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US7018603B2 - Synthesis of lithium iron sulphides and their use as cathodes - Google Patents

Synthesis of lithium iron sulphides and their use as cathodes Download PDF

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US7018603B2
US7018603B2 US10/433,680 US43368003A US7018603B2 US 7018603 B2 US7018603 B2 US 7018603B2 US 43368003 A US43368003 A US 43368003A US 7018603 B2 US7018603 B2 US 7018603B2
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lithium
sulphide
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molten
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Andrew G Ritchie
Peter G Bowles
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Qinetiq Ltd
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/007—Titanium sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C01G33/006—Compounds containing niobium, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/006—Compounds containing molybdenum, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/06—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing iron, with or without oxygen or hydrogen, and containing two or more other elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/12—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1397—Processes of manufacture of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • C—CHEMISTRY; METALLURGY
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    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to processes for the production of sulphides, in particular lithium transition metal sulphides useful in the production of batteries.
  • lithium metal rechargeable batteries particularly using sulphides, but also selenides, as cathode materials.
  • Many lithium metal/molybdenum disulphide (Li/MoS 2 ) batteries were produced but these were withdrawn following an incident in which a fire was attributed to the malfunction of such a battery.
  • Other sulphides, such as iron disulphide FeS 2 , titanium disulphide TiS 2 and selenides, such as niobium triselenide NbSe 3 have also been particularly investigated as alternative cathode materials.
  • lithium metal rechargeable batteries Although the use of lithium metal rechargeable batteries is now limited for reasons of safety, they are still used in the laboratory testing of materials. Lithium metal primary batteries using iron disulphide cathodes are manufactured.
  • lithium-ion type in which the negative electrode (anode) comprises lithium absorbed into a carbon support.
  • the negative electrode anode
  • a lithium containing cathode material which is usually lithium cobalt oxide LiCoO 2 although lithium nickel oxide LiNiO 2 , lithium manganese oxide LiMn 2 O 4 and mixed oxides are also known to have been used.
  • lithium rechargeable batteries Due to their high cost, the use of lithium rechargeable batteries at present is mainly limited to premium applications, such as portable computers or telephones. To gain access to wider markets, for example in applications such as the powering of electric vehicles, the cost must be reduced. Hence there is a strong demand for the high performance obtainable from lithium-ion batteries at much more economical prices.
  • Binary transition metal sulphides are however not suitable for direct use in lithium-ion cells as they do not contain lithium.
  • Lithium transition metal ternary sulphides such as lithium molybdenum sulphide, lithium titanium sulphide, lithium niobium sulphide and lithium iron sulphide have been suggested as electrode materials for batteries (see for example, Japanese Kokai No 10208782 and Solid State lonics 117 (1999) 273–276).
  • the conventional synthesis of lithium iron sulphide is via a solid state reaction in which lithium sulphide, Li 2 S, and ferrous sulphide, FeS, are intimately mixed together and heated under an inert atmosphere at a temperature of ca. 800° C. The reaction is diffusion controlled and the kinetics are slow. Consequently, the reaction can take up to 1 month at temperature to reach completion. This is highly inconvenient and is costly in terms of energy input. The economics of this synthesis for battery production are clearly unfavourable.
  • lithium iron sulphide can be made by an electrochemical synthesis route in which a lithium metal/iron disulphide cell is discharged, and the lithium metal is removed and replaced by a carbon anode. This process however, is not amenable to scaling up.
  • a further laboratory synthesis of lithium iron sulphide is the solid state reaction of lithium nitride, Li 3 N, with iron disulphide, FeS 2 , but again, this method is unsuitable for large scale use because of the high cost and shock sensitivity of lithium nitride.
  • FIG. 1 shows an x-ray diffraction trace for the product obtained using a first example of a process according to the present invention
  • FIG. 2 shows cycling curves for the product obtained using a first example of a process according to the present invention
  • FIG. 3 shows an x-ray diffraction trace for the product obtained using a second example of a process according to the present invention
  • FIG. 4 shows an x-ray diffraction trace for the product obtained using a third example of a process according to the present invention
  • FIG. 5 shows cycling curves for the product obtained using a third example of a process according to the present invention.
  • FIG. 6 shows an x-ray diffraction trace for the product obtained using a fourth example of a process according to the present invention.
