US20160268409A1 - Semiconductor device and manufacturing method thereof - Google Patents
Semiconductor device and manufacturing method thereof Download PDFInfo
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- US20160268409A1 US20160268409A1 US14/840,777 US201514840777A US2016268409A1 US 20160268409 A1 US20160268409 A1 US 20160268409A1 US 201514840777 A US201514840777 A US 201514840777A US 2016268409 A1 US2016268409 A1 US 2016268409A1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 110
- 238000004519 manufacturing process Methods 0.000 title claims description 19
- 150000004767 nitrides Chemical class 0.000 claims abstract description 64
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 36
- 229920005591 polysilicon Polymers 0.000 claims abstract description 36
- 230000004888 barrier function Effects 0.000 claims description 62
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 claims description 51
- 229910002601 GaN Inorganic materials 0.000 claims description 49
- 229910052751 metal Inorganic materials 0.000 claims description 40
- 239000002184 metal Substances 0.000 claims description 40
- 239000000463 material Substances 0.000 claims description 16
- 238000001020 plasma etching Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 229910021332 silicide Inorganic materials 0.000 claims description 12
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 12
- 239000010936 titanium Substances 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 194
- 239000011241 protective layer Substances 0.000 description 29
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 24
- 239000011229 interlayer Substances 0.000 description 10
- 229910052697 platinum Inorganic materials 0.000 description 10
- 238000000137 annealing Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000005036 potential barrier Methods 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004205 SiNX Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 230000005533 two-dimensional electron gas Effects 0.000 description 1
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/40—FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
- H10D30/47—FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 2D charge carrier gas channels, e.g. nanoribbon FETs or high electron mobility transistors [HEMT]
- H10D30/471—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT]
- H10D30/473—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having confinement of carriers by multiple heterojunctions, e.g. quantum well HEMT
- H10D30/4732—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having confinement of carriers by multiple heterojunctions, e.g. quantum well HEMT using Group III-V semiconductor material
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/40—FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels
- H10D30/47—FETs having zero-dimensional [0D], one-dimensional [1D] or two-dimensional [2D] charge carrier gas channels having 2D charge carrier gas channels, e.g. nanoribbon FETs or high electron mobility transistors [HEMT]
- H10D30/471—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT]
- H10D30/475—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having wider bandgap layer formed on top of lower bandgap active layer, e.g. undoped barrier HEMTs such as i-AlGaN/GaN HEMTs
- H10D30/4755—High electron mobility transistors [HEMT] or high hole mobility transistors [HHMT] having wider bandgap layer formed on top of lower bandgap active layer, e.g. undoped barrier HEMTs such as i-AlGaN/GaN HEMTs having wide bandgap charge-carrier supplying layers, e.g. modulation doped HEMTs such as n-AlGaAs/GaAs HEMTs
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- H01L29/7787—
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- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
- H01L21/28044—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities the conductor comprising at least another non-silicon conductive layer
- H01L21/28052—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities the conductor comprising at least another non-silicon conductive layer the conductor comprising a silicide layer formed by the silicidation reaction of silicon with a metal layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/306—Chemical or electrical treatment, e.g. electrolytic etching
- H01L21/3065—Plasma etching; Reactive-ion etching
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
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- H01L29/205—
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/01—Manufacture or treatment
- H10D30/015—Manufacture or treatment of FETs having heterojunction interface channels or heterojunction gate electrodes, e.g. HEMT
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/17—Semiconductor regions connected to electrodes not carrying current to be rectified, amplified or switched, e.g. channel regions
- H10D62/343—Gate regions of field-effect devices having PN junction gates
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/85—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group III-V materials, e.g. GaAs
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- H—ELECTRICITY
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/85—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group III-V materials, e.g. GaAs
- H10D62/8503—Nitride Group III-V materials, e.g. AlN or GaN
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- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/62—Electrodes ohmically coupled to a semiconductor
Definitions
- Embodiments described herein relate generally to a semiconductor device and a manufacturing method thereof.
- a nitride semiconductor is used as a material thereof.
- This semiconductor device is in a normally-off state because a p-type nitride semiconductor layer is interposed between the gate electrode and the barrier layer thereof.
- the resistance between the gate electrode and the p-type nitride semiconductor layer be further reduced.
- FIG. 1A is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a first embodiment.
- FIG. 1B is a schematic top plan view illustrating a main portion of the semiconductor device according to the first embodiment.
- FIGS. 2A to 2C are schematic cross-sectional views illustrating a manufacturing process of the main portion of the semiconductor device according to the first embodiment.
- FIGS. 3A to 3C are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the first embodiment.
- FIGS. 4A and 4B are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the first embodiment.
- FIGS. 5A to 5C are schematic cross-sectional views illustrating the manufacturing process of a gate electrode according to a reference example.
- FIG. 6 is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a second embodiment.
- FIGS. 7A to 7C are schematic cross-sectional views illustrating a manufacturing process of the main portion of the semiconductor device according to the second embodiment.
- FIGS. 8A and 8B are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the second embodiment.
- FIGS. 9A and 9B are schematic cross-sectional views illustrating a manufacturing process of a main portion of a semiconductor device according to a third embodiment.
- FIGS. 10A and 10B are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the third embodiment.
- FIGS. 11A to 11C are schematic cross-sectional views illustrating a manufacturing process of a main portion of a semiconductor device according to a fourth embodiment.
- FIGS. 12A to 12C are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the fourth embodiment.
- Embodiments provide a semiconductor device capable of reducing the electrical resistance between a gate electrode and a p-type nitride semiconductor layer and the manufacturing method thereof.
- a semiconductor device in general, according to a first embodiment, includes a first nitride semiconductor layer, a second nitride semiconductor layer on the first nitride semiconductor layer, a first electrode on the second nitride semiconductor layer, a second electrode on the second nitride semiconductor layer, a p-type third nitride semiconductor layer on the second nitride semiconductor layer, between the first electrode and the second electrode and in contact with the second nitride semiconductor layer, and a third electrode containing p-type polysilicon, on the third nitride semiconductor layer and in contact with the third nitride semiconductor layer.
- FIG. 1A is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a first embodiment.
- FIG. 1B is a schematic top plan view illustrating the main portion of the semiconductor device according to the first embodiment.
- FIG. 1A illustrates a cross section taken along the line A 1 -A 2 of FIG. 1B .
- FIG. 1B illustrates a cross section taken along the line B 1 -B 2 of FIG. 1A .
- the semiconductor device 100 includes a substrate 10 , a buffer layer 31 , a first nitride semiconductor layer (hereinafter, for example, carrier transport layer 33 ), a second nitride semiconductor layer (hereinafter, for example, barrier layer 34 ), a first electrode (hereinafter, for example, source electrode 50 ), a second electrode (hereinafter, for example, drain electrode 51 ), a third nitride semiconductor layer (hereinafter, for example, p-type GaN layer 35 ), and a third electrode (hereinafter, for example, gate electrode 52 ).
- a first nitride semiconductor layer hereinafter, for example, carrier transport layer 33
- a second nitride semiconductor layer hereinafter, for example, barrier layer 34
- a first electrode hereinafter, for example, source electrode 50
- a second electrode hereinafter, for example, drain electrode 51
- a third nitride semiconductor layer hereinafter, for example, p-type GaN layer 35
- gate electrode 52
- the substrate 10 includes, for example, silicon (Si).
- the buffer layer 31 is provided on the substrate 10 .
- the buffer layer 31 includes aluminum nitride.
- the carrier transport layer 33 is provided on the buffer layer 31 .
