PL2668163T3 - Sposób wytwarzania 6-podstawionych 4-amino-3-chloro-5-fluoro-pikolinianów - Google Patents

Sposób wytwarzania 6-podstawionych 4-amino-3-chloro-5-fluoro-pikolinianów

Info

Publication number: PL2668163T3
Authority: PL; Poland
Prior art keywords: picolinates; fluoro; chloro; amino; substituted
Prior art date: 2011-01-25

Application number

PL12739865T

Other languages

English (en)

Inventor

Kim E Arndt

James M Renga

Yuanming Zhu

Gregory T Whiteker

Christian T Lowe

Original Assignee

Dow Agrosciences Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-01-25

Filing date

2012-01-24

Publication date

2017-10-31

2012-01-24 Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc

2017-10-31 Publication of PL2668163T3 publication Critical patent/PL2668163T3/pl

Links

WRHDYOGDDZYNMT-UHFFFAOYSA-N 4-amino-3-chloro-5-fluoropyridine-2-carboxylic acid Chemical class NC1=C(F)C=NC(C(O)=O)=C1Cl WRHDYOGDDZYNMT-UHFFFAOYSA-N 0.000 title 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides

Landscapes

Organic Chemistry (AREA)
Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Dentistry (AREA)
Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Plant Pathology (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Pyridine Compounds (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

PL12739865T 2011-01-25 2012-01-24 Sposób wytwarzania 6-podstawionych 4-amino-3-chloro-5-fluoro-pikolinianów PL2668163T3 (pl)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US201161435966P	2011-01-25	2011-01-25
EP12739865.9A EP2668163B1 (en)	2011-01-25	2012-01-24	Process for the preparation of 6-substituted 4-amino-3-chloro-5-fluoro-picolinates
PCT/US2012/022285 WO2012103041A2 (en)	2011-01-25	2012-01-24	Process for the preparation of 4-amino-3-chloro-5-fluoro-6-(substituted) picolinates

Publications (1)

Publication Number	Publication Date
PL2668163T3 true PL2668163T3 (pl)	2017-10-31

Family

ID=46544648

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PL12739865T PL2668163T3 (pl)	2011-01-25	2012-01-24	Sposób wytwarzania 6-podstawionych 4-amino-3-chloro-5-fluoro-pikolinianów

Country Status (20)

Country	Link
US (3)	US20120190857A1 (pl)
EP (1)	EP2668163B1 (pl)
JP (1)	JP5739018B2 (pl)
KR (1)	KR101537879B1 (pl)
CN (2)	CN104788368B (pl)
AR (1)	AR085022A1 (pl)
AU (1)	AU2012209277B2 (pl)
BR (2)	BR112013019025A2 (pl)
CA (1)	CA2825475C (pl)
CO (1)	CO6731125A2 (pl)
HK (2)	HK1199245A1 (pl)
IL (1)	IL227646A (pl)
MX (1)	MX342328B (pl)
PL (1)	PL2668163T3 (pl)
RU (1)	RU2545021C1 (pl)
SG (1)	SG192093A1 (pl)
TW (1)	TWI592401B (pl)
UA (1)	UA106945C2 (pl)
WO (1)	WO2012103041A2 (pl)
ZA (1)	ZA201305577B (pl)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
TWI592401B (zh)	2011-01-25	2017-07-21	陶氏農業科學公司	用於製備４－胺基－３－氯－５－氟－６－（經取代的）吡啶甲酸酯的方法（一）
US9637505B2 (en)	2013-03-15	2017-05-02	Dow Agrosciences Llc	4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides
PT2970185T (pt)	2013-03-15	2023-10-06	Corteva Agriscience Llc	4-amino-6-(heterocíclico)picolinatos e 6-amino-2-(heterocíclico)pirimidino-4-carboxilatos e seu uso como herbicidas
HUE041698T2 (hu)	2013-03-15	2019-05-28	Dow Agrosciences Llc	Új 4-aminopiridin- és 6-aminopririmidin-karboxilátok mint herbicidek
US9113629B2 (en)	2013-03-15	2015-08-25	Dow Agrosciences Llc	4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides
BR102014028162A2 (pt)	2013-11-12	2015-09-08	Dow Agrosciences Llc	processo para fluoração de compostos
TW201609651A (zh)	2013-11-12	2016-03-16	陶氏農業科學公司	用於氟化化合物之過程（一）
TW201524956A (zh) *	2013-11-12	2015-07-01	Dow Agrosciences Llc	用於氟化化合物之過程（二）
TWI726900B (zh)	2015-08-04	2021-05-11	美商陶氏農業科學公司	用於氟化化合物之過程
EP3458442B1 (en)	2016-05-19	2022-12-28	Corteva Agriscience LLC	Synthesis of 6-aryl-4-aminopicolinates and 2-aryl-6-aminopyrimidine-4-carboxylates by direct suzuki coupling
CN107954925A (zh) *	2016-10-18	2018-04-24	内蒙古佳瑞米精细化工有限公司	一种2,3-二氯-5-三氟甲基吡啶前杂的去除方法
BR112021005140A8 (pt)	2018-09-19	2021-06-29	Corteva Agriscience Llc	preparação de análogos de halogênio de picloram
WO2021188654A1 (en)	2020-03-18	2021-09-23	Corteva Agriscience Llc	Improved synthesis of 6-aryl-4-aminopicolinates
BR112022018508A2 (pt)	2020-03-18	2022-10-25	Corteva Agriscience Llc	Síntese melhorada de 4-amino-6-(heterocíclico)picolinatos

