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WO1991018665A1 - Dispositif de separation a membrane a spirale, a deux tuyaux, a double flux, et a contre-courant - Google Patents

Dispositif de separation a membrane a spirale, a deux tuyaux, a double flux, et a contre-courant Download PDF

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Publication number
WO1991018665A1
WO1991018665A1 PCT/US1991/000620 US9100620W WO9118665A1 WO 1991018665 A1 WO1991018665 A1 WO 1991018665A1 US 9100620 W US9100620 W US 9100620W WO 9118665 A1 WO9118665 A1 WO 9118665A1
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WO
WIPO (PCT)
Prior art keywords
permeate
pipe
feed
fluid
membrane
Prior art date
Application number
PCT/US1991/000620
Other languages
English (en)
Inventor
Damoder Reddy
Charles E. +Di Reineke
Tag Young Moon
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/534,755 external-priority patent/US5034126A/en
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Publication of WO1991018665A1 publication Critical patent/WO1991018665A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/10—Spiral-wound membrane modules

Definitions

  • the present invention relates to an improved design for a spiral-wound membrane separation module or device.
  • a countercurrent carrier fluid may be needed.
  • gases such as air or natural gas
  • a portion of product gas may be recycled as a carrier gas in the permeate passageway.
  • the feed passageway on one side of the membrane, and the permeate passageway on the other side of the membrane are designed to produce maximum contact of the feed and permeate fluids with these two surfaces of the membrane.
  • the carrier fluid preferably flows countercurrent relative to the feed fluid.
  • modules of the known art describe a module having a specific countercurrent or cocurrent fluid in the permeate fluid passageway to facilitate in the removal of the permeate or to remove additional undesirable components from the permeate.
  • the designs of the present invention provide such a spiral-wound module and a passageway in the permeate region for a countercurrent or cocurrent fluid (or sweep gas). It also provides a method to dry liquids or gases and/or to remove undesirable components from a fluid feed.
  • the present invention relates to a spiral-wound membrane module having a permselective semipermeable membrane for use in the separation of a permeate from a fluid feed mixture, the module comprising:
  • At least one permselective membrane envelope having within the fold at least one feed spacer means for controlling the feed flow in the feed passageway,
  • At least one permeate spacer means for controlling the permeate flow in the permeate passageway and optionally for controlling the flow of a countercurrent or cocurrent fluid in the permeate,
  • the generally hollow feed pipe has a wall barrier intermediate in its length dividing the pipe into a first compartment and a second compartment, the feed pipe having means for introducing a fluid feed stream to the first compartment of the pipe and means for removing the more concentrated (feed) effluent fluid from the second compartment of the pipe, the first and second feed pipe compartments each having at least one axial opening through the pipe circumference through which the feed fluid will pass,
  • porous feed spacer means are in fluid communication with the axial openings of the first and second feed pipe compartments
  • the membrane envelope comprises a sheet membrane having a first surface and a second surface which is opposite to the first surface, wherein the membrane is generally folded once around the hollow feed pipe at the fold so that a first half of the first surface of the membrane layer faces the other half of the first surface of the membrane envelope creating a feed passageway and interposed between the first half and the other half of the first surface of the membrane is the porous fluid feed spacer means for controlling the flow of fluid in the feed passageway,
  • the permeate passageway for the fluid permeate is formed by the adjacent second membrane surfaces which are opposite to the first membrane surface, wherein the permeate passageway has porous permeate spacer means which control the flow of fluid in the permeate passageway and, if present, also control the flow of a countercurrent or cocurrent fluid in the permeate passageway between the adjacent second membrane envelope surfaces which are opposite to the first membrane surface,
  • the generally hollow permeate pipe is in the permeate passageway adjacent to and generally parallel with the feed pipe, the permeate pipe having a wall barrier intermediate in its length dividing the permeate pipe into a first permeate compartment and a second permeate compartment, the permeate pipe having means for removing the permeate from the first and second permeate compartments, where the first and second permeate pipe compartments each have at least one axial opening- through the permeate pipe circumference through which the permeate fluid passes, and the permeate passageway is in fluid communication with the axial fluid openings of the first and second permeate pipe compartments,
  • first volume space filling means (52A) to obtain a generally circular shape, for the module, which is adjacent to and in contact with the curved longitudinal outer surface of up to about one wrapping of the porous feed spacer means (55) around the feed pipe and also in contact with the outer surface of about one layer of the porous permeate spacer means around the permeate pipe
  • second volume space filling means (52B) adjacent to and in contact with about one wrapping of the permeate spacer means (58) around the permeate pipe (51B) and in contact with the outer surface of about one layer of the porous spacer means around the feed pipe (51A)
  • both volume space filling means each have an outer larger generally arcuate convex surface wherein the larger surface arc is slightly larger in diameter than the sum of the diameters of the feed pipe and the permeate pipe, and a smaller first and a smaller second inner concave intersecting arcuate surfaces which intersect each other and intersect the outer edge of the larger arc to define a linear shaped three dimensional volume having three curved face surfaces
  • the module is contained in a hollow casing having means to inject, collect and to remove the fluid feed and permeate from the casing.
