WO1992001519A1 - Procede, composition de solvant et kit pour retouches de produits metalliques peints egratignes - Google Patents
Procede, composition de solvant et kit pour retouches de produits metalliques peints egratignes Download PDFInfo
- Publication number
- WO1992001519A1 WO1992001519A1 PCT/US1991/005115 US9105115W WO9201519A1 WO 1992001519 A1 WO1992001519 A1 WO 1992001519A1 US 9105115 W US9105115 W US 9105115W WO 9201519 A1 WO9201519 A1 WO 9201519A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solvent
- touch
- paint
- painted
- groups
- Prior art date
Links
- 239000002904 solvent Substances 0.000 title claims abstract description 62
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 239000002184 metal Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000003973 paint Substances 0.000 claims abstract description 58
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 150000002430 hydrocarbons Chemical group 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 5
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 4
- 125000005843 halogen group Chemical group 0.000 claims abstract 4
- 229910052736 halogen Chemical group 0.000 claims abstract 2
- 239000003085 diluting agent Substances 0.000 claims description 9
- 238000009835 boiling Methods 0.000 claims description 5
- 150000001555 benzenes Chemical class 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 3
- 125000003158 alcohol group Chemical group 0.000 claims 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000006748 scratching Methods 0.000 abstract description 2
- 230000002393 scratching effect Effects 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- -1 e.g. Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 2
- 235000015096 spirit Nutrition 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical class CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/005—Repairing damaged coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B05D7/16—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
- B05D2401/10—Organic solvent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
Definitions
- This invention relates to a method and composition for repairing damaged painted metal surfaces. More particularly, the invention relates to a method and composition for touching up painted metal, such as for example automobile bodies formed from sheet metal, wherein the painted, enameled or lacquered finish has been inadvertently removed, as by a scratch or a chip.
- a problem often met with in applying the paint is the difficulty of applying the paint to the scratched or chipped portion without also overpainting the surrounding unmarred finish with excess paint.
- the overpainted portion no longer matches the remainder of the surface and thus continues to lack an unblemished appearance which is desirable for a complete repair of the original finish.
- individuals may have attempted to wipe away the excess new paint with a dry cloth, the problem has always been to remove the excess paint without, on the one hand, marring the original finish in those areas immediately adjacent the scratch or chip and, on the other hand, removing all of the paint applied to the chipped or scratched portion.
- the overpainted portion no longer matches the remainder of the surface and thus continues to lack an unblemished appearance which is desirable for a complete repair of the original finish.
- individuals may have attempted to wipe away the excess new paint with a dry cloth, the problem has always been
- an improved method for touching-up a marred painted surface, and an improved touch-up solvent composition are provided.
- the touch-up paint is applied to scratched or chipped painted metal
- the surface is rubbed with a soft flexible sheet material, which has been wetted with a touch-up solvent composition, to remove the excess paint inadvertently spread over the old finish surrounding the scratch or chip.
- the touch-up solvent composition can comprise any suitable paint solvent, including, e.g., mineral spirits, or other paraffinic liquid solvent.
- a novel touch-up solvent in accordance the composition of this invention, which comprises from about 1% to about 35% by wt. of an active solvent in combination with a less effective suitable paint
- the active solvent is wholly miscible with the diluent paraffinic solvent in the proportions set forth.
- the solvent composition at least about 2% by wt. and most preferably at least about 5% by wt. of the active solvent.
- the active solvent is a liquid which in substantially pure form is too strong of a solvent to be readily used without marring the original surface finish appearance.
- the suitable diluent paint solvents include, preferably, paraffinic solvents having a boiling point above about 200 % centigrade, such as heptane, the ISOPARS, including ISOPAR C, ISOPAR E, ISOPAR G, ISOPAR H and ISOPAR K, as well as various mineral spirits having a boiling point in the range of between about 200 and about 400 centigrade.
- the above so-called diluent paint solvents can be used as a touch-up solvent composition alone in the method of this invention, or as a diluent in admixture with the afore-described active solvents.
- the solvent composition is preferably provided in a kit form;
- a preferred kit comprises a container of the touch-up solvent composition suitable as a dispenser, and a soft flexible sheet, buffing aid, such as a piece of woven or non-woven fabric, which can absorb the solvent composition from the container and buff the painted surface.
- a buffing aid comprising a soft surface on an otherwise rigid substrate can also be used.
