07-27 1996-11-05 Diversey Corporation Anionic stabilized enzyme based clean-in-place system
CZ87497A3 (en) * 1995-07-28 1998-03-18 Gist-Brocades B. V. Enzyme preparation stabilized by means of salts
DE19543197A1 (en) * 1995-11-20 1997-05-22 Henkel Kgaa Cobuilderhaltige enzyme preparation
DE19545729A1 (en) 1995-12-08 1997-06-12 Henkel Kgaa Bleach and detergent with an enzymatic bleaching system
DE19600018A1 (en) 1996-01-03 1997-07-10 Henkel Kgaa Detergent with certain oxidized oligosaccharides
DE19605688A1 (en) * 1996-02-16 1997-08-21 Henkel Kgaa Transition metal complexes as activators for peroxygen compounds
WO1997036986A1 (en) * 1996-04-01 1997-10-09 Henkel Kommanditgesellschaft Auf Aktien Cleaning agent with oligoammine activator complexes for peroxide compounds
DE19620411A1 (en) 1996-04-01 1997-10-02 Henkel Kgaa Transition metal amine complexes as activators for peroxygen compounds
DE19615776A1 (en) 1996-04-20 1997-10-23 Henkel Kgaa Solubility-enhanced enzyme granules
DE19616693A1 (en) * 1996-04-26 1997-11-06 Henkel Kgaa Enol esters as bleach activators for detergents and cleaning agents
DE19619219A1 (en) 1996-05-13 1997-12-04 Hoechst Ag Enzyme pre-granules for animal feed granules
US8828432B2 (en) 1996-10-28 2014-09-09 General Mills, Inc. Embedding and encapsulation of sensitive components into a matrix to obtain discrete controlled release particles
DE19649375A1 (en) 1996-11-29 1998-06-04 Henkel Kgaa Acetonitrile derivatives as bleach activators in detergents
DE19651446A1 (en) 1996-12-11 1998-06-18 Henkel Kgaa Enveloped enzyme preparation with improved solubility
DE19700327A1 (en) * 1997-01-08 1998-07-09 Henkel Kgaa Protease and amylase detergent
DE19713852A1 (en) 1997-04-04 1998-10-08 Henkel Kgaa Activators for peroxygen compounds in detergents and cleaning agents
DE19718978A1 (en) * 1997-05-05 1998-11-12 Henkel Kgaa Process for inhibiting color transfer in textiles during washing
TW409035B (en) 1997-06-04 2000-10-21 Gist Brocades Bv Starch-based enzyme granulates
DE19732751A1 (en) 1997-07-30 1999-02-04 Henkel Kgaa New Bacillus beta glucanase
DE19732750A1 (en) 1997-07-30 1999-02-04 Henkel Kgaa Cleaning agent containing glucanase for hard surfaces
DE19732749A1 (en) 1997-07-30 1999-02-04 Henkel Kgaa Detergent containing glucanase
AU745104B2 (en) * 1997-12-20 2002-03-14 Genencor International, Inc. Granule with hydrated barrier material
US7201923B1 (en) 1998-03-23 2007-04-10 General Mills, Inc. Encapsulation of sensitive liquid components into a matrix to obtain discrete shelf-stable particles
US6723358B1 (en) 1998-03-23 2004-04-20 General Mills, Inc. Encapsulation of components into edible products
DE19819187A1 (en) 1998-04-30 1999-11-11 Henkel Kgaa Solid dishwasher detergent with phosphate and crystalline layered silicates
DE19824705A1 (en) 1998-06-03 1999-12-09 Henkel Kgaa Detergents and cleaning agents containing amylase and protease
EP1119345B1 (en) 1998-10-09 2009-04-29 General Mills, Inc. Encapsulation of sensitive liquid components into a matrix to obtain discrete shelf-stable particles
DE19850100A1 (en) 1998-10-29 2000-05-04 Henkel Kgaa Polymer granules through fluidized bed granulation
DE19857204A1 (en) 1998-12-11 2000-06-15 Henkel Kgaa Aqueous foam regulator emulsion
DE19859385A1 (en) 1998-12-22 2000-06-29 Basf Ag Process for the preparation of enzyme-containing granules
DE19908051A1 (en) 1999-02-25 2000-08-31 Henkel Kgaa Process for the preparation of compounded acetonitrile derivatives
DE19956239A1 (en) * 1999-11-23 2001-05-31 Henkel Kgaa Recovery of biotechnological products comprises an additional wash step which is carried out with a previously obtained filtration liquid
DE19956382A1 (en) * 1999-11-24 2001-05-31 Henkel Kgaa Microencapsulated enzymes retaining their activity in detergents are obtained by dispersing an aqueous enzyme solution in a starch solution and/or emulsion
EP1307547B1 (en) 2000-07-28 2005-10-26 Henkel Kommanditgesellschaft auf Aktien Novel amylolytic enzyme extracted from bacillus sp. a 7-7 (dsm 12368) and washing and cleaning agents containing this novel amylolytic enzyme
DE10058645A1 (en) 2000-11-25 2002-05-29 Clariant Gmbh Use of cyclic sugar ketones as catalysts for peroxygen compounds
AU2002233186A1 (en) 2000-11-28 2002-06-11 Henkel Kommanditgesellschaft Auf Aktien Cyclodextrin glucanotransferase (cgtase), obtained from bacillus agaradherens (dsm 9948) and detergents and cleaning agents containing said novel cyclodextrin glucanotransferase
DE10061280A1 (en) * 2000-12-08 2002-06-13 Novaprot Gmbh Cleaning-effective, surface-active combination of renewable raw materials with high fat-dissolving power
DE10102248A1 (en) 2001-01-19 2002-07-25 Clariant Gmbh Use of transition metal complexes with oxime ligands as bleach catalysts
