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WO1992005234A1 - Compositions nettoyantes - Google Patents

Compositions nettoyantes Download PDF

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Publication number
WO1992005234A1
WO1992005234A1 PCT/US1991/006752 US9106752W WO9205234A1 WO 1992005234 A1 WO1992005234 A1 WO 1992005234A1 US 9106752 W US9106752 W US 9106752W WO 9205234 A1 WO9205234 A1 WO 9205234A1
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WO
WIPO (PCT)
Prior art keywords
cleansing composition
composition according
weight
surfactant
mixtures
Prior art date
Application number
PCT/US1991/006752
Other languages
English (en)
Inventor
Rosemary Jane Welch
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AU87591/91A priority Critical patent/AU8759191A/en
Publication of WO1992005234A1 publication Critical patent/WO1992005234A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/32—Protein hydrolysates; Fatty acid condensates thereof

Definitions

  • the present invention relates to cleansing compositions.
  • it relates to foam-producing personal cleansing compositions suitable for simultaneously cleansing and conditioning the hair and/or the skin and which may be used, for example, in the form of shampoos, skin cleansers, foam bath preparations, shower products, etc.
  • the cleansing compositions are particularly designed to be suitable for use by or for babies or children.
  • Foaming cosmetic compositions must satisfy a number of criteria including cleansing power, foaming properties and mildness/low irritancy with respect to the skin, hair and the occular mucosae.
  • Skin is made up of several layers of cells which coat and protect the keratin and collagen fibrous proteins that form the skeleton of its structure.
  • the outermost of these layers referred to as the stratum corneum, is known to be composed of 250 A protein bundles surrounded by 80 A thick layers.
  • Hair similarly has a protective outer coating enclosing the hair fibre which is called the cuticle.
  • Anionic surfactants can penetrate the stratum corneum membrane and the cuticle and, by delipidization destroy membrane integrity. This interference with skin and hair protective membranes can lead to a rough skin feel and eye irritation and may eventually permit the surfactant to interact with the keratin and hair proteins creating irritation and loss of barrier and water retention functions.
  • Ideal cosmetic cleansers should cleanse the hair or skin gently, without defatting and/or drying the hair and skin and without irritating the occular mucosae or leaving skin taut after frequent use. Most lathering soaps, shampoos and bars fail in this respect.
  • Another factor which impacts on the mildness/lather benefit equation is that of providing hair and skin conditioning benefits.
  • hair conditioning or grooming agents into the shampoo formula in order to improve the condition of the hair after shampooing, ie, to make the hair more manageable, to provide greater body and lustre, to prevent fly-away, to minimize static electricity in the hair, to improve the tactile impression of the hair, to improve the hair's softness etc.
  • One class of hair conditioning agent which has received particular interest recently is the silicone class. See, for example, US-A-4741855, US-A-3849348, US-A-3990991, US-A-3822312 and US-A-4364837.
  • silicone-containing shampoos and cleansers Another important factor in formulating silicone-containing shampoos and cleansers is that of product stability.
  • This in itself imposes formulation constraints which in turn can impact on the lathering and mildness performance of the shampoo or skin cleanser.
  • these rather stringent requirements for cosmetic cleansers and shampoos limit the choice of surface-active agents, and final formulations represent some degree of compromise. Mildness is often obtained at the expense of effective cleansing, or lathering may be sacrificed for mildness, conditioning or product stability.
  • a need exists for cleansing products which will produce a foam which is abundant, stable and of high quality, which are effective hair and skin cleansers, which will condition the hair or skin, and which are very mild to the skin, hair and occ
  • the subject of the present invention is a foam-producing cleansing product suitable for personal cleansing of the skin or hair and which may be used as shampoos, skin cleansers, foam bath and shower products, etc.
  • a cleansing composition comprising:
  • R. is C_-C 22 alkyl or alkenyl
  • R 2 is hydrogen or CH,Z
  • each Z is independently C0 2 M or CH 2 C0 2
  • M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium; and/or ammonium derivatives of formula IV C 2 H 4 0H
  • n and m are numbers from 1 to 4, and R, and M are independently selected from the groups specified in (a) above;
  • the cleansing composition has a total surfactant concentration of from about 0.2% to about 20% by weight and wherein the combined concentration of the first and second amphoteric surfactants comprises at least 20% by weight of the total surfactant concentration.
  • the invention relates to a foam-producing cleansing composition with superior lathering characteristics (creaminess, abundance, stability) combined with excellent mildness to the hair, skin and occular mucosae together with good stability, cleansing ability and conditioning performance.
  • the invention relates to a cleansing product comprising the defined cleansing composition packaged within a so-called "squeeze foamer" container - a compressible dispenser equipped with a dispensing head and liquid/air mixing means, from which the cleansing composition can be easily dispensed in the form of an aqueous foam by squeezing.
