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US3266994A - Process and composition for treating of hair - Google Patents

Process and composition for treating of hair Download PDF

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Publication number
US3266994A
US3266994A US290183A US29018363A US3266994A US 3266994 A US3266994 A US 3266994A US 290183 A US290183 A US 290183A US 29018363 A US29018363 A US 29018363A US 3266994 A US3266994 A US 3266994A
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hair
tress
treating
solution
parts
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US290183A
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Carroll R Reiss
Lichtin J Leon
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Realistic Co
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Realistic Co
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Priority to US290183A priority Critical patent/US3266994A/en
Priority to AU4742/66A priority patent/AU474266A/en
Priority to GB19333/66A priority patent/GB1141837A/en
Priority to BE680599D priority patent/BE680599A/xx
Priority to FR60413A priority patent/FR1484804A/en
Priority to CH651166A priority patent/CH478568A/en
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C11/00—Transplanting machines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/20—Halogens; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof

Definitions

  • This invention relates to the treatment of hair as in the permanent waving thereof.
  • An object of this invention is to provide an improved process for waving the hair and chemicals for use in waving the hair.
  • a further object of this invention is to provide a hair waving method and chemicals for use in hair waving which produce curls which retain a tight uniform helical shape on drying and which maintains its improved shape after repeated washings or other treatments which normally weaken curl structure.
  • a reducing solution such as a solution of thioglycolic acid and ammonium hydroxide in water which produces changes in the hair by reducing keratin and which softens the hair to permit shaping of the hair on a mandrel such as a curling rod or the like.
  • An oxidizing agent is applied to the treated hair to neutralize that portion of the reducing agent which remains on the hair and to oxidize the reduced keratin to restore the strength thereof, but the strength is only partially restored upon treatment with the oxidizing agent.
  • a water-soluble, non-toxic salt of a polyvalent metal such as magneisum sulfate, aluminum sulfate, calcium acetate, calcium chlo ride, or the like to an aqueous solution of oxidizing agent.
  • a polyvalent metal such as magnesium brornate, calcium brornate, aluminum brornate or the corresponding iodates or mixtures thereof in neutralizing and treating reduced keratin of the hair.
  • the hair fibres of waves neutralized with our improved compositions have a substantially greater tensile strength than hair fibres neutralized with conventional oxidizing solutions, and the waves are longer lasting and have a lesser tendency for fibres to separate from one another.
  • Oxidizing agents with which our salts can be used include water-soluble ammonium, alkali and alkaline earth bromates, iodates, and periodates, hydrogen peroxide, and urea peroxide and the like.
  • Mixtures of the oxidizing agent and polyvalent salt can be made to form a mixture which can be dissolved in water, and in such a mixture, the oxidizing agent and polyvalent salt can be mixed in approximately the ratio desired in the neutralizing solution.
  • An example of such a mixture contains 100 parts of sodium brornate and 280 parts of MgSO -7H O, all parts being by weight.
  • the neutralizer solution it is preferred to have substantially as great a concentration of polyvalent salt as can be maintained in solution conveniently in order to obtain the maximum effect from the polyvalent salt, but lesser concentrations can be used if desired.
  • Example I A tress of hair including approximately 12 fibres of human hair was wrapped around a quater-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reductant solution containing 7.0% thioglycolic acid and suflicient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water.
  • the tress was then immersed in a neutralizer solution which contained parts of sodium bromate, 280 parts of MgSO -7H O, 3 parts of sodium lauryl ether sulfate together with sufiicient sulfuric acid to bring the composition to a pH of 6.0 and sufficient water to make 1,000 parts of neutralizer solution.
  • the tress was immersed in the neutralizer for 7 minutes.
  • the tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separatefrom one another. On immersion in water, the tress exhibited practically no motion at all, neither expanding into a large helix nor contracting into a tight knotted configuration.
