US20180304215A1 - System and method for providing deionized water with dynamic electrical resistivity - Google Patents
System and method for providing deionized water with dynamic electrical resistivity Download PDFInfo
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- US20180304215A1 US20180304215A1 US15/627,472 US201715627472A US2018304215A1 US 20180304215 A1 US20180304215 A1 US 20180304215A1 US 201715627472 A US201715627472 A US 201715627472A US 2018304215 A1 US2018304215 A1 US 2018304215A1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/22—Control or regulation
- B01F35/221—Control or regulation of operational parameters, e.g. level of material in the mixer, temperature or pressure
- B01F35/2217—Volume of at least one component to be mixed
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- B01F15/00422—
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- B01F15/00227—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/45—Mixing liquids with liquids; Emulsifying using flow mixing
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- B01F3/0861—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/20—Measuring; Control or regulation
- B01F35/21—Measuring
- B01F35/2133—Electrical conductivity or dielectric constant of the mixture
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
- G03F7/2041—Exposure; Apparatus therefor in the presence of a fluid, e.g. immersion; using fluid cooling means
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70216—Mask projection systems
- G03F7/70341—Details of immersion lithography aspects, e.g. exposure media or control of immersion liquid supply
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D11/00—Control of flow ratio
- G05D11/02—Controlling ratio of two or more flows of fluid or fluent material
- G05D11/13—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means
- G05D11/131—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by measuring the values related to the quantity of the individual components
- G05D11/132—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by measuring the values related to the quantity of the individual components by controlling the flow of the individual components
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D11/00—Control of flow ratio
- G05D11/02—Controlling ratio of two or more flows of fluid or fluent material
- G05D11/13—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means
- G05D11/135—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by sensing at least one property of the mixture
- G05D11/138—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by sensing at least one property of the mixture by sensing the concentration of the mixture, e.g. measuring pH value
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D11/00—Control of flow ratio
- G05D11/02—Controlling ratio of two or more flows of fluid or fluent material
- G05D11/13—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means
- G05D11/139—Controlling ratio of two or more flows of fluid or fluent material characterised by the use of electric means by measuring a value related to the quantity of the individual components and sensing at least one property of the mixture
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05D—SYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
- G05D21/00—Control of chemical or physico-chemical variables, e.g. pH value
- G05D21/02—Control of chemical or physico-chemical variables, e.g. pH value characterised by the use of electric means
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/2496—Self-proportioning or correlating systems
- Y10T137/2499—Mixture condition maintaining or sensing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/2496—Self-proportioning or correlating systems
- Y10T137/2499—Mixture condition maintaining or sensing
- Y10T137/2509—By optical or chemical property
Definitions
- FIG. 1A is a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with some embodiments of the present disclosure.
- FIG. 1B is a schematic view showing the system in FIG. 1A with dampers having rotating angles.
- FIG. 1C is a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with alternative embodiments of the present disclosure.
- FIG. 2A is a flow chart showing a method for providing DI water with dynamic electrical resistivity in accordance with some embodiments of the present disclosure.
- FIG. 2B is a flow chart showing another control operation in the method for providing DI water with dynamic electrical resistivity in accordance with some embodiments of the present disclosure.
- FIG. 3A is a flow chart showing a method for providing DI water having dynamic electrical resistivity is provided in accordance with some embodiments of the present disclosure.
- FIG. 3B is a flowchart showing a control operation for providing DI water with dynamic electrical resistivity in accordance with some embodiments of the present disclosure.
- first and second features are formed in direct contact
- additional features may be formed between the first and second features, such that the first and second features may not be in direct contact
- present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures.
- the apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- DI water is applied in a semiconductor fabricating process for various purposes such as developing, rinsing and/or cleaning in immersion lithography process.
- the DI water having a predetermined electrical resistivity is usually used to avoid accumulation of electrostatic charges on a surface of a wafer during a semiconductor fabricating process.
- the traditional system and method can only provide DI water with a fixed electrical resistivity regardless of a requirement of different electrical resistivities for different wafers or a same wafer in different intermediate stages of the semiconductor fabricating process to effectively reduce the accumulation of electrostatic charges. Therefore, a system and a method for providing DI water with a dynamic electrical resistivity are provided to tackle the problems described above.
- Embodiments of the present disclosure are directed to providing a system and a method of providing DI water with a dynamic electrical resistivity.
- the system includes DI water sources having different electrical resistivities and a flow control device (e.g. a damper or a flow control valve) in each of source pipes to mix DI water having different electrical resistivities, so as to obtain (mixed) DI water having a target electrical resistivity.
- the flow control device may be automatically controlled by a flow controller using a feedback loop. Accordingly, the electrical resistivity of the DI water applied to the semiconductor fabricating process is adjustable during the proceeding process, and the accumulation of electrostatic charges on the surface of the wafer may be effectively reduced.
- the system and the method of the present disclosure provide merits such as low costs, simplification and high performance of the semiconductor fabricating process. A detailed description is provided by incorporating with FIG. 1A through FIG. 3B .
- FIG. 1A is a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with some embodiments of the present disclosure.
- a system 100 includes DI water sources 110 A and 110 B, source pipes 120 A and 120 B, flow control devices 130 A and 130 B, a merging pipe 140 and a flow controller 150 .