- the barrier layer 34 is provided on the carrier transport layer 33 .
- the carrier transport layer 33 includes undoped gallium nitride (GaN), or undoped gallium aluminum nitride (Al x Ga 1-x N (0 ⁇ X ⁇ 1)).
- the barrier layer 34 includes undoped or n-type gallium aluminum nitride Al y Ga 1-y N (0 ⁇ Y ⁇ 1, X ⁇ Y)).
- Two dimensional electron gas (2DEG) is generated in the carrier transport layer 33 in the vicinity of the boundary of the carrier transport layer 33 and the barrier layer 34 .
- the source electrode 50 is provided on the barrier layer 34 .
- the source electrode 50 includes, for example, a barrier 50 a containing titanium (Ti) and an electrode 50 b containing aluminum (Al).
- the source electrode 50 is connected to the barrier layer 34 .
- the source electrode 50 forms an ohmic contact with the barrier layer 34 .
- the source electrode 50 extends, for example, in the X direction.
- the drain electrode 51 is provided on the barrier layer 34 at a distance from the source electrode 50 .
- the drain electrode 51 includes, for example, a barrier 51 a containing titanium (Ti) and an electrode 51 b containing aluminum (Al).
- the drain electrode 51 is connected to the barrier layer 34 .
- the drain electrode 51 forms an ohmic contact with the barrier layer 34 .
- the drain electrode 51 is provided alongside of the source electrode 50 and spaced therefrom in the Y direction.
- the drain electrode 51 extends in the X direction generally parallel to the source electrode 50 .
- a p-type GaN layer 35 is provided on the barrier layer 34 .
- the p-type GaN layer 35 contains p-type gallium nitride (GaN).
- the dopant element contained in the p-type GaN layer 35 is, for example, magnesium (Mg) and zinc (Zn).
- the p-type GaN layer 35 is provided at a location between, and spaced from, the source electrode 50 and the drain electrode 51 .
- the p-type GaN layer 35 is connected to the barrier layer 34 .
- the p-type GaN layer 35 likewise extends in the X direction.
- the potential under the p-type GaN layer 35 is raised and the Fermi level under the p-type GaN layer 35 is raised. Owing to this, under the p-type GaN layer 35 , the 2DEG electron cloud moves to a side of the barrier layer 34 -carrier layer 33 interface having a lower potential, in other words, in the direction away from the p-type GaN layer 35 and as a result the semiconductor device 100 becomes a normally-off device.
- the gate electrode 52 is provided on the p-type GaN layer 35 .
- the gate electrode 52 forms an ohmic contact with the p-type GaN layer 35 .
- the gate electrode 52 contains p-type polysilicon.
- the p-type dopant element is, for example, boron (B).
- the gate electrode 52 extends, for example, in the X direction.
- a protective layer 60 is provided on the barrier layer 34 .
- An interlayer insulating layer 61 is provided on the protective layer 60 .
- the protective layer 60 contains, for example, silicon nitride (SiN x ).
- the interlayer insulating layer 61 contains, for example, silicon oxide (SiO x ).
- the number of the source electrodes 50 , the drain electrodes 51 , the p-type GaN layers 35 , and the gate electrodes 52 is not restricted to the illustrated number.
- FIGS. 2A to 4B are schematic cross-sectional views illustrating the manufacturing process of a main portion of the semiconductor device according to the first embodiment.
- the buffer layer 31 is formed on the substrate 10 such as by a metal-organic chemical vapor deposition (MOCVD) process, and the carrier transport layer 33 , the barrier layer 34 , and the p-type GaN layer 35 are epitaxially grown on the buffer layer 31 in that order.
- a first layer 52 L containing p-type polysilicon is formed on the whole surface of the p-type GaN layer 35 .
- the first layer 52 L will form the gate electrode 52 after further processing.
- the first layer 52 L is formed, for example, by low-pressure Chemical Vapor Deposition (CVD) or Atomic Layer Deposition (ALD) of polysilicon.
- the first layer 52 L may be formed by ion implantation of boron into an undoped polysilicon layer and heating in the implanted layer in a nitrogen (N 2 ) atmosphere. The heating temperature is 800° C. to 900° C.
- the carrier transport layer 33 , the barrier layer 34 , the p-type GaN layer 35 , and the gate electrode 52 are formed in a stacked body 30 .
- a mask layer 90 is formed on the gate electrode material layer 52 L.
- the portion of the first layer 52 L not covered by the mask layer 90 and the p-type GaN layer 35 under the first layer 52 L not covered by the mask layer 90 are selectively removed by Reactive Ion Etching (RIE).
- RIE Reactive Ion Etching
- a mixed gas of, for example, a Cl based gas and an F based gas is used. Owing to this, the p-type GaN layer 35 and the gate electrode layer 52 L containing the p-type polysilicon are selectively formed on the barrier layer 34 . Thereafter, the mask layer 90 is removed.
- the material to form the protective layer 60 is formed on the barrier layer 34 and the gate electrode 52 . Further, a mask layer 91 is formed on the layer of material used to form the protective layer 60 . Openings 91 h are provided on the mask layer 91 at the respective positions of forming the source electrode 50 and the drain electrode 51 .
- the protective layer 60 exposed by the openings 91 h in the mask layer 91 is removed by RIE, as shown in FIG. 3A . Then, the mask layer 91 is removed.
- a conductive layer 55 containing titanium and a conductive layer 56 containing aluminum are formed in this order on the barrier layer 34 and the protective layer 60 .
- a mask layer 92 is formed on the conductive layer 56 .
- the mask layer 92 is formed, for example, at each position where a source electrode 50 and a drain electrode 51 are to be formed.
- the exposed portions of the conductive layer 56 and the conductive layer 55 under the conductive layer 56 are removed by RIE. Owing to this, the conductive layer 56 is divided into the electrode 50 b and the electrode 51 b and the conductive layer 55 is divided into the barrier 50 a and the barrier 51 a . That is, the source electrode 50 and the drain electrode 51 are formed on the barrier layer 34 to sandwich the gate electrode 52 . Then, the mask layer 92 is removed.
- an interlayer insulating layer 61 is formed on the source electrode 50 and the drain electrode 51 . Further, a mask layer 93 is formed on the interlayer insulating layer 61 . The mask layer 93 is provided with openings 93 h respectively opening over the source electrode 50 , the drain electrode 51 , and the gate electrode 52 .
- the exposed portions of the interlayer insulating layer 61 on both the source electrode 50 and the drain electrode 51 are removed by RIE. Further, the exposed portions of the interlayer insulating layer 61 and the protective layer 60 on the gate electrode 52 are removed by RIE. Thereafter, the mask layer 93 is removed.
- the interface between the source electrode 50 and the barrier layer 34 and the interface between the drain electrode 51 and the barrier layer 34 may be heated, to diffuse the metal inside the barriers 50 a and 51 a into the surface of the barrier layer 34 in contact with the source electrode 50 and the drain electrode 51 .
- This heating processing is referred to as contact annealing in the embodiment. Owing to this, the contact resistance is reduced between the source electrode 50 and the barrier layer 34 and between the drain electrode 51 and the barrier layer 34 .
- the gate electrode 52 containing p-type polysilicon is provided on the p-type GaN layer 35 .
- This gate electrode 52 is in contact with the p-type GaN layer 35 .
- the work function of the p-type polysilicon is 5.0 to 5.1 eV, and the work function of the p-type GaN is 4.5 to 7.0 eV.
- the work function of the p-type polysilicon is within the range of the work function of the p-type GaN.
