WO1992004169A1

WO1992004169A1 - Glueing method in production of fibre bodies according to the dry method

Info

Publication number: WO1992004169A1
Application number: PCT/SE1991/000570
Authority: WO
Inventors: Sven Ljungbo
Original assignee: Sven Ljungbo
Priority date: 1990-08-31
Filing date: 1991-08-30
Publication date: 1992-03-19
Also published as: SE9002781D0; SE467244B; SE9002781L; AU8534991A

Abstract

The invention relates to the glueing method at the manufacturing of fibre bodies, disks, profiles, panels, insulating carpets, packing material etc - according to the dry method. It consists in the fact that the glue is composed of water glass powder, which is mixed with the fibres which have been somewhat moistured before or during the blending and then, together with the fibres are blown into the moulder to be die-pressed to intended fibre body. During the process the glue powder is dissolved in the water present, transcending into plastic or liquid form so as to aggluminate the fibres, whereupon it dries and hardens into a solid bond during the die-pressing. To make the method work satisfactorily the silicatepowder ought to contain some water, bound as gel-liquid or water of crystallization in the alcali silicate. Thus, spray-dried water glass is appropriate as glue powder. To improve the water resistance of the fibre bodies a hardener transcending the alcali silicate to water insoluble silicates can be added. Suitable hardeners are magnesium oxide, zinc oxide or titanium dioxide.

Description

GLUEING METHOD IN PRODUCTION OF FIBRE BODIES ACCORDING TO

THE DRY METHOD

The production of fibre bodies - disks, profiles, panels etc. - by the dry method is now increasing. The method is constituted of the following processes: fibres of different types - especially wood fibres - are dispersed in an airstream. This one goes to a forming station or a moulder, where the air is exhausted by suction so that the fibres are packed together in a cake or a slab. This one is then pressed in a hot moulding press at the same time being dried and possibly cured to a body of required form and density.

To obtain sufficient strength in the final product suitable glue materials, dispersed or dissolved in water, are added. According to earlier methods the glue addition is made by injection of the glue into the steam-fiber-stream from the defibrator, producing the wood fibres. Then the fibres are dried strictly observing that the added glue must not be cured if it is a curable one. Then the fibres are dispersed in an air-stream which is blown into a diffuser, giving the air-fibre stream the right width and height, before it streams into the moulder.

According to newer methods the glue injection is made directly into the diffuser with or without previous drying of the fibres from the defibrator.

The sizes, most frequently used, are watersolutions of urea - melamine - or phenolic resins with hardeners. These sizes, however emit health-endangering fumes - formaldehyde, phenol - causing problems for the products.

Due to the newer methods tests have also been made with water glass i. e. water solutions of alkali silicates. But these solutions bring about such difficult disturbances in the process - aggregations to fibre bundles or balls with poor binding to other fibres or poor through-glueing - that no acceptable results have been achieved that way. Also other types of glue with high viscosity give similar disturbances.

According to this invention these problems are solved through adding the glue as a powder, which transcends to plastic or liquid form during the continued process and in the end hardens to a strong adhesive.

The glue powder can be water soluble and then forms a glue solution with water, which either goes with the fibres from the beginning of the process or is added though injection during the process. At the final drying the size powder transcends to a firm bond, joining the fibres. If a specially waterresistant fibre product is required also a hardener for the glue substance can be added. This hardener is added either in powder form separately or mixed with the size powder or as a solution in the water, added during the process. Alkali silicates have proved suitable as size powder. Compared to the abovementioned thermosets or curable glues they have the advantage of not emitting any harmful fumes and also of incresing the fire resistance of the fibrebodies. The constitution of the alkali silicates or the ratio, L e. the mole ratio between silicon dioxide and alkali oxide can for sodium or potassium silicates suitably lie between 1,2 and 4,7 but also other ratios give usuable alkali silicate powders.