  • a process for the production of a lithium transition metal sulphide comprises reacting a transition metal sulphide with lithium sulphide in a solvent comprising a molten salt or a mixture of molten salts.
  • the transition metal sulphide used in the process is an iron, molybdenum, niobium or titanium sulphide and is preferably an iron sulphide.
  • Ferrous sulphide, FeS, and iron disulphide, FeS 2 are inexpensive and readily available naturally occurring minerals.
  • the molten salt or mixture of molten salts comprises an alkali metal halide or a mixture of alkali metal halides, or an alkaline earth metal halide or a mixture of alkaline earth metal halides, or any mixture thereof. More preferably, the molten salt or mixture of molten salts comprises a lithium halide or a mixture of lithium halides.
  • the molten salt or mixture of molten salts comprises at least one of lithium fluoride, lithium chloride, lithium bromide or lithium iodide.
  • the reaction temperature should be sufficient to liquefy the molten salt or mixture of molten salts. This need not necessarily be the melting point of the molten salt or mixture of molten salts as the addition of the reactants may depress the melting point. Typically, reaction temperatures of less than 1000° C. and most often less than 700° C. are suitable, however dependent on the choice of solvent, reaction temperatures of less than 300° C. may be used.
  • reaction proceeds more rapidly than previously known processes. On a laboratory scale, the reaction can be completed in a few hours, with the actual reaction time dependent largely on the heating time of the furnace.
  • lithium sulphide may be bought commercially, for large scale production it is more economical to produce lithium sulphide via the reduction of lithium sulphate.
  • One convenient method is to heat lithium sulphate above its melting point of 860° C. in the presence of carbon.
  • Other standard reduction methods may equally be used, as well known in the art.
  • the product After the reaction is complete and allowed to cool, the product must be recovered from the solvent. Suitably the product is recovered by dissolution of the solvent in an organic liquid.
  • the organic liquid chosen is dependent on the composition of the solvent used, however some examples include, pyridine, ether and acetonitrile which are suitable for the dissolution of lithium chloride, lithium bromide and lithium iodide respectively. Numerous other suitable liquids will be known to those skilled in the art.
  • a mixed salt solvent it may be necessary to perform more than one dissolution process. For example, a reaction using a mixture of lithium chloride and lithium bromide as a solvent may require a first dissolution process using pyridine to remove the lithium chloride, followed by a second dissolution process using ether to remove the lithium bromide.
  • the present invention further provides a process for producing at least one lithium transition metal sulphide by reacting a transition metal sulphide with lithium sulphide in the presence of a molten salt or mixture of molten salts.
  • a plurality of lithium transition metal sulphides may be made by such a process and subsequently separated.
  • a process for producing one or more lithium transition metal sulphides by reacting one or more transition metal sulphides with lithium sulphide in the presence of a further salt with which they do not react, in an inert atmosphere, wherein the salt and at least one component are in a molten state to allow intimate mixing, the salt preferably acting as a solvent for said at least one component.
  • Lithium transition metal sulphides obtained by the above described process form a further aspect of the invention. These compounds are useful in the production of electrodes for use in batteries. In particular, they are useful in the production of electrodes for rechargeable batteries. These electrodes form the cathode, and suitable anodes are lithium ion anodes as are known in the art.
  • Suitable electrolytes are also well known and include mixtures of inorganic carbonates, for example ethylene carbonate, propylene carbonate, diethyl or dimethyl carbonates, ethyl methyl carbonate together with a lithium salt, usually lithium hexafluorophosphate, LiPF 6 , or lithium trifluoromethane sulphonate (‘triflates’), LiCF 3 SO 3 or lithium tetrafluoroborate, LiBF 4 .
  • a lithium salt usually lithium hexafluorophosphate, LiPF 6 , or lithium trifluoromethane sulphonate (‘triflates’), LiCF 3 SO 3 or lithium tetrafluoroborate, LiBF 4 .
  • Molten salts and mixtures of molten salts are not conventional solvents and their use, acting like solvents in the production of sulphides, therefore forms a further aspect of the invention. As described above, they are particularly suitable for use as solvents in reactions used in the production of lithium transition metal sulphides.
  • Li 2 FeS 2 Lithium iron sulphide, Li 2 FeS 2 was synthesised according to the following equation: Li 2 S+FeS ⁇ Li 2 FeS 2
  • FIG. 1 shows an XRD trace of the product obtained.