- Work function is defined as the energy required to remove an electron from the highest filled level in the Fermi distribution of a solid so that it is stationary at a point in a field-free zone just outside the solid at absolute zero.
- the gate electrode 52 according to the first embodiment forms an ohmic contact with the p-type GaN layer 35 .
- the contact resistance between the gate electrode 52 and the p-type GaN layer 35 according to the first embodiment is 1 ⁇ 10 ⁇ 3 ⁇ cm 2 or less.
- the work function of n-type polysilicon is about 4.0. That is, the work function of the n-type polysilicon is smaller than the work function of the p-type GaN. Accordingly, when the gate electrode 52 is n-type polysilicon electrode, a potential barrier is generated between the gate electrode 52 and the p-type GaN layer 35 . In other words, a resistance between the gate electrode 52 and the p-type GaN layer 35 does not form effective ohmic contact and the resistance between the gate electrode 52 and the p-type GaN layer 35 is high, as compared to the semiconductor device 100 .
- FIGS. 5A to 5C are schematic cross-sectional views illustrating the manufacturing process of a gate electrode according to the reference example.
- the gate electrode 52 As the material of the gate electrode 52 , one of the noble metals, platinum (Pt) is used. When using platinum (Pt), the work function of the platinum (Pt) is larger than that of the p-type GaN and the gate electrode 52 forms an ohmic contact with the p-type GaN layer 35 . However, it is difficult to etch platinum, and thus in the reference example, the gate electrode 52 is formed by lift-off processing.
- the buffer layer 31 is formed on the substrate 10 , and the carrier transport layer 33 , the barrier layer 34 , and the p-type GaN layer 35 are epitaxially grown on the buffer layer 31 in this order. Further, a mask layer 500 including a resist is formed on the p-type GaN layer 35 . The mask layer 500 is provided with an opening 500 h on the p-type GaN layer 35 at a position where the gate electrode 52 is located.
- a platinum film 501 is formed on the mask layer 500 and the p-type GaN layer 35 .
- the mask layer 500 is exposed to an organic solvent and ultrasonic energy is applied to the mask layer 500 , which causes the mask layer 500 to dissolve and allows the platinum film 501 overlying the mask layer 500 to be removed.
- a gate electrode 520 containing platinum (Pt) is formed on the p-type GaN layer 35 .
- the platinum film 501 on the p-type GaN layer 35 may also be removed during the removal of the mask layer 500 . This phenomenon becomes more likely as the width of the gate electrode 520 gets narrower. Additionally, portions of the platinum film 501 removed together with the mask layer 500 may remain within the semiconductor device as contaminating particulates.
- the p-type polysilicon used as the material of the gate electrode 52 is easily processed by RIE.
- the gate electrode 52 is processed by photolithographically forming a patterned mask, followed by RIE, not the lift-off processing of the reference example. That is, precise and reliable processing of the gate electrode 52 is possible.
- the material of the gate electrode 52 not a precious metal such as platinum but aluminum (Al) which is easily processed by RIE is used. In this case, however, the temperature of the contact annealing exceeds the melting point of the aluminum in some cases. Owing to this, the gate electrode itself melts and the shape of the gate electrode once solidified again may be different from the original shape before melting. In contrast, in the first embodiment, the p-type polysilicon is used as the material of the gate electrode 52 does not melt at the temperature of the heating processing.
- the gate electrode 52 is directly in contact with the p-type GaN layer 35 .
- the potential of the threshold value of the gate electrode 52 gets higher adjacent to the potential barrier provided by the dielectric layer.
- the gate electrode 52 is directly in contact with the p-type GaN layer 35 . Owing to this, the potential of the threshold value of the gate electrode 52 may be set as being low.
- the potential of the threshold voltage of the semiconductor device 100 is 1.0 to 2.0 V.
- the gate electrode 52 is p-type polysilicon and therefore, even when performing the heat processing on the protective layer 60 , metal does not diffuse from the gate electrode 52 into the protective layer 60 . Further, by performing the heat processing on the protective layer 60 , the protective layer 60 becomes denser. That is, according to the first embodiment, a highly insulative protective layer 60 may be obtained.
- FIG. 6 is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a second embodiment.
- the gate electrode 52 containing the p-type polysilicon further contains metal in at least a portion thereof.
- the metal includes, for example, nickel (Ni) or titanium (Ti).
- the concentration of the metal at the upper end 52 u of the gate electrode is higher than that at the lower end 52 d thereof.
- FIGS. 7A to 8B are schematic cross-sectional views illustrating the manufacturing process of a main portion of the semiconductor device according to the second embodiment.
- the p-type GaN layer 35 and the material to form the polysilicon gate electrode 52 are formed on the barrier layer 34 .
- the protective layer 60 is formed on the barrier layer 34 .
- the protective layer 60 is provided with an opening 60 h which opens the upper end 52 u of the gate electrode 52 .
- the opening 60 h is formed by forming a mask layer, using photolithographic techniques to pattern the mask, and then performing RIE to form an opening in the protective layer 60 down to the upper surface 52 u of the polysilicon gate electrode 52 .
- a metal film 70 is formed on the protective layer 60 and the upper surface 52 u of the gate electrode 52 by the sputtering method.
- the metal film 70 contains, for example, nickel (Ni) or titanium (Ti).
- the gate electrode 52 and the metal film 70 are heated and a silicide layer 52 s of the metal and the silicon of the gate 52 is formed on the upper side 52 u of the gate electrode 52 .
- the gate electrode 52 is heated so that the metal concentration therein may be higher in the upper end 52 u than in the lower end 52 d .
- the heating condition is, for example, at 350° C. for 30 seconds in the nitrogen (N 2 ) atmosphere, such that metal does not diffuse fully through the polysilicon gate 52 to reach the underlying barrier layer 34 .
- the metal film 70 on the protective layer 60 is removed using sulfuric or ammonia solution. Thereafter, the heating processing may be performed on the silicide layer 52 s .
- the heating condition is, for example, at 500° C. for 30 seconds in the nitrogen (N 2 ) atmosphere.
- openings 60 h are formed on through the protective layer 60 by PEP and RIE.
- the openings 60 h are formed at the respective positions of forming the source electrode 50 and drain electrode 51 .
- the source electrode 50 and the drain electrode 51 are formed on the barrier layer 34 .
- the interlayer insulating layer 61 is formed on the protective layer 60 .
- the bottom of the source electrode 50 and the bottom of the drain electrode 51 are heated and the metal within the barriers 50 a and 51 a may be diffused between the source electrode 50 and the barrier layer 34 and between the drain electrode 51 and the barrier layer 34 . Owing to this, a contact resistance between the source electrode 50 and the barrier layer 34 and between the drain electrode 51 and the barrier layer 34 is reduced.
- the resistivity of the gate electrode 52 is reduced to 10 to 20 ⁇ cm.
- the silicide layer 52 s is automatically formed and therefore, there is no need for lithographic masking and RIE processes to form the silicide layer 52 s.
- FIGS. 9A to 10B are schematic cross-sectional views illustrating a main portion of a semiconductor device according to a third embodiment.
- the p-type GaN layer 35 is selectively formed on the barrier layer 34 , and the gate electrode 52 containing the p-type silicon is formed over the p-type GaN layer 35 .
- the protective layer 60 is formed on the barrier layer 34 and the gate electrode 52 .
- the protective layer 60 is provided with openings 60 h .
- the openings 60 h are formed at the respective positions of forming the source electrode 50 and the drain electrode 51 .