  • Example II A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reductant solution containing 7.0% thioglycolic acid and sufiicient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water.
  • the tress was then immersed in a neutralizer solution which contained 100 parts of sodium brornate, parts of Ca(C H O -H O, 3 parts of sodium lauryl ether sulfate, sufficient sulfuric acid to bring the composition to a pH of 6.0 and sufficient water to make 1,000 parts of neutralizer.
  • the tress was immersed in the neutralizer for 7 minutes.
  • the tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
  • Example III A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held 7 minutes and was then rinsed thoroughly in tepid water.
  • the tress was then immersed in a neutralizer solution.
  • a neutralizer solution 100 parts of sodium bromate, parts of boric acid and 3 parts of sodium alkyl phenoxyether sulfonate were dissolved in 882 parts of water to form a first solution. 38 parts of were dissolved in 62 parts of the first solution, and the resultant neutralizer solution was used at once.
  • the tress was immersed in the neutralizer solution for 7 minutes.
  • the tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
  • Example IV A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reductant solution containing 7.0% thioglycolic acid and sufficient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water. The tress was then immersed in a neutralizer solution which contained parts of sodium periodate, 200 parts of MgSO -7H O and sufiicient water to make 1,000 parts of neutralizer. The tress was immersed in the neutralizer for 7 minutes.
  • the tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
  • Example V A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon.
  • the tress was immersed in a reducta-nt solution containing 7.0% thioglycolic acid and sufiicient ammonia to provide an excess and give a pH of 9.4,
  • the tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water.
  • the tress was then immersed in a neutralizer solution which contained 20 parts of sodium periodate, 300 parts of MgSO -7H O and sufficient water to make 1,000 parts of neutralizer.
  • the tress was immersed in the neutralizer for 7 minutes.
  • the tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
  • Example VI A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon.
  • the tress was immersed in la reductant solution containing 7.0% thioglycolic acid and sufiicient ammonia to provide an excess and give a pH of 9.4.
  • the tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water.
  • the tress was then immersed in a neutralizer solution which contained 250 parts of commercial 6% hydrogen peroxide solution in water, 200 parts of Ca (CzHgOz 2 H20 and sufficient water to make 1,000 parts of neutralizer.
  • the tress was immersed in the neutralizer for 7 minutes.
  • the tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent at least 18 percent by weight of a water soluble non-toxic salt of a polyvalent metal selected from the group consisting of magnesium, aluminum, and calcium.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent at least 20 percent by weight of magnesium sulfate.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqeuous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent at least 38 percent by weight of aluminum sulfate.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent approximately 18 to 20 percent by weight of calcium acetate.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth idoates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement which comprises including in the solution of oxidizing agent at least 18 percent by weight of a water-soluble nontoxic salt of a polyvalent metal selected from the group consisting of magnesium, calcium and aluminum.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth iodates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement which comprises including in the solution of oxidizing agent 20 to 30 percent by weight of magnesium sulfate.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth iodates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement which comprises including in the solution of oxidizing agent approximately 38 percent by weight of aluminum sulfate.
  • a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth iodates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement 5 6 which comprises including in the solution of oxidizing OTHER REFERENCES agent approximately 18 to 20 percent by weight of calcium De Navarre: American Perfumer and Essential Oil Re- 9.
  • a hair treating composition which consists essentiali P g 5.