  • the vertical lines 1 represent the standard trace for pure Li 2 FeS 2 taken from the JCPDS database.
  • the main peaks are co-incident with and have similar relative intensities to these lines 1 , indicating that the dominant product phase obtained was Li 2 FeS 2 .
  • the remaining peaks correspond to small amounts of unreacted starting materials.
  • FIG. 2 illustrates three cycling curves which indicate that the cathode could be repeatedly charged and discharged. This demonstrates that the product was suitable for use as a cathode material for a lithium rechargeable battery.
  • FIG. 3 shows an XRD trace of the product obtained.
  • the vertical lines 1 represent the standard trace for pure Li 2 FeS 2 taken from the JCPDS database.
  • the main peaks are co-incident with and have similar relative intensities to these lines 1 , indicating that the dominant product phase obtained was Li 2 FeS 2 .
  • the remaining peaks correspond to small amounts of unreacted starting materials.
  • FIG. 4 shows an XRD trace of the product obtained.
  • the vertical lines 1 represent the standard trace for pure Li 2 FeS 2 taken from the JCPDS database.
  • the main peaks are co-incident with and have similar relative intensities to these lines 1 , indicating that the dominant product phase obtained was Li 2 FeS 2 .
  • the remaining peaks correspond to small amounts of unreacted starting materials.
  • FIG. 5 illustrates three cycling curves which indicate that the cathode could be repeatedly charged and discharged. This demonstrates that the product was suitable for use as a cathode material for a lithium rechargeable battery.
  • Li 2 S and FeS 2 were reacted together in a molten salt solvent of lithium chloride, LiCl, at 700° C. for ca. 2 hours, under an argon atmosphere. After completion the lithium chloride was removed by refluxing in pyridine for 8 hours.
  • FIG. 6 shows an XRD trace of the product obtained. The main peaks are coincident with the lithium iron sulphides, Li 3 Fe 2 S 4 , Li 2 FeS 2 and Li 2.33 Fe 0.67 S 2 . Unlike the other examples, a single pure product was not obtained. These products are known to be suitable as battery cathode materials (A. G. Ritchie and P. G. Bowles, Process for Producing a Lithium Transition Metal Sulphide, WO 00/78673 A1, 28 Dec. 2000).

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Abstract

A process for the production of a lithium transition metal sulphide such as lithium iron sulphide, the process comprising reacting a transition metal sulphide with lithium sulphide in a solvent comprising a molten salt or a mixture of molten salts. Lithium transition metal sulphides obtained using this process are useful in the production of electrodes, in particular for rechargeable lithium batteries.

Description

CROSS REFERENCE TO RELATED APPLICATION
This application is the US national phase of international application PCT/GB01/05209 filed 27 Nov. 2001, which designated the US.
The present invention relates to processes for the production of sulphides, in particular lithium transition metal sulphides useful in the production of batteries.
BACKGROUND OF THE INVENTION
In the 1980's, there was extensive research into lithium metal rechargeable batteries, particularly using sulphides, but also selenides, as cathode materials. Many lithium metal/molybdenum disulphide (Li/MoS2) batteries were produced but these were withdrawn following an incident in which a fire was attributed to the malfunction of such a battery. Other sulphides, such as iron disulphide FeS2, titanium disulphide TiS2 and selenides, such as niobium triselenide NbSe3 have also been particularly investigated as alternative cathode materials.
Although the use of lithium metal rechargeable batteries is now limited for reasons of safety, they are still used in the laboratory testing of materials. Lithium metal primary batteries using iron disulphide cathodes are manufactured.
Virtually all modern lithium rechargeable batteries are of the lithium-ion type, in which the negative electrode (anode) comprises lithium absorbed into a carbon support. These use a lithium containing cathode material, which is usually lithium cobalt oxide LiCoO2 although lithium nickel oxide LiNiO2, lithium manganese oxide LiMn2O4 and mixed oxides are also known to have been used.
Due to their high cost, the use of lithium rechargeable batteries at present is mainly limited to premium applications, such as portable computers or telephones. To gain access to wider markets, for example in applications such as the powering of electric vehicles, the cost must be reduced. Hence there is a strong demand for the high performance obtainable from lithium-ion batteries at much more economical prices.