- the source pipes 120 A and 120 B are respectively connected to the DI water sources 110 A and 110 B in a one-to-one manner, and the flow control devices 130 A and 130 B are respectively disposed in the source pipes 120 A and 120 B in a one-to-one manner.
- the merging pipe 140 joins the source pipes 120 A and 120 B.
- the DI water sources 110 A and 110 B have different electrical resistivities.
- the electrical resistivities of the DI water source 110 A and 110 B are respectively 24 M ⁇ cm and 12 M ⁇ cm.
- the flow controller 150 is configured to control a flowrate in the source pipes 120 A and 120 B.
- the flow controller 150 includes a resistivity sensor (not shown) disposed in the merging pipe 140 for detecting an actual electrical resistivity of the mixed DI water. In operation, DI water from the DI water sources 110 A and 110 B enters the source pipes 120 A and 120 B, and then collectively enters the merging pipe 140 to be ready for subsequent processes.
- the flow control devices 130 may be flow control valves (not shown), and the flow controller 150 is configured to adjust the degrees of opening of the flow control valves.
- the flow control devices 130 may be dampers with rotating angles, and the flow controller 150 is configured to adjust the degrees of the rotating angles.
- FIG. 1B illustrates a schematic view showing the system in FIG. 1A with dampers having rotating angles.
- the flow control devices 130 A and 130 B are referred to as a damper 130 A having a rotating angle 132 A and a damper 130 B having a rotating angle 132 B, for convenience of explanation.
- the flow controller 150 is configured to adjust the rotating angles 132 A and 132 B of the dampers 130 A and 130 B to control the flowrate of the DI water from the DI water sources 110 A and 110 B. That is, the greater the rotating angles, the greater the flow rates of the DI water.
- the rotating angles 132 A and 132 B of the dampers 130 A and 130 B are in a range substantially from 0° to 90°, in which the rotating angles 132 A is defined as an included angle between a direction perpendicular to a flow direction 170 and a top surfaces 134 A of the damper 130 A, and the rotating angles 132 B is defined as an included angle between the direction perpendicular to the flow direction 170 and a top surfaces 134 B of the damper 130 B.
- the rotating angles 132 A and 132 B may not be 0° at the same time, that is, at least one of the rotating angles 132 A and 132 B is not 0°.
- the rotating angle 132 A of the damper 130 A shown by a dotted-line is 0°
- the rotating angle 132 B of the damper 130 B shown by the dotted-line is 90°
- the rotating angle 132 A of the dampers shown by a solid line is 90°
- the rotating angle 132 B of the damper 130 B shown by the solid line is 0°.
- the flow controller 150 may include a resistivity sensor 152 , in which the resistivity sensor 152 is configured to detect an electrical resistivity of the DI water in the merging pipe 140 .
- the flow controller 150 may further include a driving module 154 and a judging module 156 .
- the driving module 154 is at least signally connected to the dampers 130 A and 130 B to control the rotating angles.
- the judging module 156 is at least signally connected to the resistivity sensor 152 , so as to compare an actual electricity resistivity of the DI water in the merging pipe 140 with a target electricity resistivity.
- the judging module 156 is also signally connected to the driving module 154 .
- the system may further include a calculating module 160 .
- the calculating module 160 may be signally connected to the driving module 154 , in which the calculating module 160 is configured to calculate the rotating angles 132 A and 132 B of the damper 130 A and 130 B for obtaining the DI water having the target electrical resistivity.
- the calculating module 160 performs a calculation according to the following relationship (1):
- R stands for the target electrical resistivity
- n stands for a number of the DI water source
- Ri stands for the electrical resistivity of DI water from the i th DI water source
- Ai stands for the rotating angle of the i th damper.
- the driving module 154 and the dampers 130 A and 130 B, the resistivity sensor 152 and the judging module 156 , the driving module 154 and the judging module 156 , and/or the calculating module 160 and the driving module 154 may be further electrically connected and/or physically connected.
- the resistivity sensor 152 detects an actual electrical resistivity and sends a signal to the judging module 156 , and then the judging module 156 determines if the actual electrical resistivity is substantially equal to a target electrical resistivity and sends a signal to the driving module 154 , the driving module 154 controls the dampers 130 A and 130 B to adjust the rotating angles to adjust the flowrate of the DI water through the source pipes 120 A and 120 B, and the DI water through the adjusted dampers may be detected by the resistivity sensor 152 , thereby forming a feedback loop for controlling the electrical resistivity of water dynamically, as shown in FIG. 1B .
- FIG. 1A and FIG. 1B illustrate only two DI water sources, two sources pipes, and two flow control devices for convenience and simplification of explanation, and embodiments of the present disclosure are not limited thereto. Embodiments of more than two DI water sources, more than two sources pipes, and more than two flow control devices are described hereinafter.
- FIG. 1C illustrates a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with alternative embodiments of the present disclosure.
- a system 100 ′ includes DI water sources 110 C, 110 D, 110 E and more, source pipes 120 C, 120 D, 120 E and more, flow control devices 130 C, 130 D, 130 E and more, a merging pipe 140 ′ and a flow controller 150 ′, which are similar to the DI water sources 110 A and 110 B, the source pipes 120 A and 120 B, the flow control devices 130 A and 130 B, the merging pipe 140 and the flow controller 150 of FIG. 1A and FIG. 1B .
- the DI water sources 110 C, 110 D, 110 E and more may have at least three different electrical resistivities in some embodiments.