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US3285925A (en) *	1962-03-06	1966-11-15	Dow Chemical Co	Amino-trichloropicolinic acid compounds
US3803159A (en) *	1967-12-26	1974-04-09	Dow Chemical Co	Fluorine containing cyanopyridines
US3629424A (en) *	1967-12-26	1971-12-21	Dow Chemical Co	Cyanofluoropyridines and fungicidal compositions and methods for using the same
US4336384A (en) *	1981-04-23	1982-06-22	The Dow Chemical Company	Preparation of 4-amino-3,5,6-trichloropicolinic acid
US5807804A (en) *	1996-02-22	1998-09-15	American Cyanamid Company	Substituted pyridine herbicidal agents
FR2803592A1 (fr) *	2000-01-06	2001-07-13	Aventis Cropscience Sa	Nouveaux derives de l'acide 3-hydroxypicolinique, leur procede de preparation et compositions fongicides les contenant.
BRPI0107649B8 (pt) *	2000-01-14	2022-06-28	Dow Agrosciences Llc	Composição herbicida compreendendo ácido 4-amino-3,6-dicloropiridina-2-carboxílico ou um derivado do mesmo e método para controlar vegetação indesejável.
US6297197B1 (en)	2000-01-14	2001-10-02	Dow Agrosciences Llc	4-aminopicolinates and their use as herbicides
AR037228A1 (es) *	2001-07-30	2004-11-03	Dow Agrosciences Llc	Compuestos del acido 6-(aril o heteroaril)-4-aminopicolinico, composicion herbicida que los comprende y metodo para controlar vegetacion no deseada
UA82358C2 (uk) *	2003-04-02	2008-04-10	Дау Агросайенсиз Ллс	6-алкіл або алкеніл-4-амінопіколінати гербіцидна композиція, спосіб боротьби з небажаною рослинністю
CN102731382B (zh) *	2006-01-13	2015-09-02	美国陶氏益农公司	6-(多取代芳基)-4-氨基吡啶甲酸酯及其作为除草剂的用途
BRPI0817626B8 (pt) *	2007-10-02	2022-06-28	Dow Agrosciences Llc	ácidos 2-substituído-6-amino-5-alquil, alquenil ou alquinil-4-pirimidinacarboxílicos e ácidos 6-substituído-4-amino-3-alquil, alquenil ou aquinil picolínicos, composição herbicida que os compreende e método de controlar vegetação indesejável
US8252938B2 (en) *	2009-06-08	2012-08-28	Dow Agrosciences, Llc.	Process for the preparation of 6-(aryl)-4-aminopicolinates
GB0910766D0 (en) *	2009-06-22	2009-08-05	Syngenta Ltd	Chemical compounds
GB201008290D0 (en) *	2010-05-18	2010-06-30	Syngenta Ltd	Chemical compounds
TWI592401B (zh)	2011-01-25	2017-07-21	陶氏農業科學公司	用於製備４－胺基－３－氯－５－氟－６－（經取代的）吡啶甲酸酯的方法（一）

