Electronic Structure of the Phase from Angle-Resolved Photoemission Spectroscopy
Phys. Rev. Lett. 90, 196804 – Published 16 May, 2003
DOI: https://doi.org/10.1103/PhysRevLett.90.196804
Abstract
Yttrium can be loaded with hydrogen up to high concentrations causing dramatic structural and electronic changes of the host lattice. We report on angle-resolved photoemission experiments of the Y trihydride phase. Most importantly, we find the absence of metal bands at the Fermi level and a set of flat, H-induced bands located at much higher binding energy than predicted, indicating an increased electron affinity at H sites.