- Each of the flow control devices 130 C, 130 D, 130 E and more has its own rotating angles, for example, the flow control device 130 C has a rotating angle 132 C.
- the rotating angle 132 C is defined in a similar way as the rotating angles 132 A and 132 B of FIG. 1B and may not be repeated herein.
- the flow controller 150 ′ includes a resistivity sensor 152 ′, a driving module 154 ′ and a judging module 156 ′, which are similar to the resistivity sensor 152 , the driving module 154 and the judging module 156 of FIG. 1B .
- the following describes method for providing DI water with a dynamic electrical resistivity using the systems 100 and 100 ′, respectively.
- FIG. 2A and FIG. 2B are used to describe a method 200 for providing DI water with a dynamic electrical resistivity in accordance with some embodiments of the present disclosure.
- FIG. 1C is also incorporated, however, the following uses only the DI water sources 110 C, 110 D and 110 E, the source pipes 120 C, 120 D and 120 E, and the flow control devices 130 C, 130 D and 130 E to represent plural DI water sources, source pipes and flow control devices of FIG. 1C for convenience of explanation. Please refer to FIG. 2A and FIG. 1C .
- FIG. 2A illustrates a flow chart showing the method 200 for providing DI water with a dynamic electrical resistivity. As shown in operation 210 in FIG.
- a system for supplying DI water with different electrical resistivities is provided first, for example, the system 100 ′ of FIG. 1C .
- the system may include the merging pipe 140 ′ joining the source pipes 120 C, 120 D and 120 E that are respectively connected to DI water sources 110 C, 110 D and 110 E in a one-to-one manner, in which the DI water sources 110 C, 110 D and 110 E respectively have different electrical resistivities R 1 , R 2 and R 3 , and the flow control devices 130 C, 130 D and 130 E are respectively disposed in the source pipes 120 C, 120 D and 120 E in a one-to-one manner. That is, a number of the source pipes, DI water sources and the flow control devices may be the same.
- the flow control devices mentioned in FIG. 2A may be a flow control valve.
- the flow control devices 130 C, 130 D and 130 E may be dampers, and each of the dampers has its own rotating angle (e.g. the rotating angle 132 C of the damper 130 C). Each rotating angle is in a range substantially from 0° to 90°, and at least one of the rotating angles is not 0°.
- the following takes the dampers 130 C, 130 D and 130 E as an example of the flow control devices 130 C, 130 D and 130 E, while the example is not intended to limit the scope of the present disclosure.
- the dampers 130 C, 130 D and 130 E are initialized to supply DI water from the system. Initializing the dampers 130 C, 130 D and 130 E is aimed at setting an initial state of the dampers 130 C, 130 D and 130 E that is easier to obtain DI water having a target electrical resistivity or close to the target electrical resistivity, in which the initial state may be referred as the rotating angles of the dampers 130 C, 130 D and 130 E to perform the control operation (which will be described later at operation 230 ). To be initialized, the dampers 130 C, 130 D and 130 E may be also signally connected to a driving module 154 ′.
- the initial state may be automatically calculated by the calculating module 160 ′ in some embodiments.
- the calculating module 160 ′ may be signally connected to the driving module 154 ′ of the flow controller 150 ′, so as to transfer the calculation results to the driving module 154 ′.
- the initial state may be achieved by adjusting the rotating angles of the dampers 130 C, 130 D and 130 E, in which the initial state (i.e. the rotating angles) may be calculated by the above relationship (1).
- the initial state may be manually determined in other embodiments.
- the target electrical resistivity may be in a range from a highest electrical resistivity to a lowest electrical resistivity of the DI water in the DI water sources 110 C, 110 D and 110 E.
- FIG. 2B illustrates a flow chart showing the control operation 230 in the method 200 in accordance with some embodiments of the present disclosure.
- the control operation 230 includes operations 232 , 234 and 236 or 238 in some embodiments of the present disclosure.
- an actual electrical resistivity of DI water in the merging pipe 140 ′ is detected.
- the actual electrical resistivity may be detected by a resistivity sensor 152 ′ disposed in the merging pipe 140 ′.
- a judgement is performed to determine whether the actual electrical resistivity is equal to the target electrical resistivity or not. Determining the actual electrical resistivity may be performed by a judging module 156 ′ of the flow controller 150 ′.
- the target electrical resistivity may be setup in the judging module 156 ′ before the control operation 230 starts, and then the actual electrical resistivity is detected (as shown in operation 232 ) and signally transferred from the resistivity sensor 152 ′ to the judging module 156 ′ to perform operation 234 .
- the resistivity sensor 152 ′ and the judging module 156 ′ are signally connected to each other, and the judging module 156 ′ is able to receive a signal from the resistivity sensor 152 ′.
- the target electrical resistivity may be predetermined based on a requirement of the semiconductor fabricating process. Therefore, the target electrical resistivity of the present disclosure does not limited to a fixed value.
- the driving unit 154 ′ is at least signally connected to the judging module 156 ′, so as to receive a signal from the judging module 156 ′.
- the DI water in the merging pipe may be applied to the semiconductor fabricating process.
- the actual electrical resistivity is not equal to the target electrical resistivity (R A R T , referred as “N” in FIG.
- the flowrates through the source pipes 120 A and 120 B are adjusted by adjusting the rotating angle of the dampers 130 C, 130 D and 130 E to supply water again for repeating the control operation 230 , as shown in operation 238 .
