US4591385A - Die material and method of using same - Google Patents
Die material and method of using same Download PDFInfo
- Publication number
- US4591385A US4591385A US06/617,116 US61711684A US4591385A US 4591385 A US4591385 A US 4591385A US 61711684 A US61711684 A US 61711684A US 4591385 A US4591385 A US 4591385A
- Authority
- US
- United States
- Prior art keywords
- parts
- weight
- ammonium phosphate
- alumina
- casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title abstract description 11
- 238000000034 method Methods 0.000 title description 4
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 238000005266 casting Methods 0.000 claims abstract description 22
- 239000000919 ceramic Substances 0.000 claims abstract description 22
- 239000011230 binding agent Substances 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 15
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 15
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 15
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 10
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 10
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000008119 colloidal silica Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 abstract description 16
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 239000013504 Triton X-100 Substances 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/34—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing cold phosphate binders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61C—DENTISTRY; APPARATUS OR METHODS FOR ORAL OR DENTAL HYGIENE
- A61C13/00—Dental prostheses; Making same
- A61C13/0003—Making bridge-work, inlays, implants or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/34—Moulds, cores, or mandrels of special material, e.g. destructible materials
- B28B7/346—Manufacture of moulds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00836—Uses not provided for elsewhere in C04B2111/00 for medical or dental applications
Definitions
- the present invention relates generally to die materials used in the preparation of refractory castings, and particularly to such a material which, when mixed with a liquid binder, provides an easy flow, quick-setting castable ceramic slurry composition.
- Dry blends for use in the preparation of high temperature castable compositions are known from, for example, U.S. Pat. Nos. 2,209,035 to E. M. Prosen and 3,649,732 to K. Brigham et al.
- the known compositions generally include di-hydrated ammonium phosphate mixed with silica or glass, and magnesium oxide.
- An object of the present invention is to overcome the above and other problems in the known die materials.
- Another object of the invention is to provide a dry blend which, when mixed with a suitable liquid binder, will provide a ceramic slurry which is capable of easy flow and quick setting.
- Yet another object of the invention is to provide a method useful for making dental prostheses, according to which a ceramic casting for the purpose can be molded in a minimum of time because of the quick setting ability of the ceramic slurry composition; yet a fine detail, high strength, high temperature resistant, casting will result.
- Another object of the invention is to provide a die material which, although well suited for use as a dry blend in the making of ceramic castings for dental purposes, may also be used for electrical insulators, heat-resistant components or the like.
- a die material includes 50-80 parts by weight of magnesium oxide, 10-40 parts by weight of alumina in particulate form, 2-6 parts by weight of mono-hydrated ammonium phosphate, and 1 to 4 parts by weight of di-hydrated ammonium phosphate. Up to 25% silica can be included if desired.
- a method of making a casting includes the steps of forming an impression mold, providing a dry blend comprising 50 to 80 parts by weight of magnesium oxide, 10 to 40 parts by weight of alumina, 2 to 6 parts by weight of mono-hydrated ammonium phosphate, and 1 to 4 parts by weight of di-hydrated ammonium phosphate; then, chilling a liquid binder comprising a colloidal silica sol to about 55° F., and blending together one portion by weight of the chilled liquid binder and from 1 to 5 portions by weight of the dry blend, proportioned as indicated above, thereby forming a ceramic slurry.
- the method further includes pouring the ceramic slurry into the mold, and placing the slurry-filled mold into a hot water bath whereby the slurry is allowed to set for about 4 to 10 minutes.
- the present invention includes the preparation of a dry blend, and the mixing of the dry blend with a liquid binder such as a material known under the trade name "Ludox” which is a colloidal silica solution of about 40 weight percent solids content.
- a liquid binder such as a material known under the trade name "Ludox” which is a colloidal silica solution of about 40 weight percent solids content.
- the liquid binder used in the present invention comprises about 99.9 parts by weight of the "Ludox" material and about 0.1 parts by weight of a suitable defoamer.