2012
- 2012-01-20 TW TW101102582A patent/TWI592401B/zh not_active IP Right Cessation
- 2012-01-24 AR ARP120100234A patent/AR085022A1/es unknown
- 2012-01-24 AU AU2012209277A patent/AU2012209277B2/en not_active Ceased
- 2012-01-24 BR BR112013019025A patent/BR112013019025A2/pt not_active Application Discontinuation
- 2012-01-24 WO PCT/US2012/022285 patent/WO2012103041A2/en active Application Filing
- 2012-01-24 UA UAA201310403A patent/UA106945C2/uk unknown
- 2012-01-24 EP EP12739865.9A patent/EP2668163B1/en not_active Not-in-force
- 2012-01-24 JP JP2013551275A patent/JP5739018B2/ja not_active Expired - Fee Related
- 2012-01-24 CN CN201510105205.0A patent/CN104788368B/zh not_active Expired - Fee Related
- 2012-01-24 KR KR1020137021995A patent/KR101537879B1/ko not_active Expired - Fee Related
- 2012-01-24 BR BRBR102012001636-2A patent/BR102012001636A2/pt not_active Application Discontinuation
- 2012-01-24 CN CN201280014336.2A patent/CN103874685B/zh not_active Expired - Fee Related
- 2012-01-24 RU RU2013139300/04A patent/RU2545021C1/ru not_active IP Right Cessation
- 2012-01-24 SG SG2013056023A patent/SG192093A1/en unknown
- 2012-01-24 PL PL12739865T patent/PL2668163T3/pl unknown
- 2012-01-24 CA CA2825475A patent/CA2825475C/en not_active Expired - Fee Related
- 2012-01-24 US US13/356,669 patent/US20120190857A1/en not_active Abandoned
- 2012-01-24 MX MX2013008603A patent/MX342328B/es active IP Right Grant
2013
- 2013-07-23 ZA ZA2013/05577A patent/ZA201305577B/en unknown
- 2013-07-24 CO CO13175298A patent/CO6731125A2/es unknown
- 2013-07-24 IL IL227646A patent/IL227646A/en active IP Right Grant
2014
- 2014-02-04 US US14/171,791 patent/US9067890B2/en not_active Expired - Fee Related
- 2014-12-18 HK HK14112715.3A patent/HK1199245A1/xx unknown
- 2014-12-18 HK HK16100734.3A patent/HK1213875A1/zh unknown
2015
- 2015-06-09 US US14/734,347 patent/US9452984B2/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
KR20130121950A (ko)	2013-11-06
RU2013139300A (ru)	2015-04-10
US20150274669A1 (en)	2015-10-01
CN103874685A (zh)	2014-06-18
UA106945C2 (uk)	2014-10-27
AR085022A1 (es)	2013-08-07
CA2825475C (en)	2017-08-22
WO2012103041A3 (en)	2014-05-01
US20140142317A1 (en)	2014-05-22
ZA201305577B (en)	2014-09-25
EP2668163A2 (en)	2013-12-04
CA2825475A1 (en)	2012-08-02
BR102012001636A2 (pt)	2015-07-28
MX342328B (es)	2016-09-22
US9452984B2 (en)	2016-09-27
WO2012103041A2 (en)	2012-08-02
IL227646A (en)	2016-10-31
CN104788368B (zh)	2017-09-26
SG192093A1 (en)	2013-08-30
BR112013019025A2 (pt)	2016-07-12
CO6731125A2 (es)	2013-08-15
RU2545021C1 (ru)	2015-03-27
AU2012209277B2 (en)	2015-09-17
JP2014515725A (ja)	2014-07-03
JP5739018B2 (ja)	2015-06-24
IL227646A0 (en)	2013-09-30
HK1213875A1 (zh)	2016-07-15
MX2013008603A (es)	2013-08-12
US20120190857A1 (en)	2012-07-26
CN103874685B (zh)	2016-02-03
EP2668163B1 (en)	2017-05-10
HK1199245A1 (en)	2015-06-26
CN104788368A (zh)	2015-07-22
TWI592401B (zh)	2017-07-21
EP2668163A4 (en)	2015-03-11
US9067890B2 (en)	2015-06-30
KR101537879B1 (ko)	2015-07-17
TW201309649A (zh)	2013-03-01

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