- the rotating angles may be stepwise adjusted (increased or decreased) by the driving module 154 ′ of the flow controller 150 ′.
- the term of “stepwise” refers to adjusting the rotating angles by increasing or decreasing a fixed angle at one time.
- the fixed angle may be 0.5°, 1°, 5° or any other suitable angles.
- the degree of openings of the flow control valves may be adjusted to achieve desired flowrate.
- a feedback loop may be established. That is, the actual electrical resistivity is detected (operation 232 ), followed by the judgement of the actual electrical resistivity (operation 234 ) and the adjustment of the rotating angles ( 238 ), and the actual electrical resistivity of the DI water is detected again (operation 232 ) after the rotating angles are adjusted.
- FIG. 3A and FIG. 3B An embodiment using two DI water sources respectively having a high and a low electrical resistivity is shown to further illustrate the application of the method of the present disclosure.
- a flow chart of a method 300 for providing DI water having a dynamic electrical resistivity is provided in accordance with some embodiments of the present disclosure.
- FIG. 1B is also incorporated for clear explanation.
- a system such as the system 100 of FIG. 1B is provided.
- a diameter of the source pipes 120 A and 120 B (or so called a first source pipe and a second source pipe) may be the same in the embodiments described here.
- the DI water sources 110 A and 110 B respectively have a high and a low electrical resistivity.
- the first and second rotating angles 132 A and 132 B are initialized according to the following relationship (2):
- R ′ ⁇ ( M ⁇ ⁇ ⁇ ⁇ cm ) X ⁇ A ⁇ ⁇ 1 + Y ⁇ A ⁇ ⁇ 2 A ⁇ ⁇ 1 + A ⁇ ⁇ 2 ( 2 )
- R′ stands for the target electrical resistivity
- X stands for the high electrical resistivity
- Y stands for the low electrical resistivity
- A1 stands for the first rotating angle 132 A
- A2 stands for the second rotating angle 132 B.
- the first and second rotating angles 132 A and 132 B may be in a range substantially from 0° to 90°, and at least one of the first and second rotating angles 132 A and 132 B is not 0°.
- the high electrical resistivity X may be 24 M ⁇ cm and the low electrical resistivity Y may be 12 M ⁇ cm.
- the rotating angles A1 and A2 may be the same, for example, both the rotating angles A1 and A2 may be initialized to 45°.
- initializing the first and second rotating angles 132 A and 132 B is performed by a similar method mentioned in operation 220 of FIG. 2A and may not be repeated herein.
- FIG. 3B illustrates a flowchart showing the control operation 330 in accordance with some embodiments of the present disclosure.
- operation 331 an actual electrical resistivity of the DI water in the merging pipe 140 is detected, in which operation 331 of FIG. 3B is similar to operation 232 A of FIG. 2B and may not be repeated herein.
- operation 333 a judgement is performed to determine whether the actual electrical resistivity (R A ) is substantially equal to the target electrical resistivity (R T ).
- Operation 333 of FIG. 3B is similar to operation 234 A of FIG. 2B and may not be repeated herein.
- operation 332 operation 334 and operation 336 is performed depending on the judgement of operation 333 .
- the DI water may be applied to the semiconductor fabricating process, as shown in operation 332 .
- the first rotating angle 132 A when the actual electrical resistivity is smaller than the target electrical resistivity (R A ⁇ R T ), the first rotating angle 132 A may be increased and/or the second rotating angle 132 B may be decreased, so as to increase a percentage of the DI water having the high electrical resistivity, and/or decrease a percentage of the DI water having the low electrical resistivity, as shown in operation 334 of FIG. 3B . Therefore, the actual electrical resistivity may become closer to the target electrical resistivity.
- the first and second rotating angles 132 A and 132 B may be adjusted by a similar stepwise method mentioned in operation 236 A of FIG. 2B and may not be repeated herein.
- the first rotating angle 132 A when the actual electrical resistivity is greater than the target electrical resistivity (R A >R T ), the first rotating angle 132 A may be decreased and/or the second rotating angle 132 B may be increased, so as to decrease a percentage of the DI water having the high electrical resistivity, and/or increase a percentage of the DI water having the low electrical resistivity, as shown in operation 336 of FIG. 3B . Therefore, the actual electrical resistivity may become closer to the target electrical resistivity.
- the first and second rotating angles 132 A and 132 B may be adjusted by a similar stepwise method mentioned in operation 236 A of FIG. 2B and may not be repeated herein.
- the system and the method for providing DI water with a dynamic electrical resistivity of the present disclosure may automatically and dynamically adjust the electrical resistivity of DI water in real-time by a feedback loop. DI water having a target electrical resistivity may be easily and precisely obtained. Therefore, the same system may be applied to various semiconductor fabricating processes, and the system and the method of the present disclosure effectively reduce electrostatic charges accumulated on the surface of the wafer during different semiconductor fabricating processes. Accordingly, the system and the method of the present disclosure advantageously provide merits such as low costs, simplification and high performance.
- a system for providing deionized (DI) water with a dynamic electrical resistivity includes plural DI water sources, source pipes, flow control devices, a merging pipe and a flow controller.
- the DI water sources respectively have different electrical resistivities.
- the source pipes are respectively connected to the DI water sources in a one-to-one manner.
- the flow control devices are respectively disposed in the source pipes in a one-to-one manner.
