NL2008810C2 - Electroluminescent composition. - Google Patents
Electroluminescent composition. Download PDFInfo
- Publication number
- NL2008810C2 NL2008810C2 NL2008810A NL2008810A NL2008810C2 NL 2008810 C2 NL2008810 C2 NL 2008810C2 NL 2008810 A NL2008810 A NL 2008810A NL 2008810 A NL2008810 A NL 2008810A NL 2008810 C2 NL2008810 C2 NL 2008810C2
- Authority
- NL
- Netherlands
- Prior art keywords
- organic
- luminescent
- group
- metal
- electroluminescent composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 58
- 125000005647 linker group Chemical group 0.000 claims description 47
- 150000001875 compounds Chemical class 0.000 claims description 42
- 239000000891 luminescent agent Substances 0.000 claims description 37
- 125000000524 functional group Chemical group 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 22
- -1 nitrogen-containing carboxylates Chemical class 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 20
- 239000002184 metal Substances 0.000 claims description 20
- 125000002524 organometallic group Chemical group 0.000 claims description 16
- 239000011159 matrix material Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 12
- 239000011148 porous material Substances 0.000 claims description 11
- 229920001940 conductive polymer Polymers 0.000 claims description 10
- 230000005693 optoelectronics Effects 0.000 claims description 10
- 125000000623 heterocyclic group Chemical group 0.000 claims description 9
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 8
- 125000003277 amino group Chemical group 0.000 claims description 7
- 150000002902 organometallic compounds Chemical class 0.000 claims description 7
- 229910052733 gallium Inorganic materials 0.000 claims description 6
- 229910052738 indium Inorganic materials 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 6
- 125000004104 aryloxy group Chemical group 0.000 claims description 5
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 5
- 229910052693 Europium Inorganic materials 0.000 claims description 4
- 229910052771 Terbium Inorganic materials 0.000 claims description 4
- 150000007942 carboxylates Chemical class 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical class C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 4
- 238000000295 emission spectrum Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 150000002910 rare earth metals Chemical class 0.000 claims description 4
- 229910052706 scandium Inorganic materials 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- 229910052691 Erbium Inorganic materials 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 3
- 125000002252 acyl group Chemical group 0.000 claims description 3
- 125000004442 acylamino group Chemical group 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004414 alkyl thio group Chemical group 0.000 claims description 3
- 125000000304 alkynyl group Chemical group 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 claims description 3
- 125000005110 aryl thio group Chemical group 0.000 claims description 3
- 239000011244 liquid electrolyte Substances 0.000 claims description 3
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 claims description 3
- 150000003003 phosphines Chemical class 0.000 claims description 3
- 229920000767 polyaniline Polymers 0.000 claims description 3
- 229920000123 polythiophene Polymers 0.000 claims description 3
- 125000006296 sulfonyl amino group Chemical group [H]N(*)S(*)(=O)=O 0.000 claims description 3
- 125000004149 thio group Chemical group *S* 0.000 claims description 3
- 229910052695 Americium Inorganic materials 0.000 claims description 2
- 241000195493 Cryptophyta Species 0.000 claims description 2
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- 229910052688 Gadolinium Inorganic materials 0.000 claims description 2
- 229910052689 Holmium Inorganic materials 0.000 claims description 2
- 229910052766 Lawrencium Inorganic materials 0.000 claims description 2
- 229910052764 Mendelevium Inorganic materials 0.000 claims description 2
- 229910052781 Neptunium Inorganic materials 0.000 claims description 2
- 229910052778 Plutonium Inorganic materials 0.000 claims description 2
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- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229910052776 Thorium Inorganic materials 0.000 claims description 2
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- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 125000005067 haloformyl group Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 150000002460 imidazoles Chemical class 0.000 claims description 2
- 150000002466 imines Chemical class 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 230000001699 photocatalysis Effects 0.000 claims description 2
- 238000007146 photocatalysis Methods 0.000 claims description 2
- 229920001088 polycarbazole Polymers 0.000 claims description 2
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- 150000004032 porphyrins Chemical class 0.000 claims description 2
- 150000003222 pyridines Chemical class 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 150000003852 triazoles Chemical class 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims 2
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- 229930002875 chlorophyll Natural products 0.000 claims 1