  • the hollow permeate pipe further includes means for injecting countercurrent or cocurrent fluid (or sweep gas or carrier gas) in one compartment of the permeate pipe, and
  • the membranes for the module are all sealed at the outer edges to contain all fluids within the module passageways.
  • the feed passageway further comprises two juxtapositioned interconnected regions A-B wherein the outer region A and outer region B are each in fluid communication on one edge to the feed pipe axial openings and a second axial side of region A and a second axial side of region B are each in fluid 0 connection to opposing sides of a generally located barrier (glue line) C, which separates region A and region B immediately adjacent to and sealed to the feed pipe, wherein region A axially receives the incoming r- fluid feed which is in fluid communication with region B at interconnecting open region D of the spacer, which open region D is at a location remote to the feed pipe.
  • a generally located barrier (glue line) C which separates region A and region B immediately adjacent to and sealed to the feed pipe
  • the permeate passageway Q comprises two juxtapositioned interconnected regions E- F-G wherein outer region E and outer region G are each in fluid communication on one edge to the permeate pipe axial openings, and a second axial side of region E and a second axial side of region G are each in contact with 5 opposite sides of a generally centrally located barrier (glue line) H, which separates region E and region G immediately adjacent to and sealed to the permeate pipe wherein region E axially receives the incoming countercurrent fluid which is in fluid communication with region G at open region F of the permeate spacer, where region F is at a location remote to the permeate pipe.
  • a generally centrally located barrier (glue line) H which separates region E and region G immediately adjacent to and sealed to the permeate pipe wherein region E axially receives the incoming countercurrent fluid which is in fluid communication with region G at open region F of the permeate spacer, where region F is at a location remote to the permeate pipe.
  • the permeate spacer means comprise three juxtapositioned interconnected regions J- K-L wherein the outer higher porous region J and outer higher porous region L are each in fluid communication on one edge to the pipe axial openings and a second axial side of region J and a second axial side of region L are each connected to opposing sides of lower porosity region K, wherein region J axially receives from the pipe the incoming countercurrent fluid at low pressure which is in fluid communication with the high pressure region K which is in fluid communication with lower pressure region L wherein region K is not directly in fluid communication with any axial opening of the first or second compartments of the pipe.
  • differential fluid flow in the fluid feed passageway and in the fluid permeate passageway are produced using multiple adhesive (glue) spots which are in a generally axial configuration to the pipe wherein the glue spots have a predetermined size and spacing from one another for the purpose of controlling the flow of fluid in the permeate passageway.
  • glue spots which are in a generally axial configuration to the pipe wherein the glue spots have a predetermined size and spacing from one another for the purpose of controlling the flow of fluid in the permeate passageway.
  • any of the modules may be constructed using multiples of membrane leaves and feed spacer and permeate spacer.
  • Figure 1 is a breakaway perspective representation of one module of the art.
  • Figure 2 is a cutaway perspective representative of another module of the art.
  • Figure 3 is an end schematic representation of the module of Figure 1.
  • Figure 4 is a cutaway schematic representation of an open lay-up of the pipe and feed fluid passageway of the present invention.
  • Figure 4 A is a cutaway schematic representation of the open lay-up of the pipe and the permeate (and countercurrent fluid) passageway of the present invention.
  • Figure 4B is a schematic representation of an open lay-up of the pipe and the feed fluid passageway using glue spots ' to control the feed flow.
  • Figure 4C is a schematic representation of an open lay-up of the pipe and the permeate (and countercurrent fluid) passageway using glue spots to control the permeate flow and countercurrent fluid flow.
  • Figure 5 is cross-sectional end view of the module prior to spiral winding.
  • Figure 5A is a schematic representation and dimensions of an open lay-up of the permeate pipe and permeate fluid passageway as described in Example 1.
  • Figure 5B is a schematic representation of an open lay-up of the pipe and the permeate (or countercurrent) fluid passageway using single or optionally multiple layers of spacer grid (or different spacer grids) to obtain differential flow of the permeate gas and countercurrent or cocurrent fluid across the permeate passageway.
  • Figure 6 is a cross-sectional view of the fitting aspects of the partially spiral-wound module using the two pipes and two arcuate shaped space filling volume means.
  • Figure 7 is a perspective view of the spiral- -wound module.
  • Figure 8 is an isometric view of the spiral- -wound module in a housing.
  • Axial flow usually refers to a fluid flow entering/exiting a pipe and exiting/entering through an opening in the circumference of the pipe to a passageway
  • Countercurrent fluid refers to a countercurrent fluid or "sweep gas”. It is usually introduced at one end of the permeate pipe in a
  • the purpose of the sweep gas is to sweep the permeate passageway to facilitate the removal of the permeate.
  • the crude natural gas -j- feed will contain some water and/or carbon dioxide.