  • the cleansing compositions preferred for use herein comprise a mixture of two amphoteric surfactants, a first amphoteric surfactant being selected from imidazolinium surfactants of formula I
  • R. is C_-C 22 alkyl or alkenyl
  • 2 is hydrogen or R ⁇ >
  • each Z is independently C0 2 M or CH 2 C0 2
  • M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium; and/or ammonium derivatives of formula IV
  • R 2 wherein R-, R 2 and Z are as defined above;
  • amphoteric surfactant being selected from:
  • the cleansing compositions for use herein can also comprise other, preferably mild, surfactant components, notably, anionic surfactants.
  • surfactant components notably, anionic surfactants.
  • the mixture of the first and second amphoteric surfactants comprises at least about 60%, more preferably at least about 75% by weight of the total surfactant.
  • Suitable amphoteric surfactants of the first type are marketed under the trade name Miranol and are understood to comprise a complex mixture of species.
  • Miranols have been described as having the general formula I, although the CTFA Cosmetic Ingredient Dictionary, 3rd Edition indicates the non-cyclic structure IV.
  • CTFA Cosmetic Ingredient Dictionary, 3rd Edition indicates the non-cyclic structure IV.
  • a complex mixture of cyclic and non-cyclic species is likely to exist and both definitions are given here for sake of completeness.
  • Preferred for use herein, however, are the non-cyclic species.
  • C 11 H 23' ⁇ is C0 2 M an ⁇ R 2 s CH 2 C0 2 M ' * and tne compounds in which R. is C,,H 23 , ⁇ is C0 2 M and
  • R 2 is H.
  • materials preferred for use in the present invention include cocoamphocarboxypropionate, cocoamphocarboxy propionic acid, and especially cocoamphocarboxyglycinate (otherwise referred to as cocoamphodiacetate) .
  • Specific commercial products include those sold under the trade names of Miranol C2M Cone. N.P., Miranol C2M Cone.
  • Miranol C2M SF Miranol CM Special (Miranol, Inc.); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric .AM-2C (Rewo Chemical Group); and Schercotic MS-2 (Scher Chemicals) .
  • amphoteric surfactants of this type are manufactured and sold in the form of electroneutral complexes with, for example, hydroxide counterions or with anionic sulfate or sulfonate surfactants, especially those of the sulfated C 8 -C, g alcohol, c o -C 18 etno ⁇ y late alcohol or Cg-C, g acyl glyceride types.
  • compositions which are essentially free of anionic sulfate or sulfonate surfactants or wherein the equivalent ratio of the first amphoteric surfactant to anionic sulfate and/or sulfonate surfactant is less than about 1:1.
  • amphoteric surfactants for use as the second amphoteric surfactant include salts, especially the triethanolammonium salts and salts of N-lauryl-beta-amino propionic acid and
  • the cleansing compositions preferably contain from about 0.5% to about 10% by weight, more preferably from about 0.5% to about 4% by weight of each of the first and second amphoteric surfactants.
  • the weight ratio of first amphoteric surfactant : second amphoteric surfactant is preferably from about 10:1 to about 1:10, more preferably from about 5:1 to about 1:5, especially from about 3:1 to about 1:3, the concentrations and weight ratios of said amphoteric surfactants being based herein on the uncomplexed form of said species.
  • compositions of the invention can comprise or be supplemented by surfactants other than the amphoteric surfactants specified above.
  • the total level of surfactant in the compositions herein should generally lie in the range from about 0.2% to about 20% by weight, preferably from about 1% to about 16%, more preferably from about 1% to about 8% and especially from about 2% to about 6% by weight. It is a feature of the products of the invention that they can provide excellent foam stability and creaminess, even at low levels of cleansing surfactant.
  • a preferred optional surfactant in the compositions herein is an anionic surfactant. This is preferably present in a level of from about 0.1 to 10%, more preferably from about 0.5 to 5% and especially from about 1% to about 3% by weight.
  • Preferred anionic surfactants for inclusion herein are the fatty acid condensation products of proteins, degraded proteins or amino acids or mixtures of such condensation products.
  • the fatty acid condensation products are selected from: (i) condensation products of C 8 -C, 2 , preferably c ⁇ n ⁇ C 18 fatty acids with hydrolysed proteins, (ii) fatty acid sarcosinates derived from C 8 -C 22 preferably C, 0 -C,g fatty acids, and (iii) mixtures thereof.
  • Suitable mild synthetic detergent surfactants useful in the cleansing compositions include methyl acyl taurates; fatty acyl glycinates; N-acyl glutamates; alkyl glucosides; alkyl glycerides and ethoxylated glycerides; acyl isethionates; alkyl sulfosuccinates; alpha-sulfonated fatty acids, their salts and/or their esters; alkyl phosphate esters; ethoxylated alkyl phosphate esters; alkyl ether sulfates; glucose esters and alkylated, e.g., methyl glucose esters; mixtures of alkyl ether sulfates and alkyl amine oxides; betaines; sultaines; and mixtures thereof.
  • alkyl ether sulfates with up to 12 ethoxy groups especially ammonium and sodium lauryl ether sulfates.
  • Alkyl and/or acyl chain lengths for these surfactants are Cg-C 22 , preferably
  • Suitable mild synthetic detergent surfactants of these types include:
  • C_-C 18 monoalkyl phosphate salts preferably at least partly in the form of their polyalkanol, e.g., N,N,N'N'-tetraethanol-(ethylenediamine) (Quadrol) salts; N-(Cg-C,g fatty acyl) glutamates; C 8 -C 18 fatty acyl glycinates and/or their mixtures with additional anionic synthetic detergent surfactant, and/or mixtures thereof.
  • the cleansing compositions of the invention also contain a dispersed, insoluble silicone conditioning agent, the term "insoluble" herein meaning that the silicone is insoluble in the matrix of the cleansing composition under ambient (25°C) conditions.
  • the level of silicone in the compositions of the invention is from about 0.1% to about 5%, preferably from about 0.2% to about 3%, more preferably from about 0.5% to about 1.5% by weight. It is a feature of the compositions of the invention that they can provide fully effective hair conditioning at levels of silicone as much as 50% or more below those levels which have traditionally been utilised in the art. The silicone is especially valuable herein from the viewpoint of reducing eye-sting and providing enhanced mildness to the occular mucosae.
  • Silicones which are suitable for use herein include non-volatile polyalkyl and polyaryl siloxane gums and fluids, volatile cyclic and linear polyalkylsiloxanes, polyalkoxylated silicones, amino and quaternary ammonium modified silicones, rigid cross-linked and reinforced silicones and mixtures thereof.
  • Nonvolatile silicone gums and fluids are particularly useful as the conditioning agent component in the compositions of the present invention.
  • examples of such materials include polyalkyl or polyaryl siloxanes with the following structure:
  • R is alkyl or aryl
  • x is an integer from about 7 to about 8,000.
  • A represents groups which block the ends of the silicone chains.
  • the alkyl or aryl gro ⁇ ps substituted on the siloxane chain (R) or at the ends of the siloxane chains (A) may have any structure as long as the resulting silicones remain fluid at room temperature, are hydrophobic, are neither irritating, toxic nor otherwise harmful when applied to the hair or skin, are compatible with the other components of the composition, are chemically stable under normal use and storage conditions, and are capable of being deposited on and of conditioning hair or skin.
  • Suitable A groups include methyl, methoxy, ethoxy, propoxy, and aryloxy.
  • the two R groups on the silicone atom may represent the same group or different groups. Preferable, the two R groups represent the same group.
  • Suitable R groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl.
  • the preferred silicones are polydimethylsiloxane, polydiethylsiloxane, and polymethylphenylsiloxane. Polydimethylsiloxane is especially preferred.
  • Polyalkylsiloxanes that may be used herein include, for example, polydimethylsiloxanes with viscosities
  • siloxanes are available, for example, from the General Electric Company as the Vicasil (RTM) series and from Dow Corning as the Dow Corning 200 series.
  • the viscosity can be measured by means of a glass capilliary viscometer as set forth in Dow Corning Corporate Test
  • Polyalkylaryl siloxanes that may be used herein include, for example, polymethylphenylsiloxanes having viscosities of 15 to 65 mm 2.s-1 (centistokes) at
  • siloxanes are available, for example, from the General Electric Company as SF 1075 methyl phenyl fluid or from Dow Corning as 556 Cosmetic Grade Fluid.
  • silicones suitable for use herein include the volatile cyclic and linear polyalkylsiloxanes, especially the methylated cyclic silicones having four and five ring siloxane moieties and the linear polydimethylsiloxanes having less then nine siloxane moieties.
  • Polyalkoxylated silicones that can be used herein include, for example, a dimethyl polyoxyalkylene ether copolymer fluid having a nominal viscosity of 1200 to 1500 mm 2.s-1 (centistokes) at 25°C.
  • Preferred compounds of this type are polypropylene oxide modified dimethylpolysiloxanes (e.g. Dow Corning DC-1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide can also be used.
  • Silicones suitable herein also include cationic (e.g. amino and quaternary ammonium modified) silicones.
  • Suitable cationic silicones include:
  • Silicone conditioning agent materials also useful in the compositions of the present invention are silicone polymer materials which provide both style retention and conditioning benefits to the hair. These materials comprise rigid silicone polymers.
  • Such materials include filler reinforced polydimethylsiloxane gums including those having end groups such as hydroxyl; cross linked siloxanes, such as organic substituted silicone elastomers; organic substituted siloxane gums, including those having end groups such as hydroxyl; and resin reinforced siloxanes.
  • the silicone conditioning agent comprises a polydimethylsiloxane gum, having a viscosity greater than about 1,000,000 centipoise and a dimethicone fluid having a viscosity of from about 10 centipoise to about 100,000 centipoise, wherein the ratio of gum to fluid is from about 30:70 to about 70:30, preferably from about 40:60 to about 60:40.
  • compositions herein preferably also contain from about 0.1% to about 5%, preferably from about 0.5% to about 2% by weight of a silicone suspending agent.
  • the suspending agent can be selected from long chain acyl derivatives and long chain alkylamine oxides, said acyl derivative or amine oxide being present in the cleansing composition in cystalline form, xanthan gum, hydrophobically-modified acrylic acid polymers and mixtures thereof.
