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WO1990011343A1 - Compositions auto-moussantes a base d'huile et procede de production et d'utilisation - Google Patents

Compositions auto-moussantes a base d'huile et procede de production et d'utilisation Download PDF

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Publication number
WO1990011343A1
WO1990011343A1 PCT/US1990/001471 US9001471W WO9011343A1 WO 1990011343 A1 WO1990011343 A1 WO 1990011343A1 US 9001471 W US9001471 W US 9001471W WO 9011343 A1 WO9011343 A1 WO 9011343A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
foam
weight
composition
foaming
Prior art date
Application number
PCT/US1990/001471
Other languages
English (en)
Inventor
Mohan Vishnupad
Jose E. Ramirez
Original Assignee
Imaginative Research Associates, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/326,377 external-priority patent/US5186857A/en
Application filed by Imaginative Research Associates, Inc. filed Critical Imaginative Research Associates, Inc.
Publication of WO1990011343A1 publication Critical patent/WO1990011343A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00—Medicinal preparations characterised by special physical form
    • A61K9/10—Dispersions; Emulsions
    • A61K9/12—Aerosols; Foams
    • A61K9/122—Foams; Dry foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • A61Q9/02—Shaving preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • A61Q9/04—Depilatories
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons

Definitions

  • Liquid compositions containing oils and/or soluble waxes are well known for a variety of uses, such as cosmetic lotions, medicinal lotions, furniture polishes, cleansers for tile, glass, metal, etc. Some such compositions contain soaps and/or detergents to enable them to entrap air and produce a foam or lather during use. However if high levels of oil or oil/wax mixture are added to such aqueous compositions, the foam- or lather-producing properties of the compositions are substantially reduced. Therefore aqueous liquid compositions, capable of being poured from a non-pressurized container to form a foam-producing coating, have not been available with oil or oil/wax contents greater than about 4% or 5% by weight. Such low contents are not satisfactory where the purpose of the product is to apply coatings which are high in oil or oil/wax content.
  • Aerosol compositions containing oil and/or oil/wax ingredients and water are also well known but such compositions must be dispensed as a foam from a pressurized container and cannot be contained as a self-foaming lotion-like liquid in a non-pressurized container.
  • U.S. Patent 4,726,944 to provide self-foaming or post foaming aqueous liquid detergent compositions which are capable of being poured from a non-pressurized container and rubbed into the hair as a post-foaming shampoo.
  • Such compositions contain mixtures of anionic, amphoteric and non-ionic surfactants; water-soluble gum and a volatile hydrocarbon, and foaming occurs by evaporation of the latter as the composition is applied to the hair.
  • U.S. Patent 4,744,979 relates to similar post-foaming shaving gel compositions containing an aqueous soap solution and a mixture of surface active agents comprising amine oxides and alkanolamides.
  • lotion-like post-foaming compositions of the aforementioned types intended for the cleansing of wet or dry surfaces that contain no oil or small amounts thereof are capable of being poured as clear liquid solutions from a non-pressurized container, they function well for their intended purposes only at temperatures close to room temperature, 70-80°F. It has not been possible heretofore to produce lotion-like post-foaming compositions of these types which are detergent-based and are used for cleansing which contain large amounts of oil or oil/wax mixture for purposes of applying oil or oil/wax coatings to the skin or other wet or dry surfaces for cosmetic, medicinal, aesthetic, protective, household, automotive or other purposes. In addition, such lotion-like post-foaming compositions show a markedly increased solubility of the volatile hydrocarbon component. This property allows the non-pressurized containers to be opened at much higher temperatures, i.e., 110-120°F.
  • the present invention relates to the discovery of formulations for aqueous, lotion-like compositions which contain large amounts of dispersed oil or oil/wax mixture, greater than about 5% by weight, a volatile organic foam-producing liquid and a surfactant or detergent which increases the solubility of the foam-producing liquid in the oil or oil/wax mixture, optional additional foam suppressing agents depending on the surfactant or surfactants used, the surfactant or detergent comprising the discontinuous phase of the composition, the continuous phase comprising water.
  • composition can be poured onto a preferably wet surface and spread as a creamy lotion coating which forms a uniform fine foam within a few seconds under ambient exposure, due to the evaporation of the volatile organic foam-producing liquid, to leave an oil or oil/wax foam residue which can be rubbed over the skin or other surface for cosmetic, medicinal, aesthetic, protective, cleansing or other purposes.
  • the presence of the oil or oil/wax on the skin during the foaming action permits the oil or oil/wax mixture, and any medicaments, emollients or other additives dissolved therein or present in the water phase to penetrate the skin and displace moisture, moisture-soluble dirt skin oils or infected matter which may be withdrawn from the skin during the foaming process, for increased effectiveness in softening and treating the skin.
