WO1987002052A1 - Produit de nettoyage sous forme de pastille - Google Patents
Produit de nettoyage sous forme de pastille Download PDFInfo
- Publication number
- WO1987002052A1 WO1987002052A1 PCT/EP1986/000552 EP8600552W WO8702052A1 WO 1987002052 A1 WO1987002052 A1 WO 1987002052A1 EP 8600552 W EP8600552 W EP 8600552W WO 8702052 A1 WO8702052 A1 WO 8702052A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tablet
- weight
- mixture
- detergent
- acid
- Prior art date
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 14
- 239000003826 tablet Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000012141 concentrate Substances 0.000 claims abstract description 13
- 238000005406 washing Methods 0.000 claims abstract description 13
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 12
- 150000007524 organic acids Chemical class 0.000 claims abstract description 12
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 239000011975 tartaric acid Substances 0.000 claims abstract description 8
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 239000007938 effervescent tablet Substances 0.000 claims abstract description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 3
- 239000003599 detergent Substances 0.000 claims description 33
- 239000012459 cleaning agent Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 235000019359 magnesium stearate Nutrition 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- 229940075614 colloidal silicon dioxide Drugs 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 150000001447 alkali salts Chemical class 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000011872 intimate mixture Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920000388 Polyphosphate Polymers 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000001205 polyphosphate Substances 0.000 description 3
- 235000011176 polyphosphates Nutrition 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000271 synthetic detergent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZTGKHKPZSMMHNM-UHFFFAOYSA-N 3-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical class OS(=O)(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1S(O)(=O)=O ZTGKHKPZSMMHNM-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- MSJMDZAOKORVFC-SEPHDYHBSA-L disodium fumarate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C\C([O-])=O MSJMDZAOKORVFC-SEPHDYHBSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910001410 inorganic ion Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0052—Gas evolving or heat producing compositions
Definitions
- the present invention relates to a novel washing and cleaning agent which is in the form of an effervescent tablet which can be added to aqueous cleaning and washing liquids.
- Powdery cleaning agents are usually very voluminous, which means that more space is required for storage in retail and in the household. Even if the package is already half empty, it usually takes up the same amount of space as the full package. Even with the most modern detergents in powder form, there is some caking and clumping of the powdery filling compound towards the end of the use-up period of a pack. In the case of liquid agents, the pouring and spraying openings frequently stick together.
- washing and cleaning agent is in the form of a specially developed effervescent tablet with a defined content of the cleaning and washing agent concentrate.
- composition of such a tablet according to the invention is as follows:
- Silicon dioxide q.s.
- the agent advantageously consists in that hydroxypolycarboxylic acids, in particular citric acid and tartaric acid or monoalkali salts of unsaturated C 4 -C 6 dicarboxylic acids, alone or in a mixture, are used as the solid organic acid (s).
- hydroxypolycarboxylic acids in particular citric acid and tartaric acid or monoalkali salts of unsaturated C 4 -C 6 dicarboxylic acids, alone or in a mixture, are used as the solid organic acid (s).
- Another advantageous embodiment of the agent is that a mixture of two parts by weight of citric acid and three parts by weight of tartaric acid is used as a mixture of solid hydroxypolycarboxylic acids.
- the agent advantageously consists in that sodium monofumarate is used as the alkali salt of an unsaturated C 4 -C 6 dicarboxylic acid. It is advantageously provided that polyvinylpyrrolidone is used as the binder.
- Magnesium stearate is advantageously used as a lubricant.
- the agent consists of a tablet of the following composition (in% by weight), namely:
- An advantageous method for producing such a tablet-type detergent and cleaning agent is that a mixture of detergent concentrate, sodium hydrogen carbonate and the organic acid (s) is produced in the required weight ratio and the mixture obtained is mixed with an alcoholic solution of the binder and kneaded into a tablet mass, which is granulated by sieving, dried and sieved again, after which the lubricant and the additional flow regulating agent are added and the granules obtained are tabletted in a conventional tablet press.
- the tablet-shaped detergent and cleaning agent can advantageously be used as a cleaning additive for windscreen washer systems for motor vehicles. According to a further advantageous use of the tablet-shaped detergent and cleaning agent, it is intended for room maintenance and as a detergent.
- the process for producing the tablet according to the invention corresponds to a conventional tabletting process which is based on the special constituents of the tablet according to the invention.
- a tablet according to the invention proves to be particularly suitable for dosing cleaning additives for, for example, windshield washer systems in motor vehicles, but is in principle also suitable as a dosing form for cleaning agents and detergents in industry and household, for example for dosing an agent for room and furniture care or even as a new type Washing machine accessory.
- the tablets of the invention are packaged and stored under dry conditions.
- a blister pack such as from the
- a push-through pack of this type generally consists of an aluminum foil / plastic blister foil laminate which is glued. The required number of the plates formed is arranged in a sales package.
- Such a pack can be designed in a wide variety of ways for special applications. It can have pressure-sensitive adhesive strips on the back, which - if necessary after removing a protective film - can be used to stick the package close to the place of use. The small space requirement of the tablets according to the invention enables such use.
- the tablet according to the invention contains, as the actual active ingredient, a detergent concentrate which is the combination of the detergent-active substances and auxiliary substances, without the need for the diluents and adjusting agents required for a conventional detergent.
- a detergent concentrate is usually composed of synthetic detergents, polyphosphates, ion exchange silicates, bleaches and bleach activators, stabilizers, enzymes, brighteners and, if appropriate, fragrances and dyes.
- a mixture of anionic detergents e.g. Alkyl benzosulfonate
- nonionic detergents e.g. Alkyl polyglycol oil ether.
- Conventional polyphosphates or nitrilotriacetate (NTA) can be present as so-called builders.
- the ion exchangers are inorganic ion exchangers of the sodium aluminum silicate type.
- Bleaching agent is usually used sodium perborate, while TAED is a known additive as a bleach activator.
- Ethylenediaminetetraacetic acid (EDTA) serves as a stabilizer, further constituents are carboxymethyl cellulose, enzymes (proteases), stilbene disulfonic acid derivatives as brightening agents, and corrosion inhibitors, Geiu-'isffen and dye.
- the fillers present in conventional detergents, such as sodium sulfate or similar substances are generally not part of the detergent concentrate according to the invention. The same applies to water components present in conventional detergents.
- a typical composition of the suitable detergent is given below, which can be incorporated into a tablet according to the invention.
- Such a detergent composition consists of (in% by weight)
- Synthetic detergents namely alkylbenzenesulfonate and / or 0-20%
- Alkyl polyglycol ether 1 - 8%
- Silicone oil soap (foam inhibitor) 1 - 5%
- Ion exchange zeolites sodium aluminum silicate
- CMC Anti-shrink
- Corrosion inhibitors sodium silicate, sodium carbonate
- 2 - 30% odor and colorants 0.05 - 0.3% if necessary filler (sodium sulfate); 10 - 40%
- the kneaded mass was then pressed through a sieve with a mesh size of 710 ⁇ m, dried in vacuo for two hours at 30 to 40 ° C. and then sieved again through a 710 ⁇ m sieve.
- the granules obtained are mixed with 0.5% by weight (based on the finished overall mixture) of magnesium stearate as a lubricant with lubricating and mold release properties and the required amount of colloidal silicon dioxide as a flow regulator.
- the finished mixture was compressed in a conventional tablet press into white, round tablets with a flat surface and rounded edges. The approach described corresponded to a production quantity of 10,000 tablets with a weight of approximately 2 g each.
- the finished tablets were packed in airtight and moisture-proof packaging made of an aluminum foil PVC laminate.
- the tablets obtained were subjected to a careful quality control before packaging. Their average mass was determined by weighing 20 tablets of 2,000 mg. When the individual tablets were weighed, no more than 2 of these tablets deviated from the average mass by more than 5% by weight, and none of the tablets more than 10% by weight. The breaking strength was over 30 N and the disintegration time was 10 minutes or less.
- the cleaning and washing agent according to the invention in the form an effervescent tablet enables a safe, uniform release of the active ingredient in the amount of water used to prepare the cleaning liquid.
- a cleaning tablet according to the invention proves to be particularly advantageous in its use as an additive for windshield wiper systems, since it enables convenient introduction with precise metering at the same time.
- the tablets according to the invention proved to be extremely stable in storage. When stored under dry conditions at room temperature, they are fully usable for at least 2 years.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Produit de lavage et de nettoyage sous forme d'une pastille effervescente contenant 2 à 6% en poids d'un concentré de détergent, 40 à 60% en poids de NaHCO3, 33 à 53% en poids d'un acide organique solide, notamment d'un mélange 2/3 d'acide citrique et d'acide tartrique, 1,5 à 2,5% en poids d'un liant, notamment du polyvinylpyrolidone, et 0,1 à 1,0% en poids d'un lubrifiant ainsi que des quantités additionnelles de dioxyde de silicium colloïdal. Cette pastille effervescente de lavage est particulièrement indiquée comme additif de nettoyage pour les lave-glaces de véhicules automobiles.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3535516.6 | 1985-10-04 | ||
| DE19853535516 DE3535516A1 (de) | 1985-10-04 | 1985-10-04 | Tablettenfoermiges wasch- und reinigungsmittel, verfahren zu seiner herstellung und seine verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1987002052A1 true WO1987002052A1 (fr) | 1987-04-09 |
Family
ID=6282798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP1986/000552 WO1987002052A1 (fr) | 1985-10-04 | 1986-09-22 | Produit de nettoyage sous forme de pastille |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0239597A1 (fr) |
| AU (1) | AU6378086A (fr) |
| DE (1) | DE3535516A1 (fr) |
| WO (1) | WO1987002052A1 (fr) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0269982A3 (fr) * | 1986-12-03 | 1989-06-28 | Henkel Kommanditgesellschaft auf Aktien | Composition à base de silicates stratifiés pour le post-traitement du linge |
| EP0752466A1 (fr) * | 1995-07-05 | 1997-01-08 | The Procter & Gamble Company | Compositions détergentes non-aqueuses contenant un système effervescent |
| EP0812808A1 (fr) * | 1996-06-12 | 1997-12-17 | Cleantabs A/S | Comprimés pour adoucir l'eau |
| US5885949A (en) * | 1996-06-05 | 1999-03-23 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, BI carbonate and polyvinyl alcohol |
| WO2000022085A1 (fr) * | 1998-10-14 | 2000-04-20 | Henkel Kommanditgesellschaft Auf Aktien | Corps moules detergents et nettoyants munis d'un systeme granule effervescent exempt d'eau |
| DE10005576A1 (de) * | 2000-02-09 | 2001-08-23 | Reckitt Benckiser Nv | Reinigungsmittelzusammensetzung in Tablettenform |
| JP2007277312A (ja) * | 2006-04-03 | 2007-10-25 | Johnson Co Ltd | 発泡型粉末洗浄剤組成物 |
| RU2355747C1 (ru) * | 2008-03-11 | 2009-05-20 | Анна Ильинична Брук | Таблетированное средство для очистки стекол автомобиля |
| US20230159857A1 (en) * | 2021-11-22 | 2023-05-25 | Colgate-Palmolive Company | Effervescent Compositions and Solutions Prepared from the Same |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8909254D0 (en) * | 1989-04-24 | 1989-06-07 | Unilever Plc | Detergent compositions |
| AU647736B2 (en) * | 1989-04-24 | 1994-03-31 | Unilever Plc | Detergent compositions |
| DE19524451A1 (de) † | 1995-07-07 | 1997-01-09 | Henkel Kgaa | Farbübertragungsinhibierendes Waschmittel |
| DE19704229A1 (de) * | 1997-02-06 | 1998-08-13 | Henkel Kgaa | Cobuilderhaltiges Additiv für Wasch- oder Reinigungsmittel |
| DE19926376A1 (de) * | 1999-06-10 | 2000-12-14 | Henkel Kgaa | Lagerstabile Brausetabletten |
| DE102006029793A1 (de) * | 2006-06-27 | 2008-01-03 | Licciardi, Natale, Dipl.-Ing. | Verfahren zur Herstellung eines Schiebenreinigerkonzentrats in Tablettenform, Scheibenreinigerkonzentrat selbst und entsprechende Aufmachung |
| FR2906255B1 (fr) * | 2006-09-21 | 2012-10-19 | Euro Dorthz Production | Produit de nettoyage sous forme solide des surfaces vitrees d'un vehicule |
| DE102007031039A1 (de) * | 2007-07-04 | 2009-01-08 | Süd-Chemie AG | Verfahren zur schonenden Raffination von Pflanzenölen mit Naturbleicherde |
| CN116083178A (zh) * | 2023-03-05 | 2023-05-09 | 余姚市德派日用品有限公司 | 一种地板清洁泡腾片及其制备方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA737893A (en) * | 1966-07-05 | Armstrong Cork Company | Tablet for making window-cleaning composition | |
| GB1292482A (en) * | 1969-04-17 | 1972-10-11 | Colgate Palmolive Co | Denture soak tablets |
| DE2404494A1 (de) * | 1974-01-31 | 1975-08-14 | Blendax Werke Schneider Co | Reinigungsmittel fuer zahnprothesen |
| GB1527010A (en) * | 1975-12-22 | 1978-10-04 | Johnson & Johnson | Enzyme and active oxygen containing denture cleanser tablet |
| EP0123525A2 (fr) * | 1983-04-22 | 1984-10-31 | Warner-Lambert Company | Composition de nettoyage et son procédé de préparation |
| US4490269A (en) * | 1984-01-13 | 1984-12-25 | Warner-Lambert Company | Effervescent denture cleaning composition comprising monoperphthalate |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000177B (en) * | 1977-06-27 | 1982-01-20 | Akzo Nv | Detergent compositions |
| DE2832288C2 (de) * | 1978-07-22 | 1986-05-22 | Henkel KGaA, 4000 Düsseldorf | Reinigungsmittel zum Reinigen von Nahrungs- und Futtermitteln in Tablettenform |
-
1985
- 1985-10-04 DE DE19853535516 patent/DE3535516A1/de not_active Ceased
-
1986
- 1986-09-22 EP EP19860905791 patent/EP0239597A1/fr not_active Withdrawn
- 1986-09-22 AU AU63780/86A patent/AU6378086A/en not_active Abandoned
- 1986-09-22 WO PCT/EP1986/000552 patent/WO1987002052A1/fr not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA737893A (en) * | 1966-07-05 | Armstrong Cork Company | Tablet for making window-cleaning composition | |
| GB1292482A (en) * | 1969-04-17 | 1972-10-11 | Colgate Palmolive Co | Denture soak tablets |
| DE2404494A1 (de) * | 1974-01-31 | 1975-08-14 | Blendax Werke Schneider Co | Reinigungsmittel fuer zahnprothesen |
| GB1527010A (en) * | 1975-12-22 | 1978-10-04 | Johnson & Johnson | Enzyme and active oxygen containing denture cleanser tablet |
| EP0123525A2 (fr) * | 1983-04-22 | 1984-10-31 | Warner-Lambert Company | Composition de nettoyage et son procédé de préparation |
| US4490269A (en) * | 1984-01-13 | 1984-12-25 | Warner-Lambert Company | Effervescent denture cleaning composition comprising monoperphthalate |
Non-Patent Citations (1)
| Title |
|---|
| CHEMICAL ABSTRACTS, Vol. 85, No. 2, 26 July 1976 (Columbus, Ohio, US) see page 258, Abstract 25403b, & JP, A, 7626214 (Tatsumi Chemical Industries Co. Ltd.) 4 March 1976 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0269982A3 (fr) * | 1986-12-03 | 1989-06-28 | Henkel Kommanditgesellschaft auf Aktien | Composition à base de silicates stratifiés pour le post-traitement du linge |
| EP0752466A1 (fr) * | 1995-07-05 | 1997-01-08 | The Procter & Gamble Company | Compositions détergentes non-aqueuses contenant un système effervescent |
| US5885949A (en) * | 1996-06-05 | 1999-03-23 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, BI carbonate and polyvinyl alcohol |
| US6057281A (en) * | 1996-06-05 | 2000-05-02 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, (Bi)carbonate and polyvinyl alcohol |
| EP0812808A1 (fr) * | 1996-06-12 | 1997-12-17 | Cleantabs A/S | Comprimés pour adoucir l'eau |
| WO2000022085A1 (fr) * | 1998-10-14 | 2000-04-20 | Henkel Kommanditgesellschaft Auf Aktien | Corps moules detergents et nettoyants munis d'un systeme granule effervescent exempt d'eau |
| DE10005576A1 (de) * | 2000-02-09 | 2001-08-23 | Reckitt Benckiser Nv | Reinigungsmittelzusammensetzung in Tablettenform |
| JP2007277312A (ja) * | 2006-04-03 | 2007-10-25 | Johnson Co Ltd | 発泡型粉末洗浄剤組成物 |
| RU2355747C1 (ru) * | 2008-03-11 | 2009-05-20 | Анна Ильинична Брук | Таблетированное средство для очистки стекол автомобиля |
| US20230159857A1 (en) * | 2021-11-22 | 2023-05-25 | Colgate-Palmolive Company | Effervescent Compositions and Solutions Prepared from the Same |
| WO2023091749A1 (fr) * | 2021-11-22 | 2023-05-25 | Colgate-Palmolive Company | Compositions effervescentes et solutions préparées à partir de celles-ci |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0239597A1 (fr) | 1987-10-07 |
| DE3535516A1 (de) | 1987-04-09 |
| AU6378086A (en) | 1987-04-24 |
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