- the source electrode 50 and the drain electrode 51 connected to the barrier layer 34 are formed through the openings 60 h . Further, the interlayer insulating layer 61 is formed on the protective layer 60 , including the portion thereof over the gate electrode 52 , the source electrode 50 , and the drain electrode 51 .
- the interlayer insulating layer 61 and the protective layer 60 covering the gate electrode 52 are opened and a metal film 70 is formed on the interlayer insulating layer 61 and the gate electrode 52 .
- metal is diffused from the source electrode 50 into the surface of the barrier layer 34 and from the drain electrode 51 into the surface of the barrier layer 34 . That is, a barrier layer 34 a containing the metal is formed between the source electrode 50 and the barrier layer 34 and between the drain electrode 51 and the barrier layer 34 , the upper side of the gate electrode 52 is formed into silicide, and the gate electrode 52 containing the metal is formed.
- the source electrode 50 and the drain electrode 51 are formed before forming the gate electrode 52 into silicide. Owing to this, the contact annealing processing and the annealing processing for forming the gate electrode 52 into silicide may be performed simultaneously. Accordingly, the number of the annealing processes is reduced and the cost may be reduced.
- FIGS. 11A to 12C are schematic cross-sectional views illustrating the manufacturing process of a main portion of a semiconductor device according to a fourth embodiment.
- the carrier transport layer 33 , the barrier layer 34 , the p-type GaN layer 35 , and the material to form the gate electrode 52 containing p-type polysilicon are formed on the substrate 10 over the buffer layer 31 . Further, a metal film 70 is formed on the gate electrode 52 .
- the gate electrode 52 and the metal film 70 are heated and a silicide layer 52 s is resultantly formed by reaction therebetween as the upper side of the gate electrode 52 .
- the portions of the material for forming the gate electrode 52 and the p-type GaN layer 35 therebelow which are not covered by the mask layer 94 are removed by RIE, and the gate electrode 52 and the p-type GaN layer 35 are thus selectively formed on the barrier layer 34 . Then, the mask layer 94 is removed.
- the protective layer 60 is formed on the barrier layer 34 and the gate electrode 52 . Further, the protective layer 61 is formed on the protective layer 60 .
- openings 61 h are formed on the protective layers 60 and 61 .
- the openings 61 h are formed at the respective positions of forming the source electrode 50 , the drain electrode 51 , and the gate electrode 52 .
- the source electrode 50 (barrier 50 a and electrode 50 b ) and the drain electrode 51 (barrier 51 a and electrode 51 b ) connected to the barrier layer 34 are formed, a contact electrode 53 and a gate field plate 54 is formed on the gate electrode 52 , and a gate field plate 54 is formed on the contact electrode and over an adjacent portion of the protective layer 61 .
- the barriers 50 a and 51 b and the contact electrode 53 contain the same material.
- the electrodes 50 b and 51 b and the gate field plate 54 contain the same material.
- the openings 61 h for forming the barriers 50 a and 51 a and the contact electrode 53 may be formed simultaneously.
- the barriers 50 a and 51 b and the contact electrode 53 may be formed simultaneously.
- the electrodes 50 b and 51 b and the gate field plate 54 may be formed simultaneously.
- “on” in the case of the expression of “A is provided on B” means the case where “A is in contact with B and upper than B” as well as the case where “A is not in contact with B but just upper than B”. Further, the expression of “A is provided on B” is also applied to the case where A is under B with A and B inverted and the case where A and B are aligned alongside. This is because even if rotating the semiconductor device according to the embodiment, the structure of a semiconductor device never changes before and after the rotation.
- nitride semiconductor is intended to include all the semiconductors with the composition ratio of x, y, and z various within each range in the chemical formula B x In y Al z Ga 1-x-y-z N (0 ⁇ x ⁇ 1, 0 ⁇ y ⁇ 1, 0 ⁇ z ⁇ 1, x+y+z ⁇ 1).
- the compound further including the V group element other than N (nitrogen) the compound further including various doped elements in order to control various physical property such as conductivity, and the compound further including various elements not intended may be included in “nitride semiconductor”.
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Abstract
A semiconductor device includes a first nitride semiconductor layer, a second nitride semiconductor layer located on the first nitride semiconductor layer, a first electrode on the second nitride semiconductor layer, a second electrode on the second nitride semiconductor layer, a p-type third nitride semiconductor layer on the second nitride semiconductor layer between the first electrode and the second electrode and in contact with the second nitride semiconductor layer, and a third electrode containing p-type polysilicon on the third nitride semiconductor layer and in contact with the third nitride semiconductor layer.
Description
- This application is based upon and claims the benefit of priority from Japanese Patent Application No. 2015-051464, filed Mar. 13, 2015, the entire contents of which are incorporated herein by reference.
- Embodiments described herein relate generally to a semiconductor device and a manufacturing method thereof.
- In a semiconductor device such as a High Electron Mobility Transistor (HEMT), for example, a nitride semiconductor is used as a material thereof. This semiconductor device is in a normally-off state because a p-type nitride semiconductor layer is interposed between the gate electrode and the barrier layer thereof.
- In order to improve controllability of the switching operation of such a semiconductor device, it is preferable that the resistance between the gate electrode and the p-type nitride semiconductor layer be further reduced.
-
FIG. 1A is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a first embodiment.FIG. 1B is a schematic top plan view illustrating a main portion of the semiconductor device according to the first embodiment. -
FIGS. 2A to 2C are schematic cross-sectional views illustrating a manufacturing process of the main portion of the semiconductor device according to the first embodiment. -
FIGS. 3A to 3C are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the first embodiment. -
FIGS. 4A and 4B are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the first embodiment. -
FIGS. 5A to 5C are schematic cross-sectional views illustrating the manufacturing process of a gate electrode according to a reference example. -
FIG. 6 is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a second embodiment. -
FIGS. 7A to 7C are schematic cross-sectional views illustrating a manufacturing process of the main portion of the semiconductor device according to the second embodiment. -
FIGS. 8A and 8B are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the second embodiment. -
FIGS. 9A and 9B are schematic cross-sectional views illustrating a manufacturing process of a main portion of a semiconductor device according to a third embodiment. -
FIGS. 10A and 10B are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the third embodiment. -
FIGS. 11A to 11C are schematic cross-sectional views illustrating a manufacturing process of a main portion of a semiconductor device according to a fourth embodiment. -
FIGS. 12A to 12C are schematic cross-sectional views illustrating the manufacturing process of the main portion of the semiconductor device according to the fourth embodiment. - Embodiments provide a semiconductor device capable of reducing the electrical resistance between a gate electrode and a p-type nitride semiconductor layer and the manufacturing method thereof.
- In general, according to a first embodiment, a semiconductor device includes a first nitride semiconductor layer, a second nitride semiconductor layer on the first nitride semiconductor layer, a first electrode on the second nitride semiconductor layer, a second electrode on the second nitride semiconductor layer, a p-type third nitride semiconductor layer on the second nitride semiconductor layer, between the first electrode and the second electrode and in contact with the second nitride semiconductor layer, and a third electrode containing p-type polysilicon, on the third nitride semiconductor layer and in contact with the third nitride semiconductor layer.
- Hereinafter, preferred embodiments will be described with reference to the drawings. In the following description, the same reference numbers are attached to the same elements and features, and a repeated description as for the same materials is omitted where appropriate.
