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Silicene on Ag(111): A honeycomb lattice without Dirac bands

S. K. Mahatha1,*, P. Moras2, V. Bellini2,†, P. M. Sheverdyaeva2, C. Struzzi3, L. Petaccia3, and C. Carbone2

  • 1International Center for Theoretical Physics (ICTP), I-34014 Trieste, Italy
  • 2Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche, I-34149 Trieste, Italy
  • 3Elettra Sincrotrone Trieste, Strada Statale 14 km 163.5, I-34149 Trieste, Italy
  • *Corresponding author: sanjoymahatha@gmail.com
  • Present address: Istituto di Nanoscienze, Consiglio Nazionale delle Ricerche, 41125 Modena, Italy.

Phys. Rev. B 89, 201416(R) – Published 30 May, 2014

DOI: https://doi.org/10.1103/PhysRevB.89.201416

Abstract

The discovery of (4×4) silicene formation on Ag(111) raised the question whether silicene maintains its Dirac fermion character, similar to graphene, on a supporting substrate. Previous photoemission studies indicated that the π band forms Dirac cones near the Fermi energy, while theoretical investigations found it shifted at deeper binding energy. By means of angle-resolved photoemission spectroscopy and density-functional theory calculations we show instead that the π-symmetry states lose their local character and the Dirac cone fades out. The formation of an interface state of free-electron-like Ag origin is found to account for spectral features that were theoretically and experimentally attributed to silicene bands of π character.

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