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WO1990015848A1 - Compositions colorantes solubles dans l'eau contenant des constituants etincelants - Google Patents

Compositions colorantes solubles dans l'eau contenant des constituants etincelants Download PDF

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Publication number
WO1990015848A1
WO1990015848A1 PCT/US1989/002675 US8902675W WO9015848A1 WO 1990015848 A1 WO1990015848 A1 WO 1990015848A1 US 8902675 W US8902675 W US 8902675W WO 9015848 A1 WO9015848 A1 WO 9015848A1
Authority
WO
WIPO (PCT)
Prior art keywords
wax
composition
ciaim
water soluble
fnew
Prior art date
Application number
PCT/US1989/002675
Other languages
English (en)
Inventor
Paul M. Mandel, Jr.
Cleveland L. Hughes
Timothy N. Williams
Original Assignee
Mandel Paul M Jr
Hughes Cleveland L
Williams Timothy N
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mandel Paul M Jr, Hughes Cleveland L, Williams Timothy N filed Critical Mandel Paul M Jr
Priority to US07/834,326 priority Critical patent/US5336306A/en
Priority to PCT/US1989/002675 priority patent/WO1990015848A1/fr
Publication of WO1990015848A1 publication Critical patent/WO1990015848A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives
    • C09D5/028—Pigments; Filters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions

Definitions

  • This invention relates to a new and improved composition and process for producing coloring compositions. These have use in water soluble solid paints, poster paints, for color brushes and for roller balls, crayons, and the like.
  • the coloring compositions of this invention also contain sparkle components which are maintained as a stable and uniform solid suspension in the coloring system.
  • the present paint compositions containing such sparkle components are pleasing visually, and also tend to take on the appearance of a multi-dimension because they are usually applied in a non uniform fashion.
  • Prior art paint compositions are manufactured at comparatively high temperatures estimated at about 130°F, and produce a pairit that hardens rapidly. Consequently, heaters are generally used at various steps of the process, and this requirement makes it difficult to clean the equipment. Also, it is difficult to obtain water soluble paint compositions containing sparkle components that can be maintained as a stable and uniform suspension.
  • Water soluble paint compositions produced by prior art processes generally do not contain a smell or scent component because they are evaporated or volatized by the high processing temperature. However, if a lower processing temperature range was possible, smell components such as scents, fragrances and perfumes could be incorporated and retained in the composition.
  • a water soluble paint composition containing: water; a polymeric thickener to maintain solid components such as the color and the sparkle or glitter in a uniform and permanent suspension; a water soluble wax to thicken and harden the composition; glycerin, and the like to increase the time span of hardening to enable the mixture to flow without undue heating; and adhesive thickener; and, glitter and coloring agents.
  • the polymeric thickener may include a polyacrylic or polymeth- acrylic acid having polyfunctional groups; the polymeric acid is thickened or cured with an activator, infra.
  • a typical polymeric thickener is sold by B.F. Goodrich under the trade name of CARBOPOL.
  • Another suitable polyacrylic acid is sold as CARBCMER 941.
  • the function of the thickener is to solidify the composition as a gel near the termination of the mixing process, and this enables solids such as glitter, sparkle or color to be maintained as a uniform and permanent solid suspension.
  • thickeners included in the term 'polymeric thickener' are: nitrile latexes, styrene-butadiene latexes, polyisobutylene, acrylic latexes, rosin gum, food thickeners such as flours and starches, fumed silica, hydroxypropyl methyl cellulose, hydroxy- butyl methyl cellulose, and so forth.
  • the water soluble wax is employed to thicken and harden the composition.
  • the use of the wax offsets the cost of the more expensive adhesive thickener such as gum arabic, and also functions as an adhesive itself.
  • Typical water soluble waxes are of the microcrystalline variety, and include EMERWAX 1255 and METHOCEL.
  • Glycerin is used to enable the composition to flow with little or no application of heat and to increase the time span of hardening (to say within 48 hours).
  • the glycerin is usually employed as 99.57o U.S.P.
  • the glycerin may be replaced with sorbitol, and to a certain extent with other alcohols such as cetyl, and mixtures thereof.
  • the combination of the glycerin, wax and polymer results in a coloring composition which is liquid and pourable at a temperature in excess of about 85°F. Hence, no expensive processing equipment is required. Moreover, upon contact with air, the surface of the coloring composition will harden, and this permits subsequent handling after the processing step to facilitate pouring into molds and curing in place.
  • An activator for the polymeric thickener is used to polymerize and thereby thicken the polymer.
  • suitable catalysts or activators include triethanolamine, and other amines such as ethyl, propyl and hexyl.
  • the activator also serves as a pH buffer and to dissolve the preservative, if one is employed.
  • the polymeric thickener may be activated by hea , etc.
  • An adhesive thickener such as gum arabic or accacia gum is used to thicken the composition and act as an adhesive or binder.
  • Other adhesive thickeners such as tragacinth gum, and plant mucilages are also suitable.
  • polymeric thickener wax and adhesive thickener have similar properties, they may be used somewhat inter ⁇ changeably. Their function is to maintain the color and glitter in a permanent and solid suspension.
  • Magnesium stearate may be used to increase the hardening time and to function as a plasticizer and/or dispersing agent for the composition following processing, and also to substitute in part for the gum arabic.
  • Equivalent compounds are also available, such as Ca stearate, Na stearate, di-butyl phthalate, di-isobutyl phthalate, dioctyl adipate, etc.
  • Colors which may be employed are standard F.D. & C. colors, and non F.D. &. C colors, both water soluble, and water insoluble.
  • sparkle or glitter ingredients include those which are light reflective; light absorptive; light absorptive and which transmit a single different color; and, light absorptive and which transmit two or more different colors.
  • Suitable sparkle or glitter ingredients are sold under the generic names of TIMIRON, BIVIRON, C0L0R0NA, DICHRONA, and the like and contain varying amounts of mica and TiO ⁇ .
  • Other sparkle or glitter ingredients may include Cr(OH) « and mica, castor oil and mica, iron oxides and mica, bismuth oxychlorides , etc. These materials are sold by Mearl Products, Rona and Mallingkrodt. Aluminum and other metal particles also may be used.
  • preservatives or stabilizers when used, they may include: imidazolidienyl urea (0.25% - 0.35%); mehtyl or propyl paraben (0.757o - 1.0%, and 0.25% - 0.35%, respectively); DOWOCIL 200 (0.1% - 0.5%); and, so forth.
  • Bactericides , slimicides, etc. also may be used in addition to the preservatives or stabilizers.
  • compositions can be removed from the processing equipment and pouring equipment simply by washing with water. This enables the equipment to be changed over to a different coloring formulation without undue difficulty.
  • Polymeric thickener 0% - 0.5% ,05% - 0.5%
  • Glycerin and/or long chain alcohols 0% - 10% 1% 10%
  • Adhesive thickener 0% - 25% 8% - 25%
  • a preferred composition is, as follows: Polyacrylic acid (CARBOMER 941): 0.12%: Water soluble microcrystalline wax (EMERWAX 1255): 2%; Glycerin (U.S.P. 99.5%): 6%; amine activator (triethanolamine) : 0.17o; Adhesive thickener (gum arabic) : 12%,; Hardener (Mg stearate): 0.3%; Color: 4%; Glitter: 24%; preservative: 0.467 o ; and, Water (deionized): 517 0 , or balance.