- the merging pipe joins the source pipes.
- the flow controller includes a resistivity sensor disposed in the merging pipe, and the flow controller is configured to control a flowrate of the DI water through the source pipes.
- a method of providing deionized (DI) water with a dynamic electrical resistivity includes the following operations. First, a system is provided, and the system includes a merging pipe joining a plurality of source pipes that are respectively connected to a plurality of DI water sources in a one-to-one manner, and a plurality of flow control devices are respectively disposed in the source pipes in a one-to-one manner, in which the DI water sources respectively have different electrical resistivities. Then, the flow control devices are initialized to supply DI water from the system. Afterwards, a control operation is performed by a flow controller.
- DI deionized
- the control operation includes detecting an actual electrical resistivity of the DI water in the merging pipe by a resistivity sensor; determining if the actual electrical resistivity is substantially equal to a target electrical resistivity; and, adjusting flowrate of the flow control devices to supply the DI water.
- a method of providing deionized (DI) water with a dynamic electrical resistivity includes the following operations.
- a system is provided, and the system includes a merging pipe joining a first source pipe and a second source pipe that are respectively connected to a first DI water source and a second DI water source in a one-to-one manner, a first damper and a second damper are respectively disposed in the first and second source pipes in a one-to-one manner, in which the first and second source pipes have a same diameter, the first and second dampers have a first rotating angle and a second rotating angle respectively, and the first and second DI water sources respectively have a high electrical resistivity and a low electrical resistivity.
- the first and second rotating angles of the first and second dampers are initialized according to the following relationship, so as to supply DI water from the system:
- R ′ ⁇ ( M ⁇ ⁇ ⁇ ⁇ cm ) X ⁇ A ⁇ ⁇ 1 + Y ⁇ A ⁇ ⁇ 2 A ⁇ ⁇ 1 + A ⁇ ⁇ 2
- R′ stands for a target electrical resistivity
- X stands for the high electrical resistivity
- Y stands for the low electrical resistivity
- A1 stands for the first rotating angle
- A2 stands for the second rotating angle.
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Abstract
Description
- This application claims the benefit of the Provisional Application Ser. No. 62/487,512, filed on Apr. 20, 2017. The entire disclosures of all the above applications are hereby incorporated by reference herein.
- As semiconductor fabrication technologies are continually progressing, more and more challenges from defects on a wafer caused by accumulated charges have become important issue. For example, during an exposure/development process using an immersion lithography system, flowing water such as deionized (DI) water may introduce electrostatic charges. The accumulated electrostatic charges cause particle contamination such as particles adhering to surfaces of the immersion lithography system. The adhered particles may further migrate to a surface of the wafer and cause defects on the wafer and yield degradations.
- Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is noted that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
-
FIG. 1A is a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with some embodiments of the present disclosure. -
FIG. 1B is a schematic view showing the system inFIG. 1A with dampers having rotating angles. -
FIG. 1C is a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with alternative embodiments of the present disclosure. -
FIG. 2A is a flow chart showing a method for providing DI water with dynamic electrical resistivity in accordance with some embodiments of the present disclosure. -
FIG. 2B is a flow chart showing another control operation in the method for providing DI water with dynamic electrical resistivity in accordance with some embodiments of the present disclosure. -
FIG. 3A is a flow chart showing a method for providing DI water having dynamic electrical resistivity is provided in accordance with some embodiments of the present disclosure. -
FIG. 3B is a flowchart showing a control operation for providing DI water with dynamic electrical resistivity in accordance with some embodiments of the present disclosure. - The following disclosure provides many different embodiments, or examples, for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. For example, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed between the first and second features, such that the first and second features may not be in direct contact. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- The spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. The apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- Deionized (DI) water is applied in a semiconductor fabricating process for various purposes such as developing, rinsing and/or cleaning in immersion lithography process. The DI water having a predetermined electrical resistivity is usually used to avoid accumulation of electrostatic charges on a surface of a wafer during a semiconductor fabricating process. However, the traditional system and method can only provide DI water with a fixed electrical resistivity regardless of a requirement of different electrical resistivities for different wafers or a same wafer in different intermediate stages of the semiconductor fabricating process to effectively reduce the accumulation of electrostatic charges. Therefore, a system and a method for providing DI water with a dynamic electrical resistivity are provided to tackle the problems described above.