  • Dry natural gas, e.g., methane as a countercurrent fluid introduced to the permeate passageway, will facilitate the removal of the water present in the permeate passageway.
  • Cocurrent fluid refers to a cocurrent fluid or "sweep gas”. It is usually introduced at one end of the permeate pipe and flows in the same direction as the feed flow.
  • feed pipe refers to the generally circular pipe through which the feed fluid enters the module and from which the more concentrated feed exits.
  • the feed pipe usually has a solid barrier intermediate in its length and has at least one axial opening in the circumference before the barrier and at least one opening after the barrier.
  • Membrane refers to a thin membrane which is permselective for various fluids.
  • the membrane may be homogeneous throughout.
  • the membrane may also be asymmetric, i.e., one generally flat surface is more or less selectively permeable to the fluid than the second porous nonselective flat surface. It is also possible for the membrane to be porous on both flat surfaces, and the nonporous portion anywhere in the middle thickness of the membrane produces the permselective region.
  • Permeate pipe refers to the generally circular pipe from which the permeate exits from the module.
  • the countercurrent fluid (sweep gas) is introduced in the permeate pipe in the opposite direction to the feed flow.
  • device 10 of the art is formed of a piece of membrane 11 folded leaves 11A and 11B over a perforated tube 12 and forms a sandwich over a leaf of porous feed spacer material 13, e.g., VEXAR ® or SIMPLEX ® .
  • a membrane support sheet 14 is optionally provided.
  • the permeate spacer 16 (e.g., SIMPLEX ® ) is provided between the membrane surfaces and is in fluid communication with the core pipe 12 which has holes in its circumference.
  • the feed membrane sandwich 11A, 13 and 11B is adhesively sealed along both sides 15A and 15B and one end 15C as well as around the perforated central tube 12 where the tube meets the sandwich at area 15D.
  • the assembly 10 is then spirally rolled up by wrapping the leaf around the tube with the highly porous feed-side spacer screen 16 placed between the surfaces of the membrane.
  • the spiral-wound module 10 can be used alone or can be placed in a hollow pressure vessel with proper seals and connectors.
  • the feed fluid 13A is forced through the annular screen spacer feed channel 13 from one end of the channel 13B and exits through the other end of the channel 13C as the concentrated feed 13D.
  • permeate species will pass through the membrane 11A and 11B into the permeate channel 19 and move spirally inward and through axial holes in the circumference of tube 12 and into the central tube 12, and exit at either end of the tube 12.
  • the adhesive seals when a high pressure feed of 100 to 2,000 psi (690-13790 kPa) is used in this configuration without an enclosing high-pressure chamber, the adhesive seals often burst.
  • the relative flow patterns of the feed and permeate are in a general countercurrent configuration.
  • An alternative design is the so-called open- channel ultrafiltration device. The geometric relationship of the feed channel and the permeate channel is reversed. Shown in Figure 2 is found the device 20 of the art.
  • the feed 22A enters at one end 23A of the central pipe 21 which contains a solid plug 24 at some mid-point in the pipe, whereby the feed 22A passes through an opening(s) 26A in pipe 21 into the feed channel 27A which is sandwiched between two sheets of membrane 28A or 28B, and travels spirally outward away from the pipe.
  • the feed channel 27 has a partial partition barrier 29 (glue line) located from the general location of the plug in the central tube so that the feed fluid 22A, upon reaching the end portion of the channel at open region 27B, is deflected into the channel space 27C on the other side of partial partition 29.
  • the feed 22A then travels spirally inward toward pipe 21 through opening 26B into the portion of pipe 21B on the second side of the plug 24 and finally exits through the opposite and 23B of tube 21 as a more concentrated feed fluid 22B.
  • the permeate 30A and 30B flows in the axial direction and leaves module 10 at both edges 31A and 31B of the module membrane surface.
  • Figure 3 shows an end cross-sectional view of a single flow spiral-wound module of the art where the numbers designating the components of the module are the same as in Figure 1.
  • Module 50 ( Figures 5, 6, 7, and 8) contains two central pipes, the feed pipe 51A and the permeate
  • Feed pipe 51A and permeate pipe 51B are each divided into two compartments by means of a solid plug 51C and 51D, respectively, in such a way that the relative length of the two segments corresponds generally to the ratio of feed to concentrate volume.
  • each pipe 51A and 51B Associated with each pipe 51A and 51B is a volume space filling means 52A and 52B shaped such that the two pipes 51A and 51B and the two volume space filling means 52A and 52B (sometimes referred to as block bars) which, when collectively assembled as shown in Figure 6 produce a substantially circular cross- section around which the pendant membranes and/or spacers are spirally-wound, assembled, and secured to produce module 50.
  • Feed Fluid Passageway A piece of membrane 54 is folded to produce an envelope around the perforated feed pipe 51A (or a pipe having specifically drilled holes 56A and 56B) and the associated volume space filling means 52A into a leaf as shown in Figure 5.