DE10108459A1 (en) 2001-02-22 2002-09-12 Henkel Kgaa Stability of foam-regulator granulates for use in detergents is improved by using a carrier containing alkali carbonate and a Bronsted acid
DE10142124A1 (en) 2001-08-30 2003-03-27 Henkel Kgaa Coated active ingredient preparation for use in particulate detergents and cleaning agents
DE10163748A1 (en) 2001-12-21 2003-07-17 Henkel Kgaa New glycosyl hydrolases
DE10211389A1 (en) 2002-03-15 2003-09-25 Clariant Gmbh Ammonium nitrile compounds, used as activator for peroxide bleach in laundry, dishwasher and other detergents and disinfectants and in bleaching textile, paper and wood are new
US7431986B2 (en) 2002-07-24 2008-10-07 General Mills, Inc. Encapsulation of sensitive components using pre-emulsification
DE10304131A1 (en) 2003-02-03 2004-08-05 Clariant Gmbh Transition metal complexes with nitrogen-containing ligands are used as catalysts for peroxy compounds, especially in detergent, bleaching and cleansing agents
JP2007514025A (en) 2003-12-13 2007-05-31 ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン Multi-component thin-to-sic system
US8361946B2 (en) 2004-04-08 2013-01-29 Akzo Nobel N.V. Detergent composition
EP1754781B1 (en) 2005-08-19 2013-04-03 The Procter and Gamble Company A solid laundry detergent composition comprising anionic detersive surfactant and a calcium-augmented technology
DE102005039580A1 (en) 2005-08-19 2007-02-22 Henkel Kgaa Color protecting detergent
US7803413B2 (en) 2005-10-31 2010-09-28 General Mills Ip Holdings Ii, Llc. Encapsulation of readily oxidizable components
DE102006038448A1 (en) 2005-12-28 2008-02-21 Henkel Kgaa Enzyme-containing cleaning agent
DE102007029643A1 (en) 2006-09-08 2009-01-15 Henkel Ag & Co. Kgaa cleaning supplies
DE102007016391A1 (en) 2007-04-03 2008-10-09 Henkel Ag & Co. Kgaa Detergent or cleaning agent for preventing transfer of textile color of colored textiles from uncolored or different colored textiles in laundry, particularly in tenside containing aqueous solution, has color transfer inhibitor
DE102007028310A1 (en) 2007-06-20 2008-12-24 Clariant International Ltd. Surfactant mixtures with synergistic properties
DE102008013606A1 (en) 2008-03-11 2009-09-17 Clariant International Ltd. Process for the preparation of solid alkaline earth metal salts of secondary paraffin sulphonic acids
JP5795254B2 (en) 2008-04-09 2015-10-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Use of metal hydrazide complex compounds as oxidation catalysts
CN102958909B (en) 2010-06-28 2016-11-09 巴斯夫欧洲公司 Metal-free bleaching composition
US9051285B2 (en) 2010-12-13 2015-06-09 Basf Se Bleach catalysts
DE102011010818A1 (en) 2011-02-10 2012-08-16 Clariant International Ltd. Use of transition metal complexes as bleaching catalysts in detergents and cleaners
DE102014009836B4 (en) 2014-07-03 2017-04-06 Weylchem Wiesbaden Gmbh Sodium salts of secondary alkanesulfonates containing compounds, their preparation and use and washing, disinfecting and cleaning agents containing these
DE102015217816A1 (en) 2015-09-17 2017-03-23 Henkel Ag & Co. Kgaa Use of highly concentrated enzyme granules to increase the storage stability of enzymes
WO2017076771A1 (en) 2015-11-03 2017-05-11 Basf Se Bleach catalysts
EP3176157A1 (en) 2015-12-01 2017-06-07 Basf Se Bleach catalysts
WO2017186480A1 (en) 2016-04-26 2017-11-02 Basf Se Metal free bleaching composition
EP3372663A1 (en) 2017-03-10 2018-09-12 Basf Se Bleach catalysts
NL2021893B1 (en) 2018-10-26 2020-05-13 Citeq B V Biological pest control agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1067711B (en) * 1957-06-11 1959-10-22 Bancroft Brillotex Internat S Method of cleaning wool
US4176079A (en) * 1977-04-20 1979-11-27 The Procter & Gamble Company Water-soluble enzyme-containing article
EP0168526A1 (en) * 1983-12-07 1986-01-22 Henkel Kommanditgesellschaft auf Aktien Enzyme preparation for use in powder detergents
EP0216322A1 (en) * 1985-09-24 1987-04-01 Heinz Weber Washing composition and process for cleansing textiles

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1067711B (en) * 1957-06-11 1959-10-22 Bancroft Brillotex Internat S Method of cleaning wool
US4176079A (en) * 1977-04-20 1979-11-27 The Procter & Gamble Company Water-soluble enzyme-containing article
EP0168526A1 (en) * 1983-12-07 1986-01-22 Henkel Kommanditgesellschaft auf Aktien Enzyme preparation for use in powder detergents
EP0216322A1 (en) * 1985-09-24 1987-04-01 Heinz Weber Washing composition and process for cleansing textiles

Also Published As

Publication number Publication date
EP0564476A1 (en) 1993-10-13
ATE121770T1 (en) 1995-05-15
DE4041752A1 (en) 1992-06-25
DK0564476T3 (en) 1995-09-04
EP0564476B1 (en) 1995-04-26
WO1992011347A2 (en) 1992-07-09
DE59105338D1 (en) 1995-06-01
ES2071478T3 (en) 1995-06-16

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