WO1992009121A1 - Connexion protegee contre l'environnement - Google Patents
Connexion protegee contre l'environnement Download PDFInfo
- Publication number
- WO1992009121A1 WO1992009121A1 PCT/US1991/008542 US9108542W WO9209121A1 WO 1992009121 A1 WO1992009121 A1 WO 1992009121A1 US 9108542 W US9108542 W US 9108542W WO 9209121 A1 WO9209121 A1 WO 9209121A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sleeve
- cable
- encapsulant
- accordance
- connector
- Prior art date
Links
- 239000008393 encapsulating agent Substances 0.000 claims abstract description 40
- 230000008878 coupling Effects 0.000 claims abstract description 37
- 238000010168 coupling process Methods 0.000 claims abstract description 37
- 238000005859 coupling reaction Methods 0.000 claims abstract description 37
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 7
- 230000007613 environmental effect Effects 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 15
- 239000000499 gel Substances 0.000 description 28
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 2
- 230000013011 mating Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/46—Bases; Cases
- H01R13/52—Dustproof, splashproof, drip-proof, waterproof, or flameproof cases
- H01R13/5216—Dustproof, splashproof, drip-proof, waterproof, or flameproof cases characterised by the sealing material, e.g. gels or resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/46—Bases; Cases
- H01R13/52—Dustproof, splashproof, drip-proof, waterproof, or flameproof cases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R4/00—Electrically-conductive connections between two or more conductive members in direct contact, i.e. touching one another; Means for effecting or maintaining such contact; Electrically-conductive connections having two or more spaced connecting locations for conductors and using contact members penetrating insulation
- H01R4/70—Insulation of connections
- H01R4/72—Insulation of connections using a heat shrinking insulating sleeve
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R43/00—Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
- H01R43/005—Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors for making dustproof, splashproof, drip-proof, waterproof, or flameproof connection, coupling, or casing
Definitions
- This invention comprises an assembly and method for environmentally protecting a cable connection.
- the connector typically has a metallic coupling nut which joins the connector on the cable end to the connector receptacle on the black box, or the like.
- the coupling mechanism may be provided with threads and are screwed together, or provided with bayonet connection means or the like.
- the metal components of the connection are subject to corrosion, the degree of corrosion depending on the environment in which it is located. Corrosion leads to the deterioration of the connection and even failure of the connectors. Further, it is generally desired that the connection be readily reenterable, that is that the connector and cable can be readily removed from the receptacle. Extensive corrosion of the connectors, plug and receptacle, and mounting hardware can prevent functionality and demating of the connectors. It is therefore desirable to provide a connection which is protected from the environment and resistant to corrosion. Further, the connectors should remain dematable.
- One aspect of this invention comprises an assembly for environmentally protecting a cable connection in which an end of a cable is connected to a connector having a coupling nut, which assembly comprises:
- a layer of encapsulant positioned between at least a portion of the polymeric sleeve and the underlying cable, the encapsulant providing a circumferential environmental seal between the cable and the sleeve while permitting rotational motion between the cable and the sleeve.
- the assembly preferable further comprises a layer of encapsulant extending from the coupling nut over the hardware mounting a connector receptacle in a bulkhead to which the connector is coupled.
- Another aspect of this invention comprises a method of environmentally protecting a cable connection which an end of a cable is connected to a connector having a coupling nut, which method comprises:
- the method preferable further comprises the step of securing the coupling nut to a connector receptacle mounted in a bulkhead and positioning a layer of encapsulant over hardware mounting the connector receptacle in the bulkhead.
- the term "bulkhead” is used in this patent application to cover any wall to which the cable is connected, including the wall of a "black box", a traditional bulkhead or the like.
- the term “black box” is used to cover any enclosure containing electrical or electronic components.
- the term “cable” is used to mean any bundle of wires and includes harnesses as well as cables.
- the cable may be terminated to the connector and the termination may be insulated using an initial polymeric sleeve or other appropriate means.
- the term cable embraces the insulated cable termination.
- the polymeric sleeve positioned over the connector and adjacent cable end is preferable a dimensionally recoverable tubular article.
- a dimensionally recoverable article is one whose dimensional configuration may be made to change when subjected to an appropriate treatment.
- these articles recover, on heating, towards an original shape from which they have previously been deformed, but the term "heat- recoverable” as used herein also includes an article which, on heating, adopts a new configuration even if it has not been previously deformed.