  • the two halves of membrane 54A and 54B sandwich a piece of porous feed passageway (channel) spacer screen 55 which also wraps around the pipe 51A and volume space means 52A, as shown in Figure 5.
  • a partial barrier means 57A (glue line) is made to provide maximum contact of the feed fluid with the membrane surface in the sandwiched spacer screen of the leaf.
  • the glue line is sealed at the pipe 51A, and is sealingly extending from the central tube 51A about the location of the plug 51C to about the midpoint of the width of the membrane leaf 54 approximately one-half width to one-fourth width away from the end (remote to the pipe) of the membrane leaf 54.
  • Permeate Passageway A piece of porous spacer material 58, such as melamine-impregnated SIMPLEX ® , is wrapped around the perforated (holes 58A and 58B) in the permeate pipe 51B.
  • the associated volume space filling means 52B are at one end of the spacer, the other end of the spacer extends approximately the same length and width of the feed passageway.
  • the backing porous material 58 also has a partial barrier 57B at the location corresponding generally to the fluid barrier located in the feed channel spacer. Thus, both passageways (channels) are sealed at this barrier point to provide for maximum contact the feed fluid with the membrane surface and of the permeate fluid with cocurrent or countercurrent fluid.
  • the means to introduce and remove the cocurrent or countercurrent fluid into/from the permeate passageway are at the open ends of the permeate pipe
  • an inlet or outlet for this fluid can be an additional valve and fluid inlet/outlet to one or both ends of pipe 51B.
  • volume space filling means 52A are engaged with volume space filling means 52A and
  • Membrane 54 of assembly 50A and permeate spacer 58 of assembly 50B are then spirally rolled by wrapping around the core unit 50A to produce cylindrical module 50 as shown in Figure 7.
  • the volume space filling means 52A and 52B are each shaped having a larger generally arcuate convex linear surface (52C and 52D) which is an arc having a diameter substantially the same as the sum of the diameters of the feed pipe and the permeate pipe, and smaller first (52E, 52G) and smaller second (52F), 52H) inner concave intersecting arcuate surfaces.
  • These three arcuate surfaces (52C, 52E, and 52F and 52D, 52G, and 52H) each define a separate linear three-dimensional volume having the three curved surfaces and two generally perpendicular ends.
  • volume spaces filling means may be of any material, e.g., metal, ceramic, polymeric, porous or nonporous, so long as the material withstands the operational chemical, thermal and pressure conditions.
  • the volume space filling means may be preformed by methods known in the art and placed in the proper position prior to spiral winding.
  • a preferred method of creating the volume space filling means is to use a suitable fluid epoxy resin or a fluid polyurethane. A minimal amount of the fluid plastic is placed in the membrane spaces prior to spiral winding.
  • the membranes are then carefully spiral-wound.
  • the arcuate shape described above forms as a result of the spiral winding.
  • the proper amount of fluid polymer is important. Too little plastic will leave voids for the membrane to collapse into and possibly rupture. Too much plastic may spread extensively onto the membrane surfaces and reduce their permeability.
  • One of ordinary skill in the art may determine the appropriate amount of fluid plastic with a minimum of experimentation.
  • the open circular edges of the module membrane are contacted with an adhesive sealant 60 and capped.
  • the surface of the module may be encased in a hollow non-permeable shell.
  • the module is placed in a chamber capable of withstanding higher pressures of the order of 1000 psi to 2000 psi (6.9 to 13.8 MPa).
  • the feed stream 80 is introduced at line 63 to an optional pump 64 from which it is transported at an elevated pressure through exterior pipe 65 and a coupling opening 65A in housing 90 which surrounds spiral-wound module 50.
  • housing 90 is divided into a first compartment 71A (or 70A) and a second compartment 71B (or 70B) by a solid barrier 61 situated at any number of points intermediate of the length of the module 50 (note the phantom outline of the barrier positions 61A and 61B).
  • the feed stream 81 enters spiral-wound module 50 using pipe 51A.
  • the fluid feed 81 is conveyed through the spiral-wound membrane. A portion of the components of the fluid feed will permeate through the membrane into the permeate passageway.
  • the more concentrated feed stream 82 exits the module at 51C and enters the second chamber 71B (or 70B).
  • the feed stream 82 (purified and somewhat more concentrated) is removed through coupling 67 as the process feed effluent 87 via pipe 68.
  • Outlet pipe 68 optionally contains a throttling value 69 which controls the flow through velocity of the feed stream.
  • the fluid permeate is found in the permeate channel.
  • the countercurrent gas 84 enters module 50 via pipe 85 which becomes pipe 5ID.
  • the permeate passageway in module 50 is then subjected to this carrier fluid 84 which carries the permeate and exits module 50 in line 51B and line 66 as permeate 85 and carrier gas 86.
  • the inlet 51C and outlet 51D of the permeate tube 51B are located at the opposite ends of those of the feed tube in order to achieve countercurrent flows of fluid and sweep gas.