  • Suitable suspending agents of the long chain acyl and amine oxide varieties are described in US-A-4,741,855 to Grote et al, issued May 3, 1988. Included are esters, especially ethylene glycol esters of fatty acids having from about 16 to about 22 carbon atoms, as well as other fatty acid esters (e.g. polyethyleneglycol esters having up to about 3 ethylene oxide moieties in the glycol chain) which can be formulated in the cleansing composition in crystalline form.
  • esters especially ethylene glycol esters of fatty acids having from about 16 to about 22 carbon atoms, as well as other fatty acid esters (e.g. polyethyleneglycol esters having up to about 3 ethylene oxide moieties in the glycol chain) which can be formulated in the cleansing composition in crystalline form.
  • Other suspending agents found useful are alkanolamides of fatty acids, having from about 16 to 22 carbon atoms, preferably from 16 to 18 carbon atoms.
  • Preferred alkanolamides are stearic monoethanolamide, stearic diethanolamide, stearic monoisopropanolamide and stearic monethanolamide stearate.
  • Other long chain acyl derivatives include long chain esters of long chain fatty acids (e.g., stearyl stearate, cetyl palmitate, etc.); glyceryl esters (e.g.
  • glyceryl distearate and long chain esters of long chain alkanolamides (e.g. stearamide DEA distearate, stearamide MEA stearate).
  • Still other suitable suspending agents are alkyl (C, g _ 22 ) dimethylamine oxides such as stearyl dimethylamide oxide.
  • xanthan gum As described in U.S. Patent 4,788,006, Bolich et al., issued June 5, 1984.
  • the combination of long chain acyl derivatives and xanthan gum as a suspending system for silicone is described in U.S. Patent 4,704,272, Oh et al., issued November 3, 1987, and may also be used in the present compositions.
  • Preferred for use herein from the viewpoint of reducing eye-sting and providing enhanced mildness to the occular mucosae is a hydrophobically-modified cross-linked polymer of acrylic acid having amphipathic properties as marketed by B.F. Goodrich under the trade name Carbopol 1342, Penulem TR1 and Penulem TR2. Combinations of these polymers with xanthan gum and/or a crystalline long chain acyl derivative such as ethylene glycol distearate can also be used, although is less preferred.
  • compositions of the invention preferably also contain a hydrophilic (non-amphipathic) polymeric thickener at a level from about 0.01% to about 5%, preferable from about 0.04% to about 2% and especially from about 0.05% to about 1%.
  • the polymeric thickener is found to be valuable for enhancing the creaminess and quality of the foam without adversely affecting product dispensing characteristics.
  • the polymers may also have a hair or skin conditioning utility.
  • Suitable polymers are high molecular weight materials (mass-average molecular weight determined, for instance, by light scattering, being generally from about 2,000 to about 3,000,000 preferably from about 5,000 to about 1,000,000).
  • the viscosity of the final composition is preferably at least about 150 cps, more preferably from about 500 to 12,000 cps, especially from about 1,000 to about 10,000 cps.
  • Useful polymers are the cationic, nonionic, amphoteric, and anionic polymers useful in the cosmetic field.
  • Representative classes of polymers include cationic and nonionic polysaccharides; cationic and nonionic homopolymers and capolymers derived from acrylic and/or methacrylic acid; cationic and nonionic cellulose resins; cationic copolymers of dimethyldiallylammonium chloride and acrylic acid; cationic homopolymers of dimethyldiallylammonium chloride; cationic polyalkylene and ethoxypolyalkylene imines; quaternized silicones, and mixtures thereof.
  • cationic polymers suitable for use herein include cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.11 to 0.22) available commercially under the trade namesJaguar C-14-S(RTM) and Jaguar C-17(RTM, and also Jaguar C-16 (RTM) , wich contains hydroxypropyl substituents (d.s. of from 0.8 - 1.1) in addition to the above-specified cationic groups, and quaternized cellulose ethers available commercially under the trade names Ucare Polymer JR and Celquat.
  • cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum (d.s. of from 0.11 to 0.22) available commercially under the trade namesJaguar C-14-S(RTM) and Jaguar C-17(RTM, and also Jaguar C-16 (RTM)
  • wich contains hydroxypropyl substituents (d.s. of from 0.8 -
  • Suitable cationix polymers are homopolymers of dimethyldiallylammonium chloride available commercially under the trade name Merquat 100, copolymers of dimethyl aminoethylmethacrylate and acrylamide, copolymers of dimethyldiallylammonium chloride and acrylamide, available commercially under the trade names Merquat 550 and Merquat S, quaternized vinyl pyrrollidone acrylate or methacrylate copolymers of amino alcohol available commercially under the trade name Gafquat, and polyalkyleneimines such as polyethylenimime and ethoxylated polyethylenimine.
  • Preferred polymeric thickeners for the use herein include hydroxyethyl cellulose (e.g.
  • Natrasol 250MXR, Natrasol 250HHR Natrasol 250MXR, Natrasol 250HHR
  • methyl cellulose hydroxypropyl methyl cellulose
  • polymers of saccharides or oligosaccharides with compatible synthetic monomers quaternized polycarboxylates; and starches and starch derivatives.
  • the cleansing compositions can optionally include a hair or skin moisturizer.
  • the preferred level of moisturizer is from about 3% to about 40% by weight.
  • the moisturizer is nonocclusive and is selected from:
  • nonocclusive moisturizers are glycerine, polyethylene glycol, propylene glycol, sorbitol, polyethylene glycol and propylene glycol ethers of methyl glucose (e.g. methyl glucan-20), polyethylene glycol and propylene glycol ethers of lanolin alcohol (e.g. Solulan-75), sodium pyrrolidone carboxylic acid, lactic acid, urea, L-proline, guanidine, pyrrolidone and mixtures thereof.
  • glycerine is highly preferred.
  • water-soluble nonocclusive moisturizers examples include water-soluble hexadecyl, myristyl, isodecyl or isopropyl esters of adipic, lactic, oleic, stearic, isostearic, myristic or linoleic acids, as well as many of their corresponding alcohol esters (sodium isostearoly-2-lactylate, sodium capryl lactylate), hydrolyzed protein and other collagen-derived proteins, aloe vera gel and acetamide MEA.
  • water-soluble hexadecyl examples include water-soluble hexadecyl, myristyl, isodecyl or isopropyl esters of adipic, lactic, oleic, stearic, isostearic, myristic or linoleic acids, as well as many of their corresponding alcohol esters (sodium isostearoly-2-lactylate, sodium
  • a number of additional optional materials can be added to the cleansing compositions.
  • Such materials include proteins and polypeptides and derivatives thereof; water-soluble or solubilizable preservatives such as Germall 115, methyl, ethyl, propyl and butyl esters of hydroxybenzoic acid, EDTA, Euxyl (RTM) K400, Bronopol (2-bromo-2-nitropropane-l,3-diol) ; other moisturizing agents such as hylaronic acid, chitin, and starch-grafted sodium polyacrylates such as Sanwet (RTM) IM-1000, IM-1500 and IM-2500 available from Celanese Superabsorbent Materials, Portsmith, VA, USA and described in USA-A-4,076,663; solvents such as hexylene glycol and propylene glycol; low temperature phase modifiers such as ammonium ion sources (e.g.
  • Nonionic emollients can be included as additional skin and hair conditioning agents at levels up to about 10%, preferably from about 1% to about 6%.
  • Such materials include, for example, mineral oils, fatty sorbitan esters (see US-A-3988255, Seiden, issued October 26th 1976), lanolin and lanolin derivatives, esters such as isopropyl myristate and triglycerides such as coconut oil.
  • Water is also present at a level of from about 60% to about 99% preferably at least about 75% by weight of the compositions herein.
  • the pH of the compositions is preferably from about 4 to about 9, more preferably from about 4.5 to about 8.5, pH being controlled, for example, using a citrate buffer system.
  • the cleansing compositions herein can be packaged in conventional bottle or sachet form or alternatively in a compressible, non-aerosol dispenser of the so-called "squeeze-foamer” type which comprises a reservoir, a dispensing head, liquid/air mixing means and preferably, homogenizing means and non-return valve means.
  • a compressible, non-aerosol dispenser of the so-called "squeeze-foamer” type which comprises a reservoir, a dispensing head, liquid/air mixing means and preferably, homogenizing means and non-return valve means.
  • the compositions are preferably formulated with a lower viscosity in the range from about 1 to about 1 cps (Brookfield LVT, UL adaptor, 70°F, 60 rpm, spindle speed corrected).
  • Squeeze foamer packages are well known as exemplified by the disclosures in the following patents: US-A-3,709,437 (Wright, issued January 9th, 1973); US-A-3,937,364 (Wright, issued February 10th, 1976); US-A-4,022,351 (Wright, issued May 10th, 1977); US-A-4,147,306 (Bennett, issued April 3rd, 1979); US-A-4,184,615 (Wright, issued January 22nd 1980); US-A-4,598,862 (Rice, issued July 8th, 1986); US-A-4,615,467 (Grogan et al., issued October 7th, 1986); and FR-A-2,604,622 (Verlhulst, published April 8th, 1988).
  • the above packages do not use any propellant and are therefore safe for the consumer and the environment.
  • the cleansing composition is placed in the container reservoir which may for instance, take the form of a plastic squeeze bottle. Squeezing the container reservoir with the hand forces the composition through liquid/air mixing means where the composition is mixed with air and then preferably through a homogenizing means that makes the foam more homogeneous and controls the consistency of the foam. The foam is then discharged as a uniform, non-pressurized aerated foam through the dispensing head of the dispenser.
  • the minimum force to activate the squeeze foamer is about 1 psig, preferably from about 2 psig to about 15 psig.
  • the minimum force is related to the size of the channels in the dispenser, the viscosity of the composition, etc.
  • the density of the foam should be between about 0.002 and about 0.25 g/cc, preferably between about 0.01 and about 0.07 g/cc.
  • Foam density is inversely related to foam creaminess so lower foam densities are preferred.
  • Palm kernal oil fatty acid sarcosinate Anionic 2 Palm kernal oil fatty acid sarcosinate.
  • compositions I, II and IV are prepared by forming a cold (80°F) premix of the silicone with a portion of Amphoteric C or D and adding the premix and the perfume to a cold (80°F) main mix of all remaining components.
  • Compositions III and V are made similarly but the Carbopol and xanthan gum are dissolved in the main mix at 75° - 80° C prior to cooling to ambient temperature, the EGDS is predissolved in an aqueous solution of the anionic surfactant at 75° - 80° C and allowed to cool to ambient temperature with rapid stirring to form a crystalline EGDS dispersion, and the EGDS and silicone premix are then added to the main mix.
  • the products provide excellent in-use and efficacy benefits including cleansing, conditioning and lathering together with improved mildness benefits to the skin, hair and occular mucosae.

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Abstract

Composition nettoyante pour les soins du corps comprenant: a) environ 0,1 à environ 16 % d'un agent tensioactif amphotère à base d'imidazolinium ou d'ammomium, b) environ 0,1 à 16 % d'un agent tensioactif amphotère à base d'aminoalcanoate ou d'iminodialcanoate, c) éventuellement jusqu'à environ 10 % d'un agent tensioactif anionique, d) environ 0,1 à environ 5 % d'un agent de conditionnement dispersé composé de silicone insoluble, et e) de l'eau. Cette composition nettoyante présente une concentration totale d'agents tensioactifs comprise entre 0,2 et 20 % dont au moins 20 % se compose d'un mélange de (a) et de (b). La composition possède d'excellents avantages d'utilisation et d'efficacité, y compris en ce qui concerne le nettoyage, le conditionnement et la capacité moussante, et présente une plus grande douceur vis-à-vis de la peau, des cheveux et des muqueuses oculaires. Elle est particulièrement adaptée à être utilisée comme shampoing etc. pour des bébés ou des enfants.
PCT/US1991/006752 1990-09-21 1991-09-17 Compositions nettoyantes WO1992005234A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU87591/91A AU8759191A (en) 1990-09-21 1991-09-17 Cleansing compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB909020594A GB9020594D0 (en) 1990-09-21 1990-09-21 Cleansing compositions
GB0920594.9 1990-09-21

Publications (1)

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WO1992005234A1 true WO1992005234A1 (fr) 1992-04-02

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Country Status (8)

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CN (1) CN1061151A (fr)
GB (1) GB9020594D0 (fr)
IE (1) IE913313A1 (fr)
MA (1) MA22287A1 (fr)
MX (1) MX9101205A (fr)
NZ (1) NZ239879A (fr)
PT (1) PT98979A (fr)
WO (1) WO1992005234A1 (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993018737A1 (fr) * 1992-03-17 1993-09-30 The Procter & Gamble Company Compositions de shampooing doux
EP0636166A1 (fr) * 1992-03-25 1995-02-01 The Procter & Gamble Company Compositions de nettoyage
EP0689581A1 (fr) * 1993-01-23 1996-01-03 The Procter & Gamble Company Compositions nettoyantes
US5536450A (en) * 1993-11-12 1996-07-16 The Procter & Gamble Comany Liquid hard surface detergent compositions containing amphoteric detergent surfactant and perfume
WO1997005857A1 (fr) * 1995-08-07 1997-02-20 Unilever Plc Composition liquide de nettoyage comprenant un structurant induisant une phase lamellaire soluble
WO1997038672A1 (fr) * 1996-04-17 1997-10-23 Unilever Plc Composition de nettoyage
US5783200A (en) * 1997-01-21 1998-07-21 The Procter & Gamble Company Personal cleansing compositions
US5785979A (en) * 1997-01-21 1998-07-28 The Procter & Gamble Company Personal cleansing compositions
EP0613942B1 (fr) * 1993-03-05 1998-12-16 Colgate-Palmolive Company Composition de nettoyage corporel
EP0923950A2 (fr) * 1997-12-18 1999-06-23 Tomey Corporation Agent liquide pour des lentilles de contact
DE4129993C2 (de) * 1991-09-10 1999-10-14 Kreussler Chem Fab Waschmittel
WO2000006098A1 (fr) * 1998-07-30 2000-02-10 The Procter & Gamble Company Composition pour le conditionnement des cheveux comprenant un copolymere acide carboxylique/carboxylate, un compose de silicone et un compose ayant un point de fusion eleve
US6077816A (en) * 1995-08-07 2000-06-20 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Liquid cleansing composition comprising soluble, lamellar phase inducing structurant
US6417145B1 (en) 1997-04-07 2002-07-09 L'oreal Detergent cosmetic compositions and use thereof
DE10102009A1 (de) * 2001-01-18 2002-08-01 Cognis Deutschland Gmbh Tensidgemisch
WO2004058929A1 (fr) * 2002-12-23 2004-07-15 Alcon, Inc. Utilisation d'agents tensioactifs multifonctionnels pour le nettoyage de lentilles de contact
US6767875B1 (en) * 1999-09-03 2004-07-27 The Procter & Gamble Company Hair conditioning composition comprising carboxylic acid/carboxylate copolymer and moisturizing agent
EP1601966A2 (fr) * 2003-03-12 2005-12-07 Eppendorf 5 Prime, Inc. Procedes et compositions pour la purification d'acide nucleique provenant d'une cellule hote
EP1052971B2 (fr) † 1998-02-03 2007-02-28 Unilever Plc Produit moussant pour le nettoyage de la peau
EP1792972A1 (fr) * 2002-12-23 2007-06-06 Alcon, Inc. Utilisation d'agents actifs de surface multifonctionnels pour nettoyer les lentilles de contact
CN102626375A (zh) * 2012-03-28 2012-08-08 福建省梦娇兰日用化学品有限公司 一种含有氨基酸型表面活性剂的清洁组合物