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Description

United States Patent 3,266,994 PROCESS AND COMPOSITION FOR TREATING OF HAIR Carroll R. Reiss, Green Township, Hamilton County, and
J. Leon Lichtin, Springfield Township, Hamilton County, Ohio, assignors to The Realistic Company, Cincinnati, Ohio, a corporation of Ohio No Drawing. Filed June 24, 1963, Ser. No. 290,I83
9 Claims. (Cl. 167-811) This invention relates to the treatment of hair as in the permanent waving thereof.
An object of this invention is to provide an improved process for waving the hair and chemicals for use in waving the hair.
A further object of this invention is to provide a hair waving method and chemicals for use in hair waving which produce curls which retain a tight uniform helical shape on drying and which maintains its improved shape after repeated washings or other treatments which normally weaken curl structure.
In the waving of hair, it is common practice to soften or treat the hair with a reducing solution such as a solution of thioglycolic acid and ammonium hydroxide in water which produces changes in the hair by reducing keratin and which softens the hair to permit shaping of the hair on a mandrel such as a curling rod or the like. An oxidizing agent is applied to the treated hair to neutralize that portion of the reducing agent which remains on the hair and to oxidize the reduced keratin to restore the strength thereof, but the strength is only partially restored upon treatment with the oxidizing agent. According to our improved method, we add a water-soluble, non-toxic salt of a polyvalent metal such as magneisum sulfate, aluminum sulfate, calcium acetate, calcium chlo ride, or the like to an aqueous solution of oxidizing agent. Alternatively, we employ an aqueous solution of an oxidizing salt of a polyvalent metal such as magnesium brornate, calcium brornate, aluminum brornate or the corresponding iodates or mixtures thereof in neutralizing and treating reduced keratin of the hair. The hair fibres of waves neutralized with our improved compositions have a substantially greater tensile strength than hair fibres neutralized with conventional oxidizing solutions, and the waves are longer lasting and have a lesser tendency for fibres to separate from one another.
Oxidizing agents with which our salts can be used include water-soluble ammonium, alkali and alkaline earth bromates, iodates, and periodates, hydrogen peroxide, and urea peroxide and the like.
Mixtures of the oxidizing agent and polyvalent salt can be made to form a mixture which can be dissolved in water, and in such a mixture, the oxidizing agent and polyvalent salt can be mixed in approximately the ratio desired in the neutralizing solution. An example of such a mixture contains 100 parts of sodium brornate and 280 parts of MgSO -7H O, all parts being by weight. In the neutralizer solution, it is preferred to have substantially as great a concentration of polyvalent salt as can be maintained in solution conveniently in order to obtain the maximum effect from the polyvalent salt, but lesser concentrations can be used if desired.
The following examples are given to illustrate the invention in greater detail, but it is to be understood that the examples are given primarily by way of example, rather than by Way of limitation, except as set forth in the claims. In the following examples and in the remainder hereof, all parts or percentages are given by weight.
Example I A tress of hair including approximately 12 fibres of human hair was wrapped around a quater-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reductant solution containing 7.0% thioglycolic acid and suflicient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water. The tress was then immersed in a neutralizer solution which contained parts of sodium bromate, 280 parts of MgSO -7H O, 3 parts of sodium lauryl ether sulfate together with sufiicient sulfuric acid to bring the composition to a pH of 6.0 and sufficient water to make 1,000 parts of neutralizer solution. The tress was immersed in the neutralizer for 7 minutes. The tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separatefrom one another. On immersion in water, the tress exhibited practically no motion at all, neither expanding into a large helix nor contracting into a tight knotted configuration.
Example II A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reductant solution containing 7.0% thioglycolic acid and sufiicient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water. The tress was then immersed in a neutralizer solution which contained 100 parts of sodium brornate, parts of Ca(C H O -H O, 3 parts of sodium lauryl ether sulfate, sufficient sulfuric acid to bring the composition to a pH of 6.0 and sufficient water to make 1,000 parts of neutralizer. The tress was immersed in the neutralizer for 7 minutes. The tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
Example III A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held 7 minutes and was then rinsed thoroughly in tepid water.
