BR0300729B1 - Copper-based catalyst preparation process, catalysts thus prepared and process for obtaining ethyl acetate from ethanol. - Google Patents
Copper-based catalyst preparation process, catalysts thus prepared and process for obtaining ethyl acetate from ethanol.Info
- Publication number
- BR0300729B1 BR0300729B1 BRPI0300729-4A BR0300729A BR0300729B1 BR 0300729 B1 BR0300729 B1 BR 0300729B1 BR 0300729 A BR0300729 A BR 0300729A BR 0300729 B1 BR0300729 B1 BR 0300729B1
- Authority
- BR
- Brazil
- Prior art keywords
- catalysts
- ethanol
- copper
- prepared
- ethyl acetate
- Prior art date
Links
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 title 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title 2
- 239000003054 catalyst Substances 0.000 title 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title 1
- 229910052802 copper Inorganic materials 0.000 title 1
- 239000010949 copper Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
- C07C67/40—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester by oxidation of primary alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/394—Metal dispersion value, e.g. percentage or fraction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0300729-4A BR0300729B1 (en) | 2003-03-12 | 2003-03-12 | Copper-based catalyst preparation process, catalysts thus prepared and process for obtaining ethyl acetate from ethanol. |
| PCT/BR2004/000028 WO2004080589A2 (en) | 2003-03-12 | 2004-03-12 | Copper-based catalysts, process for preparing same and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0300729-4A BR0300729B1 (en) | 2003-03-12 | 2003-03-12 | Copper-based catalyst preparation process, catalysts thus prepared and process for obtaining ethyl acetate from ethanol. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0300729A BR0300729A (en) | 2004-11-16 |
| BR0300729B1 true BR0300729B1 (en) | 2013-04-09 |
Family
ID=32968095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0300729-4A BR0300729B1 (en) | 2003-03-12 | 2003-03-12 | Copper-based catalyst preparation process, catalysts thus prepared and process for obtaining ethyl acetate from ethanol. |
Country Status (2)
| Country | Link |
|---|---|
| BR (1) | BR0300729B1 (en) |
| WO (1) | WO2004080589A2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007147783A2 (en) * | 2006-06-21 | 2007-12-27 | Basf Se | Adsorption mass and method for eliminating co from streams of substances |
| CN108276280B (en) * | 2018-02-07 | 2020-09-25 | 中国科学院兰州化学物理研究所 | Method for preparing formate compounds |
| CN110171803B (en) * | 2019-04-29 | 2022-11-01 | 上海电气集团股份有限公司 | Method and system for preparing hydrogen from ethanol |
| CN115368237B (en) * | 2021-05-18 | 2024-07-23 | 中国石油化工股份有限公司 | Synthesis method of glyoxylate |
| CN113908841A (en) * | 2021-10-11 | 2022-01-11 | 华东师范大学 | Application of a Cu-based catalyst in the preparation of pentanediol by hydrogenolysis of furfuryl alcohol |
| CN116060003B (en) * | 2021-10-31 | 2024-05-07 | 中国石油化工股份有限公司 | Ester hydrogenation catalyst and preparation method and application thereof |
| CN114713224B (en) * | 2022-04-02 | 2023-06-23 | 厦门大学 | Catalyst for preparing ethylamine by catalyzing ethanol amination and its preparation method and application |
| CN117138783A (en) * | 2023-08-30 | 2023-12-01 | 安徽大学 | A catalyst with a double yolk egg-shaped structure wrapped with beta molecular sieve and its preparation method and application |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB312345A (en) * | 1928-05-26 | 1930-08-05 | Du Pont | Improvements in catalytic dehydrogenation |
| SU789155A1 (en) * | 1978-07-07 | 1980-12-23 | Институт катализа | Method of producing catalysts for deep oxidation of hydrocarbon |
| JPS6097047A (en) * | 1983-11-01 | 1985-05-30 | Toyota Central Res & Dev Lab Inc | oxidation catalyst |
| US4939292A (en) * | 1985-08-01 | 1990-07-03 | Phillips Petroleum Company | Synthesis of esters from alcohols containing carbon monoxide as an impurity |
| JPH0764780B2 (en) * | 1986-08-19 | 1995-07-12 | 出光興産株式会社 | Method for producing carboxylic acid ester |
| JPH03262516A (en) * | 1990-03-12 | 1991-11-22 | Riken Corp | Aldehyde converting catalyst |
| US5155077A (en) * | 1991-09-03 | 1992-10-13 | Ford Motor Company | Catalyst for purification of lean-burn engine exhaust gas |
| JPH0884911A (en) * | 1994-09-14 | 1996-04-02 | I C T:Kk | Catalyst for decomposing nitrogen oxides and method for purifying exhaust gas of diesel engine using the same |
| JP3345637B2 (en) * | 1999-05-20 | 2002-11-18 | 独立行政法人産業技術総合研究所 | Method for producing hydroxy compound and catalyst for producing the same |
-
2003
- 2003-03-12 BR BRPI0300729-4A patent/BR0300729B1/en active IP Right Grant
-
2004
- 2004-03-12 WO PCT/BR2004/000028 patent/WO2004080589A2/en active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| BR0300729A (en) | 2004-11-16 |
| WO2004080589A3 (en) | 2004-11-04 |
| WO2004080589A2 (en) | 2004-09-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 09/04/2013, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B22L | Other matters related to patents and certificates of addition of invention: notification of licence offer (art 64 par 1 of lpi) |
Free format text: CONDICOES CONTRATUAIS: 1) ROYALTIES: TAXA UNICA PARA UTILIZACAO DA TECNOLOGIA - R$ 16.000,00 (DEZESSEIS MIL REAIS) MAIS 5% (CINCO POR CENTO) SOBRE O VALOR DAS VENDAS (RECEITA LIQUIDA); 2) PRAZO: ATE O TERMINO DA VIGENCIA DA PATENTE, EM 12.03.2023; 3) CONDICOES DE PAGAMENTO: TRIMESTRAL EM FUNCAO DAS VENDAS APURADAS NO PERIODO; 4) DISPONIBILIDADE DE KNOW-HOW: SIM; 5) ASSISTENCIA TECNICA: NAO. |
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| B22L | Other matters related to patents and certificates of addition of invention: notification of licence offer (art 64 par 1 of lpi) |
Free format text: CONDICOES CONTRATUAIS: 1) ROYALTIES: TAXA UNICA PARA UTILIZACAO DA TECNOLOGIA - R$ 7.000,00 (SETE MIL REAIS) MAIS 5% (CINCO POR CENTO) SOBRE O VALOR DAS VENDAS (RECEITA LIQUIDA); 2) PRAZO: ATE O TERMINO DA VIGENCIA DA PATENTE, EM 19.05.2019; 3) CONDICOES DE PAGAMENTO: TRIMESTRAL EM FUNCAO DAS VENDAS APURADAS NO PERIODO; 4) DISPONIBILIDADE DE KNOW-HOW: SIM; 5) ASSISTENCIA TECNICA: NAO. |