  • compositions of the present invention are aqueous emulsions including pseudo emulsions and other aqueous dispersions which can be agitated within the container, prior to use, to form lotion-like liquids containing oil or oil/wax mixture dispersed within the continuous water phase.
  • compositions contain at least about 5% by weight of one or more oils, alone or in combination with one or more waxes soluble in or compatible with said oil(s), at least about 5% by weight of at least one suitable surface active agent or detergent, at least about 5% by weight of at least one volatile organic foam-producing liquid, optionally one or more foam-suppressing compounds in the amount of 2-15% by weight, and the remainder, generally less than about 60%, water.
  • the ingredient of the present compositions that enables the presence of large amounts of oil or oil/wax mixtures is the surface active agent or detergent.
  • This material preferably is present in an amount within the range of from about 5% to about 20% by weight, and preferably from 10% to about 15% by weight, to enable the incorporation of from about 5% to about 60% by weight of the oil or oil/wax mixture, preferably from 20% to about 35% by weight of said oil or oil/wax mixture.
  • compositions of the present compositions from the standpoint of increasing the solubility of the volatile hydrocarbon are both the oil and surface active agent. Their combination enables the incorporation of about 15% volatile hydrocarbons, increasing their solubility to the point that the compositions of the invention can be opened to the atmosphere at temperatures much higher than room temperature.
  • foam-supressing compounds also increases the solubility of the volatile hydrocarbon component.
  • Some surfactants by their nature do not need the addition of foam-suppressing agents, while other surfactants are not suitable for commercial utilization without them.
  • the most preferred mild surfactants that do not need foam suppressing agents are anionic materials such as sodium methyl cocoyl taurate (sodium salts of N-methyl taurine-coconut oil amides, referred to herein as SMCT) ; disodium cocamido monoisopropanol amide sulfosuccinate (disodium salts of sulfo-2-cocamide-l-methyl ethyl esters of butanedioic acid, referred to herein as DCMS) ; sodium lauryl sulfoacetate (sodium salt of sulfo-1-dodecyl ester of acetic acid, referred to herein as SLSA) ; dioctyl sodium sulfosuccinate (sodium salt of the diester of 2-ethylhexyl alcohol and sulfosuccinic acid, referred to herein as DSS) , and amphoteric materials such as coca
  • foam-suppressing compounds preferably in amounts between about 3% and 7% by weight where necessary, in combination with highly foaming surfactants allows the use of a greater variety of surfactants which, per se, are not useful for the preparation of suitable commercial products.
  • Combinations of this type can be obtained by adding alcohols, alkoxy alcohols, etc. to surfactants like sodium lauryl sulfate, referred to herein as SLS, ammonium lauryl ether sulfate, referred to herein as ALS, and many other surfactants generally of the anionic type.
  • a similar foam-controlling effect can be obtained by blending high foaming surfactants, generally of the anionic type, with low foaming surfactants.
  • the preferred low foaming surfactants used for this foam controlling effect are generally of the non-ionic and the amphoteric type. Typical of these are nonoxinol-9 (nonionic) and cocampho-carboxyl glycinate (amphoteric) , referred to herein as CCG.
  • Suitable oils for use in the compositions of the present invention include all of the conventional water-insoluble liquid or semi-solid mineral (including mixtures of petroleum derived hydrocarbons containing 10 or more carbon atoms) , vegetable, synthetic and animal oils, including fatty acid esters, lanolin, etc.
  • the particular oils selected for a particular composition will depend upon its desired function and/or its ability to dissolve additives such as fragrances, waxes, medicaments, etc.
  • Suitable waxes include semi-solid and solid vegetable, mineral, animal and synthetic waxes, present in amounts which are soluble in the oils present to form liquid oil/wax mixtures.
  • the preferred volatile organic foam-producing liquids are those having a vapor pressure from about 4 to 14 p.s.i.g. at temperatures between about 90° - 100°F, most preferably hydrocarbons having 5 or 6 carbon atoms such as isopentane, pentane and hexane.
  • the volatile organic liquid is present in an amount between about 5% and 15% by weight, preferably between 7% and 12% by weight.
  • the preferred foam suppressing agents are alcohols, alkoxy alcohols, low foaming surfactants and any other suitable compounds that help prevent the compositions of the invention from self-dispensing at temperatures well in excess of room temperature.
  • the final essential ingredient of the present compositions is water, which is present as an oil-in-water emulsion or dispersion to form the continuous phase of the self-foaming composition.
  • water is present in an amount between about 25% and 60% by weight of the composition, most preferably between about 35% and 45% by weight.
  • compositions thereof are produced by adding the oils or oil/wax mixtures to a suitable container, adding the surface active agents or detergents thereto and homogenizing at a suitable elevated temperature until the detergents are thoroughly dispersed in the oil or oil/wax phase, water being added while homogenizing.