- Embodiments of the present disclosure are directed to providing a system and a method of providing DI water with a dynamic electrical resistivity. Generally, the system includes DI water sources having different electrical resistivities and a flow control device (e.g. a damper or a flow control valve) in each of source pipes to mix DI water having different electrical resistivities, so as to obtain (mixed) DI water having a target electrical resistivity. The flow control device may be automatically controlled by a flow controller using a feedback loop. Accordingly, the electrical resistivity of the DI water applied to the semiconductor fabricating process is adjustable during the proceeding process, and the accumulation of electrostatic charges on the surface of the wafer may be effectively reduced. The system and the method of the present disclosure provide merits such as low costs, simplification and high performance of the semiconductor fabricating process. A detailed description is provided by incorporating with
FIG. 1A throughFIG. 3B . - Referring to
FIG. 1A ,FIG. 1A is a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with some embodiments of the present disclosure. As shown inFIG. 1A , asystem 100 includesDI water sources source pipes flow control devices pipe 140 and aflow controller 150. Thesource pipes DI water sources flow control devices source pipes pipe 140 joins thesource pipes DI water sources DI water source flow controller 150 is configured to control a flowrate in thesource pipes flow controller 150 includes a resistivity sensor (not shown) disposed in the mergingpipe 140 for detecting an actual electrical resistivity of the mixed DI water. In operation, DI water from theDI water sources source pipes pipe 140 to be ready for subsequent processes. - In some embodiments, the flow control devices 130 may be flow control valves (not shown), and the
flow controller 150 is configured to adjust the degrees of opening of the flow control valves. In other embodiments, the flow control devices 130 may be dampers with rotating angles, and theflow controller 150 is configured to adjust the degrees of the rotating angles. Referring toFIG. 1B ,FIG. 1B illustrates a schematic view showing the system inFIG. 1A with dampers having rotating angles. Hereinafter, theflow control devices damper 130A having arotating angle 132A and adamper 130B having arotating angle 132B, for convenience of explanation. In such embodiments, theflow controller 150 is configured to adjust therotating angles dampers DI water sources rotating angles dampers rotating angles 132A is defined as an included angle between a direction perpendicular to aflow direction 170 and atop surfaces 134A of thedamper 130A, and therotating angles 132B is defined as an included angle between the direction perpendicular to theflow direction 170 and a top surfaces 134B of thedamper 130B. Furthermore, therotating angles rotating angles rotating angle 132A of thedamper 130A shown by a dotted-line is 0°, and therotating angle 132B of thedamper 130B shown by the dotted-line is 90°. In other examples, therotating angle 132A of the dampers shown by a solid line is 90°, and therotating angle 132B of thedamper 130B shown by the solid line is 0°. - Still referring to
FIG. 1B , theflow controller 150 may include aresistivity sensor 152, in which theresistivity sensor 152 is configured to detect an electrical resistivity of the DI water in the mergingpipe 140. In some embodiments, theflow controller 150 may further include adriving module 154 and a judgingmodule 156. Thedriving module 154 is at least signally connected to thedampers module 156 is at least signally connected to theresistivity sensor 152, so as to compare an actual electricity resistivity of the DI water in the mergingpipe 140 with a target electricity resistivity. In addition, the judgingmodule 156 is also signally connected to thedriving module 154. - As shown in
FIG. 1A andFIG. 1B , in some embodiments, the system may further include a calculatingmodule 160. The calculatingmodule 160 may be signally connected to thedriving module 154, in which the calculatingmodule 160 is configured to calculate therotating angles damper module 160 performs a calculation according to the following relationship (1): -
- where R stands for the target electrical resistivity; n stands for a number of the DI water source; Ri stands for the electrical resistivity of DI water from the ith DI water source; and Ai stands for the rotating angle of the ith damper.
- In other embodiments, the
driving module 154 and thedampers resistivity sensor 152 and the judgingmodule 156, thedriving module 154 and the judgingmodule 156, and/or the calculatingmodule 160 and thedriving module 154 may be further electrically connected and/or physically connected. - In some embodiments, the
resistivity sensor 152 detects an actual electrical resistivity and sends a signal to the judgingmodule 156, and then the judgingmodule 156 determines if the actual electrical resistivity is substantially equal to a target electrical resistivity and sends a signal to thedriving module 154, thedriving module 154 controls thedampers source pipes resistivity sensor 152, thereby forming a feedback loop for controlling the electrical resistivity of water dynamically, as shown inFIG. 1B . -
FIG. 1A andFIG. 1B illustrate only two DI water sources, two sources pipes, and two flow control devices for convenience and simplification of explanation, and embodiments of the present disclosure are not limited thereto. Embodiments of more than two DI water sources, more than two sources pipes, and more than two flow control devices are described hereinafter. - Referring to
FIG. 1C ,FIG. 1C illustrates a schematic view showing a system for providing DI water with a dynamic electrical resistivity in accordance with alternative embodiments of the present disclosure. As shown inFIG. 1C , asystem 100′ includesDI water sources source pipes control devices pipe 140′ and aflow controller 150′, which are similar to theDI water sources source pipes flow control devices pipe 140 and theflow controller 150 ofFIG. 1A andFIG. 1B . It is noted that theDI water sources flow control devices flow control device 130C has arotating angle 132C. Therotating angle 132C is defined in a similar way as therotating angles FIG. 1B and may not be repeated herein. In addition, theflow controller 150′ includes aresistivity sensor 152′, adriving module 154′ and a judgingmodule 156′, which are similar to theresistivity sensor 152, thedriving module 154 and the judgingmodule 156 ofFIG. 1B . The following describes method for providing DI water with a dynamic electrical resistivity using thesystems -