-
FIG. 1A is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a first embodiment.FIG. 1B is a schematic top plan view illustrating the main portion of the semiconductor device according to the first embodiment.FIG. 1A illustrates a cross section taken along the line A1-A2 ofFIG. 1B .FIG. 1B illustrates a cross section taken along the line B1-B2 ofFIG. 1A . - As a
semiconductor device 100 according to the first embodiment, a normally-off type High Electron Mobility Transistor (HEMT) is exemplified as one example. Thesemiconductor device 100 includes asubstrate 10, abuffer layer 31, a first nitride semiconductor layer (hereinafter, for example, carrier transport layer 33), a second nitride semiconductor layer (hereinafter, for example, barrier layer 34), a first electrode (hereinafter, for example, source electrode 50), a second electrode (hereinafter, for example, drain electrode 51), a third nitride semiconductor layer (hereinafter, for example, p-type GaN layer 35), and a third electrode (hereinafter, for example, gate electrode 52). - The
substrate 10 includes, for example, silicon (Si). Thebuffer layer 31 is provided on thesubstrate 10. Thebuffer layer 31 includes aluminum nitride. - The
carrier transport layer 33 is provided on thebuffer layer 31. Thebarrier layer 34 is provided on thecarrier transport layer 33. Thecarrier transport layer 33 includes undoped gallium nitride (GaN), or undoped gallium aluminum nitride (AlxGa1-xN (0≦X<1)). Thebarrier layer 34 includes undoped or n-type gallium aluminum nitride AlyGa1-yN (0<Y≦1, X<Y)). Two dimensional electron gas (2DEG) is generated in thecarrier transport layer 33 in the vicinity of the boundary of thecarrier transport layer 33 and thebarrier layer 34. - The
source electrode 50 is provided on thebarrier layer 34. Thesource electrode 50 includes, for example, abarrier 50 a containing titanium (Ti) and anelectrode 50 b containing aluminum (Al). Thesource electrode 50 is connected to thebarrier layer 34. Thesource electrode 50 forms an ohmic contact with thebarrier layer 34. Thesource electrode 50 extends, for example, in the X direction. - The
drain electrode 51 is provided on thebarrier layer 34 at a distance from thesource electrode 50. Thedrain electrode 51 includes, for example, abarrier 51 a containing titanium (Ti) and anelectrode 51 b containing aluminum (Al). Thedrain electrode 51 is connected to thebarrier layer 34. Thedrain electrode 51 forms an ohmic contact with thebarrier layer 34. Thedrain electrode 51 is provided alongside of thesource electrode 50 and spaced therefrom in the Y direction. Thedrain electrode 51 extends in the X direction generally parallel to thesource electrode 50. - A p-
type GaN layer 35 is provided on thebarrier layer 34. The p-type GaN layer 35 contains p-type gallium nitride (GaN). The dopant element contained in the p-type GaN layer 35 is, for example, magnesium (Mg) and zinc (Zn). The p-type GaN layer 35 is provided at a location between, and spaced from, thesource electrode 50 and thedrain electrode 51. The p-type GaN layer 35 is connected to thebarrier layer 34. The p-type GaN layer 35 likewise extends in the X direction. - By providing the p-
type GaN layer 35 on the undoped or n-type barrier layer 34, the potential under the p-type GaN layer 35 is raised and the Fermi level under the p-type GaN layer 35 is raised. Owing to this, under the p-type GaN layer 35, the 2DEG electron cloud moves to a side of the barrier layer 34-carrier layer 33 interface having a lower potential, in other words, in the direction away from the p-type GaN layer 35 and as a result thesemiconductor device 100 becomes a normally-off device. - The
gate electrode 52 is provided on the p-type GaN layer 35. Thegate electrode 52 forms an ohmic contact with the p-type GaN layer 35. Thegate electrode 52 contains p-type polysilicon. The p-type dopant element is, for example, boron (B). Thegate electrode 52 extends, for example, in the X direction. - Additionally, in the
semiconductor device 100, aprotective layer 60 is provided on thebarrier layer 34. An interlayer insulatinglayer 61 is provided on theprotective layer 60. Theprotective layer 60 contains, for example, silicon nitride (SiNx). The interlayer insulatinglayer 61 contains, for example, silicon oxide (SiOx). - The number of the
source electrodes 50, thedrain electrodes 51, the p-type GaN layers 35, and thegate electrodes 52 is not restricted to the illustrated number. -
FIGS. 2A to 4B are schematic cross-sectional views illustrating the manufacturing process of a main portion of the semiconductor device according to the first embodiment. - For example, as illustrated in
FIG. 2A , thebuffer layer 31 is formed on thesubstrate 10 such as by a metal-organic chemical vapor deposition (MOCVD) process, and thecarrier transport layer 33, thebarrier layer 34, and the p-type GaN layer 35 are epitaxially grown on thebuffer layer 31 in that order. Afirst layer 52L containing p-type polysilicon is formed on the whole surface of the p-type GaN layer 35. Thefirst layer 52L will form thegate electrode 52 after further processing. Thefirst layer 52L is formed, for example, by low-pressure Chemical Vapor Deposition (CVD) or Atomic Layer Deposition (ALD) of polysilicon. Further, thefirst layer 52L may be formed by ion implantation of boron into an undoped polysilicon layer and heating in the implanted layer in a nitrogen (N2) atmosphere. The heating temperature is 800° C. to 900° C. - The
carrier transport layer 33, thebarrier layer 34, the p-type GaN layer 35, and thegate electrode 52 are formed in astacked body 30. Amask layer 90 is formed on the gateelectrode material layer 52L. - Next, as illustrated in
FIG. 2B , the portion of thefirst layer 52L not covered by themask layer 90 and the p-type GaN layer 35 under thefirst layer 52L not covered by themask layer 90 are selectively removed by Reactive Ion Etching (RIE). As the etching gas, a mixed gas of, for example, a Cl based gas and an F based gas is used. Owing to this, the p-type GaN layer 35 and thegate electrode layer 52L containing the p-type polysilicon are selectively formed on thebarrier layer 34. Thereafter, themask layer 90 is removed. - Then, as illustrated in
FIG. 2C , the material to form theprotective layer 60 is formed on thebarrier layer 34 and thegate electrode 52. Further, amask layer 91 is formed on the layer of material used to form theprotective layer 60.Openings 91 h are provided on themask layer 91 at the respective positions of forming thesource electrode 50 and thedrain electrode 51. - The
protective layer 60 exposed by theopenings 91 h in themask layer 91 is removed by RIE, as shown inFIG. 3A . Then, themask layer 91 is removed. - As illustrated in
FIG. 3B , aconductive layer 55 containing titanium and aconductive layer 56 containing aluminum are formed in this order on thebarrier layer 34 and theprotective layer 60. Further, amask layer 92 is formed on theconductive layer 56. Themask layer 92 is formed, for example, at each position where asource electrode 50 and adrain electrode 51 are to be formed. - Then, as illustrated in
FIG. 3C , the exposed portions of theconductive layer 56 and theconductive layer 55 under theconductive layer 56 are removed by RIE. Owing to this, theconductive layer 56 is divided into theelectrode 50 b and theelectrode 51 b and theconductive layer 55 is divided into thebarrier 50 a and thebarrier 51 a. That is, thesource electrode 50 and thedrain electrode 51 are formed on thebarrier layer 34 to sandwich thegate electrode 52. Then, themask layer 92 is removed. - Next, as illustrated in
FIG. 4A , aninterlayer insulating layer 61 is formed on thesource electrode 50 and thedrain electrode 51. Further, amask layer 93 is formed on theinterlayer insulating layer 61. Themask layer 93 is provided withopenings 93 h respectively opening over thesource electrode 50, thedrain electrode 51, and thegate electrode 52. - As illustrated in
FIG. 4B , the exposed portions of the interlayer insulatinglayer 61 on both thesource electrode 50 and thedrain electrode 51 are removed by RIE. Further, the exposed portions of the interlayer insulatinglayer 61 and theprotective layer 60 on thegate electrode 52 are removed by RIE. Thereafter, themask layer 93 is removed. - Then, the interface between the
source electrode 50 and thebarrier layer 34 and the interface between thedrain electrode 51 and thebarrier layer 34 may be heated, to diffuse the metal inside thebarriers barrier layer 34 in contact with thesource electrode 50 and thedrain electrode 51. This heating processing is referred to as contact annealing in the embodiment. Owing to this, the contact resistance is reduced between thesource electrode 50 and thebarrier layer 34 and between thedrain electrode 51 and thebarrier layer 34. - In the
semiconductor device 100 according to the first embodiment, thegate electrode 52 containing p-type polysilicon is provided on the p-type GaN layer 35. Thisgate electrode 52 is in contact with the p-type GaN layer 35. The work function of the p-type polysilicon is 5.0 to 5.1 eV, and the work function of the p-type GaN is 4.5 to 7.0 eV. The work function of the p-type polysilicon is within the range of the work function of the p-type GaN. Work function is defined as the energy required to remove an electron from the highest filled level in the Fermi distribution of a solid so that it is stationary at a point in a field-free zone just outside the solid at absolute zero. Accordingly, thegate electrode 52 according to the first embodiment forms an ohmic contact with the p-type GaN layer 35. For example, the contact resistance between thegate electrode 52 and the p-type GaN layer 35 according to the first embodiment is 1×10−3 Ω·cm2 or less. - Here, assuming that the material of the
gate electrode 52 is an n-type polysilicon, the work function of n-type polysilicon is about 4.0. That is, the work function of the n-type polysilicon is smaller than the work function of the p-type GaN. Accordingly, when thegate electrode 52 is n-type polysilicon electrode, a potential barrier is generated between thegate electrode 52 and the p-type GaN layer 35. In other words, a resistance between thegate electrode 52 and the p-type GaN layer 35 does not form effective ohmic contact and the resistance between thegate electrode 52 and the p-type GaN layer 35 is high, as compared to thesemiconductor device 100. - Before describing another effect of the first embodiment, a manufacturing process of a semiconductor device according to a reference example will be described.