  • the mixture is cooled to room temperature or lower and the volatile organic foam-producing liquid, cooled below its boiling point, is added while the composition is stirred with a mixer.
  • any additives are initially incorporated with the oils or oil/wax mixtures in the first step.
  • Example 14 Ingredients Wt%
  • Example 17 Ingredients Wt%
  • Example 24 Ingredients Wt%
  • Example 28 Ingredients WM
  • compositions being compared are identical in every . respect except by substitution of identical amounts of total surfactant.
  • the compositions of Example 1, 3, 7, 17 and 24 were compared with the non-functional compositions of examples 27, 28, 29, 30 and 31.
  • Each of the compositions was placed in an individual 100ml graduated cylinder, 10 ml of water was added to lOg of each composition, and the cylinder was closed and shaken vigorously ten times.
  • the initial and final volumes of the foam were recorded as 1 (0 ml increase), 3 (27 ml increase), 7 (0 ml increase), 17 (0 ml increase) , 24 (24 ml increase) , 27 (55 ml increase) , 28 (59 ml increase) , 29 (8 ml increase) , 30 (5 ml increase) and 31 (28 ml increase) .
  • the preferred compositions, Examples 1, 7 and 17, showed no tendency to foam in the sealed container under agitation, establishing the solubilizing effect on the volatile organic liquid and its suppression against escape and foaming within the container, whereby the compositions have excellent post-foaming properties after being poured onto the wet skin and scrubbed for cleansing action.
  • the compositions of Example 3 an 24 foamed somewhat but still solublized the volatile organic liquid within the oil to a sufficient extent that the composition has excellent post-foaming properties similar to those of Examples 1, 7 and 17.
  • compositions of examples 1, 3, 7, 17 and 24 when opened at temperatures much higher than room temperature, e.g. from 110 to 120°F, will not self-dispense.
  • the compositions of Examples 27 and 28 foamed excessively and self-dispensed from the container even at room temperature, although they do post-foam because the volatile liquid hydrocarbon is solublized somewhat in the oil phase but only to an unsatisfactory extent.
  • compositions of Examples 29, 30 and 31 while they showed little or no tendency to foam when agitated in the sealed container, they were non-functional when poured onto the skin and spread in the same manner as the other compositions since they do not self-foam or post-foam to any useful extent.
  • foam suppressing components in combination with highly foaming surfactants allows the preparation of suitable commercial products.
  • Preparations of this type can be obtained by adding alcohols, alkoxy alcohols, etc. to the highly foaming surfactant of Examples 27.
  • the compositions of Examples 20 and 21 show limited foam increase in the sealed container under agitation, i.e., composition 20 (23 ml increase) and composition 21 (15 ml increase) . This establishes the solubilizing effect on the volatile organic liquid and its suppression against escape and foaming within the container.
  • a similar foam-controlling effect can be obtained by blending high foaming surfactants generally of the anionic type with low foaming surfactants generally the non-ionic and amphoteric types.
  • the surfactants of the unsatisfactory compositions of Examples 29 and 31 are modified to prepare suitable commercial products by adding the low foaming surfactants of the compositions to provide additional foam-controlling effect.
  • the foaming values of composition 22 (23 ml increase) and compositions 23 (25 ml increase) illustrate the effect of the low foaming surfactants on compositions containing SLS which, by its chemical nature, will foam uncontrollably when used alone and will produce compositions which self-dispense at room temperature.
  • compositions of Examples 20, 21, 22 and 23 contain foam suppressants and demonstrate controlled foaming and will not self-dispense at temperatures from 110-120°F. All these compositions are functional when poured onto the skin and spread in the same manner as the compositions of examples 1, 3, 7, 17 and 24 since they do foam and post-foam to a useful extent.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dermatology (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des compositions liquides semblables à des lotions d'émulsion aqueuse d'huile dans de l'eau contenant de grandes quantités d'huile ou des mélanges d'huile et de cire, un liquide produisant une mousse organique volatile, et un mélange d'agent(s) de suppression de la mousse et d'agent(s) tensio-actif(s) qui augmentent la solubilité du liquide produisant la mousse dans l'huile ou dans le mélange huile/cire. Les compositions de l'invention sont des émulsions qui ne moussent pas ou ne sortent pas d'un récipient non pressurisé à des températures allant jusqu'à 120°F et peuvent être versées sur une surface mouillée à des temperatures ambiantes et étalées pour former une fine couche qui moussera ultérieurement dans des conditions ambiantes pour laisser un résidu d'huile ou de mélange huile/cire pour des usages cosmétique, médical, esthétique, protecteur ou autres. L'invention concerne également les procédés de production et d'utilisation desdites émulsions.
PCT/US1990/001471 1989-03-21 1990-03-19 Compositions auto-moussantes a base d'huile et procede de production et d'utilisation WO1990011343A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US326,377 1989-03-21
US07/326,377 US5186857A (en) 1988-11-14 1989-03-21 Self-foaming oil compositions and process for making and using same