FIG. 2A andFIG. 2B are used to describe amethod 200 for providing DI water with a dynamic electrical resistivity in accordance with some embodiments of the present disclosure.FIG. 1C is also incorporated, however, the following uses only theDI water sources source pipes flow control devices FIG. 1C for convenience of explanation. Please refer toFIG. 2A andFIG. 1C .FIG. 2A illustrates a flow chart showing themethod 200 for providing DI water with a dynamic electrical resistivity. As shown inoperation 210 inFIG. 2A , a system for supplying DI water with different electrical resistivities is provided first, for example, thesystem 100′ ofFIG. 1C . The system may include the mergingpipe 140′ joining thesource pipes DI water sources DI water sources flow control devices source pipes FIG. 2A may be a flow control valve. In other embodiments, theflow control devices rotating angle 132C of thedamper 130C). Each rotating angle is in a range substantially from 0° to 90°, and at least one of the rotating angles is not 0°. For simplifying the descriptions, the following takes thedampers flow control devices - At
operation 220, thedampers dampers dampers dampers dampers driving module 154′. - The initial state may be automatically calculated by the calculating
module 160′ in some embodiments. In such embodiments, the calculatingmodule 160′ may be signally connected to thedriving module 154′ of theflow controller 150′, so as to transfer the calculation results to thedriving module 154′. For example, the initial state may be achieved by adjusting the rotating angles of thedampers dampers driving module 154′ according to the calculation results. However, the initial state may be manually determined in other embodiments. In some embodiments, the target electrical resistivity may be in a range from a highest electrical resistivity to a lowest electrical resistivity of the DI water in theDI water sources - Next, as shown in
operation 230, a control operation is performed by aflow controller 150′.FIG. 2B illustrates a flow chart showing thecontrol operation 230 in themethod 200 in accordance with some embodiments of the present disclosure. As shown inFIG. 2B , thecontrol operation 230 includesoperations operation 232, an actual electrical resistivity of DI water in the mergingpipe 140′ is detected. In some embodiments, the actual electrical resistivity may be detected by aresistivity sensor 152′ disposed in the mergingpipe 140′. - Then, at
operation 234, a judgement is performed to determine whether the actual electrical resistivity is equal to the target electrical resistivity or not. Determining the actual electrical resistivity may be performed by a judgingmodule 156′ of theflow controller 150′. For example, the target electrical resistivity may be setup in the judgingmodule 156′ before thecontrol operation 230 starts, and then the actual electrical resistivity is detected (as shown in operation 232) and signally transferred from theresistivity sensor 152′ to the judgingmodule 156′ to performoperation 234. Accordingly, theresistivity sensor 152′ and the judgingmodule 156′ are signally connected to each other, and the judgingmodule 156′ is able to receive a signal from theresistivity sensor 152′. It is noted that the target electrical resistivity may be predetermined based on a requirement of the semiconductor fabricating process. Therefore, the target electrical resistivity of the present disclosure does not limited to a fixed value. - Next, based on the judgement of
operation 234,operation 236 oroperation 238 is performed. Therefore, the drivingunit 154′ is at least signally connected to the judgingmodule 156′, so as to receive a signal from the judgingmodule 156′. In some embodiments, when the actual electrical resistivity is equal to the target electrical resistivity (RA=RT, referred as “Y” inFIG. 2B ), as shown inoperation 236, the DI water in the merging pipe may be applied to the semiconductor fabricating process. In other embodiments, when the actual electrical resistivity is not equal to the target electrical resistivity (RA RT, referred as “N” inFIG. 2B ), the flowrates through thesource pipes dampers control operation 230, as shown inoperation 238. In some embodiments, the rotating angles may be stepwise adjusted (increased or decreased) by thedriving module 154′ of theflow controller 150′. The term of “stepwise” refers to adjusting the rotating angles by increasing or decreasing a fixed angle at one time. For example, the fixed angle may be 0.5°, 1°, 5° or any other suitable angles. In other embodiments, when theflow control devices 150′ are flow control valve (not shown), the degree of openings of the flow control valves may be adjusted to achieve desired flowrate. - In some embodiments, a feedback loop may be established. That is, the actual electrical resistivity is detected (operation 232), followed by the judgement of the actual electrical resistivity (operation 234) and the adjustment of the rotating angles (238), and the actual electrical resistivity of the DI water is detected again (operation 232) after the rotating angles are adjusted.
- An embodiment using two DI water sources respectively having a high and a low electrical resistivity is shown to further illustrate the application of the method of the present disclosure. Referring to
FIG. 3A andFIG. 3B , a flow chart of amethod 300 for providing DI water having a dynamic electrical resistivity is provided in accordance with some embodiments of the present disclosure.FIG. 1B is also incorporated for clear explanation. As shown inoperation 310 ofFIG. 3A , a system such as thesystem 100 ofFIG. 1B is provided. Furthermore, a diameter of thesource pipes FIG. 3A andFIG. 3B , theDI water sources - At
operation 320, the first and secondrotating angles -
- where R′ stands for the target electrical resistivity; X stands for the high electrical resistivity; Y stands for the low electrical resistivity; A1 stands for the first
rotating angle 132A; and A2 stands for the secondrotating angle 132B. In some embodiments, the first and secondrotating angles rotating angles rotating angles operation 220 ofFIG. 2A and may not be repeated herein. - At
operation 330, a control operation is performed.FIG. 3B illustrates a flowchart showing thecontrol operation 330 in accordance with some embodiments of the present disclosure. Atoperation 331, an actual electrical resistivity of the DI water in the mergingpipe 140 is detected, in whichoperation 331 ofFIG. 3B is similar to operation 232A ofFIG. 2B and may not be repeated herein. Then, as shown inoperation 333, a judgement is performed to determine whether the actual electrical resistivity (RA) is substantially equal to the target electrical resistivity (RT).Operation 333 ofFIG. 3B is similar to operation 234A ofFIG. 2B and may not be repeated herein. - Then, one of