- 235000019804 chlorophyll Nutrition 0.000 claims 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- 150000002311 glutaric acids Chemical class 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 150000002531 isophthalic acids Chemical class 0.000 claims 1
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- 150000003444 succinic acids Chemical class 0.000 claims 1
- 150000003504 terephthalic acids Chemical class 0.000 claims 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical group C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 claims 1
- 150000003639 trimesic acids Chemical class 0.000 claims 1
- 239000012621 metal-organic framework Substances 0.000 description 73
- 239000013206 MIL-53 Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000004411 aluminium Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000005401 electroluminescence Methods 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- 239000013078 crystal Substances 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012552 review Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000000990 laser dye Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000013177 MIL-101 Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 2
- 125000005162 aryl oxy carbonyl amino group Chemical group 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- VSSSHNJONFTXHS-UHFFFAOYSA-N coumarin 153 Chemical compound C12=C3CCCN2CCCC1=CC1=C3OC(=O)C=C1C(F)(F)F VSSSHNJONFTXHS-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
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- 239000000975 dye Substances 0.000 description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
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- 229910052747 lanthanoid Inorganic materials 0.000 description 2
- 150000002602 lanthanoids Chemical class 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000007144 microwave assisted synthesis reaction Methods 0.000 description 2
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- 229920000553 poly(phenylenevinylene) Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012990 sonochemical synthesis Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241001082241 Lythrum hyssopifolia Species 0.000 description 1
- 239000013291 MIL-100 Substances 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001266 acyl halides Chemical class 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000000231 atomic layer deposition Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
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- 230000007774 longterm Effects 0.000 description 1
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- 239000013335 mesoporous material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000013384 organic framework Substances 0.000 description 1
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- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- RPGWZZNNEUHDAQ-UHFFFAOYSA-N phenylphosphine Chemical class PC1=CC=CC=C1 RPGWZZNNEUHDAQ-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical class [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001443 photoexcitation Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920002098 polyfluorene Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
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- 238000006862 quantum yield reaction Methods 0.000 description 1
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- 230000000171 quenching effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000004729 solvothermal method Methods 0.000 description 1
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- 239000012780 transparent material Substances 0.000 description 1
- 239000006163 transport media Substances 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
- H05B33/145—Arrangements of the electroluminescent material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Electroluminescent Light Sources (AREA)
Claims (20)
1. Elektroluminescerende samenstelling omvattende een mengsel van één of meer luminescerende metaalorganische netwerken en een matrixmateriaal als de continue fase, waarbij de genoemde één of meer luminescerende metaalorganische netwerken anorganische connectors verbonden door linkers 5 omvatten, waarbij het genoemde netwerk voorts één of meer luminescerende middelen omvat, waarbij i) ten minste een deel van de genoemde linkers luminescerende linkers zijn, die één of meer luminescerende organometaaldelen en/of organische luminescerende delen als luminescerende middelen omvatten; 10 ii) één of meer luminescerende organometaalverbindingen en/of organische luminescerende verbindingen als luminescerende middelen in de poriën van het netwerk aanwezig zijn; en/of iii) één of meer luminescerende organometaalverbindingen, anorganische luminescerende verbindingen, organische luminescerende verbindingen en/of 15 organische-anorganische luminescerende verbindingen op lege metaalplaatsen van het metaalorganische netwerk worden geënt.
2. Elektroluminescerende samenstelling volgens conclusie 1, waarbij de genoemde anorganische connectors één of meer gekozen uit Al, Zn, Cu, Cr, In,
20 Ga, Fe, Sc, Ti, V, Co, Ni, La, Ce, Pr, Nb, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Ac, Th, Pa, U, Np, Pu, Am, Cm, Bk, Cf, Es, Fm, Md, No en Lr omvatten, bij voorkeur de genoemde anorganische connectors één of meer gekozen uit Al, Ga,, In, Fe, Cr en Sc omvatten, met een grotere voorkeur de genoemde anorganische connectors één of meer gekozen uit Al, In en Ga 25 omvatten.