The tress was then immersed in a neutralizer solution. In the preparation of the neutralizer, 100 parts of sodium bromate, parts of boric acid and 3 parts of sodium alkyl phenoxyether sulfonate were dissolved in 882 parts of water to form a first solution. 38 parts of were dissolved in 62 parts of the first solution, and the resultant neutralizer solution was used at once. The tress was immersed in the neutralizer solution for 7 minutes. The tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
Example IV A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reductant solution containing 7.0% thioglycolic acid and sufficient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water. The tress was then immersed in a neutralizer solution which contained parts of sodium periodate, 200 parts of MgSO -7H O and sufiicient water to make 1,000 parts of neutralizer. The tress was immersed in the neutralizer for 7 minutes. The tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
Example V A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in a reducta-nt solution containing 7.0% thioglycolic acid and sufiicient ammonia to provide an excess and give a pH of 9.4, The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water. The tress was then immersed in a neutralizer solution which contained 20 parts of sodium periodate, 300 parts of MgSO -7H O and sufficient water to make 1,000 parts of neutralizer. The tress was immersed in the neutralizer for 7 minutes. The tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
Example VI A tress of hair including approximately 12 fibres of human hair was wrapped around a quarter-inch mandrel in helical fashion, for three complete revolutions and held in place thereon. The tress was immersed in la reductant solution containing 7.0% thioglycolic acid and sufiicient ammonia to provide an excess and give a pH of 9.4. The tress was immersed in the reductant for approximately 7 minutes and was then rinsed thoroughly in tepid water. The tress was then immersed in a neutralizer solution which contained 250 parts of commercial 6% hydrogen peroxide solution in water, 200 parts of Ca (CzHgOz 2 H20 and sufficient water to make 1,000 parts of neutralizer. The tress was immersed in the neutralizer for 7 minutes. The tress was then rinsed in tepid water and removed from the mandrel. On drying in air, the tress retained its uniform helical shape with very little change in diameter and the individual fibres showed no tendency to lose their helical shape or separate from one another.
The neutralizing composition and method of treating hair are subject to variation within the spirit and scope of the appended claims.
Having described our invention, what we claim as new and desire to protect by Letters Patent is:
1. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent at least 18 percent by weight of a water soluble non-toxic salt of a polyvalent metal selected from the group consisting of magnesium, aluminum, and calcium.
2. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent at least 20 percent by weight of magnesium sulfate.
3. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqeuous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent at least 38 percent by weight of aluminum sulfate.
4. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent for reduced keratin, the improvement which comprises including in the solution of oxidizing agent approximately 18 to 20 percent by weight of calcium acetate.
5. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth idoates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement which comprises including in the solution of oxidizing agent at least 18 percent by weight of a water-soluble nontoxic salt of a polyvalent metal selected from the group consisting of magnesium, calcium and aluminum.
6. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth iodates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement which comprises including in the solution of oxidizing agent 20 to 30 percent by weight of magnesium sulfate.
7. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth iodates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement which comprises including in the solution of oxidizing agent approximately 38 percent by weight of aluminum sulfate.
8. In a process for treating hair to impart a permanent set thereto which includes the steps of treating the hair with a reducing agent for keratin and then treating the hair with an aqueous solution of an oxidizing agent selected from the group consisting of soluble ammonium, alkali, and alkaline earth iodates, periodates, and bromates, hydrogen peroxide and urea peroxide, the improvement 5 6 which comprises including in the solution of oxidizing OTHER REFERENCES agent approximately 18 to 20 percent by weight of calcium De Navarre: American Perfumer and Essential Oil Re- 9. A hair treating composition which consists essentiali P g 5. d T h 1 b ly of an aqueous solution of sodium bromate and at least 5 argann' "P an ac no Pu 0 percent by weight of magnesium Sulfate l61shec by lgtersclence Publishers, Inc., N.Y., 1957, pp.
acetate.
References Cited by the Examiner LEWIS GOTTS P E FOREIGN PATENTS 992 156 10/1951 France 10 FRANK CACCIAPAGLIA, JR., Examiner. 295,538 3/1954 Switzerland. RICHARD L. HUFF, Assistant Examiner.