- an impression mold Prior to casting a ceramic die according to the present invention, it is preferred that an impression mold be coated with a surface tension agent, comprising about 95 parts by weight of isopropanol and about 5 parts by weight of a surfactant such as Triton X-100. It has been discovered that the pre-coating of the interior surface of the impression mold with the foregoing surface tension agent serves to reduce surface tension in the molds and thus permits a void-free casting. The precoating with the surface tension agent eliminates the need for a vibrator to reduce bubbles or voids, and enhances the flowability of the ceramic slurry of the invention and the ability of the slurry to creep into intricate shapes in the mold.
- a surface tension agent comprising about 95 parts by weight of isopropanol and about 5 parts by weight of a surfactant such as Triton X-100.
- molten metal is usually applied on the finished ceramic castings to form a metal part or matrix
- facile removal of the metal part after its solidification, without damaging either the ceramic or the metal is necessary.
- a parting agent comprising about 95 parts by weight of varnish and about 5 parts by weight of mica, when brushed on the ceramic casting and allowed to air dry prior to kiln heating the casting, enables the metal part to be easily removed after it solidifies on the casting.
- a dry blend is prepared from the following materials by weight:
- the dry blend it is essential, first, to ball mill the blend of mono hydrated and di hydrated ammonium phosphate to get a fine powder. At that point, the thus formed fine powder is mixed with the other constituents: MgO, Alumina (and silica if desired) in a blending-type mixer for a time sufficient to produce uniformity of blending. This procedure must be followed to have the necessary reaction when the liquid binder is added to the dry blend.
- a liquid binder is prepared from the following materials by weight:
- the liquid binder is then chilled to about 55° F.
- a surface tension reducing agent is applied to an impression mold, any excess being shaken off.
- One portion by weight of the chilled liquid binder is then mixed with 3.75 portions by weight of the dry blend and, after being thoroughly mixed to form a ceramic slurry, the slurry mixture is poured into the cavity of the impression mold.
- the ratio of one portion of chilled liquid binder to 3.75 portions of dry blend can be varied somewhat.
- the liquid binder can be varied from 1 to 5 portions.
- the chilling of the liquid binder allows for an increased pot life for the ceramic slurry, instead of a relatively short setup of 1-2 minutes which would normally result with the described proportions of liquid binder and dry blend, were the liquid binder not chilled.
- the mold filled with the ceramic slurry is placed in a hot water bath, precautions being taken not to wet the ceramic slurry prior to setting.
- the slurry is then allowed to set in the hot water bath for 4-10 minutes, and the ceramic casting thus formed is then removed from the mold.
- a parting agent comprising 95 parts by weight of varnish and 5 parts by weight of mica is thoroughly mixed and then brushed on the ceramic casting after removal from the mold.
- the parting agent is allowed to air dry for about ten minutes, and the casting is then dry heated in a kiln at 250° F. for about one to two hours.
- Molten metal can then be applied to the ceramic casting and, after being allowed to solidify, is removed typically, for dental prosthesis, in the form of a metal jacket.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Epidemiology (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Dental Preparations (AREA)
Abstract
A die material particularly suitable for the making of castings or the like, comprises 50 to 80 parts of magnesium oxide, 10-40 parts of alumina, 2 to 6 parts of monohydrated ammonium phosphate, and 1 to 4 parts of dihydrated ammonium phosphate. The dry blend thus formed, when mixed with a chilled liquid binder containing a collodial silica sol of about 40 weight percent solids content in the ratio of one portion of the liquid binder and from 2 to 5 portions of the dry blend, forms a ceramic slurry which can be readily set in hot water within 4 to 10 minutes. The set ceramic casting is then dry heated to about 250° F. for one to two hours. Molten metal is then applied on the casting for forming a metal jacket to use in dental prostheses.
Description
1. Field of the Invention
The present invention relates generally to die materials used in the preparation of refractory castings, and particularly to such a material which, when mixed with a liquid binder, provides an easy flow, quick-setting castable ceramic slurry composition.
