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Electronic correlation in the quasi-two-dimensional electride Y2C

M. Hiraishi1, K. M. Kojima1,2, I. Yamauchi1,*, H. Okabe1,2, S. Takeshita1, A. Koda1,2, R. Kadono1,2, X. Zhang3,†, S. Matsuishi4 et al.

H. Hosono3,4, K. Hirata5, S. Otani5, and N. Ohashi5

  • 1Muon Science Laboratory and Condensed Matter Research Center, Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK-IMSS), Tsukuba, Ibaraki 305-0801, Japan
  • 2Department of Materials Structure Science, The Graduate University for Advanced Studies (Sokendai), Tsukuba, Ibaraki 305-0801, Japan
  • 3Materials and Structures Laboratory, Tokyo Institute of Technology, Yokohama, Kanagawa 226-8503, Japan
  • 4Materials Research Center for Element Strategy, Tokyo Institute of Technology (MCES), Yokohama, Kanagawa 226-8503, Japan
  • 5National Institute for Materials Sciences (NIMS), 1-1, Namiki, Tsukuba, Ibaraki 305-0044, Japan
  • *Present address: Department of Physics, Graduate School of Science and Engineering, Saga University, Saga 840-8502, Japan.
  • Present address: State Key Laboratory of Information Photonics and Optical Communications and School of Science, Beijing University of Posts and Telecommunications, Beijing 100876, China.

Phys. Rev. B 98, 041104(R) – Published 17 July, 2018

DOI: https://doi.org/10.1103/PhysRevB.98.041104

Abstract

The magnetic properties of the electride compound Y2C were investigated by muon spin rotation and magnetic susceptibility on two samples with different forms (polycrystalline and single crystalline), to examine the theoretically predicted Stoner ferromagnetism for electride bands. There was no evidence of static magnetic order in both samples even at temperatures down to 0.024 K. For the polycrystalline sample, the presence of a paramagnetic moment at the Y sites was inferred from the Curie-Weiss behavior of the muon Knight shift and susceptibility, whereas no such tendency was observed in the single-crystalline sample. These observations suggest that the electronic ground state of Y2C is at the limit between weak-to-strong electronic correlation, where on-site Coulomb repulsion is sensitive to a local modulation of the electronic state or a shift in the Fermi level due to the presence of defects and/or impurities.

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