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KR101222902B1 (ko) * 2003-08-28 2013-01-16 존슨 앤드 존슨 컨수머 캄파니즈, 인코포레이티드 개인 보호용 조성물의 자극성을 감소시키는 방법
CN101199462B (zh) * 2007-12-12 2011-06-29 天津盛世恒安科技发展有限公司 一种适于7-12个月婴儿皮肤特点的洗浴品及其制备工艺
CN101199463B (zh) * 2007-12-12 2011-06-29 天津盛世恒安科技发展有限公司 一种适于0-3个月婴儿皮肤特点的洗浴品及其制备工艺

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US4022351A (en) * 1975-04-03 1977-05-10 Hershel Earl Wright Foam dispenser
US4147306A (en) * 1977-09-28 1979-04-03 Bennett Robert S Foam producing apparatus
US4184615A (en) * 1975-04-03 1980-01-22 Wright Hershel E Foam dispensing device
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EP0153435A1 (fr) * 1977-06-29 1985-09-04 Union Carbide Corporation Composition pour le traitement des cheveux
US4598862A (en) * 1983-05-31 1986-07-08 The Dow Chemical Company Foam generating device and process
US4615467A (en) * 1985-07-24 1986-10-07 Calmar, Inc. Liquid foam dispenser
US4704272A (en) * 1985-07-10 1987-11-03 The Procter & Gamble Company Shampoo compositions
US4741855A (en) * 1984-11-09 1988-05-03 The Procter & Gamble Company Shampoo compositions
US4788006A (en) * 1985-01-25 1988-11-29 The Procter & Gamble Company Shampoo compositions containing nonvolatile silicone and xanthan gum
US4837005A (en) * 1986-09-30 1989-06-06 Union Carbide Corporation Partially hydrolyzed, poly(N-acyl)alkylenimines in personal care
US4931216A (en) * 1987-10-29 1990-06-05 Kao Corporation Detergent composition comprising an anionic or amphoteric surface active agent and a branched quaternary ammonium salt

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US3709437A (en) * 1968-09-23 1973-01-09 Hershel Earl Wright Method and device for producing foam
US3849348A (en) * 1969-04-14 1974-11-19 Colgate Palmolive Co Detergent compositions
US3822312A (en) * 1971-11-02 1974-07-02 Kao Corp Creamy rinsing agent composition
GB1470234A (en) * 1973-05-17 1977-04-14 Union Carbide Corp Shampoo containing conditioning agent
US3990991A (en) * 1974-02-01 1976-11-09 Revlon, Inc. Shampoo conditioner formulations
US4184615A (en) * 1975-04-03 1980-01-22 Wright Hershel E Foam dispensing device
US4022351A (en) * 1975-04-03 1977-05-10 Hershel Earl Wright Foam dispenser
US3937364A (en) * 1975-04-03 1976-02-10 Hershel Earl Wright Foam dispensing device
EP0153435A1 (fr) * 1977-06-29 1985-09-04 Union Carbide Corporation Composition pour le traitement des cheveux
US4147306A (en) * 1977-09-28 1979-04-03 Bennett Robert S Foam producing apparatus
US4364837A (en) * 1981-09-08 1982-12-21 Lever Brothers Company Shampoo compositions comprising saccharides
US4598862A (en) * 1983-05-31 1986-07-08 The Dow Chemical Company Foam generating device and process
US4741855A (en) * 1984-11-09 1988-05-03 The Procter & Gamble Company Shampoo compositions
US4788006A (en) * 1985-01-25 1988-11-29 The Procter & Gamble Company Shampoo compositions containing nonvolatile silicone and xanthan gum
US4704272A (en) * 1985-07-10 1987-11-03 The Procter & Gamble Company Shampoo compositions
US4615467A (en) * 1985-07-24 1986-10-07 Calmar, Inc. Liquid foam dispenser
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US4931216A (en) * 1987-10-29 1990-06-05 Kao Corporation Detergent composition comprising an anionic or amphoteric surface active agent and a branched quaternary ammonium salt