-
FIGS. 5A to 5C are schematic cross-sectional views illustrating the manufacturing process of a gate electrode according to the reference example. - In the reference example, as the material of the
gate electrode 52, one of the noble metals, platinum (Pt) is used. When using platinum (Pt), the work function of the platinum (Pt) is larger than that of the p-type GaN and thegate electrode 52 forms an ohmic contact with the p-type GaN layer 35. However, it is difficult to etch platinum, and thus in the reference example, thegate electrode 52 is formed by lift-off processing. - For example, as illustrated in
FIG. 5A , thebuffer layer 31 is formed on thesubstrate 10, and thecarrier transport layer 33, thebarrier layer 34, and the p-type GaN layer 35 are epitaxially grown on thebuffer layer 31 in this order. Further, amask layer 500 including a resist is formed on the p-type GaN layer 35. Themask layer 500 is provided with anopening 500 h on the p-type GaN layer 35 at a position where thegate electrode 52 is located. - Then, as illustrated in
FIG. 5B , aplatinum film 501 is formed on themask layer 500 and the p-type GaN layer 35. - As illustrated in
FIG. 5C , themask layer 500 is exposed to an organic solvent and ultrasonic energy is applied to themask layer 500, which causes themask layer 500 to dissolve and allows theplatinum film 501 overlying themask layer 500 to be removed. As a result, agate electrode 520 containing platinum (Pt) is formed on the p-type GaN layer 35. - In the method of patterning the
gate electrode 520 using the lift off process of the reference example, there is a possibility that theplatinum film 501 on the p-type GaN layer 35 may also be removed during the removal of themask layer 500. This phenomenon becomes more likely as the width of thegate electrode 520 gets narrower. Additionally, portions of theplatinum film 501 removed together with themask layer 500 may remain within the semiconductor device as contaminating particulates. - In contrast, in the first embodiment, the p-type polysilicon used as the material of the
gate electrode 52 is easily processed by RIE. Thegate electrode 52 is processed by photolithographically forming a patterned mask, followed by RIE, not the lift-off processing of the reference example. That is, precise and reliable processing of thegate electrode 52 is possible. - Here, assume that as the material of the
gate electrode 52, not a precious metal such as platinum but aluminum (Al) which is easily processed by RIE is used. In this case, however, the temperature of the contact annealing exceeds the melting point of the aluminum in some cases. Owing to this, the gate electrode itself melts and the shape of the gate electrode once solidified again may be different from the original shape before melting. In contrast, in the first embodiment, the p-type polysilicon is used as the material of thegate electrode 52 does not melt at the temperature of the heating processing. - Further, in the
semiconductor device 100, thegate electrode 52 is directly in contact with the p-type GaN layer 35. For example, when a dielectric layer is interposed between thegate electrode 52 and the p-type GaN layer 35, the potential of the threshold value of thegate electrode 52 gets higher adjacent to the potential barrier provided by the dielectric layer. On the contrary, in thesemiconductor device 100, thegate electrode 52 is directly in contact with the p-type GaN layer 35. Owing to this, the potential of the threshold value of thegate electrode 52 may be set as being low. For example, the potential of the threshold voltage of thesemiconductor device 100 is 1.0 to 2.0 V. - Further, the
gate electrode 52 is p-type polysilicon and therefore, even when performing the heat processing on theprotective layer 60, metal does not diffuse from thegate electrode 52 into theprotective layer 60. Further, by performing the heat processing on theprotective layer 60, theprotective layer 60 becomes denser. That is, according to the first embodiment, a highly insulativeprotective layer 60 may be obtained. -
FIG. 6 is a schematic cross-sectional view illustrating a main portion of a semiconductor device according to a second embodiment. - In a
semiconductor device 101, thegate electrode 52 containing the p-type polysilicon further contains metal in at least a portion thereof. The metal includes, for example, nickel (Ni) or titanium (Ti). The concentration of the metal at theupper end 52 u of the gate electrode is higher than that at thelower end 52 d thereof. By annealing (heat processing) the gate electrode structure including the p-type polysilicon with a metal layer thereover, a silicide of the metal,silicide layer 52 s, is formed at the upper side of thegate electrode 52. -
FIGS. 7A to 8B are schematic cross-sectional views illustrating the manufacturing process of a main portion of the semiconductor device according to the second embodiment. - For example, as illustrated in
FIG. 7A , the p-type GaN layer 35 and the material to form thepolysilicon gate electrode 52 are formed on thebarrier layer 34. - As illustrated in
FIG. 7B , theprotective layer 60 is formed on thebarrier layer 34. Theprotective layer 60 is provided with anopening 60 h which opens theupper end 52 u of thegate electrode 52. Theopening 60 h is formed by forming a mask layer, using photolithographic techniques to pattern the mask, and then performing RIE to form an opening in theprotective layer 60 down to theupper surface 52 u of thepolysilicon gate electrode 52. - As illustrated in
FIG. 7C , ametal film 70 is formed on theprotective layer 60 and theupper surface 52 u of thegate electrode 52 by the sputtering method. Themetal film 70 contains, for example, nickel (Ni) or titanium (Ti). - As illustrated in
FIG. 8A , thegate electrode 52 and themetal film 70 are heated and asilicide layer 52 s of the metal and the silicon of thegate 52 is formed on theupper side 52 u of thegate electrode 52. Thegate electrode 52 is heated so that the metal concentration therein may be higher in theupper end 52 u than in thelower end 52 d. The heating condition is, for example, at 350° C. for 30 seconds in the nitrogen (N2) atmosphere, such that metal does not diffuse fully through thepolysilicon gate 52 to reach theunderlying barrier layer 34. Then, themetal film 70 on theprotective layer 60 is removed using sulfuric or ammonia solution. Thereafter, the heating processing may be performed on thesilicide layer 52 s. The heating condition is, for example, at 500° C. for 30 seconds in the nitrogen (N2) atmosphere. - As illustrated in
FIG. 8B ,openings 60 h are formed on through theprotective layer 60 by PEP and RIE. Theopenings 60 h are formed at the respective positions of forming thesource electrode 50 anddrain electrode 51. - Then, as illustrated in
FIG. 6 , thesource electrode 50 and thedrain electrode 51 are formed on thebarrier layer 34. Further, theinterlayer insulating layer 61 is formed on theprotective layer 60. Further, the bottom of thesource electrode 50 and the bottom of thedrain electrode 51 are heated and the metal within thebarriers source electrode 50 and thebarrier layer 34 and between thedrain electrode 51 and thebarrier layer 34. Owing to this, a contact resistance between thesource electrode 50 and thebarrier layer 34 and between thedrain electrode 51 and thebarrier layer 34 is reduced. - When the carrier concentration of the p-type polysilicon layer is 1×1020 (atoms/cm3), the resistivity is about 1×103 (Ω·cm). In the second embodiment, the