2. Background Information
Dry blends for use in the preparation of high temperature castable compositions are known from, for example, U.S. Pat. Nos. 2,209,035 to E. M. Prosen and 3,649,732 to K. Brigham et al. The known compositions generally include di-hydrated ammonium phosphate mixed with silica or glass, and magnesium oxide.
The prior compositions, however, required relatively long time periods for setting of typically from 20 to 30 minutes. Moreover, in actual practice with such prior compositions, the finished casting cannot be removed from a mold for a minimum of one hour, followed by a slow firing schedule (typically 200° F./hour to 1800° F.) to produce maximum strength for the casting.
An object of the present invention is to overcome the above and other problems in the known die materials.
Another object of the invention is to provide a dry blend which, when mixed with a suitable liquid binder, will provide a ceramic slurry which is capable of easy flow and quick setting.
Yet another object of the invention is to provide a method useful for making dental prostheses, according to which a ceramic casting for the purpose can be molded in a minimum of time because of the quick setting ability of the ceramic slurry composition; yet a fine detail, high strength, high temperature resistant, casting will result.
Another object of the invention is to provide a die material which, although well suited for use as a dry blend in the making of ceramic castings for dental purposes, may also be used for electrical insulators, heat-resistant components or the like.
According to one aspect of the present invention, a die material includes 50-80 parts by weight of magnesium oxide, 10-40 parts by weight of alumina in particulate form, 2-6 parts by weight of mono-hydrated ammonium phosphate, and 1 to 4 parts by weight of di-hydrated ammonium phosphate. Up to 25% silica can be included if desired.
It should be noted here that the inclusion of the mono-hydrated ammonium phosphate in the prescribed proportion, is the key factor in producing the high strength and fast setting characteristics of the castings obtained by the present invention.
In accordance with another aspect of the invention, a method of making a casting includes the steps of forming an impression mold, providing a dry blend comprising 50 to 80 parts by weight of magnesium oxide, 10 to 40 parts by weight of alumina, 2 to 6 parts by weight of mono-hydrated ammonium phosphate, and 1 to 4 parts by weight of di-hydrated ammonium phosphate; then, chilling a liquid binder comprising a colloidal silica sol to about 55° F., and blending together one portion by weight of the chilled liquid binder and from 1 to 5 portions by weight of the dry blend, proportioned as indicated above, thereby forming a ceramic slurry. The method further includes pouring the ceramic slurry into the mold, and placing the slurry-filled mold into a hot water bath whereby the slurry is allowed to set for about 4 to 10 minutes.
The present invention includes the preparation of a dry blend, and the mixing of the dry blend with a liquid binder such as a material known under the trade name "Ludox" which is a colloidal silica solution of about 40 weight percent solids content. Preferably, the liquid binder used in the present invention comprises about 99.9 parts by weight of the "Ludox" material and about 0.1 parts by weight of a suitable defoamer.
Prior to casting a ceramic die according to the present invention, it is preferred that an impression mold be coated with a surface tension agent, comprising about 95 parts by weight of isopropanol and about 5 parts by weight of a surfactant such as Triton X-100. It has been discovered that the pre-coating of the interior surface of the impression mold with the foregoing surface tension agent serves to reduce surface tension in the molds and thus permits a void-free casting. The precoating with the surface tension agent eliminates the need for a vibrator to reduce bubbles or voids, and enhances the flowability of the ceramic slurry of the invention and the ability of the slurry to creep into intricate shapes in the mold.
Moreover, since molten metal is usually applied on the finished ceramic castings to form a metal part or matrix, facile removal of the metal part after its solidification, without damaging either the ceramic or the metal, is necessary. It has been discovered that a parting agent comprising about 95 parts by weight of varnish and about 5 parts by weight of mica, when brushed on the ceramic casting and allowed to air dry prior to kiln heating the casting, enables the metal part to be easily removed after it solidifies on the casting.
By way of example and without intending to limit the scope of the present invention, the following specific examples are provided for further illustration of the present invention.