- the active solvent comprises lower alkyl- substituted benzene, such as toluene, xylene, ethyl benzene, methylethyl benzene and propyl benzene; oxygenated aliphatic and cycloaliphatic hydrocarbon compounds, including carbonyl- containing aliphatic and cycloaliphatic compounds, such as methylethyl ketone, acetone, methylisobutylketone, diacetone alcohol, and other alkyl ketones and esters, preferably having up to about eight (8) carbon atoms; lower aliphatic esters, such as ethyl acetate, butyl acetate, propylacetate, ethyl proprionate, and preferably having up to about eight (8) carbon atoms; and the hydroxylated ethers, such as the various CELLOSOLVE compounds, i.e., mono-and di-alkly ethers of
- ethylene glycol having up to about 14 carbon atoms the aromatic-substituted such ethers, such as phenyl cellosolve, and the esters of such compounds, such as methylcellosolve acetate, n-hexyl cellosolve acetate, dibutyl cellosolve propionate and methylcellosolve acetate; and chlorinated benzenes and chlorinated aliphatic and cycloaliphatic hydrocarbons, such as 1,1,1-trichloroethane, and o-dichloro- benzene and dichlorotoluene.
- aromatic-substituted such ethers such as phenyl cellosolve
- esters of such compounds such as methylcellosolve acetate, n-hexyl cellosolve acetate, dibutyl cellosolve propionate and methylcellosolve acetate
- the least volatile materials be used; these are customarily referred to in the trade as "odorless" solvents. It is of course also necessary that the solvents be liquid at room temperature.
- the touch-up paint be permitted to at least partially set, i.e., bond to the metal substrate, before rubbing with the touch-up solvent. This further improves the final appearance of the touched-up surface, and avoids interfering with the bonding of the touch-up paint to the metal, without reducing the effectiveness of the touch-up solvent in removing the excess paint applied over the original surface.
- the touch-up paint should be permitted to rest for between about 1 and about 15 minutes, and preferably at least about three (3) minutes, before rubbing with the wetted buffing material, e.g., wetted soft cloth.
- Embodiments of this invention which are presently preferred are set forth by way of example only in the following Working Examples.
- those materials which are commonly available to the ordinary consumer in the United States market are referred to by their common or generic name, where known, as well as by the trade marks under which they are sold at retail.
- Example 1 The right fender panel of a 1988 Chevrolet Station Wagon, formed of sheet steel, has a scratch of removed paint
- SUBSTITUTE SHEET (approximately l/8th of an inch in width and 2 inches long) , extending at least partially down to the bare metal, so that the top layer of paint has been removed.
- Touch-up paint matching the color of the automobile is applied, utilizing paint from a bottle of touch-up paint recommended by the automobile company; the bottle has a brush extending from the interior of the cap. The paint is allowed to dry for five (5) minutes.
- a touch-up solvent composition formed by dissolving ten (10) parts by weight of toluene into ninety (90) parts by weight of painters' naphtha, sold as ISOPAR C, was used to thoroughly wet a soft cloth. The cloth is then used to gently rub over the touched-up, chipped area and the surrounding portions of the original paint finish, to remove all excess paint outside of the chip area. This was accomplished without removing the paint from the exposed metal surface.
- the paint in the chipped area should then be left to dry for at least two (2) hours before buffing and waxing or otherwise polishing the surface.
- the repaired chipped area was almost indistinguishable from the surrounding original finish, and there was substantially no extra paint over the original finish in the area surrounding the touched up chipped portion.