Claims (1)

  1. 9. A HAIR TREATING COMPOSITION WHICH CONSISTS ESSENTIALLY OF AN AQUEOUS SOLUTION OF SODIUM BROMATE AND AT LEAST 20 PERCENT BY WEIGHT OF MAGNESIUM SULFATE.
US290183A 1963-06-24 1963-06-24 Process and composition for treating of hair Expired - Lifetime US3266994A (en)

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Application Number Priority Date Filing Date Title
US290183A US3266994A (en) 1963-06-24 1963-06-24 Process and composition for treating of hair
AU4742/66A AU474266A (en) 1963-06-24 1966-04-27 Process and composition for treating of hair
GB19333/66A GB1141837A (en) 1963-06-24 1966-05-03 Process and composition for treating of hair
BE680599D BE680599A (en) 1963-06-24 1966-05-05
FR60413A FR1484804A (en) 1963-06-24 1966-05-05 Hair treatment process and composition for implementing this process
CH651166A CH478568A (en) 1963-06-24 1966-05-05 Methods and means for treating hair

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US290183A US3266994A (en) 1963-06-24 1963-06-24 Process and composition for treating of hair

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3628544A (en) * 1967-03-03 1971-12-21 Oreal Permanent wave-fixing composition and process
US3935868A (en) * 1972-10-02 1976-02-03 The Procter & Gamble Company Hair setting process
US3964499A (en) * 1974-10-15 1976-06-22 Wella Ag Process for permanently shaping hair
US3981312A (en) * 1975-07-03 1976-09-21 Redken Laboratories, Inc. Hair waving method with a prebonder
EP0134452A2 (en) * 1983-06-30 1985-03-20 Helene Curtis Industries, Inc. Permanent wave neutralizer composition and process
US4614200A (en) * 1983-06-30 1986-09-30 Helene Curtis Industries, Inc. Hair treating method and composition
DE4428575C1 (en) * 1994-08-12 1996-04-11 Goldwell Gmbh Permanent wave agent contg. thio cpd. reducing agent
US5635168A (en) * 1994-09-21 1997-06-03 Business Resources Group, Inc. Composition for treating hair
US5942009A (en) * 1997-03-28 1999-08-24 Brg, Ltd. Same-day waving and coloring of hair
EP2882403A1 (en) * 2012-08-13 2015-06-17 Kao Germany GmbH Aqueous oxidizing composition

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3627746A1 (en) * 1986-08-16 1988-02-18 Henkel Kgaa METHOD FOR PERMANENT HAIR DEFORMING
US6543373B1 (en) * 2000-09-01 2003-04-08 United States Sugar Corporation Methods of planting sugarcane seed to achieve a high plant density

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR992156A (en) * 1944-05-17 1951-10-15 Composition intended for the production of permanent waves of the hair
CH295538A (en) * 1951-10-26 1953-12-31 Salea S A Material to stop the action of waving agents.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR992156A (en) * 1944-05-17 1951-10-15 Composition intended for the production of permanent waves of the hair
CH295538A (en) * 1951-10-26 1953-12-31 Salea S A Material to stop the action of waving agents.

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3628544A (en) * 1967-03-03 1971-12-21 Oreal Permanent wave-fixing composition and process
US3935868A (en) * 1972-10-02 1976-02-03 The Procter & Gamble Company Hair setting process
US3964499A (en) * 1974-10-15 1976-06-22 Wella Ag Process for permanently shaping hair
US3981312A (en) * 1975-07-03 1976-09-21 Redken Laboratories, Inc. Hair waving method with a prebonder
EP0134452A2 (en) * 1983-06-30 1985-03-20 Helene Curtis Industries, Inc. Permanent wave neutralizer composition and process
EP0134452A3 (en) * 1983-06-30 1986-07-16 Helene Curtis Industries, Inc. Permanent wave neutralizer composition and process
US4614200A (en) * 1983-06-30 1986-09-30 Helene Curtis Industries, Inc. Hair treating method and composition
DE4428575C1 (en) * 1994-08-12 1996-04-11 Goldwell Gmbh Permanent wave agent contg. thio cpd. reducing agent
US5635168A (en) * 1994-09-21 1997-06-03 Business Resources Group, Inc. Composition for treating hair
US5942009A (en) * 1997-03-28 1999-08-24 Brg, Ltd. Same-day waving and coloring of hair
EP2882403A1 (en) * 2012-08-13 2015-06-17 Kao Germany GmbH Aqueous oxidizing composition

Also Published As

Publication number Publication date
CH478568A (en) 1969-09-30
GB1141837A (en) 1969-02-05
BE680599A (en) 1966-11-07
AU474266A (en) 1967-11-02

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