A dry blend is prepared from the following materials by weight:
MgO (Periclaise fused Magnorite): 69%
Tab. Alumina (325 mesh): 23%
Mono-Hydrated Ammonium Phosphate: 5.5%
Di-Hydrated Ammonium Phosphate: 2.5%
In making the dry blend, it is essential, first, to ball mill the blend of mono hydrated and di hydrated ammonium phosphate to get a fine powder. At that point, the thus formed fine powder is mixed with the other constituents: MgO, Alumina (and silica if desired) in a blending-type mixer for a time sufficient to produce uniformity of blending. This procedure must be followed to have the necessary reaction when the liquid binder is added to the dry blend.
A liquid binder is prepared from the following materials by weight:
Ludox: 99.9%
Defoamer: 0.1%
The liquid binder is then chilled to about 55° F. A surface tension reducing agent is applied to an impression mold, any excess being shaken off.
One portion by weight of the chilled liquid binder is then mixed with 3.75 portions by weight of the dry blend and, after being thoroughly mixed to form a ceramic slurry, the slurry mixture is poured into the cavity of the impression mold. The ratio of one portion of chilled liquid binder to 3.75 portions of dry blend can be varied somewhat. Thus the liquid binder can be varied from 1 to 5 portions.
The chilling of the liquid binder allows for an increased pot life for the ceramic slurry, instead of a relatively short setup of 1-2 minutes which would normally result with the described proportions of liquid binder and dry blend, were the liquid binder not chilled.
The mold filled with the ceramic slurry is placed in a hot water bath, precautions being taken not to wet the ceramic slurry prior to setting. The slurry is then allowed to set in the hot water bath for 4-10 minutes, and the ceramic casting thus formed is then removed from the mold.
A parting agent comprising 95 parts by weight of varnish and 5 parts by weight of mica is thoroughly mixed and then brushed on the ceramic casting after removal from the mold. The parting agent is allowed to air dry for about ten minutes, and the casting is then dry heated in a kiln at 250° F. for about one to two hours. Molten metal can then be applied to the ceramic casting and, after being allowed to solidify, is removed typically, for dental prosthesis, in the form of a metal jacket.
The previous example, that is Example 1, is repeated, except the dry blend is prepared as follows by weight:
MgO: 60%
Alumina: 33.5%
Monohydrated: 4.5%
Dihydrated: 2.0%
The previous examples are followed, except that the dry blend is prepared as follows:
MgO: 60%
Alumina: 32.5%
Monohydrated: 5.0%
Dihydrated: 2.5%
While the foregoing description represents the preferred embodiments of the present invention, it will be obvious to those skilled in the art that various changes and modifications may be made therein without departing from the true spirit and scope of the invention.
Claims (4)
1. A ceramic die for casting a dental prosthesis, produced by providing a composition comprising:
one portion by weight of a liquid binder, comprising colloidal silica sol of about 40% solids content, and from one to five portions by weight of a dry blend, said blend consisting essentially of 50-80 parts by weight of magnesium oxide, 10-40 parts by weight of alumina not coarser than 100 mesh, 2 to 6 parts by weight of monohydrated ammonium phosphate, and 1 to 4 parts by weight of dihydrated ammonium phosphate forming the composition into the desired shape of the die and allowing same to set.
2. A die according to claim 1, in which said dry blend consists essentially of 69 parts by weight of magnesium oxide, 23 parts by weight of alumina, 5.5 parts by weight of monohydrated ammonium phosphate, and 2.5 parts by weight of dihydrated ammonium phosphate.