- heat-recoverable articles comprise a heat- shrinkable sleeve made from a polymeric material exhibiting the property of elastic or plastic memory as described, for example, in U.S. Patents 2,027,962, 3,086,242 and 3,597,372. As is made clear in, for example, U.S.
- the original dimensionally heat-stable form may be a transient form in a continuous process in which, for example, an extruded tube is expanded immediately after extrusion, while hot, to a d mensionally heat-unstable form.
- a preformed dimensionally heat- stable article is deformed to a dimensionally heat-unstable form in a separate stage.
- the polymeric material may be crosslinked at any stage in the production of the article to enhance the desired dimensional recoverability.
- One manner of producing a heat- recoverable article comprises shaping the polymeric article into the desired heat-unstable form, subsequently crosslinking the polymeric material, heating the article to a temperature above the crystalline melting point of the polymer, deforming the article and then cooling the article while in the deformed state so that the deformed state of the article is retained.
- application of heat will cause the article to assume its original heat-stable shape.
- Dimensionally recoverable articles suitable for use in this invention may be elastomeric sleeves held in an expanded configuration by an internal or external support. Such articles recover when released from the support, not on the application of heat and are sometimes referred to as "cold-shrink" articles. Such articles are described, for example, in U.S. Patent No. 4,070,746 to Evans et al and 3,515,798 to Sievert, the entire disclosures of which are incorporated by reference.
- the polymeric sleeve can also be a double wall tubular article such as that described in U.S. Patent No. 4,868,967, the entire disclosure of which is incorporated by reference.
- a preferred polymeric sleeve for use in this invention is relatively thick walled and is preferable prepared by molding the sleeve and then rendering it heat shrinkable as discussed above.
- the sleeve can be made of any polymeric material such as, polyethylene, polyvinylidene fluoride, silicone rubber, or the like.
- the cable may be connected in line or at 90° to the connector. If it is connected at 90°, the polymeric sleeve can have a 90° bend or can be sufficiently short that it comes down on the cable before it bends.
- the polymeric sleeve is secured to the coupling nut of the connector so that rotational motion between the sleeve and the nut is prevented.
- the polymeric sleeve is bonded to the coupling nut using and hot melt adhesive such as a polyamide or ethylene vinyl acetate copolymer based adhesives.
- a curable adhesive such as an epoxy or unsaturated polyester adhesive may be used, if desired.
- the diameter of the coupling nut can be built up by bonding thereto polymeric tape or a tubular article, which may be a heat recoverable article.
- a layer of encapsulant is positioned between the sleeve and the underlying cable, cable.
- the layer of encapsulant may be a sealing material such as a grease or a gel.
- a preferred encapsulant is a gel.
- the gel preferably has a Voland Hardness of about 1 to about 525 g., more preferably about 5 to about 300 g, and most preferably about 5 to about 100 g., and also preferably has an ultimate elongation of at least about 50%, preferably at least about 100%. The elongation is measured according to the procedures of ASTM D217.
- the Voland hardness is measured using a Voland-Stevens Texture analyser Model LFRA having a 1000 g load cell, a 5 gram trigger, and a 1/4 inch(6.35 mm) ball probe.
- a 20 ml glass scintillating vial containing 10 grams of gel is placed in the Voland-Stevens Texture analyser and the stainless steel ball probe is forced into the gel at a speed of 2.0 mm a second to a penetration distance of 4.0 mm.
- the Voland Hardness value of the gel is the force in grams required to force the ball probe at that speed to penetrate or deform the surface of the gel the specified 4.0 mm.
- the Voland Hardness of a gel may be directly correlated to the ASTM D217 cone penetration hardness and the procedure and a correlation is shown in Fig. 3 of U.S. Patent No. 4,852,646 to Dittmer et al, the disclosure of which is incorporated herein by reference.
- the gel is preferably a liquid-extended polymer composition.
- the polymeric component can be for example, a silicone, polyorgano siloxane, polyurethane, polyurea, styrene-butadiene and/or styrene-isoprene block copolymers.
- the gels may be formed from a mixture of such polymers.
- the layer of gel may comprise a foam impregnated with the gel.
- the entire disclosures of the above are incorporated by reference herein for all purposes.
- the gel may be impregnated in a matrix such as a foam or fabric. Gel impregnated in a matrix is disclosed in U.S. Patents Nos. 4,690,831 to Uken et al and 4,865,905 to Debbaut et al,the entire disclosures of which are incorporated herein by reference for all purposes.