Publications (1)

Publication Number Publication Date
WO1990011343A1 true WO1990011343A1 (fr) 1990-10-04

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995013349A1 (fr) * 1993-11-10 1995-05-18 Dowbrands Inc. Produit de nettoyage automoussant multifonctionnel
WO1997000934A1 (fr) * 1995-06-23 1997-01-09 R & C Products Pty. Limited Compositions nettoyantes sous forme d'aerosols
DE19957739A1 (de) * 1999-12-01 2001-06-28 Henkel Ecolab Gmbh & Co Ohg Handwaschlotion für wiederbefüllbare Schaumerzeugungsvorrichtung
WO2004106477A1 (fr) * 2003-05-27 2004-12-09 Unilever N.V. Composition de nettoyage effervescente
EP0883680B2 (fr) † 1996-01-04 2005-12-28 S.C. Johnson & Son, Inc. Compositions nettoyantes a microemulsion auto-moussante
US7012056B2 (en) * 2003-04-17 2006-03-14 Unilever Home & Personal Care Usa Effervescent cleaning composition comprising surfactant, builder, and dissolved gas
WO2009083895A1 (fr) * 2007-12-26 2009-07-09 The Procter & Gamble Company Compositions d'hygiène corporelle contenant des agents de conditionnement de la peau

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2176423A (en) * 1936-01-13 1939-10-17 American Cyanamid & Chem Corp Esters of sulphodicarboxylic acids
US2995521A (en) * 1956-05-24 1961-08-08 Estignard-Bluard Jean Jacques Foam producing compositions
US3541581A (en) * 1967-11-13 1970-11-17 Johnson & Son Inc S C Package containing a post-foaming gel
US3912666A (en) * 1969-02-06 1975-10-14 Spitzer Joseph G Emulsified propellant compositions for foamed structures such as applicator pads, and process
US3941722A (en) * 1974-05-06 1976-03-02 Chattem Drug & Chemical Company Bath beads containing allantoin
US4048123A (en) * 1973-08-17 1977-09-13 Barnes-Hind Pharmaceuticals, Inc. Abradant skin cleanser
US4405489A (en) * 1981-01-15 1983-09-20 Carter-Wallace, Inc. Production of a post-foaming gel and system therefor
US4490355A (en) * 1983-03-14 1984-12-25 Miranol Chemical Company, Inc. Betaine based cosmetic formulations
US4554098A (en) * 1982-02-19 1985-11-19 Colgate-Palmolive Company Mild liquid detergent compositions
US4606913A (en) * 1978-09-25 1986-08-19 Lever Brothers Company High internal phase emulsions
US4626529A (en) * 1981-10-23 1986-12-02 L'oreal Oily compositions comprising a dermatological active principle, intended for the treatment of the scalp or skin
US4654213A (en) * 1985-09-11 1987-03-31 Cheesebrough-Pond's Inc. Novel anti-microbial systems containing the magnesium sulfate adduct of 2,2'-dithiobis-pyridine-1,1'-dioxide and a water soluble zinc salt
US4708813A (en) * 1985-08-14 1987-11-24 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits
US4769169A (en) * 1985-09-10 1988-09-06 Amphoterics International Limited Amphoteric surfactants for use in antimicrobial cleaning compositions