  • the crude feed pipe 51A and/or the permeate pipe 51B can be independently metal, organic polymer and composite. Suitable materials include, for example, commercially available copper, steel, aluminum, poly(carbonate) and poly(amide). Copper or aluminum are preferred.
  • the diameter of the pipes is 0.25 inches (0.64 cm) outer diameter to 4 inches (10.16 cm) outer diameter. Preferably, the diameter is between 0.25 inches (0.64 cm) and 2 inches (5.08 cm) outer diameter.
  • the length of pipes 51A and 51B is really not limited and can be from a few inches to several feet. Generally, the length is between 6 inches (15.2 cm) to 5 feet (1.5 m) .
  • the permselective membrane can be of any material which is selectively permeable to the fluid or species to be separated.
  • These membranes can be, for example, cellulose triacetate, polyperfluorosulfonic acid (PFSA), polyamide, polyvinylalcohol, polysulfone or regenerated cellulose.
  • Membranes include, for example, PFSA (See U.S. Patent No. 4,846,977 for methods of preparation) assigned to The Dow Chemical Company, Midland, Michigan 48640, or NAFI0N ® film from DuPont Co. of Wilmington, Delaware, or cellulose triacetate KODACELL ® TA-404 from Eastman Kodak, Rochester, New York.
  • the thickness can be any useful thickness, preferably between 0.1 to 100 mil. (6.00254 to 0.254 mm), more preferably 1 to 5 mil. (0.254 to 0.127 mm).
  • Membranes that are suitable for use in the present invention may be constructed of a fluoro-carbon- type material or of a hydrocarbon-type material. Such membrane materials are well-known in the art. Preferably, however, fluorocarbon materials are generally preferred because of their chemical stability.
  • Non-ionic (thermoplastic) forms of perfluorinated polymers described in the following patents are particularly suitable for use in the present invention because they are easily softened by heating and formed into useful membrane shapes.
  • Membranes which are suitable are described in the following U.S. patents: 3,282,875; 3,909,378; 4,025,405; 4,065,366; 4,116,888; 4,123,336; 4,126,588; 4,151,052; 4,176,215; 4,178,218; 4,192,725; 4,209,635; 4,212,713; 4,251,333; 4,270,996; 4,329,435; 4,330,654; 4,337,137; 4,337,211; 4,340,680; 4,357,218; 4,358,412; 4,358,545; 4,417,969; 4,462,877; 4,470,889; 4,478,695; and European Patent Application 0,027,009.
  • Such polymers usually have equivalent weight in the range
  • fluorocarbon materials for use in forming membranes are copolymers of monomer I with monomer II (as defined below).
  • monomer II as defined below.
  • a third type of monomer may be copolymerized with I and II.
  • Z and Z' are independently -H, -Cl, -F, or
  • the second type of monomer consists of one or more monomers selected from compounds represented by the general formula:
  • Y is -S0 2 Z, -CN, -C0Z, or C(R3f) (R4f)0H;
  • Z is -I, -Br, -Cl, -F, -OR, or NR1R2;
  • R is a branched or linear alkyl radical having from 1 to 10 carbon atoms or an aryl radical
  • R3f and R4f are each independently perfluoroalkyl radicals having from 1 to 10 carbon atoms;
  • R1 and R2 are independently -H, a branched or linear alkyl radical having from 1 to 10 carbon atoms or an aryl radical;
  • a 0-6;
  • b 0-6;
  • c is 0 or 1; provided a + b + c is not equal to 0;
  • N is 0 to 6;
  • Rf and Rf ' are independently -F, -Cl, perfluoroalkyl radicals having from 1 to 10 carbon atoms or fluorochloroalkyl radicals having from 1 to 10 carbon atoms.
  • Y is -SO2F or - COOCH3; n is 0 or 1; Rf and Rf ' are -F; X is -Cl or -F; and a + b + c is 2 or 3.
  • the third, and optional, monomer suitable is one or more monomers selected from the compounds represented by the general formula;
  • Y' is -F, -Cl or -Br
  • a' and b' are independently 0-3;
  • 0 0 or 1
  • n' is 0-6;
  • Rf and Rf are independently -Br, -Cl, -F, perfluoroalkyl radicals having from 1 to 10 carbon atoms, or chloroperfluoroalkyl radicals having from 1 to 10 carbon atoms;
  • the membrane may be converted to its ionic form by reacting it with, in the case of -SO2F pendant groups, 25 weight percent of NaOH under the following conditions:
  • the feed or permeate spacer materials are generally porous loosely knit organic materials. These include, for example, VEXAR ® , which is available from Conwed Corporation, St. Paul, Minnesota. VEXAR ® is useful as a permeate grid spacer at a pressure of up to 30 psig. At high feed pressures (over 50 psig), the porous membrane usually collapses into the VEXAR ® . At these higher pressures, SIMPLEX ® spacer available from Al DeCenso Fabrics, Annapolis, Maryland 21401 is particularly useful as a permeate spacer.
  • VEXAR ® which is available from Conwed Corporation, St. Paul, Minnesota.
  • VEXAR ® is useful as a permeate grid spacer at a pressure of up to 30 psig. At high feed pressures (over 50 psig), the porous membrane usually collapses into the VEXAR ® . At these higher pressures, SIMPLEX ® spacer available from Al DeCenso Fabrics
  • the plug barriers 51C and 51D are independently selected from any materials which will seal the pipe into two compartments.
  • a copper or aluminum barrier may be soldered or welded in place.
  • a polymeric material such as a polyurethane adhesive plug may be used.
  • an organic adhesive sealant is used such as polyurethane and epoxide. D.E.R.TM 410 or FullerTM 3501 are particularly useful.
  • the adhesive sealant at the edges of the feed membrane is usually an organic adhesive, such as a commercially available polyurethane or epoxide, e.g., FullerTM 3501 or D.E.R.TM 410
  • the barrier 57A and 57B provides maximum contact of the permeate and countercurrent fluid with the active membrane.
  • the barrier (glue line) can be of polyurethane or an epoxide.
  • the module can be used at temperatures lower than 0°C for the separation of gases (e.g., 0 2 N2, low boiling chlorofluorohydrocarbons, etc.).
  • gases e.g., 0 2 N2, low boiling chlorofluorohydrocarbons, etc.
  • the only limitation is when the low temperature causes the polymer to degrade or to become brittle.
  • the upper operational temperatures must be below the glass transition temperature of the polymers and membranes, usually 10°C lower or more.
  • the modules usually operate for air or natural gas dehydration at between 0°C to 70°C. Ambient temperatures are preferred.
  • the present invention relates to a module which has the advantage of some continuous process of manufacture of its component layers. The fabrication is simple and uses fewer materials.
  • two sheets of the permselective membrane 54A and 54B are optionally separated by an open feed spacer grid 55.
  • One sheet of membrane 54A is positioned first and the feed spacer 55 is placed on the top of the first membrane 54A.
  • Glue spots 90A to 90L and 90M to 90X are placed on spacer 55 at specific points.
  • Membrane sheet 54B is placed on the adhesive spots. The specific spacing between the glue spots and their location provides the proper degree of desired control of the flow in a uniform manner in the feed passageway.
  • the two sets of adhesive tabs 90A to 90L and 90M to 90X do not need to be in parallel lines to each other or substantially the same in placement, spacing or configuration. The only requirement is that they provide control of the feed fluid to produce substantially uniform fluid flow across the active portions of the permselective membrane.
  • the permeate passageway is formed by the opposite sides of the membrane surfaces which form the feed passageway.
  • a spacer material (SIMPLEX ® ) is inserted.
  • Glue (adhesive) spots 92A to 92L and 92M to 92X are placed on the permeate spacer.
  • the specific spacing between the glue spots 92A to 92L and 92M to 92X can be any distance or configuration. The important aspect is desired degree of control of the flow of the permeate and the flow of the countercurrent (or cocurrent) fluid through the permeate channel.
  • first glue spots in the permeate channel of 0.25 x 0.25 inches (0.64 x 0.64 cm) are placed in generally parallel lines axially to pipe 51B, and adjacent to the edge of the attached pipe about 3 inches (7.62 cm) in from the opposite edges of the permeate membrane 112 and 113-
  • the second glue spots 111B or lines are then placed 0.5 inches (1.27 cm) from the first two axially away from pipe 15.
  • the third glue spots 111C are then place 0.275 inches (0.95 cm) from the second ones.
  • the glue spots are then continued in two generally parallel lines adding about 0.125 inches j- (0.32 cm) in spacing between adjacent glue spots.
  • the countercurrent fluid (open arrows) in Figure 4C enters region Q and in the permeate passageway and is conveyed substantially uniformly across active c membrane region R through the glue spots into region S and exits the module with the permeate.
  • the present invention 0 relates to removal of acid or basic gases from gaseous or liquid mixtures.
  • Facilitated transport membranes are known, see, for example, J.D. Way, et al. (1989), Journal of Membrane Science, Vol. 46, pp. 309-324.
  • Facilitated transport refers to the use of a mobile complexation agent in a membrane to selectively increase the flux of one or more of the permeating species which react reversibly with the complexation agent or carriers.
  • the reactive membranes when used in the present invention achieve both high permeability and high separation factors.
  • Ion exchange resins may be used as a support for complexation agents. The carrier cannot easily be forced out of the support since the carrier is retained by strong electrostatic forces.
  • a NAFION ® or perfluorosulfonic acid (PFSA) polymer film can first be converted to the sodium salt and contacted with monopositive ions, such as monopositive ethylene diamine (HEDA + ), to produce the facilitated transport membranes.
  • monopositive ions such as monopositive ethylene diamine (HEDA + )
  • HEDA + monopositive ethylene diamine
  • Any positively charged counter ion includes, for example Ag + , Li + , Bu +2 and Ca + .