- the encapsulant layer is applied in the form of one or more wraps of a self-supporting, reinforced strip of silicone gel.
- a typical tape or strip of gel suitable for use in ;this invention is described for example in U.S. Patent No. 4,865,905 to Uken, the entire disclosure of which is incorporated herein by reference.
- the gel strip is applied to the cable before the polymeric sleeve is installed.
- a further layer of gel is also positioned between the edge of the connector and the bulkhead.
- This layer of gel may take the form of a gasket of gel placed against the bulkhead.
- the gel is provided in a annular, deformable, polymeric cap.
- the polymer sleeve may be provide with a flange, as described more fully below with regard to FIG. 1.
- FIG. 1 shows in partial cross-section, an environmentally protected cable connection of the invention.
- FIG. 2 shows application of a layer of gel to the underlying cable end prior to installation of a polymeric sleeve over the cable end and connector.
- FIG 3. shows a preferred polymeric sleeve prior to its installation over the cable end and connector.
- FIG 1 shows in partial cross-section an environmentally protected cable connection according to the invention.
- cable 10 is joined to connector 12, which consists of connector body 12, coupling nut 14 and insert 16.
- Wires 18 of the cable are electrically connected to terminals (not shown) within insert 16.
- the cable shield 20 is connected to the connector insert.
- An initial polymeric sleeve 22 has been installed over the cable termination.
- This sleeve is preferably a heat shrinkable sleeve which has been recovered onto the connector insert and cable jacket and is bonded thereto.
- the use of the initial polymeric sleeve in this manner is a conventional technique for use when the cable clamp section of the connector is metallic.
- Polymeric sleeve 24 is a heat recoverable sleeve of the assembly of this invention and has been recovered onto the coupling nut 14 of the connector and bonded thereto using a hot melt polyamide-based adhesive.
- the polymeric sleeve preferably extends to the edge of the coupling nut.
- Encapsulant 26 is positioned between the initial polymeric sleeve and the polymeric sleeve of the assembly of this invention.
- the encapsulant is preferable a silicone gel and preferably applied in strip or tape form, as discussed above. The encapsulant permits rotational (or circumferential) motion between the cable and the outer polymeric sleeve.
- Cap 28 is filled with a further layer of encapsulant 30, which is preferably a silicone gel.
- Flange 32 of polymeric sleeve 24 applies force to the gel within the cap as the coupling nut is screwed onto its mating connector receptacle 33 on bulkhead 34.
- the cap is dimensioned so that the hardware (consisting of a flange and bolts) 35 mounting the connector receptacle to the bulkhead is covered by the cap 28 and the encapsulant 30 within the cap.
- the arrangement of the cap and the flange on the polymeric sleeve provides continuing force on the encapsulant maintaining it in sealing contact with the fastening hardware, connector receptacle and bulkhead.
- the polymeric sleeve over the layer of encapsulant permits rotational motion between the cable and the sleeve.
- up to five rotations of the nut may be required to screw the nut into the receptacle.
- the encapsulant may exude from beneath the sleeve after repeated rotations.
- internal circumferential ribs (not shown) may be provided in the polymeric sleeve. It is preferred that the encapsulant be positioned under the sleeve at a location toward the coupling nut. This can result in the sleeve at its other end touching the cable jacket.
- a lubricant such as a silicone oil, may be applied to the cable jacket in that region.
- FIG. 2 shows the application of encapsulant 26 to cable 10 in the form of a self supporting strip of reinforced silicone gel. It is to be understood that other encapsulants can be used and can be applied in any convenient manner.
- FIG. 3 shows a preferred heat recoverable sleeve 24 prior to installation over the cable and connector and includes ribs 36 which aid in gripping the sleeve to unscrew the coupling nut from its mating coupler on the bulkhead. This permits ready demating of the connector which can then be readily replaced. It is preferred to use a replacement for cap 28 when the cable is re-connected to the bulkhead.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Cable Accessories (AREA)
- Connector Housings Or Holding Contact Members (AREA)
- Laying Of Electric Cables Or Lines Outside (AREA)
- Coupling Device And Connection With Printed Circuit (AREA)
- Conductive Materials (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92901252A EP0557450B1 (fr) | 1990-11-16 | 1991-11-15 | Connexion protegee contre l'environnement |
DE69131137T DE69131137T2 (de) | 1990-11-16 | 1991-11-15 | Vor umwelteinflüssen geschützte verbindung |
JP4502298A JPH06502960A (ja) | 1990-11-16 | 1991-11-15 | 環境的保護接続部 |
KR1019930701446A KR100243918B1 (ko) | 1990-11-16 | 1991-11-15 | 주변조건으로부터보호되는접속장치 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61434890A | 1990-11-16 | 1990-11-16 | |
US614,348 | 1990-11-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992009121A1 true WO1992009121A1 (fr) | 1992-05-29 |
Family
ID=24460864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1991/008542 WO1992009121A1 (fr) | 1990-11-16 | 1991-11-15 | Connexion protegee contre l'environnement |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0557450B1 (fr) |
JP (1) | JPH06502960A (fr) |
KR (1) | KR100243918B1 (fr) |
AT (1) | ATE179028T1 (fr) |
AU (1) | AU9056591A (fr) |
CA (1) | CA2096342A1 (fr) |
DE (1) | DE69131137T2 (fr) |
WO (1) | WO1992009121A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2716298A1 (fr) * | 1994-02-15 | 1995-08-18 | Cinch Connecteurs Sa | Perfectionnements aux connecteurs électriques. |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009055024A1 (de) * | 2009-12-18 | 2011-06-22 | Brose Fahrzeugteile GmbH & Co. Kommanditgesellschaft, Würzburg, 97076 | Verfahren zum Herstellen eines Leitungssatzes für eine elektrische Maschine, Leitungssatz und elektrische Maschine |
US9259865B2 (en) * | 2013-03-17 | 2016-02-16 | The Boeing Company | Seal molding system and method |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3423518A (en) * | 1966-10-11 | 1969-01-21 | Sigma Ind Inc | Heat shrinkable grommet |
US4076360A (en) * | 1974-06-21 | 1978-02-28 | The Raymond Lee Organization, Inc. | Safety device for electrical connector device |
US4186986A (en) * | 1978-11-16 | 1980-02-05 | Amp Incorporated | Sealed splice |
US4702710A (en) * | 1986-06-20 | 1987-10-27 | Georgia Tech Research Corporation | Waterproof seal assembly for electrical connector |
US4865905A (en) * | 1983-06-23 | 1989-09-12 | Raychem Corporation | Article for protection of a substrate |
-
1991
- 1991-11-15 AU AU90565/91A patent/AU9056591A/en not_active Abandoned
- 1991-11-15 KR KR1019930701446A patent/KR100243918B1/ko not_active Expired - Fee Related
- 1991-11-15 AT AT92901252T patent/ATE179028T1/de not_active IP Right Cessation
- 1991-11-15 CA CA002096342A patent/CA2096342A1/fr not_active Abandoned
- 1991-11-15 EP EP92901252A patent/EP0557450B1/fr not_active Expired - Lifetime
- 1991-11-15 DE DE69131137T patent/DE69131137T2/de not_active Expired - Lifetime
- 1991-11-15 JP JP4502298A patent/JPH06502960A/ja active Pending
- 1991-11-15 WO PCT/US1991/008542 patent/WO1992009121A1/fr active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3423518A (en) * | 1966-10-11 | 1969-01-21 | Sigma Ind Inc | Heat shrinkable grommet |
US4076360A (en) * | 1974-06-21 | 1978-02-28 | The Raymond Lee Organization, Inc. | Safety device for electrical connector device |
US4186986A (en) * | 1978-11-16 | 1980-02-05 | Amp Incorporated | Sealed splice |
US4865905A (en) * | 1983-06-23 | 1989-09-12 | Raychem Corporation | Article for protection of a substrate |
US4702710A (en) * | 1986-06-20 | 1987-10-27 | Georgia Tech Research Corporation | Waterproof seal assembly for electrical connector |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2716298A1 (fr) * | 1994-02-15 | 1995-08-18 | Cinch Connecteurs Sa | Perfectionnements aux connecteurs électriques. |
Also Published As
Publication number | Publication date |
---|---|
ATE179028T1 (de) | 1999-04-15 |
KR930702799A (ko) | 1993-09-09 |
EP0557450B1 (fr) | 1999-04-14 |
EP0557450A4 (en) | 1996-03-13 |
JPH06502960A (ja) | 1994-03-31 |
CA2096342A1 (fr) | 1992-05-17 |
DE69131137D1 (de) | 1999-05-20 |
DE69131137T2 (de) | 1999-12-16 |
KR100243918B1 (ko) | 2000-02-01 |
AU9056591A (en) | 1992-06-11 |
EP0557450A1 (fr) | 1993-09-01 |
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