3. A die as defined in claim 1, in which the particulate size of said alumina is about 325 mesh.
4. A die according to claim 2, in which the particulate size of said alumina is about 325 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/617,116 US4591385A (en) | 1984-06-04 | 1984-06-04 | Die material and method of using same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/617,116 US4591385A (en) | 1984-06-04 | 1984-06-04 | Die material and method of using same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4591385A true US4591385A (en) | 1986-05-27 |
Family
ID=24472315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/617,116 Expired - Fee Related US4591385A (en) | 1984-06-04 | 1984-06-04 | Die material and method of using same |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US4591385A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4834651A (en) * | 1987-06-01 | 1989-05-30 | Fenick Thomas J | Process of forming all porcelain dental prosthesis and thermal conducting pin for use therein |
| US4917347A (en) * | 1988-11-14 | 1990-04-17 | Fenick Thomas J | Refractory die for making porcelain dental prosthesis and a thermal conducting pin for use therein |
| US4918874A (en) * | 1988-08-05 | 1990-04-24 | The Dow Chemical Company | Method of preparing abrasive articles |
| US4980295A (en) * | 1988-11-29 | 1990-12-25 | Udy Doyle C | Process for determination of fat content |
| US5013363A (en) * | 1989-02-06 | 1991-05-07 | Olympus Optical Co., Ltd. | Mold for the casting of glass ceramic |
| US5298200A (en) * | 1987-11-18 | 1994-03-29 | G-C Dental Industrial Corp. | Dental refractory model materials |
| EP0824092A1 (en) * | 1996-08-13 | 1998-02-18 | Richard Dudley Shaw | Refractory binder |
| EP0916430A1 (en) * | 1997-11-14 | 1999-05-19 | Shera-Werkstofftechnologie Gmbh | Process for controlling the expansion of ceramic investment material and use of said material |
| US20020129745A1 (en) * | 2001-03-16 | 2002-09-19 | Semmens Blaine K. | Lightweight cementitious composite material |
| US20080167527A1 (en) * | 2007-01-09 | 2008-07-10 | Slenker Dale E | Surgical systems and methods for biofilm removal, including a sheath for use therewith |
| US20080214891A1 (en) * | 2007-03-01 | 2008-09-04 | Slenker Dale E | Systems and methods for biofilm removal, including a biofilm removal endoscope for use therewith |
| EP1043094B1 (en) * | 1999-04-09 | 2008-12-24 | SHERA-Werkstofftechnologie GmbH & Co.KG | Process for making castings |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2209035A (en) * | 1938-11-26 | 1940-07-23 | Nobilium Products Inc | Refractory investment |
| US2835618A (en) * | 1954-03-09 | 1958-05-20 | Parker Rust Proof Co | Solution and method for producing heat resistant electrical insulation coatings on ferrous surfaces |
| US3649732A (en) * | 1969-10-28 | 1972-03-14 | Ceramco Inc | Castable-refractory die composition essentially free of calcium aluminate and method of using |
| US3960580A (en) * | 1974-11-21 | 1976-06-01 | W. R. Grace & Co. | Magnesium phosphate concrete compositions |
-
1984
- 1984-06-04 US US06/617,116 patent/US4591385A/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2209035A (en) * | 1938-11-26 | 1940-07-23 | Nobilium Products Inc | Refractory investment |
| US2835618A (en) * | 1954-03-09 | 1958-05-20 | Parker Rust Proof Co | Solution and method for producing heat resistant electrical insulation coatings on ferrous surfaces |
| US3649732A (en) * | 1969-10-28 | 1972-03-14 | Ceramco Inc | Castable-refractory die composition essentially free of calcium aluminate and method of using |
| US3960580A (en) * | 1974-11-21 | 1976-06-01 | W. R. Grace & Co. | Magnesium phosphate concrete compositions |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4834651A (en) * | 1987-06-01 | 1989-05-30 | Fenick Thomas J | Process of forming all porcelain dental prosthesis and thermal conducting pin for use therein |
| US5298200A (en) * | 1987-11-18 | 1994-03-29 | G-C Dental Industrial Corp. | Dental refractory model materials |
| US4918874A (en) * | 1988-08-05 | 1990-04-24 | The Dow Chemical Company | Method of preparing abrasive articles |