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4129993C2 (de) * 1991-09-10 1999-10-14 Kreussler Chem Fab Waschmittel
TR27510A (tr) * 1992-03-17 1995-06-07 Procter & Gamble Yumusak sampuan ve yumusak sampuan ön-karisim bilesimleri ve yumusak sampuan yapimi icin yöntem ve sampuan bilesimleri.
WO1993018737A1 (fr) * 1992-03-17 1993-09-30 The Procter & Gamble Company Compositions de shampooing doux
EP0636166A1 (fr) * 1992-03-25 1995-02-01 The Procter & Gamble Company Compositions de nettoyage
EP0636166A4 (fr) * 1992-03-25 1999-02-03 Procter & Gamble Compositions de nettoyage.
EP0689581A1 (fr) * 1993-01-23 1996-01-03 The Procter & Gamble Company Compositions nettoyantes
EP0689581A4 (fr) * 1993-01-23 1996-08-21 Procter & Gamble Compositions nettoyantes
EP0613942B1 (fr) * 1993-03-05 1998-12-16 Colgate-Palmolive Company Composition de nettoyage corporel
US5536450A (en) * 1993-11-12 1996-07-16 The Procter & Gamble Comany Liquid hard surface detergent compositions containing amphoteric detergent surfactant and perfume
WO1997005857A1 (fr) * 1995-08-07 1997-02-20 Unilever Plc Composition liquide de nettoyage comprenant un structurant induisant une phase lamellaire soluble
RU2180215C2 (ru) * 1995-08-07 2002-03-10 Унилевер Н.В. Жидкая очищающая композиция, содержащая растворимый структурообразователь, вызывающий образование слоистой фазы
US6077816A (en) * 1995-08-07 2000-06-20 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Liquid cleansing composition comprising soluble, lamellar phase inducing structurant
US5968890A (en) * 1996-04-17 1999-10-19 Lever Brothers Company Cleansing composition containing polyethylene glycol
WO1997038672A1 (fr) * 1996-04-17 1997-10-23 Unilever Plc Composition de nettoyage
US5785979A (en) * 1997-01-21 1998-07-28 The Procter & Gamble Company Personal cleansing compositions
US5783200A (en) * 1997-01-21 1998-07-21 The Procter & Gamble Company Personal cleansing compositions
US6096697A (en) * 1997-01-21 2000-08-01 The Procter & Gamble Company Personal cleansing compositions providing improved hair and skin conditioning
US6417145B1 (en) 1997-04-07 2002-07-09 L'oreal Detergent cosmetic compositions and use thereof
EP0923950A3 (fr) * 1997-12-18 2000-12-27 Tomey Corporation Agent liquide pour des lentilles de contact
EP0923950A2 (fr) * 1997-12-18 1999-06-23 Tomey Corporation Agent liquide pour des lentilles de contact
EP1052971B2 (fr) † 1998-02-03 2007-02-28 Unilever Plc Produit moussant pour le nettoyage de la peau
WO2000006098A1 (fr) * 1998-07-30 2000-02-10 The Procter & Gamble Company Composition pour le conditionnement des cheveux comprenant un copolymere acide carboxylique/carboxylate, un compose de silicone et un compose ayant un point de fusion eleve
US6767875B1 (en) * 1999-09-03 2004-07-27 The Procter & Gamble Company Hair conditioning composition comprising carboxylic acid/carboxylate copolymer and moisturizing agent
DE10102009A1 (de) * 2001-01-18 2002-08-01 Cognis Deutschland Gmbh Tensidgemisch
US6995123B2 (en) 2002-12-23 2006-02-07 Alcon, Inc. Use of multifunctional surface active agents to clean contact lenses
WO2004058929A1 (fr) * 2002-12-23 2004-07-15 Alcon, Inc. Utilisation d'agents tensioactifs multifonctionnels pour le nettoyage de lentilles de contact
EP1792972A1 (fr) * 2002-12-23 2007-06-06 Alcon, Inc. Utilisation d'agents actifs de surface multifonctionnels pour nettoyer les lentilles de contact
EP1601966A2 (fr) * 2003-03-12 2005-12-07 Eppendorf 5 Prime, Inc. Procedes et compositions pour la purification d'acide nucleique provenant d'une cellule hote
EP1601966A4 (fr) * 2003-03-12 2007-05-02 Eppendorf 5 Prime Inc Procedes et compositions pour la purification d'acide nucleique provenant d'une cellule hote
CN102626375A (zh) * 2012-03-28 2012-08-08 福建省梦娇兰日用化学品有限公司 一种含有氨基酸型表面活性剂的清洁组合物

Also Published As

Publication number Publication date
GB9020594D0 (en) 1990-10-31
MX9101205A (es) 1992-05-04
MA22287A1 (fr) 1992-04-01
IE913313A1 (en) 1992-02-25
NZ239879A (en) 1994-06-27
CN1061151A (zh) 1992-05-20
PT98979A (pt) 1992-07-31

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