silicide layer 52 s is formed on the upper side of thegate electrode 52. Owing to this, the resistivity of thegate electrode 52 is reduced to 10 to 20 μΩ·cm. - Further, the
silicide layer 52 s is automatically formed and therefore, there is no need for lithographic masking and RIE processes to form thesilicide layer 52 s. -
FIGS. 9A to 10B are schematic cross-sectional views illustrating a main portion of a semiconductor device according to a third embodiment. - For example, as illustrated in
FIG. 9A , the p-type GaN layer 35 is selectively formed on thebarrier layer 34, and thegate electrode 52 containing the p-type silicon is formed over the p-type GaN layer 35. Further, theprotective layer 60 is formed on thebarrier layer 34 and thegate electrode 52. Theprotective layer 60 is provided withopenings 60 h. Theopenings 60 h are formed at the respective positions of forming thesource electrode 50 and thedrain electrode 51. - As illustrated in
FIG. 9B , thesource electrode 50 and thedrain electrode 51 connected to thebarrier layer 34 are formed through theopenings 60 h. Further, theinterlayer insulating layer 61 is formed on theprotective layer 60, including the portion thereof over thegate electrode 52, thesource electrode 50, and thedrain electrode 51. - Then, as illustrated in
FIG. 10A , theinterlayer insulating layer 61 and theprotective layer 60 covering thegate electrode 52 are opened and ametal film 70 is formed on theinterlayer insulating layer 61 and thegate electrode 52. - As illustrated in
FIG. 10B , after thesource electrode 50, thedrain electrode 51, thebarrier layer 34, themetal film 70, and thegate electrode 52 are heated, metal is diffused from thesource electrode 50 into the surface of thebarrier layer 34 and from thedrain electrode 51 into the surface of thebarrier layer 34. That is, abarrier layer 34 a containing the metal is formed between thesource electrode 50 and thebarrier layer 34 and between thedrain electrode 51 and thebarrier layer 34, the upper side of thegate electrode 52 is formed into silicide, and thegate electrode 52 containing the metal is formed. - As mentioned above, in this third embodiment, the
source electrode 50 and thedrain electrode 51 are formed before forming thegate electrode 52 into silicide. Owing to this, the contact annealing processing and the annealing processing for forming thegate electrode 52 into silicide may be performed simultaneously. Accordingly, the number of the annealing processes is reduced and the cost may be reduced. -
FIGS. 11A to 12C are schematic cross-sectional views illustrating the manufacturing process of a main portion of a semiconductor device according to a fourth embodiment. - For example, as illustrated in
FIG. 11A , thecarrier transport layer 33, thebarrier layer 34, the p-type GaN layer 35, and the material to form thegate electrode 52 containing p-type polysilicon are formed on thesubstrate 10 over thebuffer layer 31. Further, ametal film 70 is formed on thegate electrode 52. - As illustrated in
FIG. 11B , thegate electrode 52 and themetal film 70 are heated and asilicide layer 52 s is resultantly formed by reaction therebetween as the upper side of thegate electrode 52. - As illustrated in
FIG. 11C , the portions of the material for forming thegate electrode 52 and the p-type GaN layer 35 therebelow which are not covered by themask layer 94 are removed by RIE, and thegate electrode 52 and the p-type GaN layer 35 are thus selectively formed on thebarrier layer 34. Then, themask layer 94 is removed. - As illustrated in
FIG. 12A , theprotective layer 60 is formed on thebarrier layer 34 and thegate electrode 52. Further, theprotective layer 61 is formed on theprotective layer 60. - Next, as illustrated in
FIG. 12B ,openings 61 h are formed on theprotective layers openings 61 h are formed at the respective positions of forming thesource electrode 50, thedrain electrode 51, and thegate electrode 52. - Thereafter, as illustrated in
FIG. 12C , the source electrode 50 (barrier 50 a andelectrode 50 b) and the drain electrode 51 (barrier 51 a andelectrode 51 b) connected to thebarrier layer 34 are formed, acontact electrode 53 and agate field plate 54 is formed on thegate electrode 52, and agate field plate 54 is formed on the contact electrode and over an adjacent portion of theprotective layer 61. Here, thebarriers contact electrode 53 contain the same material. Further, theelectrodes gate field plate 54 contain the same material. - According to the fourth embodiment, the
openings 61 h for forming thebarriers contact electrode 53 may be formed simultaneously. Thebarriers contact electrode 53 may be formed simultaneously. Further, theelectrodes gate field plate 54 may be formed simultaneously. - In the embodiment, “on” in the case of the expression of “A is provided on B” means the case where “A is in contact with B and upper than B” as well as the case where “A is not in contact with B but just upper than B”. Further, the expression of “A is provided on B” is also applied to the case where A is under B with A and B inverted and the case where A and B are aligned alongside. This is because even if rotating the semiconductor device according to the embodiment, the structure of a semiconductor device never changes before and after the rotation.
- As mentioned above, the embodiments have been described with reference to the concrete example. The embodiment is not restricted to the above example. In other words, modifications properly made by those skilled in the art are to be included in the scope of the embodiment as far as they have the characteristics of the embodiment. Each element contained in each concrete example as mentioned above and its position, material, condition, shape, and size are not restricted to the illustrated ones but may be properly changed.
- Further, each element contained in the above mentioned embodiment may be properly combined with each other as far as technically permitted and their combination is to be included in the scope of the embodiment as far as it has the characteristics of the embodiment. Other, within the spirit of the embodiment, various changes and modifications may be easily arrived at by those skilled in the art, and it should be noted that all such changes and modifications are within the scope of the embodiment.
- Further, in the specification, “nitride semiconductor” is intended to include all the semiconductors with the composition ratio of x, y, and z various within each range in the chemical formula BxInyAlzGa1-x-y-zN (0≦x≦1, 0≦y≦1, 0≦z≦1, x+y+z≦1). Further, in the above chemical formula, it should be noted that the compound further including the V group element other than N (nitrogen), the compound further including various doped elements in order to control various physical property such as conductivity, and the compound further including various elements not intended may be included in “nitride semiconductor”.