On first inspection, the use of sulphides as cathode materials is not as attractive as the use of oxides. This is because the voltage achievable from sulphides is generally only about half of that achievable using corresponding oxides. However, the capacity of batteries incorporating sulphide based cathodes, measured in ampere hours per gram of material, is about 3 times greater than corresponding batteries incorporating oxide based cathodes. This leads to an overall advantage of about 1.5 times in terms of cathode energy density for batteries with sulphide based cathodes. A further advantage is that iron sulphides, in particular ferrous sulphide (FeS) and iron disulphide (FeS2) are inexpensive materials which may be dug out of the ground as natural occurring minerals. By contrast, lithium cobalt oxide is an expensive material, due mainly to the high cost of cobalt metal.
Binary transition metal sulphides are however not suitable for direct use in lithium-ion cells as they do not contain lithium. Lithium transition metal ternary sulphides, such as lithium molybdenum sulphide, lithium titanium sulphide, lithium niobium sulphide and lithium iron sulphide have been suggested as electrode materials for batteries (see for example, Japanese Kokai No 10208782 and Solid State lonics 117 (1999) 273–276). The conventional synthesis of lithium iron sulphide is via a solid state reaction in which lithium sulphide, Li2S, and ferrous sulphide, FeS, are intimately mixed together and heated under an inert atmosphere at a temperature of ca. 800° C. The reaction is diffusion controlled and the kinetics are slow. Consequently, the reaction can take up to 1 month at temperature to reach completion. This is highly inconvenient and is costly in terms of energy input. The economics of this synthesis for battery production are clearly unfavourable.
On a laboratory scale, lithium iron sulphide can be made by an electrochemical synthesis route in which a lithium metal/iron disulphide cell is discharged, and the lithium metal is removed and replaced by a carbon anode. This process however, is not amenable to scaling up. A further laboratory synthesis of lithium iron sulphide is the solid state reaction of lithium nitride, Li3N, with iron disulphide, FeS2, but again, this method is unsuitable for large scale use because of the high cost and shock sensitivity of lithium nitride.
The applicants have developed an economical synthesis which can be operated on a large scale to produce sulphides which have useful electrochemical properties.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will now be particularly described by way of example only with reference to the following drawings in which;
FIG. 1 shows an x-ray diffraction trace for the product obtained using a first example of a process according to the present invention;
FIG. 2 shows cycling curves for the product obtained using a first example of a process according to the present invention;
FIG. 3 shows an x-ray diffraction trace for the product obtained using a second example of a process according to the present invention;
FIG. 4 shows an x-ray diffraction trace for the product obtained using a third example of a process according to the present invention;
FIG. 5 shows cycling curves for the product obtained using a third example of a process according to the present invention; and,
FIG. 6 shows an x-ray diffraction trace for the product obtained using a fourth example of a process according to the present invention.
 DESCRIPTION OF THE INVENTION
In accordance with the present invention a process for the production of a lithium transition metal sulphide comprises reacting a transition metal sulphide with lithium sulphide in a solvent comprising a molten salt or a mixture of molten salts.
Suitably the transition metal sulphide used in the process is an iron, molybdenum, niobium or titanium sulphide and is preferably an iron sulphide. Ferrous sulphide, FeS, and iron disulphide, FeS2, are inexpensive and readily available naturally occurring minerals.
Preferably the molten salt or mixture of molten salts comprises an alkali metal halide or a mixture of alkali metal halides, or an alkaline earth metal halide or a mixture of alkaline earth metal halides, or any mixture thereof. More preferably, the molten salt or mixture of molten salts comprises a lithium halide or a mixture of lithium halides.
Most preferably, the molten salt or mixture of molten salts comprises at least one of lithium fluoride, lithium chloride, lithium bromide or lithium iodide.
The reaction temperature should be sufficient to liquefy the molten salt or mixture of molten salts. This need not necessarily be the melting point of the molten salt or mixture of molten salts as the addition of the reactants may depress the melting point. Typically, reaction temperatures of less than 1000° C. and most often less than 700° C. are suitable, however dependent on the choice of solvent, reaction temperatures of less than 300° C. may be used.
The reaction proceeds more rapidly than previously known processes. On a laboratory scale, the reaction can be completed in a few hours, with the actual reaction time dependent largely on the heating time of the furnace.
