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    Electronic Structure of the YH3 Phase from Angle-Resolved Photoemission Spectroscopy

    J. Hayoz1,*, C. Koitzsch2, M. Bovet1, D. Naumović1, L. Schlapbach1, and P. Aebi2

    • 1Département de Physique, Université de Fribourg, Pérolles, CH-1700 Fribourg, Switzerland
    • 2Institut de Physique, Université de Neuchâtel, CH-2000 Neuchâtel, Switzerland
    • *Present address: SenTec AG, Ringstrasse 39, CH-4106 Therwil BL, Switzerland.

    Phys. Rev. Lett. 90, 196804 – Published 16 May, 2003

    DOI: https://doi.org/10.1103/PhysRevLett.90.196804

    Abstract

    Yttrium can be loaded with hydrogen up to high concentrations causing dramatic structural and electronic changes of the host lattice. We report on angle-resolved photoemission experiments of the Y trihydride phase. Most importantly, we find the absence of metal d bands at the Fermi level and a set of flat, H-induced bands located at much higher binding energy than predicted, indicating an increased electron affinity at H sites.

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