- Example 1 The procedure in accordance with Example 1, above, was repeated but utilizing as the touch-up liquid composition painters ' naphtha, as purchased. It was found to be necessary to rub with greater force, and that greater care needed to be taken to avoid removing paint from the scratched area and to avoid marring the original surrounding finish.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
Procédé de réparation de surfaces métalliques endommagées. Une surface peinte abîmée, par exemple la tôle peinte formant les carrosseries de voitures ou de camions qui ont été abîmées par des égratignures ou des ébréchures faites à la peinture, exposant le métal, peut être retouchée afin de retrouver l'apparence d'une surface uniformément peinte et d'empêcher la corrosion du métal exposé, grâce à l'application d'une peinture de retouche à la surface métallique endommagée. On frotte ensuite la surface retouchée ainsi que la surface finie et non abîmée immédiatement environnante à l'aide d'un matériau en feuille souple et moelleux qui a été imbibé d'une composition de solvant pour peinture de retouche afin d'enlever tout excédent de peinture étalé par inadvertence sur l'ancienne finition entourant l'égratignure ou l'ébréchure. On ne frotte la surface retouchée avec le matériau en feuille souple imbibé de solvant que lorsque la peinture de retouche a en partie séché, généralement 1 à 15 minutes environ après l'application. La composition de solvant comprend un solvant liquide paraffinique choisi à partir du groupe composé de benzène substitué par l'alkyle inférieur et de composés d'hydrocarbure cycloaliphatique et aliphatique oxygéné et de tels composés substitués par l'halogène.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US556,225 | 1990-07-20 | ||
US07/556,225 US5077086A (en) | 1990-07-20 | 1990-07-20 | Method for the touch up of scratched painted metal products |
US07/556,774 US5082692A (en) | 1990-07-23 | 1990-07-23 | Method for the touch up of scratched painted metal products |
US556,774 | 1990-07-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992001519A1 true WO1992001519A1 (fr) | 1992-02-06 |
Family
ID=27071098
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1991/005115 WO1992001519A1 (fr) | 1990-07-20 | 1991-07-19 | Procede, composition de solvant et kit pour retouches de produits metalliques peints egratignes |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU8308391A (fr) |
WO (1) | WO1992001519A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0975439A1 (fr) * | 1997-04-18 | 2000-02-02 | Henkel Corporation | Procede de retouche pour surfaces metalliques pretraitees |
US6815009B1 (en) * | 2002-12-06 | 2004-11-09 | Magic Auto Touch Up, Inc. | Automotive paint scratch repair process |
WO2006071695A2 (fr) * | 2004-12-29 | 2006-07-06 | The Sherwin-Williams Company | Procede permettant d'appliquer un appret d'impression a l'aide d'une raclette |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3333292A (en) * | 1966-05-23 | 1967-08-01 | Oscar H Chase | Container-integrated applicator |
US3652314A (en) * | 1969-01-02 | 1972-03-28 | Schuyler Dev Corp | Method for renewing, resurfacing, and preserving phonograph records |
US3950571A (en) * | 1972-08-11 | 1976-04-13 | Mcbride La Vaughn R | Method for rehabilitating scored and marred surfaces |
US4814200A (en) * | 1985-08-26 | 1989-03-21 | International Flying Colors, Inc. | Method for restoring painted surface |
JPH01304195A (ja) * | 1988-05-31 | 1989-12-07 | Daikin Ind Ltd | 共沸組成物 |
-
1991
- 1991-07-19 AU AU83083/91A patent/AU8308391A/en not_active Abandoned
- 1991-07-19 WO PCT/US1991/005115 patent/WO1992001519A1/fr unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3333292A (en) * | 1966-05-23 | 1967-08-01 | Oscar H Chase | Container-integrated applicator |
US3652314A (en) * | 1969-01-02 | 1972-03-28 | Schuyler Dev Corp | Method for renewing, resurfacing, and preserving phonograph records |
US3950571A (en) * | 1972-08-11 | 1976-04-13 | Mcbride La Vaughn R | Method for rehabilitating scored and marred surfaces |
US4814200A (en) * | 1985-08-26 | 1989-03-21 | International Flying Colors, Inc. | Method for restoring painted surface |
JPH01304195A (ja) * | 1988-05-31 | 1989-12-07 | Daikin Ind Ltd | 共沸組成物 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0975439A1 (fr) * | 1997-04-18 | 2000-02-02 | Henkel Corporation | Procede de retouche pour surfaces metalliques pretraitees |
EP0975439A4 (fr) * | 1997-04-18 | 2000-07-12 | Henkel Corp | Procede de retouche pour surfaces metalliques pretraitees |
US6815009B1 (en) * | 2002-12-06 | 2004-11-09 | Magic Auto Touch Up, Inc. | Automotive paint scratch repair process |
WO2006071695A2 (fr) * | 2004-12-29 | 2006-07-06 | The Sherwin-Williams Company | Procede permettant d'appliquer un appret d'impression a l'aide d'une raclette |
WO2006071695A3 (fr) * | 2004-12-29 | 2006-09-08 | Sherwin Williams Co | Procede permettant d'appliquer un appret d'impression a l'aide d'une raclette |
Also Published As
Publication number | Publication date |
---|---|
AU8308391A (en) | 1992-02-18 |
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