Although lithium sulphide may be bought commercially, for large scale production it is more economical to produce lithium sulphide via the reduction of lithium sulphate. One convenient method is to heat lithium sulphate above its melting point of 860° C. in the presence of carbon. Other standard reduction methods may equally be used, as well known in the art.
After the reaction is complete and allowed to cool, the product must be recovered from the solvent. Suitably the product is recovered by dissolution of the solvent in an organic liquid. The organic liquid chosen is dependent on the composition of the solvent used, however some examples include, pyridine, ether and acetonitrile which are suitable for the dissolution of lithium chloride, lithium bromide and lithium iodide respectively. Numerous other suitable liquids will be known to those skilled in the art. When a mixed salt solvent is used it may be necessary to perform more than one dissolution process. For example, a reaction using a mixture of lithium chloride and lithium bromide as a solvent may require a first dissolution process using pyridine to remove the lithium chloride, followed by a second dissolution process using ether to remove the lithium bromide.
The present invention further provides a process for producing at least one lithium transition metal sulphide by reacting a transition metal sulphide with lithium sulphide in the presence of a molten salt or mixture of molten salts. A plurality of lithium transition metal sulphides may be made by such a process and subsequently separated.
In a further aspect, there is provided a process for producing one or more lithium transition metal sulphides by reacting one or more transition metal sulphides with lithium sulphide in the presence of a further salt with which they do not react, in an inert atmosphere, wherein the salt and at least one component are in a molten state to allow intimate mixing, the salt preferably acting as a solvent for said at least one component.
Lithium transition metal sulphides obtained by the above described process form a further aspect of the invention. These compounds are useful in the production of electrodes for use in batteries. In particular, they are useful in the production of electrodes for rechargeable batteries. These electrodes form the cathode, and suitable anodes are lithium ion anodes as are known in the art. Suitable electrolytes are also well known and include mixtures of inorganic carbonates, for example ethylene carbonate, propylene carbonate, diethyl or dimethyl carbonates, ethyl methyl carbonate together with a lithium salt, usually lithium hexafluorophosphate, LiPF6, or lithium trifluoromethane sulphonate (‘triflates’), LiCF3SO3 or lithium tetrafluoroborate, LiBF4.
Molten salts and mixtures of molten salts are not conventional solvents and their use, acting like solvents in the production of sulphides, therefore forms a further aspect of the invention. As described above, they are particularly suitable for use as solvents in reactions used in the production of lithium transition metal sulphides.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Lithium iron sulphide, Li2FeS2 was synthesised according to the following equation:
Li2S+FeS→Li2FeS2
Stoichiometric amounts of lithium sulphide, Li2S, and iron sulphide, FeS, were intimately mixed with a roughly equivalent weight of a salt or mixture of salts which constituted the solvent. The resulting mixture was placed into a nickel crucible and heated under an inert atmosphere to effect reaction. After the reaction was complete, the crucible and its contents were allowed to cool while still under an inert atmosphere, before being transferred to an inert atmosphere glove box. The salt or mixture of salts was then removed from the desired product by refluxing the powdered contents of the crucible with an organic liquid. After filtering and drying, the resultant product was analysed by x-ray powder diffraction (XRD) using a Philips PW1830 Diffractometer and CuKα radiation.
Cell cycling tests were carried out on the product as follows. Cathode sheets were made by the doctor blade method. The product was mixed with graphite and a solution of ethylene propylene diene monomer (EPDM) in cyclohexane to form a slurry. This was then coated onto an aluminium backing sheet. Negative electrodes were made by a similar method except that the active material was carbon in the form of graphite with some carbon black added, the binder was polyvinylidene fluoride dissolved in N-methylpyrrolidinone (NMP) and the metallic backing sheet was copper. The electrolyte was ethylene carbonate (EC)/diethyl carbonate (DEC)/1 molar lithium hexafluorophosphate (LiPF6). Cells were cycled at room temperature. This cell cycling procedure is described in more detail by A. Gilmour, C. O. Giwa, J. C. Lee and A. G. Ritchie, in the Journal of Power Sources, volume 65, pages 219–224.
EXAMPLE 1
Li2S and FeS were reacted together in a molten salt solvent of lithium chloride, LiCl, at 650° C. for ca. 2 hours, under an argon atmosphere. After completion, the LiCl was removed by refluxing in pyridine for 8 hours. FIG. 1 shows an XRD trace of the product obtained. The vertical lines 1 represent the standard trace for pure Li2FeS2 taken from the JCPDS database. The main peaks are co-incident with and have similar relative intensities to these lines 1, indicating that the dominant product phase obtained was Li2FeS2. The remaining peaks correspond to small amounts of unreacted starting materials.