  • HEDA + acts as a carrier for both carbon dioxide and hydrogen sulfide. Therefore, these materials can be removed from a natural gas mixture which includes species in addition to methane.
  • Facilitated transport in general, requires the sweep gas in the permeate passageway, therefore, the module of the present invention is particularly useful.
  • Figures 4 to 8 show the use of the sweep gas through the permeate passageway.
  • the present invention makes it possible for the sweep gas to have maximum contact with the permeate.
  • the sweep gas is at a pressure of between 0.01 and 50 psia (0.069 to 3 ⁇ 4.8 kPa), preferably between 1 and 25 psia (6.9 to 172.4 kPa).
  • microporous membrane support material is a commercial VESAP0R ® 3000H both available from Gelman, Ann Arbor, Michigan or a commercially available polysulfone.
  • VEXAR ® is also available from Conwed Corporation. Also see F. B. Mercer, U.K. Patent No. 836,555.
  • Other feed spacer materials include nylon and polysulfone.
  • the permeate sweep spacer material 58 ( Figure 4A or 4C) is an epoxy-coated SIMPLEX ® spacer.
  • SIMPLEX ® is an epoxy-coated polyester fabric.
  • a preferred spacer is available as SIMPLEX ® type 546E or as epoxy (Hornwood Epoxy type HC-80) coated polyester in style numbers 7921, 9628, 9661, 9771 and 1271 commercially available from A. DiCenso Textiles, Inc., Annapolis, Maryland 21401. This spacer is also used in reverse osmosis filtration cartridges.
  • the differential flow in the permeate (or feed passageway) may be obtained using multiple layers of spacer material.
  • the distributor spacer material regions L and J, Figure 5A
  • Region J-K-L may also be one spacer grid material of substantially uniform porosity.
  • distributor spacer materials in the feed or permeate passageway include commercial CONWED ® spacer materials from Conwed Corporation.
  • the adhesive to adhere the edges of the membrane to create the permeate passageway and to adhere the separator layer to pipe 51B may be the same or different.
  • a single epoxy adhesive FULLERTM FE-7621 A and B is available from H. B. Fuller Company, Chicago, Illinois.
  • the feed or permeate spacer materials are generally porous loosely knit organic materials. These include, for example, VEXAR ® 5321.
  • VEXAR ® is useful as a permeate spacer at a feed pressure of up to 30 psig (207 kPa g). At high pressures, the permselective membrane usually collapses into the VEXAR ® . At these higher pressures, SIMPLEX ® described above is particularly useful.
  • the central barrier (glue line 57A or 57B) can be of any suitable polymer, e.g., a polyurethane or an epoxide.
  • the module of the present invention can also be used for the removal of volatile organics or dissolved gases from water using a hydrophobic microporous membrane, e.g. polyolefins, polypropylene, such as
  • CELGARD ® from Hoechst-Celanese Corporation, Separation Products Division, Charlotte, North Carolina.
  • Highly organic permeable membrane such as a silicone, available from General Electric Corporation, Schenectady, New York, or Dow Corning Corporation of Midland, Michigan 48640.
  • the module can also be used to remove heavier hydrocarbons (C-2 to C-10 or greater) from natural gas using a membrane which is selective to these hydrocarbons or to methane. Silicone membranes are useful in this separation process which is commonly known as hydrocarbon dew pointing.
  • a spiral-wound module is produced according to the description provided herein.
  • the feed pipe and the permeate pipe 51B are each of 0.25 inches (0.64 cm) O.D. copper, and 2.5 feet (0.76 m) in length.
  • the perm ⁇ selective feed membrane is 2 feet x 4 feet (0.61 m x 1.22 m) sheet of homogeneous polyperfluorosulfonic acid having a 5 mil. (127 mm) thickness prepared according to U.S. Patent No. 4,846,977.
  • the porous feed spacer is a 2 foot x 2 foot (0.61 x 0.61 m) by 24 mil. (610 mm) sheet of VEXAR ® 5321 (Conwed Corporation, St. Paul, Minnesota).
  • the feed pipe and spacer have a barrier, plug, adhesive edges, holes, etc. similar to the permeate passageway of Figure 5A.
  • Figure 5A also includes pertinent dimensions and features.
  • the permeate spacer is a 2 foot by 2 foot (0.61 m x 0.61 m) by 24 mil. (610 mm) sheet of VEXAR ® 5321. See Figure 5A for the configuration of the permeate pipe, holes, barrier, spacer, adhesive, etc.
  • the volume space filling means 52A and 52B are each cut to produce an outer convex surface having a diameter about 0.5 inches (1.27 cm), and the two inner concave diameters are each about 0.25 inches (6.14 cm) or larger. These volume space filling means are about 2 feet (0.61 m) long.