But it is less suitable to use powder of calcined alkali silicate so-called rawglass. This glass requires temperatures far above 100 oC - for a sodium silicate with ratio 3,3 about 150 - 170 oC - to be solved with acceptable speed in the water, that in some phase of the production schedule before the die-pressing has been added to the fibres. The temperature inside the produced fiberbody, for instance a disk, normally does not overreach 130 - 150 oC during the die-pressing. Therefore the silicate powder ought to contain water in the form of crystallization or gel- bound water. This bound water makes the silicate powder quickly dissoluble in the water, added before the pressing already at a temperature lower than the highest presstemperatures inside the fibre body.

A silicate powder, suitable for that purpose, is spray-dried water glass. The latter is produced through spraying waterglass so it forms an aerosol, quickly being dried to powder in the hot air. Such a powder of sedium waterglass with ratio 3,3 contains such a high percentage of bound water, that it is quickly dissolved by furhter added water already at a temperature of about 100 oC.

A condition precedent for the powder-glueing method is that the glue powder is evenly distributed over the fibres at the admixture and is then not separated from those during the airtransport to the moulder. This condition is met by adding a ' suitable amount of water - 10 to 100 % of the dry weight of the fibres - moistening the fibres to make the powder adhere. This admixture can be made by simple, mechanical stirring.

If a product with a high waterresistance is wanted, a hardener, transcending the alkali silicate to waterinsoluble silicates, can be added.

Different chemical compounds of 2-rated, 3-rated or 4-rated metals can be used as such hardeners. Magnesium oxide, zink oxide and titanium dioxide have proved especially suitable as hardeners.

The following examples present some application forms of the invention without restricting the same: Example 1

Firchips are defibrated in a disk defibrator. The warm fibres are separated from the steam in a cyclone, from which they, by transport screw and conveyor belt, are taken to a cutter, which disperses them in an airstream, leading into a diffusor. In this difjiiser spraydried sodium silicate powder with ratio 3,3 is blown into the fibre-air-stream and is mixed with the fibers, ratio of components being 10 - 25 parts silicate powder to 100 parts dry fibre. The moisture content of the fibre is 30 % at the injection into the diffusor.

The fibre - powder - air stream goes from the diffusor into the moulder, forming a cake, which then is transmitted to a hot moulding press, where it is given its final form and is glued/dried to a firm disk

Example 2

Wood fibres from a defibrator are blown down into a mixer, where they are mixed with sodium silicate powder of the same type as in example 1 and with magnesium oxide, ratio of components being 8 parts silicate powder and 16 parts magnesium oxide powder to 100 parts dry fibre. The moisture content of the fibre is 35 % at the injection into the diffusor.

The mixiuie is transmitted by conveyor to an ejector, which disperses it in air and injects it into a diffusor of a moulding machine, in which it is the formed, hot moulded hardened and dried to required fiberbody.

The cake can also be dried and hardened in heat without being compressed Thus it gets appropriate density in order to be used as insulating material.

As an alternative to the magnesium oxide - silicate powder mixture a compounding of 10 parts silicate powder and 9 parts zink oxide to 100 parts dry fibre with the same moisture content as the above mentioned can be used

As indicated in the introduction of the application also other fibres than wood fibres just produced can be used to manufacture products according to the invention. Examples of other suitable fibres are paper - and paperreturn fibres, cotton- , flax- and hempfibres, syntetic polymer fibres, mineral fibres and others.

To the mixture of fibres and glue also powdered fillers as kaolin, chalk, dolomite, quartz and others can be added to attain special quantities as better fire endurance, lower costs, greater stiffness etc.

Claims

1. Process for producing fibre bodies - disks, profiles, panels, insulating carpets, packing material - according to the dry method characterised in that the glue required is added to the fibres in the form of a powder of waterglass, which during the continued process is dissolved in the water present transcending into plastic or liquid form, agglutinating the fibres, whereupon the glue dries and hards to a solid bond

2. Process according to claim 1 - characterised in that the water glasspowder contains water, bound to the alcalisilicate in the form of gel-liquid and or water of crystallization.

3. Process according to claim 1 and 2, characterised in that also a hardener is added, which converts the alcalisilicate into waterinsoluble silicates during the die-pressing, thus making the fibrebody more water -resistent.

4. Process according to claim 1, 2 and 3 characterised in that one of the metal oxides, magnesium oxide, zink oxide or titanium dioxide is used as hardener.