The product obtained was used to manufacture a cathode as described above. FIG. 2 illustrates three cycling curves which indicate that the cathode could be repeatedly charged and discharged. This demonstrates that the product was suitable for use as a cathode material for a lithium rechargeable battery.
EXAMPLE 2
Li2S and FeS were reacted together in a molten salt solvent of lithium bromide, LiBr, at 550° C. for ca. 2 hours, under an argon atmosphere. After completion, the LiBr was removed by refluxing in diethyl ether for 8 hours. FIG. 3 shows an XRD trace of the product obtained. The vertical lines 1 represent the standard trace for pure Li2FeS2 taken from the JCPDS database. The main peaks are co-incident with and have similar relative intensities to these lines 1, indicating that the dominant product phase obtained was Li2FeS2. The remaining peaks correspond to small amounts of unreacted starting materials.
EXAMPLE 3
Li2S and FeS were reacted together in a molten salt solvent of lithium iodide, Lil, at 450° C. for ca. 2 hours, under an argon atmosphere. After completion, the Lil was removed by refluxing in acetonitrile for 8 hours. FIG. 4 shows an XRD trace of the product obtained. The vertical lines 1 represent the standard trace for pure Li2FeS2 taken from the JCPDS database. The main peaks are co-incident with and have similar relative intensities to these lines 1, indicating that the dominant product phase obtained was Li2FeS2. The remaining peaks correspond to small amounts of unreacted starting materials.
The product obtained was used to manufacture a cathode as described above. FIG. 5 illustrates three cycling curves which indicate that the cathode could be repeatedly charged and discharged. This demonstrates that the product was suitable for use as a cathode material for a lithium rechargeable battery.
EXAMPLE 4
Li2S and FeS2 were reacted together in a molten salt solvent of lithium chloride, LiCl, at 700° C. for ca. 2 hours, under an argon atmosphere. After completion the lithium chloride was removed by refluxing in pyridine for 8 hours. FIG. 6 shows an XRD trace of the product obtained. The main peaks are coincident with the lithium iron sulphides, Li3Fe2S4, Li2FeS2 and Li2.33Fe0.67S2. Unlike the other examples, a single pure product was not obtained. These products are known to be suitable as battery cathode materials (A. G. Ritchie and P. G. Bowles, Process for Producing a Lithium Transition Metal Sulphide, WO 00/78673 A1, 28 Dec. 2000).
The examples described above demonstrate that the process of the present invention is suitable for use in the production of Li2FeS2 and that the product so obtained can be used as a cathode material in the manufacture of lithium rechargeable batteries. The process is significantly quicker and requires considerably less energy input than the conventional solid state synthesis of lithium iron sulphide. This leads to significant reductions in the cost of the material.
Although described with reference to the production of lithium iron sulphide, it will be clear that the process could equally be used to produce other lithium transition metal sulphides.

Claims (3)

1. A process for the synthesis of lithium iron sulphide Li2FeS2, in which reactants consisting of lithium sulphide Li2S and iron sulphide FeS react, under an inert atmosphere, in a solvent consisting essentially of a molten lithium halide salt, or a mixture of molten lithium halide salts, so as to produce Li2FeS2 as the dominant product phase, and recovering the product by dissolution of the molten salt or mixture of molten salts in at least one organic liquid.
2. The synthesis process according to claim 1 wherein the molten lithium halide salt or mixture of molten lithium halide salts comprises at least one of lithium fluoride, lithium chloride, lithium bromide or lithium iodide.
3. The process for manufacturing a cathode comprising producing lithium iron sulphide Li2FeS2 by a process according to claim 1, and subsequently using the sulphide so produced to manufacture the cathode.
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US11066307B2 (en) 2011-07-26 2021-07-20 Toyota Motor Engineering & Manufacturing North America, Inc. Polyanion active materials and method of forming the same
US10033040B2 (en) 2013-07-08 2018-07-24 The Board Of Trustees Of The Leland Standford Junior University Stable cycling of lithium sulfide cathodes through strong affinity with multifunctional binders

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