3. Elektroluminescerende samenstelling volgens conclusie 1 of 2, waarbij de luminescerende linkers het reactieproduct zijn van i) een organische linker voorzien van een functionele groep; en ii) één of meer luminescerende organometaalverbindingen en/of organische luminescerende verbindingen.
4. Elektroluminescerende samenstelling volgens conclusie 3, waarbij de 5 genoemde functionele groep wordt gekozen uit de groep bestaande uit een amine, een nitraat, een imine, een pyridyl of derivaat daarvan, en een haloformyl en een halogeen.
5. Elektroluminescerende samenstelling volgens één der conclusies 1-4, 10 waarbij de genoemde linkers porfyrinen, perylenen, carboxylaten, waaronder stikstofbevattende carboxylaten, bij voorkeur carboxylaten gekozen uit de groep bestaande uit pyridinen, imidazolen, bipyridinen, triazolen, oxaalzuren, malonzuren, barnsteenzuren, glutaarzuren, ftaalzuren, isoftaalzuren, tereftaalzuren, citroenzuren, trimesinezuren, zijn of daarop zijn gebaseerd. 15
6. Elektroluminescerende samenstelling volgens één der conclusies 1-5, waarbij de genoemde één of meer luminescerende organometaaldelen en/of organische luminescerende delen één of meer gekozen uit een zeldzaam-aardmetaal-complex, een fenyl-gebaseerd fosfine en een fosfïneoxide omvatten. 20
7. Elektroluminescerende samenstelling volgens één der conclusies 1-6, waarbij de genoemde één of meer luminescerende organometaalverbindingen en/of organische luminescerende verbindingen één of meer gekozen uit een zeldzaam-aardmetaal-complex, een fenyl-gebaseerd fosfine, een fosfineoxide, 25 gesubstitueerde fosfinen bevattende waterstof, een alkylgroep, een alkenylgroep, een alkynylgroep, een arylgroep, een aminogroep, een alkoxygroep, een aryloxygroep, een heterocyclische oxygroep, een acylgroep, een alkkoxycarbonylgroep, een aryloxycarbonylgroep, een acyloxygroep, een acylaminogroep, een alkoxycarbonylaminogroep, een 30 aryloxycarbonylaminogroep, een sulfonylaminogroep, een sulfamoylgroep, een alkylthiogroep, een arylthiogroep, een heterocyclische thiogroep of een heterocyclische groep omvatten.
8. Elektroluminescerende samenstelling volgens één der conclusies 1-7, 5 waarbij het genoemde metaalorganische netwerk een fosfineoxide- gefunctionaliseerd aminometaalorganisch netwerk of een gefosfïneerd aminometaalorganisch netwerk is.
9. Elektroluminescerende samenstelling volgens één der conclusies 1-8, 10 waarbij het genoemde netwerk een eendimensionale poriestructuur heeft.
10. Elektroluminescerende samenstelling volgens één der conclusies 1-9, waarbij het genoemde netwerk een tweedimensionale of driedimensionale poriestructuur heeft. 15
11. Elektroluminescerende samenstelling volgens één der conclusies 1-10, waarbij 50 % of meer van het aantal linkers een luminescerende middel omvatten, bij voorkeur 60 % of meer van de linkers, met een grotere voorkeur 70 % of meer, zoals 70-90 % of 70-80 %. 20
12. Elektroluminescerende samenstelling volgens één der conclusies 1-11, waarbij het materixmateriaal één of meer gekozen uit de groep bestaande uit een elektrisch geleidend polymeer, een elektrisch niet geleidend polymeer, een amalgamaatpasta en een vloeibare elektrolyt omvat, bij voorkeur het 25 elektrisch geleidende materixmateriaal één of meer elektrisch geleidende polymeren omvat.
13. Elektroluminescerende samenstelling volgens conclusie 12, waarbij de genoemde elektrisch geleidende polymeren worden gekozen uit de groep 30 bestaande uit polythiofenen, polyanilinen, polycarbazolen en polypyrrolen.