- While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
Claims (20)
1. A semiconductor device comprising:
a first nitride semiconductor layer;
a second nitride semiconductor layer on the first nitride semiconductor layer;
a first electrode on the second nitride semiconductor layer;
a second electrode on the second nitride semiconductor layer;
a p-type third nitride semiconductor layer on the second nitride semiconductor layer, at a location between the first electrode and the second electrode, and in contact with the second nitride semiconductor layer; and
a third electrode comprising p-type polysilicon on the third nitride semiconductor layer and in contact with the third nitride semiconductor layer.
2. The device according to claim 1 , wherein
the third electrode further comprises metal.
3. The device according to claim 2 , wherein
a concentration of the metal in an upper end of the third electrode is higher than a concentration of the metal in a lower end of the third electrode.
4. The device according to claim 3 , wherein the metal and at least a portion of the polysilicon of the third electrode form a metal silicide.
5. The device according to claim 3 , wherein the metal comprises at least one of nickel or titanium.
6. The device according to claim 1 , wherein the p-type third nitride semiconductor layer comprises gallium nitride.
7. The device according to claim 1 , further comprising an ohmic contact between the p-type polysilicon third electrode and the p-type third nitride semiconductor layer.
8. The device according to claim 1 , wherein the contact resistance between the p-type polysilicon third electrode and the p-type third nitride semiconductor layer is 1×10−3 Ω·cm2 or less.
9. A method of manufacturing a semiconductor device comprising:
providing a first nitride semiconductor layer;
forming a second nitride semiconductor layer on the first nitride semiconductor layer;
forming a p-type third nitride semiconductor layer on a portion of the second nitride semiconductor layer;
forming a first electrode and a second electrode on the second nitride semiconductor layer, such that the third semiconductor layer is between, and spaced from, the first electrode and the second electrode;
forming a third electrode, comprising p-type polysilicon, on the third nitride semiconductor layer;
forming a metal film on the third electrode; and
heating the first electrode, the second electrode, the second nitride semiconductor layer, the metal film, and the third electrode to form a metal containing nitride semiconductor layer between the first electrode and the second nitride semiconductor layer, between the second electrode and the second nitride semiconductor layer, and between the third electrode comprising the p-type polysilicon and the metal film formed on the third electrode.
10. The method according to claim 9 , further comprising:
heating the third electrode such that the concentration of the metal film formed on the third electrode is at a higher concentration in an upper end of the third electrode than in a lower end of the third electrode.
11. The method according to claim 9 , wherein the heating of the third electrode and the metal film formed on the third electrode is undertaken before forming the first and second electrodes on the second nitride semiconductor layer.
12. The method according to claim 9 , wherein a further heating of the third electrode metal film formed on the third electrode is undertaken after forming the first and second electrodes on the second nitride semiconductor layer.
13. The method according to claim 9 , wherein the heating of the first electrode, the second electrode, the second nitride semiconductor layer, the metal film, and the third electrode to form a metal containing nitride semiconductor layer between the first electrode and the second nitride semiconductor layer, between the second electrode and the second nitride semiconductor layer, and between the third electrode comprising the p-type polysilicon and the metal film formed on the third electrode, occur simultaneously.
14. The method according to claim 9 , wherein an ohmic contact is formed between the p-type polysilicon third electrode and the p-type third nitride semiconductor layer.
15. The method according to claim 9 , wherein the contact resistance between the p-type polysilicon third electrode and the p-type third nitride semiconductor layer is 1×10−3 Ω·cm2 or less.
16. The method according to claim 9 , wherein
the p-type third nitride semiconductor layer on a portion of the second nitride semiconductor layer and the third electrode, comprising p-type polysilicon, located on the third nitride semiconductor layer, are defined simultaneously using reactive ion etching.
17. A semiconductor device, comprising:
a substrate;
a buffer layer disposed on the substrate;
a carrier layer disposed on the buffer layer;
a barrier layer disposed on the carrier layer;
a first p-type layer disposed on a portion of the barrier layer; and
a second p-type layer of a different material than the than the first p-type layer disposed on the first p-type layer and forming an ohmic contact therewith.
18. The device of claim 17 , wherein the first p-type layer comprises gallium nitride and the second p-type layer comprises polysilicon.
19. The device of claim 18 , wherein the second p-type layer comprising polysilicon further comprises a metal non-uniformly distributed therein.
20. The device of claim 19 , wherein the concentration of the metal in the second p-type layer changes in the depth direction of the second p-type layer.
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Cited By (4)
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US20180212047A1 (en) * | 2017-01-24 | 2018-07-26 | Taiwan Semiconductor Manufacturing Co., Ltd. | Group iii-v device structure |
US20210320196A1 (en) * | 2020-04-13 | 2021-10-14 | Vanguard International Semiconductor Corporation | Semiconductor device and method for forming the same |
US20220189947A1 (en) * | 2020-12-14 | 2022-06-16 | Vanguard International Semiconductor Corporation | Semiconductor device and operation circuit |
EP4068388A1 (en) * | 2021-03-30 | 2022-10-05 | Samsung Electronics Co., Ltd. | Power semiconductor device and method of manufacturing the same |
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CN109545851A (en) * | 2018-10-22 | 2019-03-29 | 复旦大学 | Enhanced GaN base power device and preparation method thereof |
JP7300840B2 (en) * | 2019-02-04 | 2023-06-30 | ローム株式会社 | Manufacturing method of nitride semiconductor device |
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US20130069117A1 (en) * | 2011-09-21 | 2013-03-21 | Kabushiki Kaisha Toshiba | Nitride semiconductor device |
US20140097505A1 (en) * | 2012-03-26 | 2014-04-10 | Kabushiki Kaisha Toshiba | Semiconductor device having nitride layers |
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JP5564815B2 (en) * | 2009-03-31 | 2014-08-06 | サンケン電気株式会社 | Semiconductor device and manufacturing method of semiconductor device |
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2015
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US20130069117A1 (en) * | 2011-09-21 | 2013-03-21 | Kabushiki Kaisha Toshiba | Nitride semiconductor device |
US20140097505A1 (en) * | 2012-03-26 | 2014-04-10 | Kabushiki Kaisha Toshiba | Semiconductor device having nitride layers |
Cited By (8)
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US20180212047A1 (en) * | 2017-01-24 | 2018-07-26 | Taiwan Semiconductor Manufacturing Co., Ltd. | Group iii-v device structure |
US11114543B2 (en) * | 2017-01-24 | 2021-09-07 | Taiwan Semiconductor Manufacturing Co., Ltd. | Group III-V device structure |
US20210320196A1 (en) * | 2020-04-13 | 2021-10-14 | Vanguard International Semiconductor Corporation | Semiconductor device and method for forming the same |
US11527606B2 (en) * | 2020-04-13 | 2022-12-13 | Vanguard International Semiconductor Corporation | Semiconductor device and method for forming the same |
US20220189947A1 (en) * | 2020-12-14 | 2022-06-16 | Vanguard International Semiconductor Corporation | Semiconductor device and operation circuit |
US11569224B2 (en) * | 2020-12-14 | 2023-01-31 | Vanguard International Semiconductor Corporation | Semiconductor device and operation circuit |
EP4068388A1 (en) * | 2021-03-30 | 2022-10-05 | Samsung Electronics Co., Ltd. | Power semiconductor device and method of manufacturing the same |
US12218206B2 (en) | 2021-03-30 | 2025-02-04 | Samsung Electronics Co., Ltd. | Power semiconductor device and method of manufacturing the same |
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