ES2174093T3 - CLEANING AGENT WITH ACTIVATING COMPLEXES FOR PEROXI COMPOUNDS. - Google Patents
CLEANING AGENT WITH ACTIVATING COMPLEXES FOR PEROXI COMPOUNDS.Info
- Publication number
- ES2174093T3 ES2174093T3 ES96927691T ES96927691T ES2174093T3 ES 2174093 T3 ES2174093 T3 ES 2174093T3 ES 96927691 T ES96927691 T ES 96927691T ES 96927691 T ES96927691 T ES 96927691T ES 2174093 T3 ES2174093 T3 ES 2174093T3
- Authority
- ES
- Spain
- Prior art keywords
- sup
- sub
- hydrogen
- atoms
- rent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
COMO ACTIVADORES PARA COMPUESTOS DE PEROXI EN SOLUCIONES LIMPIADORAS PARA SUPERFICIES DURAS, ESPECIALMENTE PARA LA VAJILLA, SE UTILIZAN COMPLEJOS DE METALES DE TRANSICION (III) DE FORMULA (I), EN LA QUE UM ES MANGANESO, HIERRO, COBALTO, RUTENIO O MOLIBDENO, R ES UN RESTO ALQUILENO, ALQUENILENO, FENILENO O CICLOALQUILO, QUE ADEMAS DEL SUSTITUYENTE X PUEDE SER OPCIONALMENTE ALQUILO Y/O ARILO SUSTITUIDO, CON UN TOTAL DE ENTRE 1 Y 12 ATOMOS DE C, DONDE DENTRO DE R LA DISTANCIA MAS CORTA ENTRE LOS ATOMOS DE N QUE FORMAN UN COMPLEJO CON UM ES DE 1 A 5 ATOMOS; X ES -H, -OR SUP,3}, -NO SUB,2}, -F, -CL, -BR O -I; R SUP,1}, R SUP,2} Y R SUP,3}, INDEPENDIENTEMENTE UNOS DE OTROS, SON HIDROGENO O UN RADICAL ALQUILO CON ENTRE 1 Y 4 ATOMOS DE C; Y SUP,1} E Y SUP,2}, SON INDEPENDIENTEMENTE UNOS DE OTROS, HIDROGENO O UN SUSTITUYENTE DESPLAZADOR DE ELECTRONES, Z SUP,1} Y Z SUP,2} SON INDEPENDIENTEMENTE HIDROGENO, -CO SUB,2}M, SO SUB,3}M O -NO SUB,2}, M ES HIDROGENO O UN METAL ALCALINO COMO LITIO, SODIO O POTASIO Y A ES UN LIGANDO ANIONICO EQUILIBRADOR DE LA CARGA. LOS LIMPIADORES PARA LA VAJILLA CONTIENEN PREFERENTEMENTE ENTRE 0,005 % EN PESO Y 0,1 % EN PESO DE DICHOS COMPLEJOS ACTIVADORES.AS ACTIVATORS FOR PEROXY COMPOUNDS IN CLEANING SOLUTIONS FOR HARD SURFACES, ESPECIALLY FOR THE CHAIN, FORMULA (I) TRANSITION METAL COMPLEXES ARE USED, IN WHICH UM IS MANGANESE, IRON, COBALT, RUTENIUM OR GRINDING IT IS A REST RENT, ALKYLENE, PHENYLENE OR CYCLOALKYL, THAT IN ADDITION TO THE SUBSTITUTE X CAN BE OPTIONALLY RENT AND / OR ARILO REPLACED, WITH A TOTAL BETWEEN 1 AND 12 ATOMS OF C, WHERE R WITHIN THE DISTANCE AT N THAT FORM A COMPLEX WITH UM IS 1 TO 5 ATOMS; X ES -H, -OR SUP, 3}, -NO SUB, 2}, -F, -CL, -BR OR -I; R SUP, 1}, R SUP, 2} AND R SUP, 3}, INDEPENDENTLY ONE OF OTHERS, ARE HYDROGEN OR A RADICAL RENT WITH BETWEEN 1 AND 4 ATOMS OF C; AND SUP, 1} EY SUP, 2}, ARE INDEPENDENTLY ONE OF OTHERS, HYDROGEN OR A SUBSTITUTE ELECTRONIC DISPLACER, Z SUP, 1} YZ SUP, 2} ARE INDEPENDENTLY HYDROGEN, -CO SUB, 2} M, SO SUB, 3} MO -NO SUB, 2}, M IS HYDROGEN OR AN ALKAL METAL AS A LITHIUM, SODIUM OR POTASSIUM IS ALREADY A BALANCING ANIONIC BINDING OF THE LOAD. THE DISHWASHERS CLEANERS PREFERENTLY CONTAIN BETWEEN 0.005% BY WEIGHT AND 0.1% BY WEIGHT OF SUCH ACTIVATOR COMPLEXES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19529904A DE19529904A1 (en) | 1995-08-15 | 1995-08-15 | Detergent with activator complexes for peroxygen compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2174093T3 true ES2174093T3 (en) | 2002-11-01 |
Family
ID=7769474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96927691T Expired - Lifetime ES2174093T3 (en) | 1995-08-15 | 1996-08-06 | CLEANING AGENT WITH ACTIVATING COMPLEXES FOR PEROXI COMPOUNDS. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0846156B1 (en) |