14. Elektroluminescerende samenstelling volgens één der conclusies 1-13, waarbij het genoemde mengsel 2-50 gew.-% van de één of meer luminescerende poreuze metaalorganische netwerken, zoals 5-25 gew.-%, gebaseerd op het totale gewicht van het mengsel, omvat. 5
15. Elektroluminescerende samenstelling volgens één der conclusies 1-14, waarbij het genoemde mengsel twee of meer luminescerende poreuze metaalorganische netwerken omvat, en waarbij elk van de genoemde luminescerende metaalorganische netwerken een verschillend of overlappend 10 emissiespectrum heeft.
16. Werkwijze voor het bereiden van een elektroluminescerende samenstelling volgens één der conclusies 1-15, omvattende i) het bereiden van een metaalorganisch netwerk onder gebruikmaking 15 van een organische linker met een functionele groep, bij voorkeur een functionele groep volgens conclusie 5; ii) het laten reageren van de genoemde functionele groep met één of meer luminescerende organometaalverbindingen en / of organische luminescerende verbindingen; en daarna 20 iii) het mengen van het genoemde metaalorganische netwerk met een materixmateriaal, waarbij stap i) voorafgaand aan stap ii) wordt uitgevoerd of waarbij stap ii) voorafgaand aan stap i) wordt uitgevoerd. 1 Werkwijze voor het bereiden van een elektroluminescerende 25 samenstelling volgens één der conclusies 1-15, omvattende i) het bereiden van een metaalorganisch netwerk onder gebruikmaking van een organische linker; iii) het absorberen van één of meer luminescerende organometaalverbindingen en/of organische luminescerende verbindingen bij 30 het inwendige oppervlak van het metaalorganische netwerk; en daarna iii) het mengen van het genoemde metaalorganische netwerk met een materixmateriaal, waarbij stap i) voorafgaand aan stap ii) wordt uitgevoerd of waarbij stap ii) voorafgaand aan stap i) wordt uitgevoerd. 5
18. Opto-elektronische inrichting omvattende een elektroluminescerende samenstelling volgens één der conclusies 1-15.
19. Opto-elektronische inrichting volgens conclusie 18 in de vorm van een 10 lichtemitterende inrichting.
20. Toepassing van een opto-elektronische inrichting volgens conclusie 18 of 19 voor het laten groeien van algen of andere chlorofylbevattende organismen, het verlichten van broeikassen, zonnecellen, verlichtingspanelen 15 en/of fotokatalyse.
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Citations (3)
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|---|---|---|---|---|
| US20080287583A1 (en) * | 2004-07-05 | 2008-11-20 | Kri, Inc. | Organic/Inorganic Composite |
| US20090242839A1 (en) * | 2006-03-22 | 2009-10-01 | Holger Winkler | Gas-phase infiltration of phosphors into the pore system of inverse opals |
| WO2011133999A1 (en) * | 2010-04-30 | 2011-11-03 | Commonwealth Scientific And Industrial Research Organisation | Crystallisation facilitators for the synthesis of metal organic frameworks |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080287583A1 (en) * | 2004-07-05 | 2008-11-20 | Kri, Inc. | Organic/Inorganic Composite |
| US20090242839A1 (en) * | 2006-03-22 | 2009-10-01 | Holger Winkler | Gas-phase infiltration of phosphors into the pore system of inverse opals |
| WO2011133999A1 (en) * | 2010-04-30 | 2011-11-03 | Commonwealth Scientific And Industrial Research Organisation | Crystallisation facilitators for the synthesis of metal organic frameworks |
Non-Patent Citations (1)
| Title |
|---|
| YUANJING CUI ET AL: "Luminescent Functional Metal-Organic Frameworks", CHEMICAL REVIEWS, vol. 112, no. 2, 8 February 2012 (2012-02-08), pages 1126 - 1162, XP055052696, ISSN: 0009-2665, DOI: 10.1021/cr200101d * |
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