operation 332,operation 334 andoperation 336 is performed depending on the judgement ofoperation 333. The following describes in detailed. It is noted that, although the rotating angles are initiated to theoretical values for obtaining the DI water having the target electrical resistivity, the actual situation (e.g. precision of the flowrate of the DI water sources, a change in diameters of the pipes, etc.) of the DI water sources and the source pipes may further affect the actual electrical resistivity. Therefore, detecting and adjusting operations are required to make the actual electrical resistivity more precise and closer to the target electrical resistivity. - In some embodiments, when the actual electrical resistivity is substantially equal to the target electrical resistivity (RA=RT), the DI water may be applied to the semiconductor fabricating process, as shown in
operation 332. - In some embodiments, when the actual electrical resistivity is smaller than the target electrical resistivity (RA<RT), the first
rotating angle 132A may be increased and/or the secondrotating angle 132B may be decreased, so as to increase a percentage of the DI water having the high electrical resistivity, and/or decrease a percentage of the DI water having the low electrical resistivity, as shown inoperation 334 ofFIG. 3B . Therefore, the actual electrical resistivity may become closer to the target electrical resistivity. As shown inFIG. 3B , thecontrol operation 330 may be repeated fromoperation 331 afteroperation 334 is performed. Thecontrol operation 330 may be repeated till the actual electrical resistivity is substantially equal to the target electrical resistivity (RA=RT). In some embodiments, the first and secondrotating angles FIG. 2B and may not be repeated herein. - In some embodiments, when the actual electrical resistivity is greater than the target electrical resistivity (RA>RT), the first
rotating angle 132A may be decreased and/or the secondrotating angle 132B may be increased, so as to decrease a percentage of the DI water having the high electrical resistivity, and/or increase a percentage of the DI water having the low electrical resistivity, as shown inoperation 336 ofFIG. 3B . Therefore, the actual electrical resistivity may become closer to the target electrical resistivity. As shown inFIG. 3B , thecontrol operation 330 may be repeated fromoperation 331 afteroperation 336 is performed. Thecontrol operation 330 may be repeated till the actual electrical resistivity is substantially equal to the target electrical resistivity (RA=RT). In some embodiments, the first and secondrotating angles FIG. 2B and may not be repeated herein. - The system and the method for providing DI water with a dynamic electrical resistivity of the present disclosure may automatically and dynamically adjust the electrical resistivity of DI water in real-time by a feedback loop. DI water having a target electrical resistivity may be easily and precisely obtained. Therefore, the same system may be applied to various semiconductor fabricating processes, and the system and the method of the present disclosure effectively reduce electrostatic charges accumulated on the surface of the wafer during different semiconductor fabricating processes. Accordingly, the system and the method of the present disclosure advantageously provide merits such as low costs, simplification and high performance.
- According to some embodiments of the present disclosure, a system for providing deionized (DI) water with a dynamic electrical resistivity is provided. The system includes plural DI water sources, source pipes, flow control devices, a merging pipe and a flow controller. The DI water sources respectively have different electrical resistivities. The source pipes are respectively connected to the DI water sources in a one-to-one manner. The flow control devices are respectively disposed in the source pipes in a one-to-one manner. The merging pipe joins the source pipes. The flow controller includes a resistivity sensor disposed in the merging pipe, and the flow controller is configured to control a flowrate of the DI water through the source pipes.
- According to some embodiments of the present disclosure, a method of providing deionized (DI) water with a dynamic electrical resistivity. The method includes the following operations. First, a system is provided, and the system includes a merging pipe joining a plurality of source pipes that are respectively connected to a plurality of DI water sources in a one-to-one manner, and a plurality of flow control devices are respectively disposed in the source pipes in a one-to-one manner, in which the DI water sources respectively have different electrical resistivities. Then, the flow control devices are initialized to supply DI water from the system. Afterwards, a control operation is performed by a flow controller. The control operation includes detecting an actual electrical resistivity of the DI water in the merging pipe by a resistivity sensor; determining if the actual electrical resistivity is substantially equal to a target electrical resistivity; and, adjusting flowrate of the flow control devices to supply the DI water.
- According to some embodiments of the present disclosure, a method of providing deionized (DI) water with a dynamic electrical resistivity. The method includes the following operations. First, a system is provided, and the system includes a merging pipe joining a first source pipe and a second source pipe that are respectively connected to a first DI water source and a second DI water source in a one-to-one manner, a first damper and a second damper are respectively disposed in the first and second source pipes in a one-to-one manner, in which the first and second source pipes have a same diameter, the first and second dampers have a first rotating angle and a second rotating angle respectively, and the first and second DI water sources respectively have a high electrical resistivity and a low electrical resistivity. Then, the first and second rotating angles of the first and second dampers are initialized according to the following relationship, so as to supply DI water from the system:
-
- where R′ stands for a target electrical resistivity; X stands for the high electrical resistivity; Y stands for the low electrical resistivity; A1 stands for the first rotating angle; and A2 stands for the second rotating angle. Next, a control operation is performed by a flow controller. The control operation includes detecting an actual electrical resistivity of the DI water in the merging pipe by a resistivity sensor; determining if the actual electrical resistivity is substantially equal to the target electrical resistivity; and, adjusting the first and/or second angle to supply the DI water.
- The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the present disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure.
Claims (20)
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US16/673,771 US11130107B2 (en) | 2017-04-20 | 2019-11-04 | Method for providing deionized water with dynamic electrical resistivity |
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