| DE (2) | DE19529904A1 (en) |
| ES (1) | ES2174093T3 (en) |
| WO (1) | WO1997007191A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19620267A1 (en) * | 1996-05-20 | 1997-11-27 | Henkel Kgaa | Catalytically active activator complexes with N¶4¶ ligands for peroxygen compounds |
| DE19710370A1 (en) * | 1997-03-13 | 1998-09-17 | Henkel Kgaa | Use of cage metal-enclosed transition metal complexes to enhance coverage |
| DE19713851B4 (en) * | 1997-04-04 | 2006-07-20 | Henkel Kgaa | Use of complexes of molybdenum, vanadium or tungsten to enhance the bleaching action |
| DE19728021A1 (en) * | 1997-07-01 | 1999-01-07 | Clariant Gmbh | Metal complexes as bleach activators |
| EP1105454A1 (en) * | 1998-08-19 | 2001-06-13 | Ciba SC Holding AG | Manganese complexes as catalysts for peroxygenated compounds to clean hard surfaces, especially dishes |
| DE10058645A1 (en) | 2000-11-25 | 2002-05-29 | Clariant Gmbh | Use of cyclic sugar ketones as catalysts for peroxygen compounds |
| DE10102248A1 (en) | 2001-01-19 | 2002-07-25 | Clariant Gmbh | Use of transition metal complexes with oxime ligands as bleach catalysts |
| DE10345273A1 (en) | 2003-09-30 | 2005-04-21 | Clariant Gmbh | Use of transition metal complexes with lactam ligands as bleach catalysts |
| DE102004003710A1 (en) | 2004-01-24 | 2005-08-11 | Clariant Gmbh | Use of transition metal complexes as bleaching catalysts in detergents and cleaners |
| DE102011010818A1 (en) | 2011-02-10 | 2012-08-16 | Clariant International Ltd. | Use of transition metal complexes as bleaching catalysts in detergents and cleaners |
| CN105350277A (en) * | 2015-12-16 | 2016-02-24 | 上海市纺织科学研究院 | Low-temperature bleaching formula and technology for cellulose fiber spunlace nonwoven fabric |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8908416D0 (en) * | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
| GB8915781D0 (en) * | 1989-07-10 | 1989-08-31 | Unilever Plc | Bleach activation |
| ES2100925T3 (en) * | 1990-05-21 | 1997-07-01 | Unilever Nv | WHITENING ACTIVATION. |
| CA2085642A1 (en) * | 1991-12-20 | 1993-06-21 | Ronald Hage | Bleach activation |
| ATE169330T1 (en) * | 1993-06-19 | 1998-08-15 | Ciba Geigy Ag | INHIBITION OF REABSORPTION OF MIGRING DYES IN THE WASH SOLUTION |
| ATE269392T1 (en) * | 1994-07-21 | 2004-07-15 | Ciba Sc Holding Ag | BLEACHING AGENT COMPOSITION FOR FABRIC |
| EP0807159B1 (en) * | 1995-02-02 | 2000-05-24 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt chelated catalysts |
-
1995
- 1995-08-15 DE DE19529904A patent/DE19529904A1/en not_active Withdrawn
-
1996
- 1996-08-06 WO PCT/EP1996/003465 patent/WO1997007191A1/en active IP Right Grant
- 1996-08-06 ES ES96927691T patent/ES2174093T3/en not_active Expired - Lifetime
- 1996-08-06 DE DE59608926T patent/DE59608926D1/en not_active Expired - Lifetime
- 1996-08-06 EP EP96927691A patent/EP0846156B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO1997007191A1 (en) | 1997-02-27 |
| EP0846156A1 (en) | 1998-06-10 |
| DE19529904A1 (en) | 1997-02-20 |
| EP0846156B1 (en) | 2002-03-20 |
| DE59608926D1 (en) | 2002-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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