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2176423A (en) * 1936-01-13 1939-10-17 American Cyanamid & Chem Corp Esters of sulphodicarboxylic acids
US2995521A (en) * 1956-05-24 1961-08-08 Estignard-Bluard Jean Jacques Foam producing compositions
US3541581A (en) * 1967-11-13 1970-11-17 Johnson & Son Inc S C Package containing a post-foaming gel
US3912666A (en) * 1969-02-06 1975-10-14 Spitzer Joseph G Emulsified propellant compositions for foamed structures such as applicator pads, and process
US4048123A (en) * 1973-08-17 1977-09-13 Barnes-Hind Pharmaceuticals, Inc. Abradant skin cleanser
US3941722A (en) * 1974-05-06 1976-03-02 Chattem Drug & Chemical Company Bath beads containing allantoin
US4606913A (en) * 1978-09-25 1986-08-19 Lever Brothers Company High internal phase emulsions
US4405489A (en) * 1981-01-15 1983-09-20 Carter-Wallace, Inc. Production of a post-foaming gel and system therefor
US4626529A (en) * 1981-10-23 1986-12-02 L'oreal Oily compositions comprising a dermatological active principle, intended for the treatment of the scalp or skin
US4554098A (en) * 1982-02-19 1985-11-19 Colgate-Palmolive Company Mild liquid detergent compositions
US4490355A (en) * 1983-03-14 1984-12-25 Miranol Chemical Company, Inc. Betaine based cosmetic formulations
US4708813A (en) * 1985-08-14 1987-11-24 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits
US4769169A (en) * 1985-09-10 1988-09-06 Amphoterics International Limited Amphoteric surfactants for use in antimicrobial cleaning compositions
US4654213A (en) * 1985-09-11 1987-03-31 Cheesebrough-Pond's Inc. Novel anti-microbial systems containing the magnesium sulfate adduct of 2,2'-dithiobis-pyridine-1,1'-dioxide and a water soluble zinc salt

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995013349A1 (fr) * 1993-11-10 1995-05-18 Dowbrands Inc. Produit de nettoyage automoussant multifonctionnel
WO1997000934A1 (fr) * 1995-06-23 1997-01-09 R & C Products Pty. Limited Compositions nettoyantes sous forme d'aerosols
AU699687B2 (en) * 1995-06-23 1998-12-10 Reckitt Benckiser (Australia) Pty Limited Aerosol cleaning compositions
US6150318A (en) * 1995-06-23 2000-11-21 Reckitt Benckiser Australia Limited Aerosol cleaning compositions
EP0883680B2 (fr) † 1996-01-04 2005-12-28 S.C. Johnson & Son, Inc. Compositions nettoyantes a microemulsion auto-moussante
DE19957739A1 (de) * 1999-12-01 2001-06-28 Henkel Ecolab Gmbh & Co Ohg Handwaschlotion für wiederbefüllbare Schaumerzeugungsvorrichtung
US7012056B2 (en) * 2003-04-17 2006-03-14 Unilever Home & Personal Care Usa Effervescent cleaning composition comprising surfactant, builder, and dissolved gas
WO2004106477A1 (fr) * 2003-05-27 2004-12-09 Unilever N.V. Composition de nettoyage effervescente
US6933266B2 (en) * 2003-05-27 2005-08-23 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Effervescent cleaning composition for use in fabric washing
WO2009083895A1 (fr) * 2007-12-26 2009-07-09 The Procter & Gamble Company Compositions d'hygiène corporelle contenant des agents de conditionnement de la peau

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