  • Another suitable composition is, as follows: Polyacrylic acid; 0.15%; Wax: 2.8%;Glycerin: 7.25%; activator: 0.15%; Adhesive thickener: 10%; Hardener: 0.3%; Color: 4.5%; Glitter: 29.5%; Preservative: 0. 357o; and, Water: 45%, or balance.
  • Another suitable composition is, as follows: Polymeric thickener: 0.15%; Wax: 2%; Glycerin: 8.75%; Activator: 0.15%; Adhesive: 10.25%; Hardener: 0.35%; Color: 3%; Sparkle: 21%; Preservative: 0.35%; and, Water: 547o, or balance.
  • a typical composition is, as follows: Water: 727 D ; CARBOMER 941: 0.76%; EMERWAX 1255: 4%; Glycerin: 8%; Activator: 0.76%; Preservative: 0.15% - 0.35%; Color: 3%; and, Glitter: 12%,
  • a suitable crayon composition is, as follows:
  • a preferred crayon composition is, as follows: Water soluble wax (EMERWAX 1255): 54.5%; Water soluble wax(MULTIWAX W 445): 5.9%; Polymeric thickener(CAB-0-SIL H55) silica gel: 1.2%; Polymeric thickener (non-ionic, water soluble, cellulose ethers: METHOCEL - Dow Chemical) 1.2%; Color: 6.0%; Sparkle: 30%; and, Preservative: 1.2%.
  • This composition as in the other compositions, has a processing temperature which is in the same range. Also, following application to a surface, such as paper, the sparkle appearance can be enhanced simply by rubbing.
  • a suitable process for their manufacture includes: 1. adding CARBOMER and water to a high speed shear blender and mixing for about 10 minutes to obtain a uniform blend; 2. the blend is heated to about 130°F for about 20 minutes to hour with added glycerin and EMERWAX. This heating will melt the wax, and blending is continued for an additional hour to 40 minutes to obtain a blending time of about 1 hour for the mixture of CARBOMER, water, glycering and EMERWAX; 3. the balance of the ingredients (except the activator) are added, and the blending is continued at a reduced temperature of about 115°F - 120°F for about hour; 4. the activator is then added last and the blending is continued for about 15 minutes; 5.
  • the ingredients are poured to a machine filler at about 90°F - 115°F, and poured and then hardened in situ for up to about 48 hours.
  • a similar procedure is followed in the case of poster paints, color brushes and roller balls.
  • the ingredients are heated and blended for a sufficient time to obtain a uniform melt, the components being added in the same order as for color paints, where appropriate. If it is desired to incorporate scents, perfumes, flavors, etc., into the composition, these may be added in step 3. These can include licorice, chocolate, lemon, lime, fragrances, etc.
  • water insoluble components may be used and still produce a phase compatable compound. This is obtained by linking components such as water insoluble thickeners, waxes, colors and adhesives to the water soluble components using dispersing agents such as quaternary ammonium compounds, polysorbates , polyethylene glycols (PEG compounds), etc. This technique enables compounds such as stearic acid and cetyl alcohol to be substituted in place of or used in conjunction with the microcrystalline wax.
  • dispersing agents such as quaternary ammonium compounds, polysorbates , polyethylene glycols (PEG compounds), etc.
  • waxes may be employed provided they are either in an emulsion form, or if they are emulsifyable.
  • these waxes are non toxic, such as cosmetic and/or petroleum waxes, and these include paraffin, polyethylene, polymerized and microcrystalline waxes.
  • the most preferred waxes are both non toxic and edible, and these waxes are usually derived from edible products; examples include beeswax, candelilla, carnauba (Brazil), vegetable waxes, etc.
  • typical waxes which are usable include water insoluble waxes which can be used with linking compounds to form phase stable emulsions such as bayberry wax and bees waxes, and substit ⁇ utes for these myricyl esters such as palmitates, stearates and oleates; synthetic waxes; ceresin, otherwise known as earth wax, and which may contain paraffin, and substitutes such as mineral and ozacerite waxes; parffin waxes; polymer waxes such as low molecular weight polypropylene and polyethylenes; spermaceti wax (cetyl palmitate); candelilla wax; lanolin and lanesterol waxes; palm wax; carnauba and ouricury waxes; rice bean wax; vegetable waxes; lignit (montan) waxes; Japan wax, and mixtures or blends of these.
  • water insoluble waxes which can be used with linking compounds to form phase stable emulsions such as bayberry wax and bee
  • waxes may be purchased as wax emulsions, i.e., the wax has been converted, by the manufacturer or processor, to an emulsion by blending with one or more liners causing them to emulsify. If the wax is not purchased as an emulsion, it must be converted to an emulsion by the purchaser by blending the wax with one or more suitable linkers.
  • linkers and/or emulsifiers which can be used to produce a wax emulsion include: alcohol ethoxylates; PEG esters, monostearates; phosphate esters; polysorbate esters; monoglycerides; polyglyceryl esters; sorbitol esters, etc.
  • the linkers or emulsifiers should be non toxic, and preferably edible, such as polysorbates, glycerol and sorbitol esters, etc.
  • Adhesives which are suitable are those which are non toxic, and which do not cure in air, in the case of water colors or crayons.
  • the adhesives employed in this invention are transparent or transluscent, and this enables less color and glitter to be used in the composition compared to those compositions which employ opaque adhesives.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Des compositions colorantes solubles dans l'eau qui contiennent une suspension stable et uniforme de constituants colorés et étincelants ou scintillants. Le procédé de fabrication des compositions colorantes utilise un domaine de températures plus bas que celui de l'état de la technique; ceci réduit le besoin de chauffer les équipements et en facilite le nettoyage.
PCT/US1989/002675 1987-03-16 1989-06-19 Compositions colorantes solubles dans l'eau contenant des constituants etincelants WO1990015848A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US07/834,326 US5336306A (en) 1987-03-16 1989-06-19 Water soluble coloring compositions containing sparkle components
PCT/US1989/002675 WO1990015848A1 (fr) 1989-06-19 1989-06-19 Compositions colorantes solubles dans l'eau contenant des constituants etincelants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1989/002675 WO1990015848A1 (fr) 1989-06-19 1989-06-19 Compositions colorantes solubles dans l'eau contenant des constituants etincelants

Publications (1)

Publication Number Publication Date
WO1990015848A1 true WO1990015848A1 (fr) 1990-12-27

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Application Number Title Priority Date Filing Date
PCT/US1989/002675 WO1990015848A1 (fr) 1987-03-16 1989-06-19 Compositions colorantes solubles dans l'eau contenant des constituants etincelants

Country Status (1)

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WO (1) WO1990015848A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0746589A4 (fr) * 1992-06-02 1996-01-19 Gillette Co Encre effa able
EP1840173A1 (fr) * 2006-03-31 2007-10-03 Imperial Chemical Industries PLC Composition de peinture aqueuse solide comprenant un sel d'un acide gras

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3864294A (en) * 1972-11-02 1975-02-04 Chesebrough Ponds Gelled coating compositions and method of making same
US3993492A (en) * 1975-04-14 1976-11-23 Otis Bill Woolly Water soluble transfer coating material and articles incorporating same
JPS5379626A (en) * 1976-12-24 1978-07-14 Orientaru Sangiyou Kk Method of producing aqueous soluble solid bar drawing member
US4221593A (en) * 1977-09-12 1980-09-09 Mitsuboshi Printing Ink Co., Ltd. Golden-colored printing ink
US4229334A (en) * 1977-12-22 1980-10-21 Koh-I-Noor Hardtmuth, Oborovy Podnik Plastic modified writing compositions
US4256494A (en) * 1978-10-20 1981-03-17 Sakura Color Products Corp. Erasable ink composition for writing on an impervious surface
JPS5659879A (en) * 1979-10-20 1981-05-23 Pentel Kk Water-soluble solid drawing material
US4348234A (en) * 1979-03-20 1982-09-07 Ciba-Geigy Corporation Coating compositions for the production of a recording material
EP0082497A1 (fr) * 1981-12-19 1983-06-29 Herberts Gesellschaft mit beschränkter Haftung Composition de revêtement aqueuse, article revêtu de cell-ci et utilisation de pigments d'interférence pour celle-ci
DE3321953A1 (de) * 1983-06-18 1984-12-20 Wanfried-Druck Kalden Gmbh, 3442 Wanfried Verfahren zum bronzieren von mit unterdruckfarbe behandelter farbdrucke
JPS6086177A (ja) * 1983-10-19 1985-05-15 Nippon Oil & Fats Co Ltd メタリツク塗料組成物
US4565581A (en) * 1981-12-24 1986-01-21 Merck Patent Gesellschaft Mit Beschrankter Haftung Nacreous pigments having improved light fastness, their preparation and use

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3864294A (en) * 1972-11-02 1975-02-04 Chesebrough Ponds Gelled coating compositions and method of making same
US3993492A (en) * 1975-04-14 1976-11-23 Otis Bill Woolly Water soluble transfer coating material and articles incorporating same
JPS5379626A (en) * 1976-12-24 1978-07-14 Orientaru Sangiyou Kk Method of producing aqueous soluble solid bar drawing member
US4221593A (en) * 1977-09-12 1980-09-09 Mitsuboshi Printing Ink Co., Ltd. Golden-colored printing ink
US4229334A (en) * 1977-12-22 1980-10-21 Koh-I-Noor Hardtmuth, Oborovy Podnik Plastic modified writing compositions
US4256494A (en) * 1978-10-20 1981-03-17 Sakura Color Products Corp. Erasable ink composition for writing on an impervious surface
US4348234A (en) * 1979-03-20 1982-09-07 Ciba-Geigy Corporation Coating compositions for the production of a recording material
JPS5659879A (en) * 1979-10-20 1981-05-23 Pentel Kk Water-soluble solid drawing material
EP0082497A1 (fr) * 1981-12-19 1983-06-29 Herberts Gesellschaft mit beschränkter Haftung Composition de revêtement aqueuse, article revêtu de cell-ci et utilisation de pigments d'interférence pour celle-ci
US4565581A (en) * 1981-12-24 1986-01-21 Merck Patent Gesellschaft Mit Beschrankter Haftung Nacreous pigments having improved light fastness, their preparation and use
DE3321953A1 (de) * 1983-06-18 1984-12-20 Wanfried-Druck Kalden Gmbh, 3442 Wanfried Verfahren zum bronzieren von mit unterdruckfarbe behandelter farbdrucke
JPS6086177A (ja) * 1983-10-19 1985-05-15 Nippon Oil & Fats Co Ltd メタリツク塗料組成物

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0746589A4 (fr) * 1992-06-02 1996-01-19 Gillette Co Encre effa able
EP1840173A1 (fr) * 2006-03-31 2007-10-03 Imperial Chemical Industries PLC Composition de peinture aqueuse solide comprenant un sel d'un acide gras
WO2007112869A1 (fr) * 2006-03-31 2007-10-11 Imperial Chemical Industries Limited Composition de peinture solide aqueuse comprenant un sel d'un acide gras

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