| US4917347A (en) * | 1988-11-14 | 1990-04-17 | Fenick Thomas J | Refractory die for making porcelain dental prosthesis and a thermal conducting pin for use therein |
| US4980295A (en) * | 1988-11-29 | 1990-12-25 | Udy Doyle C | Process for determination of fat content |
| US5013363A (en) * | 1989-02-06 | 1991-05-07 | Olympus Optical Co., Ltd. | Mold for the casting of glass ceramic |
| EP0824092A1 (en) * | 1996-08-13 | 1998-02-18 | Richard Dudley Shaw | Refractory binder |
| EP0916430A1 (en) * | 1997-11-14 | 1999-05-19 | Shera-Werkstofftechnologie Gmbh | Process for controlling the expansion of ceramic investment material and use of said material |
| EP1043094B1 (en) * | 1999-04-09 | 2008-12-24 | SHERA-Werkstofftechnologie GmbH & Co.KG | Process for making castings |
| US20020129745A1 (en) * | 2001-03-16 | 2002-09-19 | Semmens Blaine K. | Lightweight cementitious composite material |
| US20050058832A1 (en) * | 2001-03-16 | 2005-03-17 | Semmens Blaine K. | Lightweight cementitious composite material |
| US7255738B2 (en) | 2001-03-16 | 2007-08-14 | Conservation Roofing Systems, Inc. | Lightweight cementitious composite material |
| US6833188B2 (en) | 2001-03-16 | 2004-12-21 | Blaine K. Semmens | Lightweight cementitious composite material |
| US20080167527A1 (en) * | 2007-01-09 | 2008-07-10 | Slenker Dale E | Surgical systems and methods for biofilm removal, including a sheath for use therewith |
| US20110009699A1 (en) * | 2007-01-09 | 2011-01-13 | Medtronic Xomed, Inc. | Methods for biofilm removal |
| US20080214891A1 (en) * | 2007-03-01 | 2008-09-04 | Slenker Dale E | Systems and methods for biofilm removal, including a biofilm removal endoscope for use therewith |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4591385A (en) | Die material and method of using same | |
| US6779590B2 (en) | Phosphate investment compositions and methods of use thereof | |
| US2701902A (en) | Method of making molds | |
| US3751276A (en) | Refractory laminate based on negative sol or silicate and positive sol | |
| US2209035A (en) | Refractory investment | |
| US3649732A (en) | Castable-refractory die composition essentially free of calcium aluminate and method of using | |
| JPH0335839A (en) | Molding material | |
| US3303030A (en) | Refractory mold | |
| US3647488A (en) | Dental prosthesis model base composition containing calcium fluoride | |
| US2818619A (en) | Refractory mold, method of making same and composition therefor | |
| US3436236A (en) | Refractory composition | |
| US5373891A (en) | Investment material and mold for dental use and burnout thereof | |
| US4243420A (en) | Particulate material for forming molds and method for producing same | |
| EP0179649A2 (en) | Ceramic materials | |
| JPH02207940A (en) | Molding material of phosphate system | |
| US2851752A (en) | High strength investment casting mold | |
| US3309212A (en) | Manufacture of ceramic shapes or bodies | |
| JPS6287427A (en) | Mold material | |
| US2949375A (en) | Siliceous casting cores | |
| US2195452A (en) | Method of making articles of porcelain | |
| US3802891A (en) | Semi-permanent refractory molds and mold parts | |
| US598632A (en) | Samuel johnston | |
| SU790023A1 (en) | Current-conducting coating for manufacturing casting moulds by lost patterns by electrophoresis method | |
| JPH08104535A (en) | Releasing material slurry | |
| US2211789A (en) | Refractory mold material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: AREMCO PRODUCTS, INC. 23 SNOWDEN AVENUE, OSSINGING Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:PEARSALL, JEANNINE A.;REEL/FRAME:004288/0803 Effective date: 19840528 Owner name: AREMCO PRODUCTS, INC.,NEW YORK Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PEARSALL, JEANNINE A.;REEL/FRAME:004288/0803 Effective date: 19840528 |
|
| REMI | Maintenance fee reminder mailed | ||
| FPAY | Fee payment |
Year of fee payment: 4 |
|
| SULP | Surcharge for late payment | ||
| REMI | Maintenance fee reminder mailed | ||
| LAPS | Lapse for failure to pay maintenance fees | ||
| FP | Expired due to failure to pay maintenance fee |
Effective date: 19940529 |
|
| STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |