US8530905B2 - Organic light-emitting display apparatus - Google Patents
Organic light-emitting display apparatus Download PDFInfo
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- US8530905B2 US8530905B2 US11/590,999 US59099906A US8530905B2 US 8530905 B2 US8530905 B2 US 8530905B2 US 59099906 A US59099906 A US 59099906A US 8530905 B2 US8530905 B2 US 8530905B2
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- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/22—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/17—Passive-matrix OLED displays
- H10K59/173—Passive-matrix OLED displays comprising banks or shadow masks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/122—Pixel-defining structures or layers, e.g. banks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/805—Electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/14—Carrier transporting layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/17—Carrier injection layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/18—Carrier blocking layers
Definitions
- the present invention relates to an organic light-emitting display apparatus, and, more particularly, to an organic light-emitting display apparatus for blocking or preventing an electrode of an organic light-emitting device from being bent and shorted with another electrode of the organic light-emitting device and for blocking or preventing impurities from penetrating into an organic layer through the bent portions of the electrode.
- FIG. 1 is a cross-sectional view of an organic light-emitting device of a conventional organic light-emitting display apparatus.
- the organic light-emitting device includes a first electrode 21 , a second electrode 22 facing the first electrode 21 , and a plurality of organic layers 31 , 32 , 33 , 34 , and 35 formed between the first electrode 21 and the second electrode 22 .
- Electric signals having opposite polarities are respectively applied to the first electrode 21 and the second electrode 22 .
- the strength of an electric field is relatively high at the edge portions of the first electrode 21 or at the corner portions of the second electrode 22 .
- the organic layers 31 , 32 , 33 , 34 , and 35 between the first electrode 21 and the second electrode 22 may be damaged or destroyed due to a relatively strong electric field generated at the adjacent portions, so that the first electrode 21 may be shorted with the second electrode 22 (i.e., a short circuit or short may be generated between the first electrode 21 and the second electrode 22 ).
- pixel defining layers (PDLs) 10 which cover the edge portions of the first electrode 21 are formed to increase distances between the edge portions of the first electrode 21 and the second electrode 22 in order to block or prevent such a failure from occurring.
- the organic layers 31 , 32 , 33 , 34 , and 35 formed on the upper surfaces of the first electrode 21 and the pixel defining layers 10 are bent near the boundaries of the first electrode 21 and the pixel defining layers 10 .
- the second electrode 22 having a polarity opposite to that of the first electrode 21 is also bent over the boundaries of the first electrode 21 and the pixel defining layers 22 . Accordingly, an electric field is concentrated at the bent portions of the second electrode 22 , thereby possibly causing the second electrode 22 to be shorted with the first electrode 21 as shown in FIG. 2 .
- the second electrode 22 through which light passes is formed of a transparent or translucent electrode.
- the thin second electrode 22 is bent over the boundaries of the first electrode 21 and the pixel defining layers 10 , external impurities, etc., may penetrate into the organic layers 31 , 32 , 33 , 34 , and 35 between the first electrode 21 and the second electrode 22 through the bent portions, which may cause a failure of the organic light-emitting apparatus or reduces the lifespan of the organic light-emitting display apparatus.
- An aspect of the present invention provides an organic light-emitting display apparatus for blocking or preventing an electrode of an organic light-emitting device from being bent and shorted with another electrode of the organic light-emitting device and for blocking or preventing impurities from penetrating into an organic layer through bent portions of an electrode.
- an organic light-emitting display apparatus including: a first electrode; a pixel defining layer formed to have a thickness away from the first electrode and covering edge portions of the first electrode; a light-emitting layer on the first electrode; a second electrode on the light-emitting layer; and a stepheight lowering layer over a portion where the first electrode contacts the pixel defining layer, and between the first electrode and the light-emitting layer or between the light-emitting layer and the second electrode, to reduce a bend of the second electrode over the portion where the first electrode contacts the pixel defining layer.
- a hole injection layer is between the first electrode and the second electrode, and the stepheight lowering layer is formed of substantially the same material as the hole injection layer.
- the hole injection layer is integrated with the stepheight lowering layer.
- a hole transporting layer is between the first electrode and the second electrode, and the stepheight lowering layer is formed of substantially the same material as the hole transporting layer.
- the hole transporting layer is integrated with the stepheight lowering layer.
- an electron injection layer is between the first electrode and the second electrode, and the stepheight lowering layer is formed of substantially the same material as the electron injection layer.
- the electron injection layer is integrated with the stepheight lowering layer.
- an electron transporting layer is between the first electrode and the second electrode, and the stepheight lowering layer is formed of substantially the same material as the electron transporting layer.
- the electron transporting layer is integrated with the stepheight lowering layer.
- a hole blocking layer is between the first electrode and the second electrode, and the stepheight lowering layer is formed of substantially the same material as the hole blocking layer.
- the hole blocking layer is integrated with the stepheight lowering layer.
- At least one of a hole injection layer, a hole transporting layer, an electron injection layer, and a hole blocking layer is between the first electrode and the second electrode, and the stepheight lowering layer is formed of at least one of a hole injection layer forming material, a hole transporting layer forming material, an electron injection layer forming material, an electron transporting layer forming material, or a hole blocking layer forming material.
- the stepheight lowering layer has an opening positioned to correspond to a center portion of the light-emitting layer.
- the stepheight lowering layer has a center portion positioned to correspond to a center portion of the light-emitting layer, and the center portion of the stepheight lowering layer has a thickness within a range to resonate light emitted from the light-emitting layer.
- the stepheight lowering layer has a center portion positioned to correspond to a center portion of the light-emitting layer, and the center portion of the stepheight lowering layer has a thickness depending on a wavelength of light emitted from the light-emitting layer.
- the thickness of the center portion of the stepheight lowering layer is an even multiple or an odd multiple of a half-wavelength of light emitted from the light-emitting layer.
- an organic light-emitting display apparatus including: a first electrode; a pixel defining layer formed to have a thickness away from the first electrode and covering edge portions of the first electrode; a light-emitting layer on the first electrode; a second electrode on the light-emitting layer; and an organic layer disposed between the first electrode and the light-emitting layer or between the light-emitting layer and the second electrode, wherein a portion of the organic layer over where the first electrode contacts the pixel defining layer is thicker than a portion of the organic layer corresponding to a center portion of the light-emitting layer so that a bend of the second electrode is reduced over the portion of the organic layer over where the first electrode contacts the pixel defining layer.
- the organic layer is at least one of a hole injection layer, a hole transporting layer, an electron injection layer, an electron transporting layer, or a hole blocking layer.
- FIG. 1 is a cross-sectional view of an organic light-emitting device of a conventional organic light-emitting display apparatus
- FIG. 2 is a photograph showing a phenomenon in the conventional organic light-emitting device in which an electrode is shorted with another electrode at portions where the electrode is bent;
- FIG. 3 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a first embodiment of the present invention
- FIG. 4 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a second embodiment of the present invention.
- FIG. 5 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a third embodiment of the present invention.
- FIG. 6 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a fourth embodiment of the present invention.
- FIG. 3 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a first embodiment of the present invention.
- the organic light-emitting device is formed on a substrate 100 .
- the substrate 100 can be formed of a variety of plastic materials such as glass, acryl, etc., and can be also formed of a metal.
- the present invention is not thereby limited, and the substrate 100 included in the organic light-emitting device according to the present embodiment can be formed of various other suitable materials.
- the organic light-emitting device includes a first electrode 121 , a second electrode 122 facing the first electrode 121 , and one or more organic intermediate layers formed between the first electrode 121 and the second electrode 122 .
- the one or more organic intermediate layers include at least one light-emitting layer 133 as illustrated in FIG. 3 .
- the organic intermediate layers will be described in more detail below.
- the first electrode 121 functions as an anode electrode
- the second electrode 122 functions as a cathode electrode.
- the polarities of the first electrode 121 and the second electrode 122 can be reversed.
- the first electrode 121 can be used as a transparent electrode or a reflective electrode.
- the first electrode 121 can be formed of ITO, IZO, ZnO, or In 2 O 3 .
- the first electrode 121 can be formed by: (1) forming a reflective layer with Ag, Mg, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, or mixtures thereof; and (2) forming another layer with ITO, IZO, ZnO, or In 2 O 3 on the reflective layer.
- the second electrode 122 can also be used as a transparent electrode or a reflective electrode.
- the second electrode 122 can be formed by: (1) depositing a first layer with a transparent electrode forming material, such as ITO, IZO, ZnO, or In 2 O 3 , thereof on the organic intermediate layers applied on the first electrode 121 ; and (2) forming subsidiary electrode lines or bus electrode lines Li, Ca, LiF/Ca, LiF/Al, Al, Mg, or combinations thereof on the first layer (or between the organic intermediate layers and the first layer).
- the formation of the subsidiary electrode lines or bus electrode lines may be made before the deposition of the first layer.
- the second electrode 122 when used as a reflective electrode, the second electrode 122 can be formed by depositing (or only depositing) the above-mentioned Li, Ca, LiF/Ca, Li/Al, Al, Mg, or combinations thereof on the organic intermediate layers.
- pixel defining layers (PDLs) 110 are formed with a certain or predetermined thickness away from the first electrode 121 in a manner that covers the edge portions of the first electrode 121 .
- the pixel defining layers 110 define light-emitting areas and increase distances between the edge portions of the first electrode 121 and the second electrode 122 , thereby blocking or preventing an electric field from being concentrated at the edge portions of the first electrode 121 and thus blocking or preventing the first electrode 121 from being shorted with the second electrode 122 .
- the organic layers can be formed of low molecular organics or polymer organics.
- the organic layers formed between the first electrode 121 and the second electrode 122 are formed of low molecular organics.
- a hole injection layer (HIL) 131 a hole transporting layer (HTL) 132 , a light-emitting layer (EML) 133 , an electron transporting layer (ETL) 134 , and an electron injection layer (EIL) 135 can be formed in the order as shown (or listed), from the first electrode 121 through to the second electrode 122 .
- HIL hole injection layer
- HTL hole transporting layer
- EML electron transporting layer
- EIL electron injection layer
- These organic layers can be formed of copper phthalocyanine (CuPc), N,N′-di(naphthalene-1-yl)- N, N′-diphenyle-benzidine (NPB), tris-8-hydroxyquinoline aluminum (Alq3), etc.
- CuPc copper phthalocyanine
- NPB N,N′-di(naphthalene-1-yl)- N, N′-diphenyle-benzidine
- Alq3 tris-8-hydroxyquinoline aluminum
- all of the above-mentioned organic layers 131 , 132 , 133 , 134 , and 135 do not need to be formed. In only embodiment, only some of the organic layers 131 , 132 , 133 , 134 , and 135 are selectively formed. Also, although not illustrated in FIG. 3 , a hole blocking layer (HBL) can be further formed between the EML 133 and the ETL 134 . Also, one or more other suitable organic layers can be formed with or between the organic layers. Also, when the first electrode 121 functions as a cathode electrode and the second electrode 122 functions as an anode electrode, the above arrangement of the organic layers 131 , 132 , 133 , 134 , and 135 can vary.
- the organic layers between the first electrode 121 and the second electrode 122 are formed of polymer organics
- the organic layers can be composed of a hole transporting layer and a light-emitting layer.
- the hole transporting layer is formed of PEDOT (Poly-3,4-Ethylenedioxythiophene)
- the light-emitting layer is formed of polymer organics, such as Poly-Phenylenvinylene (PPV) and Polyfluorene.
- a stepheight lowering layer 136 is formed between the first electrode 121 and the light-emitting layer 133 .
- the stepheight lowering layer 136 is formed between the hole transporting layer 132 and the light-emitting layer 133 ; however, the present invention is not limited to this.
- the stepheight lowering layer 136 can be formed between the hole injection layer 131 and the hole transporting layer 132 a .
- the stepheight lowering layer 136 can also be formed between the first electrode 121 and the hole injection layer 131 .
- the stepheight lowering layer 136 can be formed between (or with) these layers. It is also possible that the stepheight lowering layer 136 is formed between the light-emitting layer 133 and the second electrode 122 . Also, the stepheight lowering layer 136 can be formed between various organic layers formed between the light-emitting layer 133 and the second electrode 122 .
- the stepheight lowering layer 136 has an opening positioned to correspond to the center portion of the light-emitting layer 133 , as illustrated in FIGS. 3 and 4 , and is disposed over the first electrode 121 and the pixel defining layer 110 , thereby reducing the bend of the second electrode 122 over portions where the first electrode 121 contacts the pixel defining layers 110 .
- the second electrode 122 is bent less (or smoothly bent without a sharp edge), so that the electric field concentration at the bent portions is reduced. Accordingly, embodiments of the present invention can block or prevent the first electrode 121 from being shorted with the second electrode 122 .
- the organic light-emitting device is a top emission device in which light is emitted to the outside through the second electrode 122
- the second electrode 122 is bent less over portions where the first electrode 121 contacts the pixel defining layers 110 (even if the second electrode 122 is thin)
- embodiments of the present invention can block or prevent external impurities, etc., from penetrating into the organic layers 131 , 132 , 133 , 134 , and 135 between the first electrode 121 and the second electrode 122 through the bent portions.
- the stepheight lowering layer 136 can be formed of a variety of materials.
- the stepheight lowering layer 136 can be formed of the same material as an organic layer formed between the first electrode 121 and the second electrode 122 . That is, if a hole injection layer is formed between the first electrode 121 and the second electrode 122 , the stepheight lowering layer 136 can be formed of the same material as the hole injection layer. If a hole transporting layer is formed between the first electrode 121 and the second electrode 122 , the stepheight lowering layer 136 can be formed of the same material as the hole transporting layer.
- the stepheight lowering layer 136 can be formed of the same material as the hole blocking layer. If an electron transporting layer is formed between the first electrode 121 and the second electrode 122 , the stepheight lowering layer 136 can be formed of the same material as the electron transporting layer. Likewise, if an electron injection layer is formed between the first electrode 121 and the second electrode 122 , the stepheight lowering layer 136 , can be formed of the same material as the electron injection layer.
- the stepheight lowering layer 136 can be formed of at least one of a hole injection layer forming material, a hole transporting layer forming material, an electron injection layer forming material, an electron transporting layer forming material, or a hole blocking layer forming material.
- the stepheight lowering layer 136 may be formed of one or more other suitable materials which do not block the light passing between the first electrode 121 and the second electrode 122 .
- FIG. 5 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a third embodiment of the present invention.
- the organic light-emitting device according to the third embodiment of the present invention is different from the organic light-emitting devices according to the above-described first and second embodiments, in that a stepheight lowering layer 136 a has a certain portion (and not an opening) that is formed to correspond to the center portion of a light-emitting layer 133 .
- the thickness of the center portion of the stepheight lowering layer 136 a is within a range (or a predetermined range) that can resonate light emitted from the light-emitting layer 133 .
- the light-emitting layer 133 can be a light-emitting layer that emits different wavelengths of light.
- the center portion of the stepheight lowering layer 136 a can have the same thickness regardless of the wavelengths of light emitted from the light-emitting layer 133 .
- the center portion of the stepheight lowering layer 136 can have a thickness corresponding to a least common multiple of a minimum thickness value capable of resonating the red light, a minimum thickness value capable of resonating the green light, and a minimum thickness value capable of resonating the blue light.
- the thickness of the center portion of the stepheight lowering layer 136 depends on a wavelength of light emitted from the light-emitting layer 133 .
- the thickness of the center portion of the stepheight lowering layer 136 can be an even multiple or an odd multiple of a half-wavelength of light emitted from the light-emitting layer 133 .
- Determination of whether the thickness of the center portion of the stepheight lowering layer 136 is an even multiple or an odd multiple of a half-wavelength of light emitted from the light-emitting layer 133 depends on whether an index of refraction of the stepheight lowering layer 136 is greater or smaller than indices of refraction of the upper and lower layers of the stepheight lowering layer 136 . This is because a phase of light varies according to whether the index of refraction of the stepheight lowering layer 136 is greater or smaller than the indices of refraction of the upper and lower layers of the stepheight lowering layer 136 , and accordingly a condition causing a constructive interference in the stepheight lowering layer 136 varies.
- the bend of the second electrode 122 over the portions where the first electrode 121 contacts the pixel defining layers 110 can be reduced, thereby preventing defects from being generated in the organic light-emitting device, enhancing a yield of the organic light-emitting device, increasing a lifespan of the organic light-emitting device, and improving a brightness characteristic of the organic light-emitting device.
- FIG. 6 is a cross-sectional view of an organic light-emitting device included in an organic light-emitting display apparatus according to a fourth embodiment of the present invention.
- the organic light-emitting device according to the fourth embodiment is different from the organic light-emitting devices according to the above-described embodiments, in that an organic layer (e.g., layer 132 a ) formed between a first electrode 121 and a second electrode 122 is used to reduce the bend of the second electrode 122 without separately forming a stepheight lowering layer.
- an organic layer e.g., layer 132 a
- the at least one organic layer may be one of a hole injection layer, a hole transporting layer, an electron injection layer, an electron transporting layer, and a hole blocking layer.
- a hole injection layer 131 , a hole transporting layer 132 a , an electron injection layer 134 , and an electron transporting layer 135 are formed between the first electrode 121 and the second electrode 122 , and the thickness of the hole transporting layer 132 a is varied (or adjusted) in order to lower the bend of the second electrode 122 .
- a stepheight lowering layer function (e.g. a function of the layer 136 of the first embodiment illustrated in FIG. 3 ) is integrated with the layer 132 a as a single layer.
- the embodiment can block or prevent an electric field from being concentrated at specific portions (or bent portions) of the second electrode to thus block or prevent the first electrode from being shorted with the second electrode.
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KR1020050104926A KR100659105B1 (en) | 2005-11-03 | 2005-11-03 | Organic light emitting display device |
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WO2009017026A1 (en) * | 2007-07-31 | 2009-02-05 | Sumitomo Chemical Company, Limited | Organic electroluminescence element and method for manufacturing the same |
KR100932989B1 (en) * | 2008-08-20 | 2009-12-21 | 삼성모바일디스플레이주식회사 | OLED display and manufacturing method thereof |
JP4849175B2 (en) * | 2010-02-25 | 2012-01-11 | 住友化学株式会社 | Light emitting device and manufacturing method thereof |
KR20110112992A (en) * | 2010-04-08 | 2011-10-14 | 삼성모바일디스플레이주식회사 | Organic light emitting device and method for manufacturing same |
WO2012147390A1 (en) * | 2011-04-28 | 2012-11-01 | 昭和電工株式会社 | Organic light-emitting element, production method for organic light-emitting element, display device, and illumination device |
JP7604240B2 (en) | 2021-01-15 | 2024-12-23 | 株式会社ジャパンディスプレイ | Display device and method for manufacturing the same |
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US7276453B2 (en) * | 2004-08-10 | 2007-10-02 | E.I. Du Pont De Nemours And Company | Methods for forming an undercut region and electronic devices incorporating the same |
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US7276453B2 (en) * | 2004-08-10 | 2007-10-02 | E.I. Du Pont De Nemours And Company | Methods for forming an undercut region and electronic devices incorporating the same |
US20080210931A1 (en) * | 2004-08-10 | 2008-09-04 | Nugent Truong | Methods for forming an undercut region and electronic devices incorporating the same |
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