  • the VEXAR ® spacer is wrapped once around feed pipe 51A, the space filling means of plastic epoxy polymer material is placed adjacent to the pipe 51A as shown on Figure 5. This grouping is then placed within the loosely folded permselective membrane 54 to obtain two facing permselective surfaces of 2 feet by 2 feet
  • the permeate pipe 51B is wrapped with one layer of the permeate spacer (SIMPLEX ® or VEXAR ® ) 58 0 and space filling means 52B is placed adjacent to the wrapped pipe 51A as shown in Figure 6.
  • Assembly 50A and 50B are combined as shown in Figure 5. All edges of the membrane are coated with polyurethane adhesive.
  • j- Barriers 57A and 57B are created using a polyurethane adhesive line.
  • the pendant membranes and spacer are then spirally-wound producing the module of Figure 7.
  • Example 2 Air Dehydration 0
  • the module of Example 1 is connected to a moist air crude feed line 51A wherein the moist air has greater than 90 percent of saturation water content, and a pressure of 8 psig (55.2 kPa g).
  • a counter-current c dry air (less than 0.01 percent water), at a rate of 0.0831 cfm (0.0392 liters/sec.) is introduced in the permeate pipe at point 51E. No permeate exits at point 51E.
  • the permeate gas exits at 51C with the counter- current gas 51F.
  • Feed/Sweep flow rate of feed/flow rate of sweep gas
  • Pw in cm Hg water vapor pressure on wet gas feed in centimers of mercury
  • Example 2 The module of Example 1 connected to a methane gas line saturated with water at a pressure of about 8 psig (55.2 kPa g).
  • Countercurrent dry methane (less than about 0.1 ppm water) is introduced in the permeate pipe at point 51E. No permeate gas exits at 51E.
  • the permeate gas or vapor exits at point 51C with the counter-current gas.
  • the exiting methane has about 90 percent of the water removed. See Table 2.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

Conception améliorée d'un dispositif de séparation à membrane à spirale. Le module amélioré (50) comporte un tuyau d'alimentation (51A) séparé en compartiments (A, B) qui sont reliés axialement à une pièce d'espacement poreuse (55) entourée d'une enveloppe membraneuse (54). Un tuyau de perméat séparé (51B) est contigu et en général parallèle au tuyau d'alimentation en fluide (51A); il est en communication fluidique avec une couche d'espacement poreuse distincte (58). Quand les membranes d'alimentation poreuses (54) sont réunies par des éléments de remplissage ayant une forme complémentaire appropriée (52A, 52B), on obtient un dispositif de séparation à membrane à spirale avec deux tuyaux placés au centre. Le module de séparation (50) à membrane comporte en outre des éléments permettant d'ajouter un perméat de fluide (gaz) de balayage à contre-courant ou à co-courant.
PCT/US1991/000620 1990-06-07 1991-01-29 Dispositif de separation a membrane a spirale, a deux tuyaux, a double flux, et a contre-courant WO1991018665A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US534,755 1990-06-07
US07/534,755 US5034126A (en) 1990-01-29 1990-06-07 Counter current dual-flow spiral wound dual-pipe membrane separation

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WO1991018665A1 true WO1991018665A1 (fr) 1991-12-12

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002238A3 (fr) * 2001-06-26 2003-08-28 Sartorius Gmbh Module spirale pour filtration tangentielle
EP2349544A1 (fr) * 2008-10-17 2011-08-03 General Electric Company Ensemble séparateur à membrane enroulée en spirale
WO2012057900A1 (fr) * 2010-10-28 2012-05-03 General Electric Company Élément d'osmose inverse multi-feuilles
CN103143259A (zh) * 2013-02-27 2013-06-12 新加坡三泰水技术有限公司 螺旋型薄膜元件及其制备方法
CN109999673A (zh) * 2019-05-08 2019-07-12 上海凯鑫分离技术股份有限公司 一种卷式膜元件

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3872014A (en) * 1974-03-11 1975-03-18 Aerojet General Co Membrane separation apparatus

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3872014A (en) * 1974-03-11 1975-03-18 Aerojet General Co Membrane separation apparatus

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003002238A3 (fr) * 2001-06-26 2003-08-28 Sartorius Gmbh Module spirale pour filtration tangentielle
EP2349544A1 (fr) * 2008-10-17 2011-08-03 General Electric Company Ensemble séparateur à membrane enroulée en spirale
WO2012057900A1 (fr) * 2010-10-28 2012-05-03 General Electric Company Élément d'osmose inverse multi-feuilles
CN103143259A (zh) * 2013-02-27 2013-06-12 新加坡三泰水技术有限公司 螺旋型薄膜元件及其制备方法
CN103143259B (zh) * 2013-02-27 2014-10-29 新加坡三泰水技术有限公司 螺旋型薄膜元件及其制备方法
CN109999673A (zh) * 2019-05-08 2019-07-12 上海凯鑫分离技术股份有限公司 一种卷式膜元件
CN109999673B (zh) * 2019-05-08 2024-02-13 上海凯鑫分离技术股份有限公司 一种卷式膜元件

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